• Journal of the Korean Chemical Society
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• v.28 no.5
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• pp.284-292
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• 1984

This paper aims to predict the substituent and Lewis acid catalysis effect or reactivity on the regioselectivity of (4+2) cycloaddition reaction of the substituted-E-arene-diazocyanides and nitrosobenzenes. Frontier orbital theory (FMO) has been applied to thermal and catalyzed Diels-Alder reaction by means of CNDO/2 and EHT-SPD methods. It has been found that: (1) The above reaction is positive rho(${\rho}$) values in Hammett equation, so it takes normal electron demand reaction, and four-frontier orbitals and Anh methods are identical with experimental major regioisomer.(2) When electron withdrawing radicals are substituted HOMO and LUMO energies of dienophiles are reduced, and the reactivity is increased. (3) The major regioisomer is predicted as B type, as the Lewis acid makes complexes of dienophile, and polaries LUMO coefficients of dienophile in an opposite way. (4) The linear correlation of Hammett is indicated in the graph of stabilized energies(${\Delta}$E) and sigma(${\sigma}$).

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.19 no.1
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• pp.16-28
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• 2007

The results of experimental investigation of coherent structures beneath wind-generated waves in deep water are presented. Vorticity fields of deepwater wind waves were visualized by analyzing the velocity fields obtained by PIV measurements under different wind and fetch conditions. In addition, spatio-temporal evolution of the coherent structures and subsequent changes in vertical profiles of the instantaneous vorticity were qualitatively examined. It was found that a coherent structure is formed right underneath the wave crest and traveled in phase with the surface wave. The direction of rotation of the coherent structure was contrary to the wave orbital motion when wind speed is less than 10 m/s, while was same as the wave orbital motion when wind speed is approximately 13 m/s and wave breaking occurs at the wave crest. In the near-surface region, complex vortex-vortex interactions were observed according to the traveling of the coherent structure. In contrast, coherent structures far below the water surface changed little due to weak influence of orbital motion by the surface waves.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.19 no.10
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• pp.2373-2379
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• 2015

COMS(Communication, Ocean and Meteorological Satellite), the first Korean geostationary meteorological satellite, provides free meteorological information through HRIT/LRIT(High/Low Rate Information Transmission) service. This work presents the development of data receiver circuit that is essential to the implementation of a low-cost meteorological information receiver system. The data receiver circuit processes the data units according to the specification of physical layer and data link layer of HRIT/LRIT service. For this purpose, the circuit consists of a Viterbi decoder, a sync. word detector, a derandomizer, a Reed-Solomon decoder and so on. The circuit also supports PCI express interface to pass the information data on to the host PC. The circuit was implemented on an FPGA(field programmable gate array) and its function was verified through simulations and hardware implementation.

• Journal of the Institute of Electronics Engineers of Korea SC
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• v.37 no.1
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• pp.19-29
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• 2000

Because the previous simulation tool for attitude control of satellite was designed for the modeling of rigid body and PD controller, the attitude error can be made more than the limitation value for keeping for communication link, and then the communication link can be lost at moving of satellite. So, for rapid attitude restoration and design of stable and modernized controller, the modelling of rigid body and flexible body structure for moving GEO and LEO satellites were performed. Also the minimum time controller is designed for the rapid restoration of attitude error at communication broken and to minimize the disconnection period from ground communication system during the satellite stationkeeping. The linear regulator is designed using the space state vector that is better than accuracy and stability of PD controller. Firstly the simulation was performed for comparison of the rigid and stability of PD controller. Firstly the simulation was performed for comparison of the rigid and flexible models using PD controller and the case of the pitch angle changing by ground command, and the case of the periodic north-south stationkeeping are performed for the analysis of response characteristics of each controller when the attitude is changed. As a result, the flexible body model represents more sililar results of real situation than the rigid body model. The minimum time controller can restore 7 times rapidly than PD controller for its lost attitude. The linear regulator has several merits for capability of adaptation against the external disturbance, stability and response time. In future, we can check the estimated results using this satellite model and controller for real operation. Futhermore the development of new controller and training can be supported.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.12
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• pp.6427-6433
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• 2013

For trains to run safely and quickly, the train should always follow the preceding train at a proper spacing. For this purpose, a certain distance between the stations is set for each block section. For the safe operation of trains in one block section, only one train service for an automatic block system is needed. The existing block system is composed an ABS, which is a linked track circuit and line sideway system through the interlocking system. The interlocking system is being replaced with a domestic electronic interlocking system. On the other hand, the block system still uses the relay format of an analog system, and is independently installed of the line sideway systems. Therefore, the existing block system has many problems in terms of construction and maintenance. In addition, the existing domestic line is used for ABS and LEU , which is installed separately, despite the train being controlled by the information of the same signal at the same location. This is not efficient in terms of each product price and the maintenance costs. This paper introduces an integrated electronic block system and the field test results. The field test was carried out through a periodic inspection performed eight times from January to late August.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.8
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• pp.5534-5540
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• 2015

This In the railway signaling system, applications of axle counter in addition to track circuit goes on increasing for detecting train position. Consequently, this paper compares sensor methods of axle counter with between geo-magnetism method and proximity sensor method. And it presents differences and results, to improve reliabilities of train detection and axle counting. Also, this article presents an applied result which is based on field experience, with regard to installation, considering attachment condition of sensor part for accurate axle counting. This study acquires expandability that is able to perform not only axle counting function but also various other functions (direction detection of train, speed detection of train, and so on). It was a result of a change of design in order to judge phase difference of sensors, to improve reliability of axle counting. Furthermore, it does not subordinate to characteristics (type, weight of train). And it is confirmed that the omission of axle counting was not occurred in 350km/h. This was the result of Lab test after the construction of transfer equipment of trial axle and Test Bed for axle counting. Both of them are self-productions. Through this, it prepares foundation which is able to apply not only to train detection but also to speed of passing trains, formation number of trains, detector locking condition - when the train passes the section of switch point, and level crossing devices. Furthermore, it would be judged to contribute safety train operation if proximity sensor method applies to the whole railway signaling system from now on.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.39C no.3
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• pp.298-306
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• 2014

The railway signalling system for safe train operation regulates the train speed to ensure the safety distance between consecutive trains by using wayside facilities such as track circuits and interlocking systems. In addition, this signalling system controls the trackside equipment such as a railway point along the train line. This ground-equipment-based train control systems require high CAPEX and OPEX. To deal with these problems, the train control system using the on-board controller has been recently proposed and its related technologies have been widely studied. The on-board-controller-based train control system is that the on-board controller can directly control the trackside equipment on the train line. In addition, if this system is used, the wayside facilities can be simplified, and as a result, the efficient and cost-effective train control system can be realized. To this end, we have developed the prototypes of the on-board controller and wayside object control units which control the point and crossing gate and performed the integrated operation simulation in a testbed. In this paper, before the field test of the on-board-controller-based train control system, we perform the preliminary field trial including the installation test, wireless access test, interface test with other on-board devices, and normal operation test.

• Journal of the Korean Chemical Society
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• v.18 no.2
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• pp.85-96
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• 1974

Extended H ckel Theory and CNDO/2 MO calculation methods have been applied to $C_6H_5YCH_2Cl$(Y = None, -$CH_2$-, -O-, -S-, -CO-, -$SO_2$-). It has been shown that charge distributions in molecules are mainly controlled by the migration of valence inactive electron, giving the order of ${\sigma}$-acceptor and ${\pi}$-donor effects -O- > -S- > -$CH_2$- > -$SO_2$-. The -CO- group exceptionally acts as ${\sigma}$-donor and ${\pi}$-acceptor. It was also predicted that, $S_N2$ reactivities of C$C_6H_5YCH_2Cl$ would be in the order of -O-${\thickapprox}$-CO- >>-S-${\thickapprox}$None > -$CH_2$-, neglecting solvent effect. From the results of our studies, we conclude that the structural factors influencing 의 $S_N$ reactivities will be: (1) positive charge developments on reaction center carbon atom (2) energy level of ${\sigma}$-antibonding unoccupied MO with respect to C-Cl bond. (3) ${\sigma}$-antibonding strength of C-Cl bond at that level.

• Journal of the Korean Chemical Society
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• v.17 no.2
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• pp.95-104
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• 1973

Ground electronic structures and SNreactivities of a series of alkylchlorides (methyl,ethyl, iso-propyl, trans n-butyl, sec-butyl, tert-butylchloride) have been studied using approximate $({\sigma}-MO)$ method, such as EHT and CNDO/2. It was found that CNDO/2 gives better results for the systems such as alkylchlorides whose structural differences are not remarkable, in comparison with EHT method. According to CNDO/2 results, calculated dipole moments for alkylchlorides are slightly higher than observed values, showing the order of primary < secondary < tertiary alkylchlorides. It was also found that highest occupied(HO) MO's are completely or nearly degenerate, and show relatively weak $\pi$-antibonding nature between$\alpha$-carbon and Cl atoms. Furthermore, the electrons in this MO are largely confined to Cl atom, and hence these behaves as likely as p-lone pair electrons of Cl atom. On the contrary, lowest unoccupied (LU) MO's show strong $\sigma$-antibonding nature between $\alpha$-carbon and Cl atoms whose electron clouds are directed along the C-Cl axis. It has been discussed that the$S_N2$ reactivities of alkylchlorides may largely be controlled by ${\sigma}^{\ast}$ LUMO, and the antibonding strength between $\alpha$-carbon and Cl atoms in this MO may become the measure of $S_N2$reactivity. The relationship between $S_N2$reactivity and C-Cl bond polarizability has also been discussed. It has been suggested that the unique structure factors determining $S_N1$reactivities may be $\pi$-antibonding strength between $\alpha$-carbon and Cl atoms in HOMO and C-Cl bond strength in ground state.

• The Korean Journal of Air & Space Law and Policy
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• v.29 no.1
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• pp.199-236
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• 2014

This paper analyses from the perspective of distributive justice the legal mechanisms for international allocation of orbital slots, which are of co-owned nature and thereby limited natural resources in outer space. The allocative function is delegated to the International Telecommunication Union. The Radio Regulation, amongst such other legal instruments as the Constitution and Convention, by which the ITU and contracting States thereof abides, dictates how the orbital positions are distributed. Thus, the RR is thoroughly reviewed in the essay. The mechanisms are in a broad sense categorized into two systems: 'a posteriori system' where the 'first come, first served' principle prevails; and 'a priori system' designed to foster the utilisation of the slots by those who lack space resources and are, in especial, likely to be marginalised under the former system. The argument proceeds on the premise that a posteriori system places the under-resourced States in unfavourable positions in the securement of the slots. In contrast with this notion, seven factors were instantiated for an assertion that the degradation of the distributive justice derived from the 'first come, first served' rule, which lays the foundation for the system, could be either mitigated or counterbalanced by the alleged exceptions to the rule. However, the author of this essay argues for counterevidences against the factors and thereby demonstrating that the principle still remains as an overwhelming doctrine, posing a threat to the pursuit of fair allocation. The elements he set forth are as in the following: 1) that the 'first come, first served' principle only applies to assignments capable of causing harmful interferences; 2) the interoperability of the principle with the 'rule of conformity' with the all the ITU instruments; 3) the viability of alternative registrations, as an exception of the application of the principle, on the condition of provisional and informational purposes; 4) another reference that matters in deciding the priority: the types of services in the TFA; 5) the Rule of Procedure H40 proclaiming a ban on taking advantage of coming first to the Register; 6) the technical factors and equity-oriented norms under international and municipal laws along with; 7) the changes of 'basic characteristics' of registered assignments. The second half of this essay illustrates by examining the relevant Annexes to the Regulation that the planned allocation, i.e., a priori system, bear the structured flaws that hinder the fulfillment of the original purpose of the system. The Broadcasting and Fixed Satellite Systems are the reviewed Plans in which the 'first come, first served' principle re-emerges in the end as a determining factor to grant the 'right to international recognition' to administrations including those who has not the allotted portions in the Plan.