• Title/Summary/Keyword: 고팽창

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The Properties of Flow and Compressive Strength of Mortar According In Replacement Ratio of Rapidly-Chilled Steel Slag Pine Aggregate (급냉 제강 슬래그 잔골재 대체율에 따른 모르타르의 유동성 및 압축강도 특성)

  • Cho Sung-Hyun;Kim Jin-Man;Kim Moon-Han;Han Ki-Suk
    • Journal of the Korea Concrete Institute
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    • v.17 no.1 s.85
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    • pp.77-84
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    • 2005
  • The steel slag, a by-product which is produced by refining pig iron during the manufacture of steel, is mainly used as road materials after aging. It is necessary to age steel slag for long time in air because the reaction with water and free-CaO in steel slag could make the expansion of volume. This problem prevents steel slag from being used as aggregate for concrete. However, steel slag used in this study was controled by a air-jet method which rapidly cools substance melted at a high temperature. The rapidly-chilled method would prevent from generation of free-CaO in steel slag. This study dealt with the influence of the using rate of rapidly-chilled steel slag on flow, dosage of SP, W/C ratio, and strength of mortar by statistical experimental design. Also, the results of this experiment were approved by statistical analysis methods, such as analysis of variance and F-testing. As results of F-testing, this paper proved at $1\%$ level of significance that the more the using rate of rapidly-chilled steel slag increased, the more this affected the enhancement of flow, the decrease of dosage of SP and W/C ratio, and the development of compressive strength. Also, considering the fluidity and compressive strength of mortar, it is desirable to use $75\%$ of rapidly-chilled steel slag for river sand.

Industrial restructuring and uneven regional development in the 1980s (산업구조조정과 지역불균등발전 : 1980년대)

  • ;Choi, Byung-Doo
    • Journal of the Korean Geographical Society
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    • v.29 no.2
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    • pp.137-165
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    • 1994
  • Structural adjustment of industry (or industrial restructuring) seems to be inherent in the process of capitalist economic development, which tends to be proceeded with shifts from one stage to another in order to overcome structural crises generated in each stage. The structural adjustment of industry is necessarily accompanied with regional restructuring, since it is not only projected on spece, but also mediated by space. Such a restructuring necessitates industrial and uneven regional devlopment through which capital can seek excessive profits over the rate of socio-spatial average. The industrial restructuring and uneven regional development in the 1980s in Korea can be seen as a process in which capital attempted with a strong support of the govenment to overcome the crises in the end of 1970s and hence to go on rapid economic growth. In this process, capital, especially monopoly capital concentrated into few conglomerates, pursued both extensive expansion and intensive development of industry simultaneously. In results, the Korean economy could eliminate some of peripheral characters and maturate the Fordist accumulation system. The extensive expansion of the Korean industry in the 1980s was stimulated mainly through the enlargement and adjustment of investment for equipment facilities which was planned to exclude or rationalize traditional light industries on some places, and to continue rapid growth of key heavy-chemical industries, especially of fabricated metal industry, on other places. In this process, keeping mainly the existing developmental axis which polarized the Seoul Metroplitan region and the Southeast region in Korea, the enhancing spatial mobiiity of capital and the further differentiating division of labour enforced a tendency of concentration of all types of industry in the Seoul Metropolitan region, and at the same time provoked the diffusion of some industries over Jeolla and Chungchong regions in a considerable extent. The intensive development of industriai structure in the 1980s was pursued through the strategic encouragement of subcontracting small firms mainly which produced assembling components, the technical enhancement and factory (semi-) automation, and the enrichment of service industries for estate management, finance, distribution and retailing which supported and complemented the production of goods. In this process, enabling capital to extend and elaborate its domination over space through the reorganization of regulating systems, the Fordist division of labour generated a socio-spatial hierarchy in the nation-wide scale that characterized: the Seoul Metropolitan region as an overmaturated (or overarching) Fordist region performing the conceptive functions of management, research and development, in which all types of industry (including service industries) tended to be reconcentrated; Kyungsang region as a maturated Fordist region with excutive branches of large conglomerates and with subcontracting firms around them which produced standardized products through the automized production processes in secialized Fordist industries or rationalized traditional industries; and Jeolla and Chungchong regions as newly devloping Fordist regions with newly migrated branches and some subcontracting small firms-in relatively older Fordist industries or partly rationalized traditional industries. From these analyses, it can be argued that the structural adjustment of the Korean industry in the 1980s, which had carried out both through the extensive expansion and the intensive deveiopment, strengthened further uneven regional development process, even though it appears to have reduced apparently the economic and regional disparity by balancing numerically large and small firms and by extending the Fordist industrial space nation-wideiy. And it seems more persuasive to see that the Korean industrial structure in the 1980s maturated the Fordist system of accumulation, but not yet transformed towards the post-Fordist (or the so-called flexible) accumulation system, even though the Korean economy in the 1990s seems to be under a pressure of restructuring towards the latter system.

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Nano-Powder 제조를 위한 RF Thermal Plasma Torch System 개발 및 Nano-Si 특성 연구

  • Song, Seok-Gyun;Son, Byeong-Gu;Kim, Byeong-Hun;Lee, Mun-Won;Sin, Myeong-Seon;Choe, Seon-Yong;Kim, Seong-In
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.179-179
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    • 2012
  • 국내에는 나노 분말 제조를 위한 RF 열플라즈마 시스템 제조 기술이 확보되어 있지 않고, 또한 나노 파우더 제조를 위한 공정 기술 역시 외국 업체에 전적으로 의존하고 있다. 본 연구에서는 나노 분말 제조를 위한 RF 열 플라즈마 토치 시스템 개발과 고품질의 나노 파우더 합성 공정 기술을 확립하여 필요 기관에 제공하는데 있다. 80 kW RF Plasma torch system의 설계 및 제작을 위해 플라즈마 Simulator인 CFD-ACE+를 이용하여 플라즈마 토치 및 반응로 내의 온도 분포, 유체 유동, 열전달 등의 해석을 통해 플라즈마 토치 및 반응로의 반경 및 길이, 구조의 설계 값을 도출하여 반응로를 설계하여 RF 파워, RF 플라즈마 토치(Torch), 반응기(Reactor), 사이클론(Cyclone), 포집부(Collector), 열교환기 및 진공배기 시스템으로 구성하였다. Si 나노 소재의 경우, 이차전지 음극재에 적용이 가능한 대표적인 소재로서 높음 비용량과 충/방전시 부피팽창을 감소시킬 수 있어 이차전지의 고용량 구현을 위해서는 가장 중요한 소재중 하나로 많은 관심 재료로 평가 받고 있다. 따라서 본 연구에서는 상용화된 Si 원료 powder를 사용하여 고상 분체 공급 장치를 통하여 고온의 플라즈마를 통과시켜 기상화 및 결정화과정을 통해 Si 나노분말을 제조하였다. 공정 변수로서 공정압력 및 플라즈마 power, Gas의 변화량에 따른 나노 분말의 제조 특성에 대한 실험을 진행한 후 제조된 나노 분말을 비표면적측정(BET) 및 SEM 측정 결과 분석을 통하여 시스템 특성을 파악하였으며 제조된 Si 나노 파우더는 이차전지 음극재로서 770 mAh/g의 용량과 93%@50 cycle 수준의 유지율을 나타내었다.

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Synthesis of CO2 Adsorbent with Various Aminosilanes and its CO2 Adsorption Behavior (다양한 아미노실란을 이용한 이산화탄소 흡착제 합성 및 흡착 특성)

  • Jeon, Jae Wan;Ko, Young Soo
    • Applied Chemistry for Engineering
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    • v.27 no.1
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    • pp.80-85
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    • 2016
  • The carbon dioxide adsorption behavior of silica with a large specific surface area and pore volume functionalized with aminosilane compounds via in-situ polymerization and functionalization method were investigated. The organosilanes include amino functional group capable of adsorbing carbon dioxide. Elemental analyzer, in situ FT-IR and thermogravimetric analyzer were used to characterize the sorbents and to determine their $CO_2$ adsorption behavior. Comparison of different aminosilane loading in the support revealed that polyaminosilane functionalization of 70% of the pore volume in the support was better in terms of the adsorption capacity and amine efficiency than that of 100% of the pore volume of the support. Furthermore, the sorbents showed a higher adsorption capacity at an adsorption temperature of $75^{\circ}C$ than at $30^{\circ}C$ due to the thermal expansion of synthesized polyaminosilanes inside the pore of silica. The N-[3-(trimethoxysilyl)propyl]ethylenediamine (2NS) sorbent with 70% of the pore volume functionalized showed the highest adsorption capacity of 9.2 wt% at $75^{\circ}C$.

A study on the measurement of thermophysical properties of ${Al}_{2}{O}_{3}, {Si}_{3}{N}_{4}$ and SiC series by a single rectangular pulse heating (방향파 펄스 가열에 의한 ${Al}_{2}{O}_{3}, {Si}_{3}{N}_{4}$, SiC 계열의 열물성치 측정에 관한 연구)

  • 차경옥;장희석;이흥주
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.1
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    • pp.145-156
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    • 1990
  • In this study, thermophysical properties of the engineering ceramic materials such as $Al_{2}$O$_{3}$, Si$_{3}$N$_{4}$ and SiC were measured b y a single rectangular pulse heating method. The values of thermal diffusivities, specific heats, and thermal conductivities were measured as a function of temperature ranging form room temperature to 1300K. The measured thermal properties of one group of ceramic material were compared with those of other group and discussed in detail in connection with the chemical composition. Thus, some criteria for thermal design with the engineering ceramic materials were proposed.

Fabrication and Stability of Pd Coated Ta/YSZ Cermet Membrane for Hydrogen Separation (Pd 코팅된 Ta/YSZ 수소분리막의 제조 및 안정성)

  • Lee, Sang-Jin;Jeon, Sung-Il;Park, Jung-Hoon
    • Membrane Journal
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    • v.20 no.1
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    • pp.69-75
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    • 2010
  • Cermet membrane was fabricated with tantalum as hydrogen-permeable metal and $Y_2O_3$-stabilized $ZrO_2$ (YSZ) as ceramic supporter. Ta/YSZ cermet membrane was prepared through pre-sintering in He atmosphere and then main sintering under high vacuum and the impurities to originate from sintering and brazing could be removed by mechanical polishing. As-prepared membrane showed dense structure with continuous channel of tantalum. Hydrogen permeation experiment was conducted in the region of $200{\sim}350^{\circ}C$ using Ta/YSZ membrane coated with Pd for hydrogen dissociation. The crack in membrane was formed at $300^{\circ}C$ and the Pd coating layer has flaked off in spots. XRD results showed that tantalum reacted with hydrogen to form $Ta_2H$. The lattice expansion by $Ta_2H$ caused deterioration for membrane.

Preparation of Expanded Graphite using Perchloric Acid and It's Application as Anode Materials for High Power Li-ion Secondary Battery (과염소산을 이용한 팽창흑연의 제조 및 고출력 리튬이온전지 음극재로의 응용)

  • Park, Yul-Seok;Zheng, Hua;Kim, Myung-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.1
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    • pp.85-94
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    • 2011
  • Expanded graphites were used as anode materials of high power Li-ion secondary battery. The expanded graphite was prepared by mixing the graphite with $HClO_4$ as a intercalation agents and $KMnO_4$ as a oxidizing agents. The physical and electrochemical properties of prepared expanded graphites through the variation of process variables such as contents of intercalation agent and oxidizing agent, and heat treatment temperature were analyzed for determination of optimal conditions as the anode of high power Li-ion secondary battery. After examing the electrochemical properties of expanded graphites at the different preparing conditions, the optimal conditions of expanded graphite were selected as 8 wt.% of oxidizing agent, 400 g of intercalation agent for 20 g of natural graphite, and heat treatment at $1000^{\circ}C$. The sample showed the improved charge/discharge characteristics such as 432 mAh/g of initial reversible capacity, 88% of discharge rate capability at 10 C-rate, and 24 mAh/g of charge capacity at 10 C-rate. However, the expanded graphite had the problems of potential plateaus like natural graphite and lower initial efficiency than the natural graphite.

Synthesis of Si-SiC-CuO-C Composite from Silicon Sludge as an Anode of Lithium Battery (실리콘 슬러지로부터 리튬전지(電池) 음극용(陰極用) Si-SiC-CuO-C 복합물의 합성(合成))

  • Jeong, Goo-Jin;Jang, Hee-Dong;Lee, Churl-Kyoung
    • Resources Recycling
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    • v.19 no.4
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    • pp.51-57
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    • 2010
  • As a recycling of Si sludge from Si wafer process, a Si-SiC-CuO-C composite material was synthesized and investigated as an anode material for lithium batteries. The Si sludge consisted of Si, SiC, machine oil, and metallic impurities. The oil and metal impurities was removed by organic washing, magnetic separation, and acid washing. The Si-SiC-CuO-C composite from the recovered Si-SiC mixture was prepared by high-energy mechanical milling. According to the electrochemical tests such as charge-discharge capacity and cycling behavior, it showed the improved cycle performance. The SiC and CuO-related phases were presumed to restrain the volume expansion of the anode and Fe, however, should be removed below 10 ppm prior to synthesis of the composite because it caused the capacity loss of the active material itself.

Text extraction in images using simplify color and edges pattern analysis (색상 단순화와 윤곽선 패턴 분석을 통한 이미지에서의 글자추출)

  • Yang, Jae-Ho;Park, Young-Soo;Lee, Sang-Hun
    • Journal of the Korea Convergence Society
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    • v.8 no.8
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    • pp.33-40
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    • 2017
  • In this paper, we propose a text extraction method by pattern analysis on contour for effective text detection in image. Text extraction algorithms using edge based methods show good performance in images with simple backgrounds, The images of complex background has a poor performance shortcomings. The proposed method simplifies the color of the image by using K-means clustering in the preprocessing process to detect the character region in the image. Enhance the boundaries of the object through the High pass filter to improve the inaccuracy of the boundary of the object in the color simplification process. Then, by using the difference between the expansion and erosion of the morphology technique, the edges of the object is detected, and the character candidate region is discriminated by analyzing the pattern of the contour portion of the acquired region to remove the unnecessary region (picture, background). As a final result, we have shown that the characters included in the candidate character region are extracted by removing unnecessary regions.

Vibration Control of the Continuous System Under White Noise Disturbance (백색잡음가진을 받는 연속체의 진동제어)

  • Paik, Jong-Han;Heo, Hoon
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 1994.10a
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    • pp.116-120
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    • 1994
  • 최근 항공우주 및 생산자동화 분야의 급격한 발달에 따라 정밀도와 효율성을 향상시키기 위해 저중량, 고강도 구조물이 요구된다. 그러나 경량화 추세로 인해 수반되는 구조물의 유연성 증가로 외력에 대한 구조응답의 진폭이 커지고 구조물의 피로 수명이 단축되어 매우 위험한 상황에 이를 수 있다. 이런 바람직하지 않은 진동현상을 제어하기 위해 여러 제어이론을 응용한 진동억제시스템의 연구가 활발하며, 신소재인 압전재료의 개발로 새로운 방향이 제시되고 있다. 압전재료는 유연한 구조물에 부착되어 압전재료의 수축, 팽창 운동에 의해 발생된 에너지를 부착된 구조물에서의 제어력으로 사용되어, 진동 혹은 자세 및 형상 제어에 활용되고 있다. 압전재료에 대한 연구로는 Crawley, de Luis3가 보의 표면 혹은 내부에 압전세라믹을 부착하여 액튜에이터로 사용하는 경우 집중모멘트를 가하는 역할을 함을 밝혔고, Hanagud, obal은 압전재료를 센서와 액튜에이터로 사용해 복합재료 보에 대한 최적 진동제어 알고리즘을 개발, 그 성능에 대한 효과를 조사하였고 임의의 위치에 부착된 센서 및 액튜에이터를 고려한 복합재료 보의 운동방정식을 유한요소법을 이용 유도하였으며 변위율 피드백(rate feedback)과 모달피드백(modal feedback) 제어기를 적용하여 진동제어 효과를 고찰하였다. 그리고 Tomas, James, Hubbard는 압전필름을 액튜에이터로 사용해 복합재료 보에 Liapunov 제어기와 변위율 피드백 제어기를 사용하여 능동감쇠기를 설계하였고, Lee, Chaing, Sullivan은 압전필름을 센서와 액튜에이터로 사용해 평판에 변위율 피드백 제어기를 적용한 능동감쇠기를 설계하고 실험적으로 수행하였다. Base가 백색잡음가진을 지속적으로 받을 때 보끝의 움직임이 최소가 되도록 제어하고자 연구를 수행 중인 바 그 결과로소 본 논문에서는 적용시켰고 F-P-K 방정식을 이용해 확률영역으로 변환하여 LQR 제어기와 pole allocation 제어기를 시스템에 적용시켜 우수한 특성을 갖음을 제어 시뮬레이션의 결과를 통해 입증하였다.

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