• Proceedings of the KSEEG Conference
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• 2007.04a
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• pp.170-172
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• 2007

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2010.04a
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• pp.409-411
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• 2010

• Journal of the Korean Chemical Society
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• v.43 no.1
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• pp.1-7
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• 1999

Metal colloidal particles have been prepared by a photo-chemical process in an aqueous solution containing semiconductor nanocrystallites. Metal colloidal particles produced in CdS and AgBr exhibit different absorption spectra. Au particles produced in solution with CdS show typical Au plasmon resonance absorption spectra. On the other hand Ag particles in solution with AgBr shows surface plasmon resonance absorption spectra which are red-shifted, as compared to that of a dispersion of homogeneous Ag colloidal particles in the same host. The extent of red-shift depends on the UV illumination time. This phenomenon is interpreted within the context of effective medium theory for small volume fractions. From the theory, a metal coated particle predicts Ag plasmon resonance, red shifted with respect to 400 nm that would be associated with a silver particle in solution. The absorption peak position is very sensitive to the coating thickness.

• Korean Chemical Engineering Research
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• v.45 no.5
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• pp.415-423
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• 2007

Photocatalytic water splitting (PWS) is the most promising technology to produce $H_2$ energy directly from renewable water and solar light. In spite of the remarkable progress made in the last decade, there are still many technical challenges remaining particularly in finding new photocatalytic materials with high efficiency and durability. This article discusses the application of nanocomposite materials in search of new photocatalytic materials for solar hydrogen production from water. It has been demonstrated that smart combination and modification of known materials and functions could be fruitful approach for the purpose.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.8
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• pp.829-836
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• 2005

In this study, the characteristics of atrazine decompositon with photo-chemical oxidation process was investigated by the oxidation products analysis. The main products of the process were OIET(2-hydroxy-4-ethylamino-6-isopropylamino s-triazine), OIAT(2-hydroxy-4-amino-6-isopropylamino s-triazine) and OAAT(2-hydroxy-4,6-diamino-s-triazine), resulting i n dechlorination or hydroxylation as the main mechanism of the photo-chemical oxidation process. Through the material balance analysis of TOC and chloride ion in the aqueous solution, it was concluded that mineralization of the atrazine was not occurred but the dechlorination of atrazine had been completed.

• Journal of the Korean Society for Precision Engineering
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• v.24 no.5
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• pp.104-109
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• 2007

Photochemical patterning of self-assembled mono layers (SAMs) has been performed by diode pumped solid state (DPSS) 3rd harmonic Nd:$YVO_4$ laser with wavelength of 355 nm. SAMs patternings of parallel lines have subsequently been used either to generate compositional chemical patterns or fabricate microstructures by a wet etching. This paper describes a selective etching process with patterned SAMs of alkanetiolate molecules on the surface of gold. SAMs formed by the adsorption of alkanethiols onto gold substrate employs as very thin photoresists. In this paper, the influence of the interaction between the functional group of SAMs and the etching solution is studied with optimal laser irradiation conditions. The results show that hydrophobic functional groups of SAMs are more effective for selective chemical etching than the hydrophilic ones.

• Korean Journal of Food Science and Technology
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• v.1 no.1
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• pp.45-50
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• 1969

On the basis of UV spectral changes and TBA reaction, malonaldehyde (MA) in aqueous solution receives considerable photochemical modification by UV light of short wavelengths around $260m{\mu}$. When aflatoxin is added in the solution, UV light of long wavelengths around $360m{\mu}$ induces such changes quite rapidly and although the rate of change is rather slow, it is also true even with ordinary laboratory illumination(fluorescent). The modification is irreversible in nature and the role of aflatoxin in this reaction is identified as a photosensitizer. The mechanism involved in this modification is apparently due to the parallel dimerization of MA molecules, but not by head to tail combination of the molecules.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.37 no.3
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• pp.227-236
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• 2011

The new sunscreen agent, methoxycinnamidopropyl polysilsesquioxane, is manufactured as polymeric particles with an organic/inorganic hybrid composition. We have already reported the manufacturing method, physical properties, and sunprotection effects of methoxycinnamidopropyl polysilsesquioxane. In this study, we evaluated the photochemical properties and photostabilities of methoxycinnamidopropyl polysilsesquioxane that has the same functional group as a typical organic sunscreen agent, ethylhexyl methoxycinnamate (EHMC). Using the correlation of UV absorbance and fluorescence, we studied photostabilizers to enhance the photostability of methoxycinnamidopropyl polysilsesquioxane. Finally, we confirmed that octocrylene, ethylhexyl methoxycrylene, and bis-ethylhexyloxyphenol methoxyphenyl triazine were good photostabilizers for methoxycinnamidopropyl polysilsesquioxane.

• Journal of the Mineralogical Society of Korea
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• v.23 no.2
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• pp.161-170
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• 2010

Many microbes, including both bacteria and fungi, produce manganese (Mn) oxides by oxidizing soluble Mn(II) to form insoluble Mn(IV) oxide minerals, a kinetically much faster process than abiotic oxidation. These biogenic Mn oxides drive the Mn cycle, coupling it with diverse biogeochemical cycles and determining the bioavailability of environmental contaminants, mainly through strong adsorption and redox reactions. This mini review introduces recent findings based on quantum mechanical density functional theory that reveal the detailed mechanisms of toxic metal adsorption at Mn oxide surfaces and the remarkable role of Mn vacancies in the photochemistry of these minerals.

• Proceedings of the Plant Resources Society of Korea Conference
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• 2021.04a
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• pp.44-44
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• 2021

본 연구는 제주지역의 골프 코스에서 하절기 고온기간에 온도의 상승을 비롯한 다양한 환경변화로 인하여 생육 장애가 심한 한지형 잔디인 perennial ryegrass (Lolium perenne L.), Kentucky bluegrass (Poa pratensis L.), creeping bentgrass (Agrostis palustris Huds.) 3종에 대하여 엽록소형광과 엽록소지수를 측정하여 골프 코스와 스포츠 필드에서 잔디 선정과 관리를 위한 기본적인 정보를 얻기 위하여 수행하였다. F_o 값은 3종 모두 하절기 초기에는 낮고 후기에 다소 증가하는 양상을 보였다. 그러나, perennial ryegrass의 경우는 하절기 초기와 후기 간의 F_o 값의 변화가 컸으며, 특히, 후기에 F_o 값은 다른 2종 월등하게 보다 높았다. F_m 값은 3종 모두 하절기 초기에는 낮고 하절기 후기에 증가하였으나 3종 간의 차이는 크지 않았다. 광계 II의 광화학적 효율의 척도인 F_v/F_m 값은 3종 모두에서 하절기 초기에 낮고, 후기에 다소 증가하는 양상을 보였으나, 하절기 후기에 Kentucky bluegrass와 creeping bentgrass는 perennial ryegrass에 비해 F_v/F_m 값이 다소 높아 하절기 고온에서도 보다 더 잘 적응하는 것으로 보인다. 엽록소지수는 perennial ryegrass와 Kentucky bluegrass에서는 뚜렷하게 하절기 초기에는 낮고 후기에 높은 양상을 보였으나, creeping bentgrass는 조사기간 내내 낮은 상태를 유지하였다. 이상의 결과로부터 Kentucky bluegrass가 하절기 후기의 고온이나 빈번한 강우에 의한 습한 조건에 가장 강하고, perennial ryegrass가 가장 취약한 것으로 사료된다.