• Cement Symposium
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• no.27
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• pp.6-13
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• 2000

• Proceedings of the KAIS Fall Conference
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• 2009.12a
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• pp.1026-1029
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• 2009

현재 남해안 굴양식산업은 어업인들의 중요한 소득원이 되고 있으나, 굴양식장에서 발생되는 굴패각은 처리곤란 및 악취발생으로 인해 또 다른 해양오염원으로 그 문제성이 심각하게 대두되고 있는 실정이다. 굴양식장에서 연간 약 28~30만여톤의 굴패각이 발생되고 있으며, 그 중 10~20%는 종패부착용이나 비료로 재활용되고 있고, 80~90%는 매립되거나 야적 방치된다고 보고되고 있다. 본 연구에서는 굴패각을 재활용하고자 굴껍질의 성분분석을 실시하여 나노고분자세라믹 코팅제의 세라믹 소재로써의 적용 가능성여부를 확인하였고, 경기도 P정수장 내 여과지 콘크리트 벽면에 코팅처리하여 그 성능을 확인하였다. 그 결과 패각의 굴껍질은 90%이상이 탄산칼슘($CaCO_3$)로 이루어져 있었으며, 굴껍질을 재활용한 나노고분자세라믹 코팅제는 pH 7.5~8.5로서 일반수도를 측정한 pH 7.3~7.8과 유사한 결과를 보였다. 또한, 나노고분자세라믹 코팅제의 콘크리트 벽면에 대한 부착강도는 한국산업규격에 제시된 폴리머의 방수재료 부착강도인 8~10(kg.f/$cm^2$)이상의 값이 나타남에 따라 패각의 굴껍질을 재활용한 나노고분자세라믹 코팅제의 경기도 P정수장 내 여과지 콘크리트 벽면 코팅제로써 적용이 가능한 것으로 확인 되었다.

• Clean Technology
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• v.19 no.2
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• pp.134-139
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• 2013

VOCs such as formaldehyde and benzene in a control chamber were adsorbed onto gypsum incorporating oyster shell powder, which was solidified and dried. VOC was first exposed in air and then gypsum mortar was placed in the chamber for 180 min for adsorption. The mortar was prepared with 0, 10, 30, and 50% of oyster shell powder. Two initial concentrations of VOCs including formaldehyde were $27.7{\sim}28.5mg/m^3$ or $175{\sim}150{\mu}g/m^3$. We found out that the initial concentrations did not seem to make any difference in adsorption performance but higher oyster content strongly led to higher adsorption. We used a convection-diffusion-adsorption model to compare the experiment. The model which considers diffusion coefficients of adsorbates and affinity of the adsorbents well represented the experimental data with a fair agreement.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.4
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• pp.458-465
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• 2017

The purpose of the present study was to examine the method of physically processing oyster shells for use as raw material(aggregate) through experimentation. The results of the experiment found that the adequate particle size of the pulverized oyster shells should be smaller than 10mm due to their shape. Also, after considering various particle size distributions and residual rates by particle size, the study found the cutter mill to be the most suitable tool for pulverizing oyster shells. The use of a cutter mill resulted in recovery rates of 97.3%, 98.2%, and 98.9% for inner screens of 8mm, 12mm, and 20mm respectively, revealing how the increase of screen size results in slightly higher recovery rates. The experiment involving the difference between the inner screen of the cutter mill and the speed of the inverter shows that a smaller screen size and a faster inverter speed result in a lower fineness modulus, while a rise in inverter speed for an identical screen made possible the material recovery of a much lower range of particle sizes.

• Tunnel and Underground Space
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• v.27 no.5
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• pp.312-323
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• 2017

In this study, an influence of mixing ratio among firing oyster shell, non-firing oyster shell, magnetic separated converter steel slag and fly ash used as admixtures on strength properties of soil cement was evaluated by correlation analysis among compressive strength, deformation modulus and mixing ratio of admixtures. As a result, the strength of the specimens containing non-firing oyster shells was found to be larger than that of firing oyster shells, and it was confirmed that firing oyster shells could negatively affect the strength of soil cement specimens unlike previous studies. In addtion, there was a positive correlation between the ratio of magnetic separated converter slag and strength properties, so it is confirmed that it can be used as an admixture.

• Journal of the Korean Geotechnical Society
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• v.20 no.9
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• pp.17-23
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• 2004

Strength and deformation characteristics of oyster shell-sand mixtures were investigated to utilize waste oyster shell being treated as a waste material. Standard penetration test (SPT) is a common method to obtain in-situ strength in sand. However, in case of oyster shell-sand mixtures, there was no information between SPT N-value and internal friction angle of mixture soils. In this paper SPT experiments from several large scaled model chamber tests and large scaled direct shear tests were carried out with varying unit weight of oyster shell-sand mixtures. Appropriate correlations were in tile study observed among N-value, unit weight and internal friction angle, which make it possible to estimate in-situ strength from SPT and the coefficient of volume compressibility from the confined compression tests to compute the settlement of oyster shell-sand mixtures.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2000.04a
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• pp.371-372
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• 2000

국내 해안에는 양식업에서 부산물로 다량 발생되는 굴, 홍합, 대합 등의 패각들이 해안에 야적되어 연안어장의 오염, 공유수면 관리상의 지장, 자연경관의 훼손 및 보건 위생상의 문제 등으로 환경오염을 초래하고 있다(정종현 등, 1998). 현재 폐 패각의 총발생량은 355,000톤 정도이며, 이 중 종묘채묘용으로 재사용되는 양을 제외하면, 토지개량제로서의 이용 등을 포함한 재활용율은 약 30%정도로 낮은 실정이다. (굴수협전국조합, 1999). 더구나 처리비용이 비싸기 때문에 발생되는 폐 패각은 대부분 방치되고 있는 실정이다. (중략)

• Clean Technology
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• v.19 no.2
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• pp.90-94
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• 2013

We investigated one-dimensional thermal conduction for gypsum objects incorporating oyster shell powder. We presumed that according to the portion of oyster shell in the hybrid structure conductive characteristics of that would also change as some physicochemical properties such as volatile organic compound (VOC) adsorption were found to be changed considerably. Based on Fourier's 2nd law of heat conduction an analytical analysis in a flat slab (one axis perpendicular to an infinite plane) was performed. We found that composition of oyster shell and conduction-related coefficients and parameters could greatly influence on the thermal profile of that conduction, and some model experiments also served for it in the affirmative.

• Journal of the Korean Society for Marine Environment & Energy
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• v.16 no.2
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• pp.138-142
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• 2013

As an early warning system to reduce the damage of aquacultured mollusks due to low salinity water, we investigated the possibility of a biomonitoring system measuring the shell valve movement (SVM) of Pacific oyster (Crassostrea gigas) by using the Hall element sensor. In high salinity water of 27 psu, SVMs of Pacific oyster showed spikes which mean a relatively fast closing condition after opened condition of average 10-15 mm, and then the SVM showed back to opening condition slower than closing speed. In water salinity of 20-27 psu, the SVMs were similar to that of 27 psu. However, below 17 psu, it showed abnormal valve movements such as spending more time for shell closure. In 10 psu, we could not detected SVMs due to closed condition during experiment periods. Thus, if we quickly detect abnormal environmental variations like low salinity using bio-monitoring of SVM, it may be contribute to increased productivity by dramatically reducing damages in aquaculture.

• Journal of the Korea Concrete Institute
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• v.14 no.4
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• pp.540-548
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• 2002

The purpose of this study is to analyze the application of oyster shells (OS) as aggregates for concrete. For this purpose, five reference mixes with W/C ratios of 0.4 ∼0.6 at intervals of 0.05 were used. The replacement proportion of OS was varied with ratios of 0, 10, 30, 50 and 100％ by volume of fine or coarse aggregate in the reference mixes. OS was washed and crushed for using as aggregates. New chemical reaction between crushed OS aggregate and cement paste was tested through XRD and SEM analysis. Two strength properties (compressive and flexural) were considered. Strength tests were carried out at the ages of 1, 3, 7, 14 and 28 days. The variations of workability, air content and density, drying shrinkage of the specimens with different proportions of OS were also studied. Finally, the hollow concrete block using OS as a substitute material for fine aggregate was made for testing the application of OS. Experimental results showed that my new chemical reaction did not occur due to mixing OS in concrete. The workability and strengths decreased with increase in proportion of OS. The same trend was observed in density and unit weight, but air content increased due to the inherent pores in OS, which showed a possibility to produce light weight concrete with low strength by using OS as coarse aggregates for concrete. Tests on hollow concrete block showed that the compressive strength and absorption ratio were satisfied with quality requirements when the fine aggregate was substituted with OS up to 50％ in volume.