• Title/Summary/Keyword: 공정능력분석

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Change of Particle Size of Magnesium Silicate According to Reaction Conditions and Evaluation of Its Polyol Purification Ability (반응 조건에 따른 규산마그네슘의 입도 변화 및 폴리올 정제 능력평가)

  • Yoo, Jhongryul;Jeong, Hongin;Kang, Donggyun;Park, Sungho
    • Korean Chemical Engineering Research
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    • v.58 no.1
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    • pp.84-91
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    • 2020
  • The efficiency of the synthetic magnesium silicate used in basic polyols and edible oil purification is evaluated by its purification ability and filtration rate and is affected by the particle size and surface area of magnesium silicate. In this study, it was investigated the change on the particle size of magnesium silicate was influenced by the reaction temperature, injection rate, injection order (Si, Mg) and Mg/Si reaction mole ratio. The synthesized magnesium silicate was compared and analyzed for the synthesis, grinding, and refining processes. In the synthesis process, the reaction temperature and feed rate did not affect the average particle size change of magnesium silicate, while the reaction molar ratio of Mg / Si and the order of injection acted as main factors for the change of average particle size. The average particle size of magnesium silicate increased by 8.7 ㎛ from 54.4 ㎛ to 63.1 ㎛ at Mg injection when Mg molar ratio increased from 0.125 to 0.500, and increased by about 4.8 ㎛ from 47.3 ㎛ to 52.1 ㎛ at Si injection. The average particle size according to the order of injection was 59.1 ㎛ for Mg injection and 48.4 ㎛ for Si injection and the difference was shown 10.7 ㎛, therefore the filtration rate was about 2 times faster under the condition of Mg injection. That is, as the particle size increases, the filtration time is shortened and washing filtration rate can be increased to improve the productivity of magnesium silicate. The cake form of separated magnesium silicate after filtration becomes a solid through drying process and is used as powdery adsorbent through the grinding process. As the physical strength of the dried magnesium silicate increased, the average particle size of the powder increased and it was confirmed that this strength was affected by the reaction molar ratio. As the reaction molar ratio of Mg / Si increased, the physical strength of magnesium silicate decreased and the average particle size after grinding decreased by about 40% compared to the average particle size after synthesis. This reduction of strength resulted in an improvement of the refining ability due to the decrease of the average particle size and the increase of the amount of fine particle after the pulverization, but it resulted in the decrease of the purification filtration rate. While the molar ratio of Mg/Si was increased from 0.125 to 0.5 at Mg injection, the refining ability increased about 1.3 times, but the purification filtration rate decreased about 1.5 times. Therefore, in order to improve the productivity of magnesium silicate, the reaction molar ratio of Mg / Si should be increased, but in order to increase the purification filtration rate of the polyol, the reaction molar ratio should be decreased. In the synthesis parameters of magnesium silicate, the order of injection and the reaction molar ratio of Mg / Si are important factors affecting the changes in average particle size after synthesis and the changes of particle size after grinding due to the changes of compressive strength, therefore the synthetic parameter is an important thing that determines productivity and refining capacity.

Process Optimization of Peptides Production from Protein of Sea Cucumber and Its Antioxidant Capacity Analysis (해삼 단백질로부터 펩타이드 제조 최적공정 확립 및 항산화 특성)

  • Ha, Yoo Jin;Yoo, Sun Kyun
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.2
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    • pp.338-348
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    • 2017
  • Protein hydrolysates derived from plants and animals having antioxidant, suppression of hypertension, immunodulatory, alleviation of pain, and antimicrobial activity has been known as playing important role like hormone. This study was performed to optimize the hydrolysis of protein of sea of cucumber by a flavourzyme. The ranges of processes were the reaction temperature of 40 to $60^{\circ}C$, pH 6 to 8, and enzyme concentration 0.5 to 1.5%(w/v). As a result, the optimization of process was determined at temperature of $48-50^{\circ}C$, pH of 7.0-7.2, and enzyme concentration of 1.0-1.1%(w/v), and degree of hydrolysis was 43-45 at above conditions. The molecular weight of hydrolysate was distributed to 500-3,500 Da and showed typical peptides. Inhibition concentration ($IC_{50}$) of peptides of DPPH radical scavenging activity, Superoxide anion radical scavenging activity, Hydroxy radical scavenging activity, $Fe^{2+}$ cheating activity was 1.25, 3.40, 10.3, and 22.11 mg/mL, respectively. Therefore, we expect that those products are useful as functional food ingredients.

The effect of technology capability of product development process on R&D sales performance: Focusing on the moderating effect of government support by the growth stage (제품개발공정의 기술능력이 R&D 매출 성과에 미치는 영향: 성장단계별 정부지원의 조절효과를 중심으로)

  • Kim, Sunyoung;Ba, Kuk Jin;Park, Sangmoon;Choi, Yun Jeong
    • Journal of Technology Innovation
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    • v.22 no.4
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    • pp.235-259
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    • 2014
  • New product or new technology developments are directly linked to a firm's survival and thus their performance and improvement are gaining attention in the midst of rapidly changing business environment and aggravating competition. However, despite SMEs' significance in the national economy, they are limited in terms of size and resources in possession, so the government provides a variety of supports as a policy. According to a study on the organizational life cycle, a firm's limits and difficulties differ by growth stage, so the supports need to be tailored. Based on the data from 2,575 firms that responded to the "2011 SMEs Technological Statistics," how technological capability level and deviation in the R&D process affect the R&D sales performance was studied. The result of analysis revealed that the technological capability has a positive impact on the R&D sales performance. It was also learned that the relationship between deviation in the technological capability and R&D sales performance was moderated by the government support. For the hypothesis that the government support would have a different moderating effect by growth stage for the impact the technology level has on the R&D sales performance, the empirical analysis showed a different meaningful moderating effect for each growth stage. The theoretical implications of the study are that, instead of a simple relation of dynamics that does not take the growth stages into account, it suggested a more realistic causal relationship model that reflects the complex environment the SMEs are in and that the need for measuring and using the deviation in technological capability as a research variable has been justified. The practical implications are that the government policy for supports can be tailored to a growth stage and that the guidelines have been suggested to effectively use the government funding by encouraging the SMEs in a different growth stage to adapt to the customized policy.

Modelling of Nitrogen Oxidation in Aerated Biofilter Process with ASM3 (부상여재반응기에서 ASM3를 이용한 질산화 공정 모사)

  • Jun, Byonghee
    • Journal of the Korean GEO-environmental Society
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    • v.8 no.4
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    • pp.19-25
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    • 2007
  • Process analysis with ASM3 (Activated Sludge Model3) was performed to offer basic data for the optimization of aerated biofilter (ABF) process design and operation. This study was focused on the simulation of the nitrification reaction in ABF which was a part of the advanced nutrient treatment process using bio-adsorption. The ABF process has been developed for the removal of suspended solids and nitrification reaction in sewage. A GPS-X (General Purpose Simualtor-X) was used for the sensitivity analysis and operation assessment. Sensitivity of ASM3 parameters on ABF was analysed and 4 major parameters ($Y_A$, $k_{sto}$, ${\mu}_A$, $K_{A,HN}$) were determined by dynamic simulation using 70 days data from pilot plant operation. The optimized values were 0.14 for $Y_A$, 3.5/d for $k_{sto}$, 2.7/d for ${\mu}_A$ and 1.1 mg/L for $K_{A,HN}$, respectively. Simulation with optimized parameter values were conducted and TN, $NH_4{^+}-N$ and $NO_3{^-}-N$ concentrations were estimated and compared with measured data at the range of 10 min to 4 hrs of hydraulic retention time (HRT). The simulated results showed that optimized parameter values could represent the characteristics of ABF process. Especially, the ABF showed relatively high nitrification rate (60%) under very short HRT of 10 min. As a consequence, the ABF was thought to be successfully used in the site which having high variation of influent loading rate.

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유연소재 천 기반의 슈퍼캐패시터 저장체의 전기화학적 성능 향상

  • Yun, Tae-Gwang;O, Min-Seop;Hu, Liangbing;Hyeon, Seung-Min;Han, Seung-Min
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.697-698
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    • 2013
  • 최근에 유연한 성질을 갖는 전자기기들의 수요가 증가하면서, 그에 따라서 유연 전자기기를 뒷받침 해줄 수 있는 에너지 저장체의 유연한 성질도 중요성이 점점 부각되고 있으며 많은 연구가 진행되고 있다. 유연한 에너지 저장체의 많은 연구들이 유연한 금속 박막이나 특수 공정처리가 필요한 고분자를 이용하고 있으나, 대부분의 유연 에너지 소자들은 에너지 저장체의 성능에 비해 고온과 산 약품과 같은 환경이 필요하며, 비용과 시간이 많이 소모되고 있다. 그에 반해 섬유는 앞에서와 같이 특수 공정 처리가 따로 필요하지 않으며 상온에서도 손 쉽게 이용 가능하며, 신축성이 뛰어난 장점이 있기 때문에 효율적, 비용적으로 유연한 에너지 저장체에 유리한 소재이다. 몸에 해로운 산과 같은 약품처리의 필요도 없으며, 용매를 흡수하는 능력이 뛰어나기 때문에 용매를 이용한 도포 방법을 사용하면 다양한 물질을 폭넓게 적용 가능하다. 그리고 적용 분야에 맞춰서 섬유의 종류를 조절하면 다양한 성질을 갖는 천 기반의 에너지 저장체가 형성되며, 면 섬유가 수소 결합과 높은 반데르 발스 결합에 의해 탄소나노튜브와 결합하여 높은 에너지 밀도를 갖는 에너지 저장체를 형성하는 것을 분석한 논문들도 보고되고 있다. 면 섬유의 특수한 성질을 이용하여 에너지 저장체를 제작하고 이를 확인하기 위해서 일반 합성 섬유인 polyester와 면 섬유를 비교 제작하였으며, 용매의 형태로 손쉽게 도포 가능한 물질은 탄소 계열의 활물질들이며, 탄소 나노 튜브나 그래핀 등이 분산된 용액을 이용해 천에 도포 가능하다. 탄소 계열의 활물질들은 대표적인 슈퍼캐패시터 물질이며, 천에 도포를 함으로써 천 기반의 슈퍼캐패시터를 제작하였다. 일반 합성 섬유 polyester와 CNT를 결합한 형태의 전극은 최대 에너지 축전 용량(Maximum specific capacitance)이 53.6 F/g으로 나타났으며, 면 섬유와 CNT를 결합한 형태의 전극은 최대 에너지 축전 용량이 122.1 F/g으로 나타났다. 따라서 면 섬유에서 높은 에너지 저장 능력을 보이는 것을 실험적으로 확인하였으며, 에너지 저장 능력이 뛰어난 면 섬유를 다음 전극 디자인에서도 일률적으로 적용하였다. 슈도캐패시터의 대표적 물질인 금속 산화물인 망간 산화물(MnO2)을 3전극 도금 시스템을 이용하여 에너지 축전 용량과 에너지 밀도를 올리는 전극을 제작하였다. 특히 망간 산화물의 형태는 표면적을 극대화하기 위해서 평균 지름은 200~300 nm 정도 되는 나노 입자의 형태로 제작하였다. 그 결과, 확연하게 에너지 축전 용량이 향상되었으며, 최대 에너지 축전 용량은 282.0 F/g, 에너지전력 밀도는 14.2 Wh/kg으로 나타나서 금속 산화물의 형태가 주는 효과를 확인할 수 있었다. 하지만 나노 입자의 형태로 제작된 금속 산화물은 문제점이 발생하였다. 금속 산화물의 전기 전도성이 매우 낮기 때문에, 전기 전도성에 비례해서 전력 밀도의 값이 표현되는데, 전기 전도성이 급격히 감소하기 때문에 전력 밀도도 급격한 감소가 나타난다. 다음과 같이 전기 전도성 물질을 첨가하는 방법은 추가의 공정이 필요한 단점이 있지만 오직 기계적인 인장응력만을 가해서 에너지 밀도와 전력 밀도를 증가시키는 전극을 제작하였다. 인장응력을 섬유 기반의 전극에 가했을 시에 가닥들간의 접촉 증가와 CNT가 정렬되면서 특정 변형률(strain) 이전에서는 전기 전도성이 최대 50% 이상 증가하는 것을 확인할 수 있었으며, 선행 연구에서 보고되었다. 이를 이용해서 전기 전도성과 직결되는 전력 밀도의 양도 증가시키고 에너지 밀도의 증가 여부까지 확인한 결과 인장을 가하기 전 면 섬유의 전력 밀도와 에너지 밀도는 6.4 kW/kg and 6.1 Wh/kg으로 나타났으나 30% 변형 인장 후에는11.4 kW/kg과 7.1 Wh/kg으로 나타났다. 그리고 망간 산화물을 첨가한 전극 역시 4.9 kW/kg과 14.2 Wh/kg으로 나타났었으나 인장 이후 전력 밀도는 14.2 kW/kg, 에너지 밀도는 17.6 Wh/kg으로 확연하게 증가한 것을 확인하였다.

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월성1호기 중수증기 회수계통 운전원의 운전능력 향상

  • 박종범;양승권
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.11a
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    • pp.121-126
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    • 1996
  • 월성1호기의 경우 운전원이 중수증기 회수계통 현장 검사(Survey)에 약 3시간 정도를 소요하고 있으며, 자료의 분석과 수집을 위해 각 기기 제어반(Panel)에 기록계(Recorder)를 설치하여 기록된 기록지를 통해서 작업해야 만 한다. 이처럼 기존 설비의 경우 운전원은 많은 시간과 작업 부담을 갖고 운전하게 될 뿐만 아니라 다른 계통을 점검하는데 필요한 많은 시간을 얻기가 어려운 형편이다. 그러나 PLC SYSTEM 내의 한 부분인 공정감시제어를 위한 MMI(Man Machine Interface) SOFTWARE를 사용하여 조사할 경우 약 3분이면 중수증기회수 전 계통을 점검할 수 있고, 경향감시(Trend) 기능을 사용하면 기록계 설치 없이도 과거나 현재의 변화 추이 및 문제점 분석은 물론 계통 결함 발생시 발생되는 경보기능으로 운전원의 신속한 인지가 가능하게 된다.

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Performance Analysis comparisons for the CBT and PIM Multicast Protocol (CBT와 PIM 멀티캐스트 라우팅 프로토콜 비교에 관한 성능분석)

  • 최원혁;이광재;김정선
    • Proceedings of the Korea Multimedia Society Conference
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    • 2002.11b
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    • pp.649-652
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    • 2002
  • 멀티캐스트는 현재 일-대-글 통신서비스로부터 일-대-다 또는 다-대-다 통신서비스에서 신뢰성을 요구하는 새로운 요구가 많아지고 있다. 그리고 최근 대두되고 있는 멀티미디어 응용을 지원하기 위해서는 광대역 네트워크의 링크, 실시간 전송, 보다 효과적인 멀티캐스트 프로토콜이 요구된다. 멀티캐스트 프로토콜 알고리즘에는 DVMRP, MOSPF, CBT, PIM 구조의 멀티캐스팅 프로토콜 있다. 이는 네트워크 패킷의 특성을 송수신의 경로비용으로 라우터 자체의 근거리 알고리즘이 적용되고 있다. 본 연구에서는 멀티캐스트 프로토콜인 CBT와 PIM-DM종단간의 특징을 이용하여 비교 분석하여 이용하여 각 데이터 패킷 전송을 위한 공정하고 실용적인 대역폭 사용하고 대역폭과 데이터처리능력 시뮬레이션 상에서 구현하고 성능을 평가한다.

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The Influence of Problem-solving ability and Critical thinking on the Major Satisfaction of Dental Hygiene Student -Focused on Mediating Effects of Critical Thinking- (치위생 전공 학생의 문제해결능력과 비판적사고가 전공만족도에 미치는 영향 -비판적사고의 매개효과를 중심으로-)

  • Eom, Suk;Choi, Yu-Jin;Lee, Byung-Ho
    • Journal of the Korea Convergence Society
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    • v.10 no.12
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    • pp.151-158
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    • 2019
  • This study was conducted to identify the level of problem-solving ability, critical thinking and satisfaction level of students majoring in dental hygiene, and to identify the impact of problem-solving ability and critical thinking on major satisfaction levels. The research target collected data through a structured questionnaire for 259 students majoring in dental hygienics located in North and South Gyeongsang Province. The analysis results showed that the problem-solving ability of the study subjects was 2.56, critical accidents were 2.58, and the major satisfaction level was 2.32, and the problem-solving ability, critical thinking and major satisfaction level were positively correlated with each other. Among the lower factors of problem solving ability, solution performance and solution model were significant factors that could improve major satisfaction, and among the lower factors of critical thinking, intellectual fairness, intellectual passion/interest, and systematicness were significant factors that could improve major satisfaction. Critical thinking also significantly mediated problem solving ability and major satisfaction level (β=).2602, BCCI [.0908~.4529]). Based on the results, it is believed that dental hygiene education needs to be developed in addition to the establishment of an educational environment that can enhance the ability to solve problems and critical thinking, and that research should be continued to check its effects.

Purification of Lysozyme from Egg White by Multicycle Ion Exchange Chromatography (다중 이온교환크로마토그래피를 이용한 계란난백에서 리소짐의 분리)

  • 허윤석;김형원;김인호
    • KSBB Journal
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    • v.18 no.2
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    • pp.122-126
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    • 2003
  • Multi-cycle chromatographic separation of Iysozyme from egg white was investigated. Multi-cycle chromatography was performed by repeated cycling(one cycle: resin equilibration, sample loading, washing, elution). Two types of cation exchange resins, Cellufine CM C-200 and Bio-rex 70, were used to determine the optimum condition for the separation of Iysozyme by multi-cycle chromatography. The resin was equilibrated in 20 mM Na-phosphate buffer(pH 7.0). Chromatograms of UV absorbance levels of every cycle were compared to confirm the eluting ability of Iysozyme in the two types of gel. Collected samples from eluting regions in every cycle were assayed by 15% SDS-PAGE.

A Simulation-Based Capacity Analysis of a Block-Assembly Process in Ship Production Planning (시뮬레이션을 이용한 블록조립 공정 능력 분석)

  • Song, Young-Joo;Lee, Dong-Kun;Choe, Sung-Won;Woo, Jong-Hun;Shin, Jong-Gye
    • Journal of the Society of Naval Architects of Korea
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    • v.46 no.1
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    • pp.78-86
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    • 2009
  • A capacity calculation and process analysis is a very important part for the entire ship production planning. Ship's production plan is set up with a concept that the product is produced based on the capacity achievable by the processes while general manufacturing sets up the production plan based on product lead-time. Therefore, in case the calculation of capacity for each process of shipbuilding yard is different from actual conditions, a series of production plan - ship table composition, dual schedule plan and execution schedule plan, etc - may accumulate errors, lose reliability of planning information and cause heavy cost deficit in this course. In particular, in case of new shipbuilding yard, stocks between processes are built up and half blocks are not supplied in timely manner, and that is sometimes due to the clumsiness of the operator but it is more often because of the capacity to execute each process is not logically calculated. Therefore, this paper presents the process to calculate the assembly leadtime and assembly process capacity for shipbuilding yard assembly factory. This paper calculated the block type for calculation of assembly lead time based on block DAP(detailed assembly procedure), and introduced cases that calculate production capacities by assembly surface plate by considering the surface plate occupied area of the blocks that change depending on assembly field area and assembly processes through assembly simulation.