• Title/Summary/Keyword: 광추출

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A Study on the Solvent Extraction Mechanism of Nickel(Ⅱ) with N-Benzylisonitrosoacetylacetone Imine by Spectrophotometry (분광광도법에 의한 Ni(Ⅱ)-N-Benzylisonitrosoacetylacetone Imine착물의 용매추출 반응메카니즘)

  • Heung Lark Lee;Zun Ung Bae;Dong-Gyu Kim
    • Journal of the Korean Chemical Society
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    • v.36 no.4
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    • pp.546-551
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    • 1992
  • Reaction mechanism on the solvent extraction of nickel(Ⅱ) with N-benzylisonitrosoacetylacetone imine(HIAANB) was studied spectrophotometrically. Absorbance was measured by changing the ligand HIAANB concentration in the chloroform organic phase and the pH values in the agueous solution phase. From the absorbance data, the reaction rate was found to be the first order for HIAANB concentration and the inverse first one for [$H^+$]. The rate determining step of the extraction reaction and the rate equation are as follows; $Ni^{2+}$+HIAANB ${\to}$ Ni-IAANB$^+$$H^+$ -d[Ni$^{2+}$] / dt = K'[Ni$^{2+}$][HIAANB]$_0$ / [H$^+$] Calibration curve for the spectrophotometric determination of nickel(Ⅱ) ion in the aqueous solution was linear below the concentration of 1.17 ppm at the optimum experimental condition. And the ligand-to-metal ratio, the relationship between extractability and pH of the aqueous phase, and the effect of diverse ion on the determination of nickel(Ⅱ) ion were examined.

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3D Faces Reconstruction Using Structured Light Images (구조 광 영상을 이용한 3차원 얼굴 복원)

  • Lee, Duk-Ryong;Oh, Il-Seok
    • Proceedings of the Korea Contents Association Conference
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    • 2008.05a
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    • pp.15-18
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    • 2008
  • This paper proposes a method to reconstruct the 3-D face using structured light image. First of all, we suppose that each sight vector of a projector and camera are parallel. We project the structured light in the shape of lattice on the background to acquire the reference-structured light image. This image is used to calibrate the projector and camera. Since then, we acquire the face-structured light image which is projected the same structured light on the face. These two structured light images are used to reconstruct the 3-D face through the variation which is measured from the positional difference of feature vectors. In our experiment result, we could reconstruct the 3-D face image as recognize through these simple devices.

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An Enhancement Technique for Separation of Direct Light and Global Light Using High Frequency Illumination pattern (고주파 조명패턴을 사용한 직접광과 간접광의 분리성능 향상 기법)

  • Jo, Mi-Ri-Na;Park, Dong-Gyu
    • Journal of Korea Multimedia Society
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    • v.12 no.9
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    • pp.1262-1272
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    • 2009
  • In computer graphics, there exist many studies about illumination and radiance for a realistic description of the 3D modeling and rendering. When we see a scene, the scene is lit by a source of light and the radiance of the points by a source in the scene. The radiance has direct light and glight component. The direct light gets lights directly from light source, but the global light gets lights indirectly by interreflections among complicated geometrical components. In this paper, we studied a method for increasing the accuracy of separating direct light and global light components from a scene by using high frequency illumination pattern. For experiments, we applied the separating method of Nayar's and found the best configurations for the separation through the experiments. We improved the separation accuracy of direct and global light by measuring the value of unilluminated area, which depends on the characteristics of object. Furthermore, we enhanced invisible scene of the global light by applying the image filtering technique.

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Photoprotection and Anti-inflammatory Effects of Chinese Medical Plants (약용식물추출물의 광보호 효과와 항염증 효과 연구)

  • Jin-Hwa, Kim;Sung-Min, Park;Gwan-Sub, Sim;Bum-Chun , Lee;Hyeong-Bae, Pyo
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.30 no.2
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    • pp.227-233
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    • 2004
  • Chronic exposure to solar radiation, particularly ultraviolet (UV) light, causes a variety of adverse reactions on human skin, such as sunburn, photoaging and photocarcinogenesis. Free radicals and reactive oxygen species (ROS) caused by UV exposure or other environmental facts play critical roles in cellular damage. And, repeated-UV irradiation activated the expression of the matrix metalloproteinase (MMP) and induced skin irritation. Therefore, the development of effective and safe photoprotectants that can reduce and improve the skin damage has been required. The purpose of this study was to investigate the photo-protective effect of several chinese medical plants (Juniperus chinensis) on the UV -induced skin cell damages. We tested free radical and superoxide scavenging effect in vitro. Fluorometric assays of the proteolytic activities of MMP-1 (collagenase) were performed using fluorescent collagen substrates. UVA induced MMP-1 synthesis and activity were analyzed by enzyme-linked immunosorbent assay (ELISA) and gelatin-based zymography in skin fibroblasts. We also examined anti-inflammatory effects by the determination test of proinflammatory cytokine, interleukin 6 in HaCaT keratinocytes. Expression of prostaglandin E$_2$ (PGE$_2$) after UVB irradiation was measured by competitive enzyme immunoassay(EIA) using PGE$_2$ monoclonal antibody. In the human skin we tested anti-irritation effect on the SLS-induced damage skin after appling the extract containing emulsion. We found that Juniperus chinensis extract had potent radical scavenging effect by 98% at 100$\mu\textrm{g}$/mL. The extract of Juniperus chinensis showed strong inhibitory effect on MMP-1 activities by 97% at 100 $\mu\textrm{g}$/mL and suppressed the UVA induced expression of MMP-1 by 79% at 25$\mu\textrm{g}$/mL. This extract also showed strong inhibition on MMP-2 activity in UVA irradiated fibroblast by zymography. In the test of proinflammatory cytokines of human keratinocytes Juniperus chinensis extract decreased expression of interleukin 6 about 30%. The amount of PGE$_2$ by HaCaT keratinocytes was significantly increased at the doses of above 10 mJ/$\textrm{cm}^2$ of UVB (p < 0.05). At the concentrations of 3.2-25$\mu\textrm{g}$/mL of this extract, the production of PGE$_2$ by HaCaT keratinocytes (24 h after 10mJ/$\textrm{cm}^2$ UVB irradiation) was significantly inhibited in culture supernatants (p < 0.05). In SLS-induced skin irritation model in vivo, we found to reduce skin erythema and improve barrier recovery after appling Juniperus chinensis extract containing emulsion when compared to irritated non-treated and placebo-treated skin. Our results suggest that Juniperus chinensis extract can be effectively used for the prevention of UV and SLS-induced adverse skin reactions and applied as anti-aging and anti-irritation cosmetics.

The Study on Desalting Method for Removing Chloride ions and Corrosion Products of Iron artifacts (철제유물의 탈염처리 방법 및 부식생성물에 관한 연구)

  • Yu, Jae Eun;Hwang, Hyun Sung;Koh, Kyong Shin
    • 한국문화재보존과학회:학술대회논문집
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    • 2002.02a
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    • pp.45-52
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    • 2002
  • 본 연구에서는 KaOH, $K_2CO_3$, Sodium, 그리고 1차 이온수 용액의 $Cl^-$ 이온 추출량과 부식생성물의 생성순위, 부식물 생성, 그리고 부식물 제거에 관하여 관찰하였으며 이 연구로 아래와 같은 결과를 얻었다. $Cl^-$ 이온 추출량에 대한 실험 결과 NaOH은 탈염 초기에는 Cl- 이온을 잘 추출시켰으나 탈염 횟수가 증가하면서 $Cl^-$ 이온의 추출량이 급감하였다. 또한 유물 중량 변화에도 감소폭이 가장 심하였다. $K_2CO_3$은 NaOH나 1차이온수 용액과 비교해 보면 이 방법은 탈염처리동안 $Cl^-$ 이온을 꾸준히 추출시켜 주었으며 다른 탈염용액에 비해 유물 중량변화가 거의 관찰되지 않았다. Sodium 용액은 $K_2CO_3$ 용액과 마찬가지로 탈염처리 동안 $Cl^-$ 이온을 꾸준히 추출시켰으며 다른 탈염 용액에 비해 $Cl^-$ 이온 추출량이 가장 많았다. 하지만 이 용액은 약품 내에 불순물인 $Cl^-$ 이온을 $3\~5\;ppm$을 기지고 있어 보존처리자가 탈염처리를 할 때 좀 더 신중하게 생각해야 할 것 같다. 1차 이온수 용액은 부식인자가 $Cl^-$이온을 완전하게 제거해주지는 못하였지만, pH가 $7.5\~7.9$로 다른 탈염 용액에 비해서 전위차가 낮으며, 별도로 탈알칼리 처리를 하지 않아도 되기 때문에 유물손상은 극소화할 수가 있다. 따라서 이 용액은 부식이 매우 심한 철제 유물이나 균열이 많은 주조 철편과 같은 유물을 처리할 때 적절한 용액이다. 부식생성물 관찰에서는 출토 철기 유물에 생성된 부식물은 주로 인철광$(\gamma-FeOOH)$, 침철광$(\alpha-FeOOH)$, 적금광$(\beta-FeOOH)$, 그리고 자철광$(Fe_3O_4)$이다. 인위적 부식에서는 전부 인철광의 부식물이 생성되었고 자연적 부식에서는 모두 침철광의 부식물이 생성되었다. 특히 철제 표면에 자연적으로 생성된 공식 녹을 XRD 분석한 결과 적금광으로 동정되었다. 이런 모든 시편들을 각 탈염방법에 따라 탈염처리한 후 XRD와 SEM-EDS으로 분석한 결과 인철광과 침철광은 어떠한 변화도 보이지 않았고, 다만 적금광으로 동정된 시편만이 잔존하지 않았다. 철기 제작별 $Cl^-$ 이온 추출량과 탈염효과에 대한 비교 실험은 이온 크로마토그래피 분석 결과와 마찬가지로 단조 철제유물이 주조 철제보다 $Cl^-$ 이온을 많이 가지고 있었으며, 탈염 처리 후에는 $Cl^-$ 이온은 전혀 발견되지 않았다. 이상의 결과 $K_2CO_3$와 Sodium 용액은 탈염처리에서 가장 적합한 탈염처리 용액으로 알수가 있었으며 특히 어떠한 탈염 용액으로 유물을 처리한다 해도 철제유물에 생성된 부식물은 제거되지 않는다는 것을 알게 되었다. 따라서 보존처리자는 유물 표면의 부식 상태만을 보고 처리하기 보다는 철기제작물로 고려하여 처리하는 것이 필요하다. 또한 금속에 부식을 야기시키는 $Cl^-$ 이온과 부식물을 완전하게 제거하여 탈염처리를 하는 것이 유물 부식을 최대한 지연시킬 수 있는 것이라 생각된다.

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Antioxidant and photoprotective activities of various extracts from the roots of Rumex crispus L. (소리쟁이(Rumex crispus L.) 뿌리 추출물의 항산화 및 광피해 억제 효과)

  • Kim, Yeon-Soon;Suh, Hwa-Jin;Park, Shin
    • Food Science and Preservation
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    • v.20 no.5
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    • pp.684-690
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    • 2013
  • The antioxidant and photoprotective effects of various extracts from the roots of Rumex crispus L. were evaluated. The concentrations ($IC_{50}$) of various extracts required to exert a 50% reducing effect on a DPPH radical were found to be 0.005~0.093 mg/mL. The ethyl acetate extract showed a more remarkable effect than the positive control ascorbic acid. The concentrations ($QC_{50}$) of the butanol and ethyl acetate extracts required to exert a 50% reducing effect on the singlet oxygen $^1O_2$ were found to be 0.464 and 0.365 mg/mL, respectively. Both extracts were also found to protect the in vitro biological system from the detrimental effect of a singlet oxygen $^1O_2$ on type II photosensitization in E. coli and genomic DNA. Among all the tested extracts, the ethyl acetate and butanol extracts contained higher amounts of total phenolic contents. The results suggest that our study may contribute to the development of new bioactive products with potential applications to the reduction of photo-produced oxidative stress involving reactive oxygen species in living organisms.

Opto-Digital Implementation of Convergence-Controlled Stereo Target Tracking System (주시각이 제어된 스테레오 물체추적 시스템의 광-디지털적 구현)

  • 고정환;이재수;김은수
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.27 no.4B
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    • pp.353-364
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    • 2002
  • In this paper, a new onto-digital stereo object-tracking system using hierarchical digital algorithms and optical BPEJTC is proposed. This proposed system can adaptively track a moving target by controlling the convergence of stereo camera. firstly, the target is detected through the background matching of the sequential input images by using optical BPEJTC and then the target area is segmented by using the target projection mask which is composed by hierarchical digital processing of image subtraction, logical operation and morphological filtering. Secondly, the location's coordinate of the moving target object for each of the sequential input frames can be extracted through carrying out optical BPEJTC between the reference image of the target region mask and the stereo input image. Finally, the convergence and pan/tilt of stereo camera can be sequentially controlled by using these target coordinate values and the target can be kept in tracking. Also, a possibility of real-time implementation of the adaptive stereo object tracking system is suggested through optically implementing the proposed target extraction and convergence control algorithms.

Design and embodiment about pulse modeling of light investigation for disease treatment by skin color (피부색에 따른 병변치료를 위한 광조사펄스모델링에 대한 설계 및 구현)

  • Kim, Whi-Young
    • Journal of the Korea Computer Industry Society
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    • v.7 no.5
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    • pp.563-572
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    • 2006
  • Advantage that light transmission treatment way of most suitable through skin can investigate light directly in part ar there is difference in ability photoelectricity month by diverse complexion of horn character department which is branch or head of a family outside part of skin and treatment according to various patient can be inappropriate. By result that this research uses color information after search each color ingredient that ingredient of HIS and YIQ that use method, color information to use skin impedance way and color information through skin area ion and difference video to do fixed measuring by light investigation way by skin impedance corresponds to skin color in an experiment though is most universal result according to patient's skin model area detection each single person's skin model through videotex automatically create and because measuring, investigate skin color, energy, wave length, approximately, transmission time, model of most suitable that draw pulse delay and so on and want and special quality, and saved standard of disease treatment pulse modeling by skin impedance, and design and manufacture light investigation pulse modeling system of most suitable by skin subordinate, and constructed suitable treatment pulse database by skin color.

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Feature Vector Extraction for Solar Energy Prediction through Data Visualization and Exploratory Data Analysis (데이터 시각화 및 탐색적 데이터 분석을 통한 태양광 에너지 예측용 특징벡터 추출)

  • Jung, Wonseok;Ham, Kyung-Sun;Park, Moon-Ghu;Jeong, Young-Hwa;Seo, Jeongwook
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2017.10a
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    • pp.514-517
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    • 2017
  • In solar photovoltaic systems, power generation is greatly affected by the weather conditions, so it is essential to predict solar energy for stable load operation. Therefore, data on weather conditions are needed as inputs to machine learning algorithms for solar energy prediction. In this paper, we use 15 kinds of weather data such as the precipitation accumulated during the 3 hours of the surface, upward and downward longwave radiation average, upward and downward shortwave radiation average, the temperature during the past 3 hours at 2 m above from the ground and temperature from the ground surface as input data to the algorithm. We analyzed the statistical characteristics and correlations of weather data and extracted the downward and upward shortwave radiation averages as a major elements of a feature vector with high correlation of 70% or more with solar energy.

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A study on building spectral library for classification of algae species based on hyperspectral technique (초분광 영상 기반 조류종 분류를 위한 기초라이브러리 구축에 대한 연구)

  • Kim, Jong Min;Kim, Young Do;Kyun, Yeong Hwa;Kim, Dong Soo
    • Proceedings of the Korea Water Resources Association Conference
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    • 2020.06a
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    • pp.160-160
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    • 2020
  • 조류는 계절별 기상 및 수질 조건에 따라 규조, 녹조, 남조의 발생 및 천이가 이루어지는데 최근 기후 변화로 인해 출연종 별 발생 및 천이의 시기 또한 빨라지고 있다. 이 중 남조류의 경우 초여름에 발생하여 급격한 증식으로 대발생되어 녹조현상을 야기하고 이는 해당 수역의 생태계 파괴, 그 이외에도 사회적, 경제적, 환경적인 측면에서 많은 문제를 유발한다. 하천·호소의 조류의 발생과 거동에 대한 이해와 효과적인 대응책 마련을 위하여 현상에 대한 모니터링이 선행되어야 하지만 기존 조사방식은 점, 선 단위의 간헐적 측정을 통해 진행되고 있어 많은 인력과 시간이 필요로 하고 있는 실태이다. 현재 이에 따른 문제 해결을 위한 하천·호소의 원격탐사 기법을 이용한 조류의 발생 및 거동에 대한 모니터링 연구가 많이 진행되고 있다. 본 연구에서는 초분광 영상을 이용한 원격 탐사 모니터링을 위한 선행연구를 위해 400-1000 nm에서 NIR(visNIR)파장을 분석할 수 있는 초분광 카메라 CORNING사의 micro HSITM 410 shark와 영상 흔들림 보정을 위한 DJI사의 로닌-MX를, 이용하여 현재 녹조류, 남조류 5종의 배양액과 방사보정을 위해 99% 반사율의 반사판과 함께 촬영하여 영상을 수집하였다. 수집된 영상을 통하여 방사보정 및 해당 Base 제거를 통한 조류의 분광 정보 추출 과정을 통해 조류별 분광 정보를 추출, 분석하여 해당 조류의 분광특성을 파악하고 기초 라이브러리를 구축하여 제시함으로 추후 하천·호소에서의 초분광 영상 기반 원격탐사 모니터링에 적용하고자 한다.

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