• Korean Chemical Engineering Research
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• v.60 no.2
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• pp.300-307
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• 2022

Time-resolved serial femtosecond crystallography (TR-SFX) is a powerful technique for determining temporal variations in the structural properties of biomacromolecules on ultra-short time scales without causing structure damage by employing femtosecond X-ray laser pulses generated by an X-ray free electron laser (XFEL). The mixing rate of reactants and biomolecule samples, as well as the hit rate between crystal samples and x-ray pulses, are critical factors determining TR-SFX performance, such as accurate image acquisition and efficient sample consumption. We here develop two distinct sample delivery systems that enable ultra-fast mixing and on-demand droplet injecting via pneumatic application with a square pulse signal. The first strategy relies on inertial mixing, which is caused by the high-speed collision and subsequent coalescence of droplets ejected through a double nozzle, while the second relies on on-demand pneumatic jetting embedded with a 3D-printed micromixer. First, the colliding behaviors of the droplets ejected through the double nozzle, as well as the inertial mixing within the coalesced droplets, are investigated experimentally and numerically. The mixing performance of the pneumatic jetting system with an integrated micromixer is then evaluated by using similar approaches. The sample delivery system devised in this work is very valuable for three-dimensional biomolecular structure analysis, which is critical for elucidating the mechanisms by which certain proteins cause disease, as well as searching for antibody drugs and new drug candidates.

• Journal of the Korean GEO-environmental Society
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• v.13 no.12
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• pp.5-16
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• 2012

The second scientific antarctic station of South Korea is under construction at Terra Nova Bay located in eastern Antarctica. Ground condition in the Antarctica is frozen in general, but there are seasonal frozen grounds with active layers sporadically. When the active layer is frozen, frost heaving occurs that might cause the differential movement of frozen ground and the failure of structures. Therefore, it is necessary to determine the frost heaving susceptibility of soils at Terra Nova Bay before starting antarctic station construction. This study presents experimental investigation of the frost heaving susceptibility of soil samples with variation of particle sizes and unfrozen water contents. The soil samples were taken from five different locations at Terra Nova Bay and physical properties, unfrozen water content, and frost heaving tests were performed. For the frost heaving tests, soil specimens were frozen with constant freezing temperatures at the top and with drainage at the bottom in order to stimulate the frost heaving. The frost heaving tests provide volume expansion, volumetric strain, and heaving rate which can be used to analyze the relationship between the frost heaving vs. particle size and the frost heaving vs. unfrozen water content. Experimental results show that the more the fine contents exist in soils, the more frost heaving occurs. In addition, the frost heaving depends on unfrozen water content. Experimental data can be used to evaluate the frost heaving susceptibility of soils at the future construction site in the Antarctica.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.38 no.8
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• pp.677-685
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• 2014

A direct carbon fuel cell (DCFC) generates electricity directly by converting the chemical energy in coal. In particular, a DCFC system with a solid oxide electrolyte and molten carbonate anode media has been proposed by SRI. In this system, however, there are conflicting effects of temperature, which enhances the ion conductivity of the solid electrolyte and reactivity at the electrodes while causing a stability problem for the anode media. In this study, the effect of temperature on the stability of a carbon-carbonate mixture was investigated experimentally. TGA analysis was conducted under either nitrogen or carbon dioxide ambient for $Li_2CO_3$, $K_2CO_3$, and their mixtures with carbon black. The composition of the exit gas was also monitored during temperature elevation. A simplified reaction model was suggested by considering the decomposition of carbonates and the catalyzed Boudouard reactions. The suggested model could well explain both the measured weight loss of the mixture and the gas formation from it.

• Journal of Korea Water Resources Association
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• v.41 no.4
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• pp.379-394
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• 2008

Recently, extreme precipitation events beyond design capacity of hydraulic system have been occurred and this is the causes of failure of hydraulic structure for flood prevention and of severe flood damage. Therefore it is very important to understand temporal and spatial characteristics of extreme precipitation events as well as expected changes in extreme precipitation events and distributional characteristics during design period under future climate change. In this paper, climate change scenarios were used to assess the impacts of future climate change on extreme precipitation. Furthermore, analysis of future extreme precipitation characteristics and I-D-F analysis were carried out. This study used SRES B2 greenhouse gas scenario and YONU CGCM to simulate climatic conditions from 2031 to 2050 and statistical downscaling method was applied to establish weather data from each of observation sites operated by the Korean Meteorological Administration. Then quantile mapping of bias correction methods was carried out by comparing the simulated data with observations for bias correction. In addition Modified Bartlett Lewis Rectangular Pulse(MBLRP) model (Onof and Wheater, 1993; Onof 2000) and adjust method were applied to transform daily precipitation time series data into hourly time series data. Finally, rainfall intensity, duration, and frequency were calculated to draw I-D-F curve. Although there are 66 observation sites in Korea, we consider here the results from only Seoul, Daegu, Jeonju, and Gwangju sites in this paper. From the results we found that the rainfall intensity will be increased and the bigger intensity will be occurred for longer rainfall duration when we compare the climate conditions of 2030s with present conditions.

• Journal of the Institute of Electronics and Information Engineers
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• v.50 no.8
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• pp.83-93
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• 2013

By comparing Wiener's MMSE on stochastic signal transmission with Shannon's mutual information first proved by C.E. Shannon in terms of information theory, connections between two approaches were investigated. What Wiener wanted to see in signal transmission in noisy channel is to try to capture fundamental limits for signal quality in signal estimation. On the other hands, Shannon was interested in finding fundamental limits of signal quantity that maximize the uncertainty in mutual information using the entropy concept in noisy channel. First concern of this paper is to show that in deriving limits of Shannon's point to point fundamental channel capacity, Shannon's mutual information obtained by exploiting MMSE combiner and Wiener filter's MMSE are interelated by integro-differential equantion. Then, At the meeting point of Wiener's MMSE and Shannon's mutual information the upper bound of spectral efficiency and the lower bound of energy efficiency were computed. Choosing a proper lattice-type code of a mod-${\Lambda}$AWGN channel model and MMSE estimation of ${\alpha}$ confirmed to lead to the fundamental Shannon capacity limits.

• Journal of the Korean School Mathematics Society
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• v.24 no.2
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• pp.173-190
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• 2021

This study analyzed the proof of the inverse square law, which is said to be the core of Newton's , in relation to the geometric limit. Newton, conscious of the debate over infinitely small, solved the dynamics problem with the traditional Euclid geometry. Newton reduced mechanics to a problem of geometry by expressing force, time, and the degree of inertia orbital deviation as a geometric line segment. Newton was able to take Euclid's geometry to a new level encompassing dynamics, especially by introducing geometric limits such as parabolic approximation, polygon approximation, and the limit of the ratio of the line segments. Based on this analysis, we proposed to use Newton's geometric limit as a tool to show the usefulness of mathematics, and to use it as a means to break the conventional notion that the area of the curve can only be obtained using the definite integral. In addition, to help the desirable use of geometric limits in school mathematics, we suggested the following efforts are required. It is necessary to emphasize the expansion of equivalence in the micro-world, use some questions that lead to use as heuristics, and help to recognize that the approach of ratio is useful for grasping the equivalence of line segments in the micro-world.

• Clean Technology
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• v.27 no.1
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• pp.85-92
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• 2021

A solar water battery is a system that generates power using solar energy. It is a combination of photoelectrochemical cells and an energy storage system. It can simultaneously convert and store solar energy without additional external voltage. Solar water batteries consist of photoelectrodes, storage electrodes and counter electrodes, and their properties and combination are important for the performance and the efficiency of the system. In this study, we tried to find the effect that changing the components of solar water batteries has on its system. The effects of the counter electrode during discharge, the kinds of photoelectrode and storage electrode materials, and electrolytes on the solar energy conversion and storage capacitance were studied. The optimized composition (TiO2 : NaFe-PB : Pt foil) exhibited 72.393 mAh g-1 of discharge capacity after 15 h of photocharging. It indicates that the efficiency of solar energy conversion and storage is largely affected by the configuration of the system. Also, the addition of organic pollutants to the chamber of the photoelectrode improved the battery's photo-current and discharge capacity by efficient photoelectron-hole pair separation with simultaneous degradation of organic pollutants. Solar water batteries are a new eco-friendly solar energy conversion and storage system that does not require additional external voltages. It is also expected to be used for water treatment that utilizes solar energy.

• School Mathematics
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• v.19 no.1
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• pp.95-116
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• 2017

Through the teaching experiments, we investigated a series of processes for obtaining the differential coefficient at x=0 of the exponential function $y=2^x$ based on the process of constructing the natural constant e and the understanding of it. and all of the students who participated in this study were students who had no experience of calculating the derivative of the exponential function. The purpose of this study was not to generalize the responses of students but to suggest implications for mathematical concept mapping related to calculus by analyzing various responses of students participating in experiments. It is expected that the accumulation of research data derived in this kind of research on the way of understanding and composition of learners will be an important basic data for presenting the learning model related to calculus.

• Korean Journal of Soil Science and Fertilizer
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• v.24 no.4
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• pp.302-305
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• 1991

Six low-molecular-weight organic acids from decomposing plant residues were analyzed, which were formic, acetic, succinic, malic, tartaric, and citric acids. Straws of rice, barley, wheat, and rye were put under acid- hydrolysis after decomposition for different periods of time. The contents of organic acids in the hydrolysates were determined. 1. The relative molarity of a low-molecular-weight organic acid varies with the passage of the time of decomposition. 2. In general, formic and acetic acids were the major low-molecular-weight organic acids in all samples. 3. Malic acid was found to be only in a trace amount in rice and barley straws, and in their decomposed residues. 4. The relative molarities of total monocarboxylic acids(formic and acetic) increased with the progressing time of decomposition, far exceeding those of dicarboxylic and tricarboxylic acids combined together. 5. Formic and acetic acids were compensatory for each other and they were supposed to persist for a long time in soil environment.

• Korean Journal of Food Science and Technology
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• v.36 no.3
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• pp.416-422
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• 2004

Efficacy of surface sterilization and physicochemical properties of electrolyzed water manufactured depending on electrolyte, materials, and type of electrolytic diaphragm used were investigated. Physical properties of electrolyzed water manufactured from diaphragm system showed the highest effectiveness under at distance between diaphragms of 1.0 mm and 20% NaCl supplying rate of 6 mL/min. ORP, HClO (should defined) content, and pH at above conditions were 1,170 mV, 100 ppm, and 2.5, respectively. Two-stage electrolyzed system was more effective than one-stage one. Electrolyzed water manufactured from non-diaphragm system at 4 mL/min supplying rate of 20% NaCl was similar to the most effective diaphragm system, whereas ORP, HClO content, and pH were 800 mV, 200 ppm, and 9, respectively. Sealed electrolyzed water could be preserved more than one month at room temperature with ORPs of 750 and 1,150 mV in non-diaphragm and diaphragm systems, respectively, and at HClO content of 100 ppm. Physicochemical properties of electrolyzed water manufactured from electrolytic diaphragm of $IrO_{2}$ and Pt+Ir were more effective than that of Pt. ORP and HClO contents of electrolyzed water manufactured from various electrolytes were high in order of NaCl>KCl>$CaCl_{2}$, whereas no differences were observed among electrolytes in sterilization efficacy. Twelve kinds of microorganisms tested (initial total count, $10^{5}-10^{6}CFU/mL$) were sterilized within 1-2 min by electrolyzed water.