• Title/Summary/Keyword: 금속유물

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Silicon thin films and solar cells by HWCVD (열선 화학 기상 증착법에 의한 실리콘 박막 및 태양전지 특성)

  • Kim Sang-Kyun;Lee Jeong Chul;Jeon Sang Won;Lim Chung Hyun;Ahn Sae Jin;Yun Jae Ho;Kim Seok Ki;Song Jinsoo;Park S-J;Yoon Kyung Hoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.205-208
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    • 2005
  • 최근 열선 화학 기상 증착법(HWCVD)은 낮은 온도에서 TFT용 Poly Si 중착을 할 수 있다는 점과 실리콘 박막을 빠른 속도로 증착할 수 있다는 점에서 각광을 받고 있다. 본 연구에서는 HWCVD를 이용하여 태양전지를 제조하고 그 특성을 평가하였다. 조건에 따른 실리콘 박막의 특성 변화를 알기 위해 corning glass 및 실리콘 wafer에 다양한 조건에서 단위 박막(intrinsic layer)을 증착하였고 이 결과를 바탕으로 p/i/n 구조의 태양전지를 제조하였다. Ta 열선 온도는 1700-2000도였고 가스 원료인 $SiH_4$와 수소의 비율을 조절하면서 그 영향을 관찰하였다. 태양전지의 경우 p충과 n충은 PECVD로 증착하였으며 단위박막 및 태양전지 i충 증착시 기판과 열선간의 거리는 7cm, 기판 온도는 $200^{\circ}C$$250^{\circ}C$로 고정하였고 작업압력은 30mTorr였다. 단위 박막 특성 평가를 위해 암/광 전도도, SEM, Raman Scattering, FT-IR등을 사용하였으며 태양전지 특성 평가를 위해 I-V 및 Spectral response를 측정하였다. 열선 온도가 증가함에 따라 증착속도 및 결정화 분율은 증가하였다. 특히 비정질에서 결정질로 전이되는 구간은 매우 좁았으며 여러 분석 방법에서 일치되는 결과를 보였다. $SiH_4$ 유량이 늘어날수록 비정질이 결정질로 바뀌는 열선 온도가 증가하였으며 기판 온도가 낮을 경우 또한 결정으로 바뀌는 열선 온도가 증가하였다. 태양전지의 경우 열선 온도가 증가함에 따라 $V_{oc}$ 및 W가 낮아졌으며 $J_{sc}$, 는 증가하는 경향을 보였으며 결정질 비율이 증가하는 것을 관찰할 수 있었다. 이러한 경향은 quantum efficiency 결과에서도 확인할 수 있었다.용을 반복하면서 석재 내부와 외부의 암석 및 결정에 균열과 미세열극 등이 생성되어 석재 자체의 구조적 안정성에 영향을 주고 있다. 따라서 감은사지 석탑은 지리적 환경 차이로 인해 일반적인 환경의 석조물들과는 다른 형태의 풍화양상을 보이고 있어서 풍화양상 및 풍화형태에 대한 정확한 연구와 이해를 바탕으로 보존대책이 마련되어야 한다.되었다. 이런 모든 시편들을 각 탈염방법에 따라 탈염처리한 후 XRD와 SEM-EDS으로 분석한 결과 인철광과 침철광은 어떠한 변화도 보이지 않았고, 다만 적금광으로 동정된 시편만이 잔존하지 않았다. 철기 제작별 $Cl^-$ 이온 추출량과 탈염효과에 대한 비교 실험은 이온 크로마토그래피 분석 결과와 마찬가지로 단조 철제유물이 주조 철제보다 $Cl^-$ 이온을 많이 가지고 있었으며, 탈염 처리 후에는 $Cl^-$ 이온은 전혀 발견되지 않았다. 이상의 결과 $K_2CO_3$와 Sodium 용액은 탈염처리에서 가장 적합한 탈염처리 용액으로 알수가 있었으며 특히 어떠한 탈염 용액으로 유물을 처리한다 해도 철제유물에 생성된 부식물은 제거되지 않는다는 것을 알게 되었다. 따라서 보존처리자는 유물 표면의 부식 상태만을 보고 처리하기 보다는 철기제작물로 고려하여 처리하는 것이 필요하다. 또한 금속에 부식을 야기시키는 $Cl^-$ 이온과 부식물을 완전하게 제거하여 탈염처리를 하는 것이 유물 부식을 최대한 지연시킬 수 있는 것이라 생각된다.TEX>$88\%$)였다.(P=0.063). 결론: 본 연구에서는 MTHFR C/T & T/T 유전자 다형성이 위암의 발생과 그 위치에 대해 관련이 있는 것으로 여겨지고, 흡연력, 음주력과는 관련이 없는 것으로 여겨진다.험이 커지는 경향을 보였으나, 나이 및 병기, 종양의 크기, MD-BED $Gy_{10}$ 등의 예후 인자를 보정한 다변

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A study on the production techniques and prototype of the mother-of-pearl chrysanthemum pattern box from the Goryeo Dynasty (고려 나전국화넝쿨무늬상자의 제작기법 고찰 및 원형 연구)

  • LEE Heeseung;LEE Minhye;KIM Sunghun;LEE Hyeonju
    • Korean Journal of Heritage: History & Science
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    • v.57 no.1
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    • pp.126-144
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    • 2024
  • The chrysanthemum vine pattern box from the Goryeo Dynasty expresses in great detail the representative features of Goryeo Dynasty lacquerware with mother-of-pearl, such as engraving patterns on the surface of fine mother-of-pearl, expressing vine stems using metal wires, and twisting metal wires to form the boundaries of each patterns. While the lacquerware with mother-of-pearl that remains today from the Goryeo Dynasty has the form of a sutra box and a box with lid, the chrysanthemum vine pattern box that is the subject of this study is in the shape of a box with a separate lid and body, making it difficult to estimate the purpose of production or the stored contents. In this study, we attempted to confirm the formative characteristics of the chrysanthemum vine pattern box in order to confirm its original form, and to investigate its structure and production technique through X-ray transmission. In addition, we attempted to identify the use and production purpose of the box by classifying and comparing the previously known lacquerware with mother-ofpearl from the Goryeo Dynasty by type. As a result of the investigation, fabric was confirmed the bottom of body and inner box through X-ray images. Through this, it was confirmed that the 'Mogsimjeopichilgi'(wooden core grabbing fabric technique) of wrapping the object with fabric was used. And through wood grain, it was possible to confirm the wooden board composition of the part presumed to be the restored part and the part presumed to have had existing Jangseog. In addition, it was confirmed that the joints were connected in a Majdaeim(part to part). Based on the survey results, a total of 14 pieces, including 9 Sutra boxes, 3 boxes, and 2 small boxes, that remain from the Goryeo Dynasty were classified by type and examined for similarity. Among them, there is a "Chrysanthemum Vine Pattern Sutra Box" from a private collection in Japan, a "Black Lacquered Chrysanthemum Arabesque Bun Sutra Box" from the Tokugawa Art Museum, a "Sutra Holder" from the British Museum, and a "Small Box with a Mother-of-Pearl Chrysanthemum Vine Pattern" from a private collection in Korea. The pattern composition of five points was most similar to the subject of this study. As a result of comparing the damage pattern, formative characteristics, and structural features of each part, it is presumed that the sutra holder in the British Museum was transformed into its current form from the original the chrysanthemum vine patterned box. Lastly, in order to confirm the purpose of production, that is, the use of this box, we investigated examples of Tripitaka Koreana printed version produced at a time similar to the social atmosphere of Goryeo at the time. Following the Mongol(元) invasion after the Goryeo military regime at the time, sutras appeared to pray for the stability of the nation and the soul of an individual, and with the development of domestic printing and paper in the 13th century, it gradually coincided with the transition from a scroll to a folded form, and the form of a box changed from a box. It is believed that the storage method also changed.

Technical Trends in the Patents and Papers for the Recycling of Organic Residues from Waste Printed Circuit Boards (특허(特許)와 논문(論文)으로 본 폐(廢)PCB 유기계(有機界) 잔유물(殘留物) 재활용(再活用) 기술(技術) 동향(動向))

  • Lee, Dai-Soo;Shin, Sera;Cho, Young-Ju;Cho, Bong-Gyoo
    • Resources Recycling
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    • v.22 no.2
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    • pp.71-77
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    • 2013
  • Electronic products such as appliances, computers, and cellular phones have printed circuit boards (PCBs) in common and the PCBs in the waste electronic products contain valuable metals and organic resins. In Korea, recovery and recycling of the organic resins as well as the valuable metallics from the wastes are required indeed as the most of resources are being imported from abroad. In this article, the patents and papers for the recycling of organic residues from the waste PCBs were collected and analyzed. The open patents of USA (US), European Union (EP), Japan (JP), and Korea (KR) and SCI journals from 1979 to 2012 were investigated. The patents and journals were collected using key-words and filtered by the definition of the technology. The patents and journals were analyzed by the years, countries, companies, and technologies and the technical trends were discussed in this paper. It is showed sluggish relatively activity of published papers and patent applications for polymer manufacturing technology in local and abroad.

Conservation of metal artifacts excavated from tumulus in Chodang-dong, Kangreung City (강릉시 초당동 고분 출토 금속유물 보존)

  • Yu, Jae-Eun
    • 보존과학연구
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    • s.21
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    • pp.77-99
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    • 2000
  • Tumuli located in Chodang-dong in Kangreung City are sitesexcavated by the Museum of Kangreung University in 1993.Ofthese sites, a gilt bronze crown and gilt bronze sword with ring pommel with a tri-leaf ornament were excavated from the B-16tumulus. Underneath the gilt bronze crown was the gilt bronzes word with ring pommel with tri-leaf ornament, and these artifacts were treated with Polyurethane foams on the spot followed by special measures for conservation. This manuscript describes measures for conservation andanalysis with regard to the gilt bronze crown, gilt bronze sword with ring pommel with tri-leaf ornament and gilt bronze beltornaments. Bronze on the gilt bronze crown was completely corroded, therefore it was consolidated together with soil in the back of the artifact with Paraloid B72 after cleaning. Polyurethanefoams bottom was finished by applying the mixture of Epoxy resinAW106 and HV935K with soil. On the sword with ring pommel, the wooden part of the hilt was coated with Paraloid B72 (in Xylene) and the blade was consolidated with Paraloid NAD-10 30% after desalting with Sodium sesquicarbonate method. The gilt bronzebelt ornaments were treated with 3% Benzotriazole, coated with Paraloid B72 and then joined by using Cyanlacrylate. Specimens for the gilt bronze crown and gilt bronze belt ornaments were produced and gilding layers were examined under a metallographic microscope. The gilt bronze crown and the gilt bronze belt ornament maintained relatively good gilding quality with uniform gilding layers. Analysis of wood for the sheath of the sword with ring pommel revealed it to be Juglans mandshurica. Further more, analysis of constituents for a blue colored grassbead from dissolution of Polyurethane foams found it to be from the $Na_2O$-CaO-$AI_2O_3$-$SiO_2$ family.

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Some case histories to detect underwater buried objects by electrical and magnetic methods (수중 매장물 조사에 응용되는 전기 및 자기 탐사사례)

  • JUNG Hyun Key;Park Yeong-Sue;Lim Mutaek;Rim Hyoungrae
    • 한국지구물리탐사학회:학술대회논문집
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    • 2004.08a
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    • pp.118-137
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    • 2004
  • Recently underwater geophysical problems for historical relics or UXO's are raised frequently. This study includes the applicabilities and limitations of the recent underwater metal detector and domestic case stories for underwater survey by electrical and magnetic method. Direct or indirect case stories are electrical and vertical magnetic gradiometry surveys beneath Han-river bottom for planning subway tunnel, electrical exploration on lake-bottom, electrical exploration on the tidal flats using high-power transmitter, and borehole three-component magnetic and electromagnetic surveys for detecting the undersea objects. A design of potable real-time, high-speed measurement system using multi-channel array sensors is also introduced here. Further study will be focussed on practical field applications of the fast water-bottom scanning system which is lately required by actual field.

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Issues in Ancient Metal Wire Inlay: A Case Study of Relics from Baekje (고대 금속 선상감 기법의 쟁점과 그 해석 - 백제 선상감 자료를 중심으로 -)

  • Choi, Gieun
    • Conservation Science in Museum
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    • v.20
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    • pp.13-30
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    • 2018
  • Ancient metal objects with inlaid designs were mainly decorated using the wire inlay technique in which "V"- or "U"-shaped grooves were cut in a metal object and then filled with gold or silver. Previous studies on ancient metal objects featuring wire inlay generally attempted to ascertain the inlay techniques applied by examining photomicroscopes acquired during conservation treatment. However, they had limitations when examining wire inlay technique to the minute details. Wire inlay technique can be better investigated by enlarging X-ray films of relics using stereoscopic microscopy under transmitted light. The core processes of the wire inlay technique involve cutting grooves using a chisel and creating the inlay wires, but researchers hold varying opinions about the two processes. This study analyzed the entirety of the materials able to shed light on the main processes applied in Baekje wire inlay by examining X-ray films of relics through stereoscopic microscopy. This exhaustive research revealed that two types of techniques were used for wire inlay during the Baekje period. One is a plastic process of engraving dotted lines using a chisel and is found mostly in objects from the Cheonan and Gongju areas. The other is a cutting process that incises fine lines and was used mostly in relics from the Osan, Seosan, and Wanju areas. It is likely that the Baekje wire inlay techniques feature regional differences because the respective techniques were used or introduced by different groups of people.

Properties of AlSi etching using the MERIE type reactor (MERIE형 반응로를 이용한 AlSi의 식각 특성)

  • 김창일;김태형;장의구
    • Electrical & Electronic Materials
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    • v.9 no.2
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    • pp.188-195
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    • 1996
  • The AlSi etching process using the MERIE type reactor carried out with different process parameters such as C1$_{2}$ and N$_{2}$ gas flow rate, RF power and chamber pressure. The etching characteristics were evaluated in terms of etch rate, selectivity, uniformity and etched profile. As the N2 gas flow rate is increased, the AlSi etch rate is decreased and uniformity has remained constant within .+-.5%. The etch rate is increased and uniformity is decreased, according to increment of the C1$_{2}$ gas flow rate, RF power and chamber pressure. Selective etching of TEOS with respect to AlSi is decreased as the RF power is increased while it is increased by increment of the C1$_{2}$ gas flow rate and chamber pressure, on the other hand, selective etching of photoresist with respect to AlSi is increased by increment of the C1$_{2}$ gas flow rate and chamber pressure, it is decreased as the N$_{2}$ gas flow rate is increased.

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An Illustration of ‘茶’(tea) Inscription in Epigraphs’ (금석문(金石文)에 나타난 ‘차(茶)’ 자소고(字小考))

  • Lee, Hung-Suk
    • Journal of the Korean Society of Food Culture
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    • v.3 no.1
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    • pp.7-16
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    • 1988
  • An epigraph is an inscription mainly on a metal or stone monument, but some cases on bones or tortoise carapaces, ceramics, and coins. The '茶' inscriptions in 251 epigraphs in Korea are on 16 monuments, one tile, and one ceramic. By kingdom 5 belongs to shilla and 13 to Korea. The first '茶' inscription in on the Changsung-Tap of Borimsa Temple in Changhung-Kun, Chullanam-Do, which was established in 884 A.D. Religiously most of them are related to Buddism. Tea was most valued among valuables like gold, perlume, beads, etc. and so bestowed by kings. The study of epigraphs shows that our tea culture had most prospered diring the Kingdoms of Shilla and Korea.

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Conservation of the Iron Vessel (철제용기의 보존처리)

  • Park, Haksoo;Choi, Heeyoon;Kim, Woohyun;Kwon, Hyuknam
    • Conservation Science in Museum
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    • v.5
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    • pp.17-22
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    • 2004
  • The metal vessel which was excavated during the Japanese rule and separated into many pieces was conserved. The relic was stabilized through conservation treatment, and its original shape was restored. After the conservation treatment, it was discovered that the metal vessel has the bottom part and a catch near the mouth and was made in a streamline shape which becomes narrower inward. Radiographic examination test revealed many pores which were produced during the process of casting. It was found through the analysis of the metal structure that the material used was hypereutectic white cast iron with primary graphites.

Metallugical Study on the Iron Artifaets Ecavated from Buso Sangong (부소산성 출토 고대 철기유물에 대한 금속학적 연구)

  • Im, Seon-Gi;Gang, Dae-Il;Mun, Hwan-Seok;Park, Dong-Gyu;Gang, Seong-Gun
    • 보존과학연구
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    • s.13
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    • pp.37-58
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    • 1992
  • Iron artifacts from Busǒ Sansǒng inffered to late Baikjae periodwere studied on the aspects of metallugy. These materials were the largest size ever since excavated. From the analytical results these artifacts were found to be pureiron system without impurities or hypo-eutectoid steel system in below 0.3% in carbon contents. From the content of phosphorus in the range of 0.03∼0.05% as aim purity it was shown that charcoal were used for making these iron artifacts from sponge iron not fusion method. By observing metallugical structure it was found that iron artifacts was manufactured by repetitive folding and hammering forging method and some by heating method for adding carbon with cool water. This method were to improve the quality of the soften steel to harden one. In addition to those above repetitive hammering method eliminated the nonferrous materials such as slag inclusion and remained relatively pure ferrite.

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