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Preparation of Poly(vinylbenzyl chloride)-grafted Fluoropolymer Films by Using Radiation Grafting Method  

Fei, Geng (Radiation Research Division for Industry and Environment Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute)
Sohn, Joon-Yong (Radiation Research Division for Industry and Environment Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute)
Lee, Youn-Sik (Division of Semiconductor & Chemical Engineering, Nanomaterials Processing Research Center, Chonbuk National University)
Nho, Young-Chang (Radiation Research Division for Industry and Environment Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute)
Shin, Jun-Hwa (Radiation Research Division for Industry and Environment Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute)
Publication Information
Polymer(Korea) / v.34, no.5, 2010 , pp. 464-468 More about this Journal
Abstract
In this study, a vinylbenzyl chloride (VBC) monomer was successfully grafted onto the several fluoropolymer films including poly(tetrafluoroethylene-co-hexafluoropropylene) (FEP), poly(tetrafluoroethylene-co-perfluoropropylvinyl ether) (PFA), and poly(ethylene-co-tetrafluoroethylene) (ETFE) films by using a simultaneous irradiation method. The results indicated that PVBC graft polymer can be easily grafted onto the ETFE film than other fluorinated films under the same irradiation condition. The grafted films were characterized by using FTIR, TGA, and SEM-EDS instruments. The elongation at the breaking of the grafted films was found to decrease with an increase of degree of grafting (DOG). The PVBC-grafted ETFE films were found to have better mechanical properties than other PVBC-grafted fluorinated films.
Keywords
vinylbenzyl chloride; fluoropolymer; radiation; grafting;
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1 R. C. T. Slade and J. R. Varcoe, Solid State Ionics, 176, 585 (2005).   DOI   ScienceOn
2 T. N. Danks, R. C. T. Slade, and J. R. Varcoe, J. Mater. Chem., 12, 3371 (2002).   DOI   ScienceOn
3 S. D. Alexandratos and X. Zhu, Macromolecules, 36, 3436 (2003).   DOI   ScienceOn
4 J. Shin, F. Geng, S.-A. Kang, B.-S. Ko, P.-H. Kang, and Y. C. Nho, J. Appl. Polym. Sci., 113, 2858 (2009).   DOI   ScienceOn
5 J. Chen, M. Asano, Y. Maekawa, and M. Yoshida, J. Memb. Sci., 277, 249 (2006).   DOI   ScienceOn
6 J. Chen, M. Asano, T. Yamaki, and M. Yoshida, J. Memb. Sci., 269, 194 (2006).   DOI   ScienceOn
7 H.-P. Brack, H. G. Bührer, L. Bonorand, and G. G. Scherer, J. Mater. Chem., 10, 1795 (2000).   DOI   ScienceOn
8 J. Chen, M. Asano, Y. Maekawa, and M. Yoshida, J. Polym. Sci. Part A: Polym. Chem., 46, 5559 (2008).   DOI   ScienceOn
9 S. J. Blanksby and G. B. Ellison, Acc. Chem. Res., 36, 255 (2003).   DOI   ScienceOn
10 J. Chen, M. Asano, M. Yoshida, and Y. Maekawa, J. Appl. Polym. Sci., 101, 2661 (2006).   DOI   ScienceOn
11 K. R. Park, P. H. Kang, and Y. C. Nho, React. Funct. Polym., 65, 47 (2005).   DOI   ScienceOn
12 G. Fei, S.-A. Kang, B.-S. Ko, Y.-S. Lee, Y. C. Nho, and J. Shin, J. Appl. Polym. Sci., 117, 2380 (2010).   DOI   ScienceOn
13 T. R. Dargaville, G. A. George, D. J. T. Hill, and A. K. Whittaker, Prog. Polym. Sci., 28, 1355 (2003).   DOI   ScienceOn
14 J. Shin, B.-S. Ko, S.-A. Kang, G. Fei, Y. C. Nho, and P.-H. Kang, Nucl. Instrum. Meth. B, 267, 791 (2009).   DOI   ScienceOn
15 B. Gupta, F. N. Büchi, G. G. Scherer, and A. Chapir, J. Memb. Sci., 118, 231 (1996).   DOI   ScienceOn
16 H. F. Mark, N. M. Bikales, C. G. Overberger, and C. Menges, Encyclopedia of Polymer Science and Engineering, Wiley, New York, Vol 5, p 614 (1988).
17 S. Holmberg, P. Holmlund, C. E. Wilén, T. Kallio, G. Sundholm, and F. Sundholm, J. Polym. Sci. Part A: Polym. Chem., 40, 591 (2002).   DOI   ScienceOn
18 H. Herman, R. C. T. Slade, and J. R. Varcoe, J. Memb. Sci., 218, 147 (2003).   DOI   ScienceOn
19 L. Gubler, S. A. Gürsel, and G. G. Scherer, Fuel Cells, 5, 317 (2005).   DOI   ScienceOn
20 M. M. Nasef and E.-S. A. Hegazy, Prog. Polym. Sci., 29, 499 (2004).   DOI   ScienceOn
21 Y. Kimura, M. Asano, J. Chen, Y. Maekawa, R. Katakai, and M. Yoshida, Radiat. Phys. Chem., 77, 864 (2008).   DOI   ScienceOn
22 G. Fei, J. Shin, S.-A. Kang, B.-S. Ko, P.-H. Kang, Y.-S. Lee, and Y. C. Nho, J. Polym. Sci. Part A: Polym. Chem., 48, 563 (2010).   DOI   ScienceOn
23 A. W. Trochimczuk and S. D. Alexandratos, J. Appl. Polym. Sci., 52, 1273 (1994).   DOI   ScienceOn
24 J. Chen, U. Septiani, M. Asano, Y. Maekawa, H. Kubota, and M. Yoshida, J. Appl. Polym. Sci., 103, 1966 (2007).   DOI   ScienceOn
25 J. Chen, M. Asano, T. Yamaki, and M. Yoshida, J. Appl. Polym. Sci., 100, 4565 (2006).   DOI   ScienceOn
26 J. Chen, M. Asano, T. Yamaki, and M. Yoshida, J. Memb. Sci., 256, 38 (2005).
27 G. Schmidt-Naake, M. $B\ddot{o}hme$, and A. Cabrera, Chem. Eng. Technol., 28, 720 (2005).   DOI   ScienceOn
28 F. Cardona, G. A. George, D. J. T. Hill, F. Rasoul, and J. Maeji, Macromolecules, 35, 355 (2002).   DOI   ScienceOn
29 M. M. Nasef and H. Saidi, J. Memb. Sci., 216, 27 (2003).   DOI   ScienceOn