• Journal of Radiation Industry
• /
• v.8 no.1
• /
• pp.49-52
• /
• 2014

Kenaf fibers have excellent properties and possess the potential to be outstanding reinforcing fillers in cement. The grafting of poly(ethylene glycol) methacrylate (PEGMA) to the kenaf fibers is important in improving the compatibility between the fibers and the cement. PEGMA was grafted onto kenaf fibers using gamma-ray radiation. The radiation dose ranged from 20 to 60 kGy, and the dose rate was $10kGy\;h^{-1}$. The degree of grafting increased with increased radiation doses. FT-IR analysis revealed an increase in PEGMA content after gamma-ray radiation induced grafting, further evincing the attachment of PEGMA to the kenaf fibers. The mechanical properties of the gamma-ray grafted kenaf fiber/cement composites were superior to those of the ungrafted kenaf fiber/cement specimens.

• Journal of the Korea Institute of Military Science and Technology
• /
• v.22 no.1
• /
• pp.35-41
• /
• 2019

Ferrocene and ferrocene derivatives have been widely used as a burning rate catalyst for composite solid propellants. However, its tendency to migrate through the propellant grain and to crystallize at the surface changes the composition of propellant which results in unpredictable burning rate. To overcome the weakness of ferrocene catalyst, we designed a polymer containing ferrocene, poly(glycidyl azide-co-glycidyl ferrocenyl ether) (GAFP). GAFPs were synthesized from poly(epichlorohydrin-co-glycidyl ferrocenyl ether) (PEGF) which has ferrocenyl ethers in its pendant groups. The structures of GAFPs were confirmed by FT-IR, $^1H$ and $^{13}C$ NMR spectral analyses. Thermal properties of the GAFPs were evaluated using differential scanning calorimeter (DSC). As the contents of ferrocene increased, the glass transition temperature ($T_g$) of the GAFPs shifted to a higher temperature, and the decomposition temperature ($T_d$) decreased because the ferrocene worked as a burning rate catalyst.

• Journal of the Korean Society for Precision Engineering
• /
• v.5 no.4
• /
• pp.24-31
• /
• 1988

The Upper Bound Solution has been used to investigate the effect of the various parameters on the floating-plug tube-drawing precess. A kinematically admissible velocity field considering the change of the tube thickness is proposed for the deformation process. Taking into account the position of the plug in the deforming region, shear energy at entrance and exit, friction energy on contact area, homogeneous energy are calculated. The theoretical values in proposed velocity field are good agreement with experimental values, It is investigated that the tube thickness in the deforming region is changed slightly toward minimization of deforming energy and then the drawing stress in lower than the crawing stress in the velocity field that the tube thickness is uniform.

• Journal of KIISE:Software and Applications
• /
• v.30 no.1_2
• /
• pp.73-80
• /
• 2003

The Java programming language is designed for developing effective applications in a heterogeneous network environment. Major problem in Java is its performance. many attractive features of Java make the development of software easy, but also make it expensive to support ; applications written in Java are often much slower than their counterparts written in C or C++. To use Java`s attractive features without the performance penalty, sophisticated optimizations and runtime systems are required. Optimising Java bytecode has several advantages. First, the bytecode is independent of any compiler that is used to generate it. Second, the bytecode optimization can be performed as a pre=pass to Just-In-Time(JIT) compilation. Many attractive features of Java make the development of software easy, but also make it expensive to support. The goal of this work is to develop automatic construction of code optimizer for Java bytecode. We`ve designed and implemented a Bytecode Optimizer that performs the peephole optimization, bytecode-specific optimization, and method-inlining techniques. Using the Classfile optimizer, we see up to 9% improvement in speed and about 20% size reduction in Java class files, when compared to average code using the interpreter alone.

• Polymer(Korea)
• /
• v.39 no.1
• /
• pp.136-143
• /
• 2015

Poly(vinyl alcohol) (PVA) was grafted onto the multiwalled carbon nanotube (MWCNT) using ultrasound in water and modified MWCNT/PVA nanocomposite was prepared. Modified MWCNT had a good affinity with PVA matrix and showed improved dispersion state along with uniform properties. Therefore, the electrical percolation threshold was observed at 0.1 wt% MWCNT. 3.0 wt% modified MWCNT/PVA composite had 50% higher tensile strength, 430% higher elongation at break, and 100% greater modulus. Since the modified MWCNT acted as a nucleation agent, the crystallization temperature increased to $8.5^{\circ}C$ and the crystallinity increased to 11.5% at 5.0 wt% loading concentration.

• Polymer(Korea)
• /
• v.38 no.3
• /
• pp.378-385
• /
• 2014

Multiwall carbon nanotubes (MWCNTs) were modified with a water soluble polymer, poly(vinyl alcohol), PVA, using a simple ultrasonic wave in water. Under the irradiation of ultrasound, PVA chains were severed as macroradicals and instantly grafted onto the surface of MWCNTs due to the radical scavenging effect of MWCNTs. To control the grafting PVA onto MWCNTs, the ultrasonication power and irradiation time were changed from 300 to 500 W and from 10 to 50 min, respectively. The grafted PVA onto MWCNTs was confirmed by FTIR, TGA, SEM, and TEM. Dispersion stability of the modified MWCNTs was monitored by Turbiscan. The amount of grafted PVA on MWCNTs increased with the increase in the sonication power and irradiation time. The grafted PVA on MWCNTs induced the improved dispersion stability of the modified MWCNTs in water. These findings exhibit that ultrasound can be readily used for the grafting polymer chains on MWCNTs.

• Journal of Adhesion and Interface
• /
• v.10 no.1
• /
• pp.23-29
• /
• 2009

We investigated effects of a compatibilizer on the rheological properties during mixing and thermal properties of polypropylene (PP)-natural fiber composites. Two types of natural fibers (cotton fiber and wood fiber) were compared. maleic anhydride grafted PP was used for a compatibilizer. On increasing the amounts of the compatibilizer, the torque values of composites were increased, regardless of the kind of fibers. X-ray diffraction (XRD) and differential scanning calorimetry (DSC) results showed a slight increase in the degree of crystallinity with adding the compaibilizing agent, while the effects of the kind of fibers were marginal. It may be considered, however, the cotton fiber exhibits better interaction with PP-g-MAH than the natural fiber based on the rheographs, DSC, and XRD results.

• Polymer(Korea)
• /
• v.34 no.5
• /
• pp.464-468
• /
• 2010

In this study, a vinylbenzyl chloride (VBC) monomer was successfully grafted onto the several fluoropolymer films including poly(tetrafluoroethylene-co-hexafluoropropylene) (FEP), poly(tetrafluoroethylene-co-perfluoropropylvinyl ether) (PFA), and poly(ethylene-co-tetrafluoroethylene) (ETFE) films by using a simultaneous irradiation method. The results indicated that PVBC graft polymer can be easily grafted onto the ETFE film than other fluorinated films under the same irradiation condition. The grafted films were characterized by using FTIR, TGA, and SEM-EDS instruments. The elongation at the breaking of the grafted films was found to decrease with an increase of degree of grafting (DOG). The PVBC-grafted ETFE films were found to have better mechanical properties than other PVBC-grafted fluorinated films.

• Journal of the Korean Applied Science and Technology
• /
• v.25 no.4
• /
• pp.459-468
• /
• 2008

Methyl methacrylate(MMA) was grafted onto microcrystalline cellulose(MCC) with ceric ammonium nitrate(CAN) as a redox initiator at the various conditions. The cellulose triacetate(CTA) composite films added MCC and MMA-grafted MCC powders were prepared on a glass plate. The graft yield(GY) and graft efficiency(GE) of the grafted MCC were calculated with the simple equations by the weight balance method. The double bond of C=O on the grafted MCC surfaces was confirmed by the fourier transform infrared spectroscopy with attenuated total reflection(FT-IT ATR) spectrophotometer. After grafting, the degree of crystallinity of cellulose powders was decresed by judging from x-ray diffraction(XRD) data. Scanning electron microscope(SEM) photos showed the only solvent and CAN solution could change the roughness of MCC powders and the effect of powder dispersions in composite matrix. The tensile strength of MCC/CTA composite films was decreased with increase of MCC powder contents. When 5% grafted MCC was added, the tensile strength of grafted MCC/CTA composite films was increased from 82.3 MPa to 97.2 MPa. The thermal property of powders was also analyzed by the thermogravimetric analysis(TGA).

• Polymer(Korea)
• /
• v.33 no.3
• /
• pp.268-271
• /
• 2009

In this study, the distribution behaviors of the polystyrene sulfonic acid (PSSA) grafting polymer across the FEP-g-PSSA membranes prepared by a simultaneous irradiation method, were investigated by analyzing the cross-section of the membranes with a SEM-EDX instrument. The effects of irradiation conditions such as the degree of grafting, FEP film thickness, and grafting solvent on the distribution of the grafting polymer were mainly studied in this experiment. The results indicate that to obtain the evenly grafted FEP-g-PSSA membranes, the higher degree of grafting is required as the film thickness increases, and the lower dose rate are more effective than the higher dose rate at the given dose.