• Applied Chemistry for Engineering
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• v.32 no.4
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• pp.467-471
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• 2021

A ladder-like polysilsesquioxane (LPMA64) functionalized with a crosslinkable group was synthesized and used for the preparation of organic-inorganic hybrid gel polymer electrolytes through a thermal crosslinking process of the liquid electrolytes. A small weight percent of LPMA64 polymer crosslinker (5 wt%) was able to form a well-developed network structure, resulting in good dimensional stability with high ionic conductivity. The lithium-sulfur batteries fabricated with organic-inorganic hybrid gel polymer electrolytes exhibited stable C-rate and cycling performance with excellent Coulombic efficiency due to the alleviated lithium polysulfide shuttling effect during prolonged cycling. The result demonstrates that the organic-inorganic hybrid gel polymer electrolytes could be a promising candidate electrolyte for application in lithium-sulfur batteries.

• Food Science and Industry
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• v.52 no.4
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• pp.375-386
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• 2019

Carbohydrates play an important role in not only providing the body with calories but also giving taste and texture in foods. Recently, there is a growing interest in low-calorie carbohydrate materials due to obesity and the resulting diseases caused by excessive intake of calories. Polydextrose and sugar alcohols have calories of 2.0 kcal/g and 2.4 kcal/g, respectively. In addition to being a low-calorie material, polydextrose can be widely used as a dietary fiber source, thereby reducing calories and supplementing fiber. Sugar alcohols have sweetness comparable to a table sugar but they are not calculated as a sugar, so it can meet the government's sugar reduction policy. Also, polydextrose and sugar alcohols are not easily decomposed by heat and acid, and thus can be used without being affected by food manufacturing processes.

• Membrane Journal
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• v.31 no.3
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• pp.184-199
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• 2021

As a branch of covalent organic frameworks (COF), covalent triazine frameworks (CTF) are inherently porous structures composed of networks of repeating hexagonal triazine rings fabricated via the ionothermal trimerization reaction. They also contain plenty of nitrogen functional groups that increase affinity for some chemicals while rejecting others. Because of their tunable properties, many researchers have synthesized and tested CTFs for gas and liquid separation processes. Various studies of novel CTFs, mixed CTF composites, and CTF membranes have experimented for gas adsorption/separation (e.g., CO₂, C₂H₂, H₂, etc.) and desalination. Some CTF studies have determined the limits and potentials through advanced computer simulations while subsequent experiments have tested CTFs for photocatalytic properties, suggesting recyclability for greater sustainability. In this review, the covalent triazine framework-based separation membrane is discussed.

• Resources Recycling
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• v.30 no.4
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• pp.46-53
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• 2021

Biomass can be considered as chemical energy obtained from nature, and includes all living organisms such as plants, animals, and microorganisms. Biomass is eco-friendly, is easily obtainable from the environment, and can be recycled without special treatment processes. Biomass can also be converted into bioenergy fuel through pyrolysis and fermentation. Therefore, it has been considered as a renewable energy source, which prevents the depletion of natural resources such as fossil fuels. In this study, torrefaction to increase the carbon content in various types of biomass sources (sawdust, rice straw, rice bristles, coffee ground, and waste wood) was conducted under an inert atmosphere and at a temperature of 523~573K. The possibility of using torrefied biomass as an alternative to solid fuel for industrial purposes was analyzed by examining the carbon concentration and combustion behaviors.

• The Journal of the Convergence on Culture Technology
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• v.8 no.2
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• pp.337-342
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• 2022

Although printing technology has recently been widely used in IT fields including displays and fuel cells, residual and thermal stress are generated by a manufacturing process of stacking the layers of the print head and result in the substrate deformation and nozzle plate crack, which may cause ink leaks or not be ejected onto a desired region. Therefore, in this paper, we propose a new design of thermal inkjet print head with a robust and reliable structure. Diverse types of inkjet print head such as a rib, pillar, support wall and individual feed hole are designed to reduce the deformation of the substrate and nozzle plate, and their feasibility is numerically investigated through FEA analysis. The numerical results show that the maximum stress and deformation of proposed print head dramatically drops to at least 40~50%, and it is confirmed that there is no nozzle plate cracks and ink leakage through the fabrication of pillar and support wall typed print head. Therefore, it is expected that the proposed head shape can be applied not only to ink ejection in the normal direction, but also to large-area printing technology.

• Journal of Environmental Science International
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• v.31 no.7
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• pp.637-652
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• 2022

In this study, the contributions of emissions (foreign and domestic) and atmospheric physical and chemical processes to PM_2.5 concentrations were evaluated during a high PM_2.5 episode (March 24-26, 2018) observed on the Jeju Island in the spring of 2018. These analyses were performed using the community multi-scale air quality (CMAQ) modeling system using the brute-force method and integrated process rate (IPR) analysis, respectively. The contributions of domestic emissions from South Korea (41-45%) to PM_2.5 on the Jeju Island were lower than those (81-89%) of long-range transport (LRT) from China. The substantial contribution of LRT was also confirmed in conjunction with the air mass trajectory analysis, indicating that the frequency of airflow from China (58-62% of all trajectories) was higher than from other regions (28-32%) (e.g., South Korea). These results imply that compared to domestic emissions, emissions from China have a stronger impact than domestic emissions on the high PM_2.5 concentrations in the study area. From the IPR analysis, horizontal transport contributed substantially to PM_2.5 concentrations were dominant in most of the areas of the Jeju Island during the high PM_2.5 episode, while the aerosol process and vertical transport in the southern areas largely contributed to higher PM_2.5 concentrations.

• Journal of Korea Foundry Society
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• v.43 no.4
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• pp.187-193
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• 2023

Shell core making is an excellent process in terms of formability and desanding, but when the molten aluminum comes into con- tact with the shell core, gas generation by pyrolysis of the resin is inevitable. In addition, when the ventilation is inadequate, pores will remain inside the casting, which can directly lead to defects of the casting. While studies on the gas generation behavior of shell core making have been reported, the modeling of gas generation has not been extensively investigated. We will develop a gas evolution analysis method that considers the relationship between temperature and gas quantity for the core to be developed. We then use the developed method to analyze the flow and solidification behavior of metal molten metal during core mold design and low-pressure casting of cylinder head products, and predict the occurrence of casting defects to derive a casting method that min- imizes the occurrence of defects.

• Journal of Korea Foundry Society
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• v.43 no.4
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• pp.194-200
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• 2023

The heat transfer of the mold in the casting process has been calculated by considering the mold as a uniform isotropic material. Since the mold was not a uniform isotropic material, however, the calculation was performed with approximate values, and in particular, estimated values were used when considering compaction and the amount of added binder. In this study, a calculation algorithm of the thermal properties of the sand mold was developed. An algorithm for calculating the thermal conductivity and specific heat based on a thermal resistance model in the case of mono-dispersed sand grains was also developed and applied to sand molds with various size distributions. The thermal properties of sand were calculated for artificial sand, and relatively close values compared to the experimental values were obtained.

• Transactions of the Korean hydrogen and new energy society
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• v.34 no.3
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• pp.256-266
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• 2023

Hydrogen production can be classified based on the energy source, primary reactor type, and whether or not it emits carbon dioxide. Utilizing color representation proves to be an effective means of expressing these distinctive characteristics. Among the various clean hydrogen production techniques, there has been a growing interest in turquoise hydrogen production, which involves the decomposition of methane or other fossil fuels. This method offers advantages in terms of large-scale production and cost reduction through the sale of solid-carbon byproduct. In this study, an extensive literature review was conducted to select and analyze several promising candidates for turquoise hydrogen production processes. The efficiency and economics of these processes were evaluated using stream data reported in the literature sources. The findings indicate that the levelized cost of hydrogen production (LCOH) is significantly influenced by the sales of byproducts, specifically the solid-carbon and carbon monoxide byproducts.

• Korean Journal of Materials Research
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• v.33 no.11
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• pp.475-481
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• 2023

Recently, the electron transport layer (ETL) has become one of the key components for high-performance perovskite solar cell (PSC). This study is motivated by the nonreproducible performance of ETL made of spin coated SnO₂ applied to a PSC. We made a comparative study between tin oxide deposited by atomic layer deposition (ALD) or spin coating to be used as an ETL in N-I-P PSC. 15 nm-thick Tin oxide thin films were deposited by ALD using tetrakisdimethylanmiotin (TDMASn) and using reactant ozone at 120 ℃. PSC using ALD SnO₂ as ETL showed a maximum efficiency of 18.97 %, and PSC using spin coated SnO₂ showed a maximum efficiency of 18.46 %. This is because the short circuit current (Jsc) of PSC using the ALD SnO₂ layer was 0.75 mA/cm² higher than that of the spin coated SnO₂. This result can be attributed to the fact that the electron transfer distance from the perovskite is constant due to the thickness uniformity of ALD SnO₂. Therefore ALD SnO₂ is a candidate as a ETL for use in PSC vacuum deposition.