• Analytical Science and Technology
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• v.16 no.2
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• pp.110-116
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• 2003

A study has been done on the separation of iodide from spent pressurized water reactor (PWR) fuels and its quantitative determination using ion chromatography. Spent PWR fuels were dissolved with mixed acid of nitric and hydrochloric acids (80 : 20 molL%) which can oxidize iodide to iodate to prevent it from be vaporized. After reducing ${IO_3}^-$ ­to $I_2$ in 2.5 M $HNO_3$ with $NH_2OH{\cdot}HCl$, Iodine was selectively separated from actinides and all other fission products with carbontetrachloride and back-extracted with 0.1 M $NaHSO_3$. Recovered iodide was determined using the ion chromatograph of which the column was installed in a glove box for the analysis of radioactive materials. In practice, spent PWR fuel with 42,000~44,000 MWd/MtU was analyzed and its quantity was compared to that calculated by burnup code, ORIGEN2. The agreement was achieved with a deviation of -8.3~-0.5% from the ORIGEN 2 data, $324.5{\sim}343.6{\mu}g/g$.

• Analytical Science and Technology
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• v.16 no.6
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• pp.431-437
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• 2003

Metalization yield of uranium oxide to uranium metal from lithium reduction process of spent pressurized water reactor (PWR) fuels was measured using thermogravimetric analyzer. A reduced metal produced in the process was divided into a solid and a powder part, and each metalization yield was measured. Metalization yield of the solid part was 90.7~95.9 wt%, and the powder being 77.8~71.5 wt% individually. Oxidation behaviour of the quartemary alloy was investigated to take data on the thermal oxidation stability necessary for the study on dry storage of the reduced metal. At $600{\sim}700^{\circ}C$, weight increments of alloy of Mo, Ru, Rh and Pd was 0.40~0.55 wt%. Phase change on the surface of the alloy was started at $750^{\circ}C$. In particular, Mo was rapidly oxidized and then the alloy lost 0.76~25.22 wt% in weight.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2003.11a
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• pp.632-635
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• 2003

For the disposal of low-level radwaste from nuclear power plant need the determination of levels of radio nuclides in radwaste. These nuclides include the difficult-to-measure nuclides, so indirect methodology for the determination of the difficult-to-measure nuclides have to be developed. In this work, for the determination of $^129I(t_{1/2}=1.57{\times}10^7 years)$ in low-level radwaste from nuclear power plant is investigated. Recovery of Iodide in simulated waste($UO_2$ pellet) as a soluble and radwaste(resin, woolen fabric)as a insoluble samples are measured. After pretreatment of sample, $I_2$ are extracted from aqueous solution with $CCl_4$. Then I are extracted from $CCl_4$ with 0.1M $NaHSO_3$ aqueous solution. iodide in aqueous solution are determined by ion chromatography. The overall recovery yield is 76.7 (RSD 1.7%) for mixed-acid digestion method. Incase of woolen fabrics, overall recovery yield is 74.3 (RSD 2.2%) and recovery of iodide in resin 56.5(RSD 5.6%) for alkaline fusion method.

• Journal of Aquaculture
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• v.11 no.4
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• pp.581-592
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• 1998

To know on the distribution and ecological characteristics of genus Corbicula field survey made from August 1997 to July 1998 in the North Kyungsang Province. Three species, i.e. Corbicula japonica, C. leand and C. papyracea, were inhabited in the North Kyungsang Provice. C. japonica was dioecious and oviparous species and C. leana and C. papyracea were monoecious and viviparous species.

• Analytical Science and Technology
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• v.13 no.4
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• pp.474-483
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• 2000

An inductively coupled plasma atomic emission spectrometer/shielding system was specially designed and built for the analysis of radioactive materials. Both of an inductively coupled plasma source and a sample transfer system to be contacted with radioactive materials was installed in a stainless steel glove box. In terms of analytical capability and radiation safety, characteristic feature of the system was investigated. Its applicability to the determination of fission products and corrosion products in the radioactive materials such as spent fuel dissolver solution and the primary coolant of nuclear power reactors was evaluated. In the concentration range $0.01-0.1mgL^{-1}$, the relative standard deviation was found to be less than 5%.

• Journal of Wetlands Research
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• v.20 no.3
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• pp.201-209
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• 2018

In this study, the water quality index was calculated using the water quality monitoring data of the major tributaries of the Nakdong River and long-term trend analysis was performed to identify the tributaries requiring priority management. We used a Real-Time Water Quality Index method implemented by the Ministry of Environment. Linear regression as a parametric method and Mann-Kendall Test and Sen Slope Test as a nonparametric method were applied for the trend analysis. The water quality index of major tributaries except for Migeon2 and Seokyo2 was in the range below Fair grade and there were no significant trends for the rest of the sites except Bukan, Chennae, Hogye, Yongdeok. Therefore, in order to improve the water quality of the main stream, management of the tributaries should be preceded.

• Korean Journal of Microbiology
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• v.51 no.4
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• pp.389-397
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• 2015

Dongchun, one of the representative streams in urban area, is a downstream that is connected to Hogyechun, Bujeonchun, Jeonpochun, Danggamchun, and Gayachun as its upstream. Hogyechun has been mostly covered with concrete structures for decades, causing sewage pollution from the upstream, overflow of the downstream region and other serious pollution that gave rise to many civil complaints from the residents nearby. In this study, we analyzed 3 stations, including control station for water quality and malodor changes of Hogyechun after applying the microbial augmentation (BM-2) for a few months including the rainy season. Amounts (g/h) of DO in the middle site (Middle) and the downstream site (Borim) increased by 1.7 times compared with the upstream site (Chuhae) after augmentation for about 2 months. Amounts (g/h) of COD and $NO_3{^-}N$ decreased by 2 and 1.7 times, respectively, in the middle and downstream sites while SS increased by 7.5 and 22 times in the middle and downstream sites, respectively. Moreover, odor removal efficiencies at the middle and downstream sites were 65% and 19%, respectively, indicating the microbial activity in reduction of malodor in the polluted stream. The dominant microbial species of the sampling sites were Hydrogenophaga caeni, Sphaerotilus natans, Acidovorax radicis, Acidovorax delafieldii, and Cloacibacterium rupense. Densities of the two species Sphaerotilus natans and Acidovorax delafieldii were significantly increased in the middle site after augmentation which possessed potential odor removal and denitrification activity, respectively. Potential pathogens (e.g., Arcobacter cryaerophilus) were also removed from the middle site after the implementation.

• Korean Journal of Environmental Agriculture
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• v.25 no.2
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• pp.138-146
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• 2006

To understand the status of water quality and work out a suitable countermeasures in Seonakdong watershed which has poor agro- environmental condition because of severe point and non-point source pollution by popularized city and near sea, we investigated the pollution sources and water quality from '03 and '05 and the result were mapped with GIS and RS for end-users's convenient comprehense and conjunction of water quality and geological data. The most degraded tributary was Hogeo stream which was affected directly by highly popularized Gimhae city, the main pollution source of the watershed. The pollution of tributaries in watershed increased the T-N of main body that reached over 4 mg/L during dry season. Pyeonggang stream and the lower part of main water way were suffered from high salt contents induced near sea and the EC value of those area were increased to 2.25 dS/m. The delivered loads of T-N and T-P were largest in Joman river as 56% and 61% of total delivered loads 1mm tributaries because of lots of stream flow. When Management mandate for irrigation water in Seonakdong river watershed was mapped for estimating integrated water quality as the basis of classification of EC and T-N contents in water, Hogeo and Shineo catchments were showed the requiring countermeasures none against nutrients hazard and Pyeonggang catchment was the vulnerable zone against nutrients and salts hazard. As the result, Seonakdong watershed had very various status of water quality by characteristics of catchments and countermeasures for improving water quality and crop productivity safely should changed depend on that.

• Korean Journal of Heritage: History & Science
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• v.53 no.4
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• pp.118-135
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• 2020

It is not uncommon in Korea to see the structure and function of a garden remain intact as well as its form. Yi Cheon-bo's Historic House (Gyeonggi-do Cultural Heritage Item No. 55), located in Sang-myeon, Gapyeong-gun, Gyeonggi-do, is considered an example of very valuable garden heritage, although its family history, location, and remaining buildings and natural cultural assets are not fully intact. Along with Yi Cheon-bo's Historic House, this study attempted to explore the possibility of restoration of the forest houses and gardens by highlighting the high value of Yi Cheon-bo's Historic House through research into the typical layout of private households in northern Gyeonggi Province and Gapyeong County, comparative review of aerial photographs from 1954, and interviews with those involved. The results of the study are as follows: In this study, the presence of Banggye-dongmun and Bansukam in the Banggyecheon area, where the location of the garden was well-preserved, was examined across the landscape of the outer garden, while the location of Yi Cheon-bo's Historic House, the appearance of feng shui, and the viewing axis were considered. Also, the appearance of the lost main house was inferred from the arrangement and shape of the Sarangchae and Haengrangchae that remain in the original garden, and the asymmetry of the Sarangchae Numaru and the hapgak shape on the side of the roof. In addition, the three tablets (Pyeonaeks) of Sanggodang (尙古堂), Bangyejeongsa (磻溪精舍), and Okgyeongsanbang (玉聲山房) were used to infer the landscape, use, and symbolism of the men's quarters. Also, a survey was conducted on the trees that existed or existed in the high prices. Incidentally, it was confirmed that information on boards and cultural properties of Yeonha-ri juniper (Gyeonggi-do Monument No. 61) was recorded to a much lesser extent than the actual required standard, and the juniper trees remaining in the front of Haengrangchae should also be re-evaluated after speculation. On the other hand, as a result of estimating the original shape as a way of pursuing completeness of the garden through restoration of the lost women's quarters and shrine, it is estimated that the main house was placed in the form of a '口' or a 'be warped 口' on the right (north) side of the men's quarters. By synthesizing these results, a restoration alternative for Yi Cheon-bo's Historic House was suggested.

• Analytical Science and Technology
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• v.16 no.4
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• pp.261-268
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• 2003

To investigate the matrix effect of sample for hydrogen analysis by inert gas fusion-thermal conductivity detection, calibration factor for the hydrogen analyser of the inert gas fusion-thermal conductivity detection method was measured with hydrogen standard materials in Ti, Zr-2.5Nb and by hydrogen gas dosing method. Also the hydrogen extraction efficiency for the different sample matrix, Ti and Zr-2.5Nb, was evaluated without adding tin flux. The calibration factor of the hydrogen analyser which was calibrated by hydrogen standard material in Zr-2.5Nb and Ti was 2~3% and 14% higher than that by hydrogen gas dosing method, respectively. Based on the results of calibration factor measurement, it could be concluded that the hydrogen extraction efficiency of the Ti matrix sample will be 12% lower than that of the Zr-2.5Nb. And according to the experimental results of hydrogen recovery test by no tin flux, the hydrogen recovery percentage of the Ti and Zr-2.5Nb matrix sample was about 70% but the recovery rate of Ti matrix sample was slightly lower than that of Zr-2.5Nb.