• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.12 no.1
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• pp.7-17
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• 2014

Molten salt electrorefining process achieves uranium deposits at cathode using an electrochemical processing of spent nuclear fuel. In order to recover pure uranium from cathode deposit containing about 30wt% salt, the adhered salt should be removed by cathode process (CP). The CP has been regarded as one of the bottle-neck of the pyroprocess as the large amount of uranium is treated in this step and the operation parameters are crucial to determine the final purity of the product. Currently, related research activities are mainly based on experiments consequently it is hard to observe processing variables such as temperature, pressure and salt gas behavior during the operation of the cathode process. Hence, in this study operation procedure of cathode process is numerically described by using appropriate mathematical model. The key parameters of this research are the amount of evaporation at the distillation part, diffusion coefficient of gas phase salt in cathode processor and phase change rate at condensation part. Each of these conditions were composed by Hertz-Langmuir equation, Chapman-Enskog theory, and interphase mass flow application in ANSYS-CFX. And physical properties of salt were taken from the data base in HSC Chemistry. In this study, calculation results on the salt gas behavior and optimal operating condition are discussed. The numerical analysis results could be used to closely understand the physical phenomenon during CP and for further scale up to commercial level.

• KSBB Journal
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• v.10 no.1
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• pp.97-104
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• 1995

A computer simulation of biochemical process was carried out using Macintosh-based BioDesignerTM developed at Bioprocess and Engineering Center(BPEC) of MIT. Based on the assumptions and flask culture experiments, a porcine growth hormone (PGH, Porcine Somatotropin) production process was simulated by a two-stage continuous culture. The economical and sensitivity analyses were evaluated for the scale-up production of PGH. A high return on investment (ROI, 104%/year) suggested that the process be profitable. However, sensitivity analysis indicated that ROI was dependent on the yield of PGH, selling price, dose and the achievement of projected market penetration.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1993.11a
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• pp.57-63
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• 1993

냉열발전기술은 일본에서 많이 연구되어 다수의 상업 플랜트가 가동되고 있다. 일본에서는 천연가스 공급압력의 이원화(40 kgf/$\textrm{cm}^2$, 10 kgf/$\textrm{cm}^2$)로 직접 팽창방식을 적용할 수 있어 냉열발전의 경제성이 유리한 반면 국내에서는 비교적 높은 압력(70kgf/$\textrm{cm}^2$)의 단일 압력 공급체계에 적합한 냉열발전 시스템을 모색하여야 한다. 특히 발전용량 규모가 비교적 적은 냉열발전 시스템의 경제성 측면의 불리한 점을 고려할 때 적용 가능한 해당 발전공정들에 대해 전산모사의 방법을 이용하여 다양한 설계조건에서 최적의 조건들을 검토하여야 한다. 따라서 본 연구에서는 LNG의 저온 Exergy를 이용한 Rankine Cycle, LNG의 압력 Exergy를 이용한 부분팽창 Cycle 및 이 두 싸이클의 혼합 공정인 Linde 공정에 대해 현재 인수기지에서 운영되고있는 각종 설비들의 설계 데이타를 기준으로 상용모사기인 ASPEN PLUS를 이용, 국내 천연가스 공급 체계에 의거 각 공정별 최대 및 최적의 전력 발생 조건들을 검토하였다. 공정별 출력 및 엑서지 효율을 비교한 결과 약 3 ~ 6 Mw의 전력을 생산할 수 있음을 알 수 있었으며 최대 엑서지 효율은 37 %를 얻을 수 있었다. 또한 부분직접팽창방식의 최적시스템을 제시하였고 동일한 전열면적인 경우 부분직접팽창과 랭킨 싸이클의 성능은 비슷한 것으로 확인되었다.

• Journal of Soil and Groundwater Environment
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• v.13 no.1
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• pp.32-42
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• 2008

A surfactant recovery and reuse process by selective adsorption with activated carbon was proposed to reduce surfactant cost in a soil washing process. Mathematical model simulation was performed for the whole process, which consists of soil washing, soil recovery, and soil re-washing. The optimal range of surfactant dosage was $6{\sim}10$-fold critical micelle concentration in soil. The efficiency of surfactant reuse process was decreased with increasing the dosage of activated carbon. Effectiveness factor for activated carbon significantly altered the efficiency of the reuse process unlike effectiveness factor for soil. Total requirement of surfactant was reduced to 20-30% with the reuse process compared to the conventional soil washing process. The contamination of wastewater after soil washing was reduced with the reuse process. This mathematical model can be used to estimate performance of the whole process of soil washing including surfactant recovery and to obtain optimal ranges of operating conditions without extra labor-intensive experimental works.

• Korean Chemical Engineering Research
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• v.46 no.4
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• pp.739-746
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• 2008

The aim of this study is finding the optimal design parameters and the optimal operation variables of a reactive distillation column. Different from steady state optimization, dynamic optimization makes it possible considering operation ability as well as design problems at process design step. For performing dynamic optimization, dynamic simulation should be done first. If dynamic simulation is already finished, dynamic optimization can be performed with less effort than that of dynamic simulation.Reactive distillation systems involving reaction and separation in a single unit have the potential to reduce capital and operating costs, particularly when reaction have conversion constraint or when azeotropes exist making conventional separation difficult and expensive. This study here present work on the continuous distillation process, the homogeneous catalyzed esterification of methanol and acetic acid, the synthesis of methyl acetate. Based on an equilibrium stage model of a reactive distillation column a dynamic optimization problem was formulated and solved. And the results were verified by performing dynamic simulation and showing the variation of conversion and purity as the variation of the operation variables. As the results of dynamic optimization, this study found optimal feed ratio, reflux ratio and reboiler duty of this system. And as this study applied it to dynamic simulations the dynamic characteristics of a reactive distillation column are showed under optimal operating condition.

• Journal of Korea Foundry Society
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• v.42 no.5
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• pp.273-281
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• 2022

In order to understand the solidification behavior and microstructural evolution of the Al-Cu-Si ternary eutectic alloy system, changes of the microstructure of the Al-Cu-Si ternary eutectic alloy with different cooling rates were investigated. When the mold preheating temperature is 500℃, primary Si and Al2Cu dendrites are observed, with (α-Al+Al2Cu) binary eutectic and needle-shaped Si subsequently observed. In addition, even when the mold preheating temperature is 300℃, primary Si and Al2Cu dendrites can be observed, and both (α-Al+Al2Cu+Si) areas observed and areas not observed earlier appear. When the mold preheating temperature is 150℃, bimodal structures of the binary eutectic (α-Al+Al2Cu) and ternary eutectic (α-Al+Al2Cu+Si) are observed. When the preheating temperature of the mold is changed to 500℃, 300℃, and 150℃, the greatest change is in the Si phase, and upon reaching the critical cooling rate, the ternary eutectic of (α-Al+Al2Cu+Si) forms. If the growth of the Si phase is suppressed upon the formation of (α-Al+Al2Cu+Si), the growth of both Al and Cu is also suppressed by a cooperative growth mechanism. As a result of analyzing the Al-27wt%Cu-5wt%Si ternary eutectic alloy with a different alloy design simulation programs, it was confirmed that different results arose depending on the program. A computer simulation of the alloy design is a useful tool to reduce the trial and error process in alloy design, but this effort must be accompanied by a task that increases reliability and allows a comparison to microstructural results derived through actual casting.

• Journal of Korean Society of Environmental Engineers
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• v.39 no.8
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• pp.489-493
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• 2017

Microbial fuel cells (MFC) are bio-electrochemical processes that can convert various organic materials present in wastewater into electrical energy. For scaling-up and practical application of MFC, it is necessary to investigate the effect of anode size, electrode distance, and total area of anode on substrate degradation. Spaced electrode assembly (SPA) type microbial fuel cell with multiple anodes treating domestic wastewater was used for simulation. According to computer simulation results, the shorter the distance between electrodes than the size of single electrode, the faster the substrate degradation rate. Particularly, when the total area of the anode is large, the substrate decomposition is the fastest. In this study, it was found that the size of the anode and the distance between the electrodes as well as the cathode electrode, which is known as the rate-limiting step in the design of the microbial fuel cell process, are also important factors influencing the substrate degradation rate.

• Journal of the Korean Society for Nondestructive Testing
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• v.30 no.1
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• pp.20-30
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• 2010

In this paper, a new tomographic scan method with fixed installed detectors and rotating source from gamma projector was presented to diagnose the industrial plants which were impossible to be examined by conventional tomographic systems. Weight matrix calculation method which was suitable for volumetric detector and statistical iterative reconstruction method were applied for reconstructing the simulation and experimental data. Monte Carlo simulations had been performed for two kinds of phantoms. Lab scale experiment with a same condition as one of phantoms, had been carried out. Simulation results showed that reconstruction from photopeak counting measurement gave the better results than from the gross counting measurement although photopeak counting measurement had large statistical errors. Experimental data showed the similar result as Monte Carlo simulation. Those results appeared to be promising for industrial tomographic applications, especially for petrochemical industries.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.10 no.11
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• pp.3253-3259
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• 2009

In this study, a computer simulation has been performed for the refrigeration cycle using mixed refrigerants in order to decrease the process stream temperature to $-20^{\circ}C$. Refrigerant supply temperature was assumed to be $-30^{\circ}C$ considering the temperature difference as $10^{\circ}C$ with process stream. Peng-Robinson equation of state model was selected for the computer simulation. A new alpha function proposed by Twu et al was used for an accurate prediction of pure component vapor pressure experimental data. One fluid mixing rules were used for the estimation of mixture vapor-liquid equilibria calculations. A commercial process simulator, PRO/II with PROVISION was utilized for the simulation of the overall refrigeration process. In order to minimize the compressor power consumption, we have optimized the two-stage compression system by varying the first stage compressor outlet pressure. Finally, we could obtain the minimum total power 755.7kW at the first stage compressor outlet pressure, 6 bar.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.9
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• pp.4643-4651
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• 2013

In this study, we have surveyed the new technologies in the cryogenic distillation of ITER, equilibrium reactors and helium refrigeration cycle contained in the isotope separation system (ISS). We also have collected thermodynamic and transport properties for $H_2$, HD, $D_2$, HT, DT and $T_2$ components of which properties are not built in a general purpose chemical process simulators such as Aspen Plus and PRO/II with PROVISION. Verification works have been performed to compare between literature data and simulation results. For the simulation of ISS involving six hydrogen isotope components, four distillation columns and two equilibrium reactors are used for the separation of $D_2$ and DT from $T_2$.