• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.5
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• pp.23-29
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• 2019

This study applies to the surface modification technique by coating the surface of aggregates using the modified paste such as cementitious materials in order to develop completely recycling technology of coarse aggregate. In this case, coating thickness of modified aggregate can be considered that the decision is dependent on the viscosity and tenacity of modified paste. In this study identify the flow properties of the fresh modified paste, and examined for the coating thickness of modified aggregate. As a result, it was possible to design a quantitative coating thickness of modified paste assuming that a modified paste to a Bingham Fluid and consider by excess paste theory and rheology constant (yield value). Accordingly, it is considered that the quantitative mix design of concrete using by surface modified aggregates will be possible.

• Journal of the Korea Concrete Institute
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• v.19 no.5
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• pp.539-547
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• 2007

The effects of binder and alumina content on the setting time, drying shrinkage, strength, freezing and thawing resistance and water absorption of polymer-modified pastes with alumina powder were examined. As a result the setting time of the polymer-modified pastes with alumina powder tended to delay with increasing binder content. Irrespective of the type of polymer, the drying shrinkage of the polymer-modified pastes with alumina powder tended to decrease with increasing binder content and alumina powder content. Regardless of the type of polymer, the tensile and adhesion strengths of the polymer-modified pastes with alumina powder tended to increase with increasing binder content and alumina powder content. Irrespective of the type of polymer, the durability factors of the polymer-modified pastes with alumina powder tended to increase with increasing alumina content. Irrespective of the type of polymer, the water absorptions of the polymer-modified pastes with alumina powder tended to decrease with increasing binder content and alumina content.

• Journal of the Korea Institute of Building Construction
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• v.18 no.1
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• pp.51-57
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• 2018

The objective of the present study is to examine the feasibility on the development of high-insulation concrete using aerogels with hydrophilic surface treatment. To prevent the segregation and enhance the dispersibility of agerogels in the cement pastes, the substrate of aerogels was modified to be hydrophobic property using surfactant. The modified aerogels were added from 0% to 100% of the cement volume at the interval of 25% under the constant cement content. Some cement pastes showed segregation phenomenon and flocculation of aerogels during mixing phase. The addition of aerogels decreased the compressive strength of cement pastes but enhanced the thermal conductivity. The thermal conductivity of pastes with 100% aerogels was lower by 43% when compared with that measured in the conventional paste. To improve the compressive strength and insulation capacity of concrete containing aerogels, a reliable surface treatment method of aerogels needs to be further investigated.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2015.11a
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• pp.226-227
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• 2015

인쇄회로기판에 솔더 페이스트를 인쇄하기 위하여 스테인리스 스틸 (Stainless steel, (i.e., SUS)) 재질의 솔더 페이스트 인쇄용 스텐실 마스크가 사용되고 있다. 하지만, 솔더 페이스트가 스텐실 마스크에 쉽게 달라붙기 때문에 솔더 페이스트에 의한 오염으로 인하여 생산성이 떨어지며, 스텐실 마스크 수명이 짧아지는 문제점이 발생되고 있다. 이를 해결하기 위하여 본 연구에서는 스텐실 마스크 표면에 소수성을 가진 고분자 코팅을 함으로써 솔더 페이스트가 쉽게 붙는 것을 억제하고자 하였다. 더욱 중요하게 스텐실 마스크에 전해연마 및 플라즈마 처리를 통한 표면 개질을 부여함으로써 고분자 코팅의 내구성을 향상시키고자 하였다.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.445-447
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• 2008

본 연구에서는 다중벽 탄소나노튜브용 표면개질제를 리빙라디칼중합법을 통하여 제조하고, 이를 이용하여 표면개질되고 분산제어된 다중벽탄소나노튜브를 제조하고 염료감응형 태양전지의 대전극 재료로 사용하였다. 우선 리빙라디칼중합법 중 nitroxide mediated polymerization (NMP) 기술을 이용하여 poly(maleic anhydride-co-p-acetoxystyrene)-block-poly(p-acetoxystyrene)를 합성하고, 공중합체중의 maleic anhydride기에 이미드화 반응을 통하여 pyrene기를 도입하였다. 공중합체 중의 p-acetoxystyrene 반복단위들은 가수분해 반응을 통하여 p-hydroxystyrene 반복단위로 변환하였으며, 제조된 공중합체의 구조와 열 특성 등을 GPC, GC, $^1H$-NMR, TGA을 통하여 분석하였다. 제조된 공중합체를 이용하여 다중벽 탄소나노튜브의 표면을 polymer wrapping법으로 처리하였고, 표면개질된 탄소나노튜브의 분산성을 다양한 용매에서 비교분석하였다. 표면이 개질되고 페이스트 내에의 분산성이 향상된 다중벽탄소나노튜브를 염료감응태양전지의 대전극 제조에 응용하였으며, 표면처리 및 분산제어 여부에 따른 제작 특성 및 동작특성 등을 평가하였다.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.1
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• pp.66-74
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• 2021

The objective of this study is to evaluate the practical application potential and limitations of the modified fly ash(MFA) by vibration grinding as a partial replacement of ordinary portland cement(OPC). The test parameters investigated were the replacement level of fly ash(FA) and FA for OPC, varying from 10% to 40%, and curing temperatures of 5, 20, and 40℃. The various characteristics(including slump, air content, bleeding, setting time, compressive strength development, and hydration products) of MFA concrete were measured and then compared with those of the concrete with conventional FA. Test resul ts showed that the MFA prefers to FA in reducing the bl eeding of fresh concrete and enhancing the compressive strength gain at an early age. The compressive strength ratios between MFA and FA concrete specimens at an age of 1 day were 135%, 146%, and 111% at the curing temperatures of 5, 20, and 40℃, respectively. The corresponding ratios at an age of 28 days were approximately 110%, regardless of the curing temperatures. The X-ray diffraction analysis also revealed less calcium hydroxide products in MFA pastes than in FA pastes.

• Journal of the Korea Concrete Institute
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• v.18 no.2 s.92
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• pp.227-232
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• 2006

This article presents the results of experimental study that investigates the effect of filler and shrinkage reducing agent influencing on the strength properties of MMA-modified polymer paste that was produced to develop the surface-repair and coating materials of the concrete structures. Results show that the flexural and compressive strengths of the polymer paste increased 29 and 27%, respectively, when the aluminum hydroxide completely replaced the calcium carbonate as the filler Furthermore, when the shrinkage reducing agent was used 30%, both strengths decreased about 29% comparing to when the agent was not used. As in the cases of flexural and compressive strengths, the adhesive strength increased as the content of aluminum hydroxide as the filler increased, and it decreased as the content of shrinkage reducing agent increased. The adhesive strength with a dry concrete substrate turned out to be $30{\sim}40%$ higher than that with a wet concrete substrate.

• Journal of the Korea Concrete Institute
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• v.28 no.3
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• pp.341-348
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• 2016

At present, about 40 million tons of concrete is dismantled each year, which accounts for the largest portion of the total amount of construction waste with 60.8%. It is known about 97.5% of it is recycled. However, most of the usage of waste concrete is limited to lower value-added business areas, and considering the increasing amount of waste concrete generated due to the deterioration of structures, the need for converting waste concrete to structural concrete is urgent. Therefore, this study aims at estimating the period for the optimum carbonation reforming to improve the quality of recycled aggregate, by making use of the method of accelerated carbonation reforming of the bonding heterogeneous (cement paste and mortar) for the purpose of converting recycled aggregate to structural concrete. Based on the period appropriate for the heterogeneous thickness and each bonding thickness of recycled aggregate which was drawn from previous studies, the changes in the characteristics and physical properties of pore structure according to progress of accelerated carbonation were analyzed. The result shows that with the progress of carbonation, the pore volume and the percentage of water absorption of the bonding heterogeneous decreased and the density increased, which indicates improvement of the product quality. But after certain age, the tendency was reversed and the product quality deteriorated. Synthesizing the results of previous studies and those of the present study, this study proposed 4 days and 14 days respectively for the period for the optimum carbonation reforming of recycled fine aggregate and recycled coarse aggregate.

• Polymer(Korea)
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• v.37 no.4
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• pp.470-477
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• 2013

Multi-walled carbon nanotube (MWCNT) based nano-composite pastes having a high filler content are prepared for the facile fabrication of a counter electrode (CE) of dye-sensitized solar cell (DSSC). A polystyrene-based functional block copolymer is prepared through a controlled "living" radical polymerization technique, affording a surface modifier for the dispersion control of MWCNT in the paste. Physical dispersion through a ball-milling method additionally confirms the importance of the dispersion control, providing DSSC with enhanced processibility and improved solar-to-electricity energy conversion efficiency (${\eta}$) values. The performances of the DSSCs are further improved through the incorporation of minor amount of platinum (Pt) nanoparticles into the MWCNT pastes. The DSSC with the Pt/MWCNT hybrid CE exhibits very high ${\eta}$ values, which is superior to that of DSSC with the standard Pt CE.

• Journal of the Korea Concrete Institute
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• v.28 no.3
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• pp.329-340
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• 2016

Increase in demotion and repair works on buildings in the construction market generates a large amount of construction waste. Recycling of construction waste is important for saving of resources, preservation of environment and constant advance of the construction industry. Accordingly, the environmental and economic value of recycled aggregate, which is produced after waste concrete is crushed, is increasingly highlighted. It is generally known that compared to concrete made of ordinary aggregate, concrete made of recycled aggregate has low quality, and the low quality is dependent on the amount of the bonding heterogeneous (cement paste and mortar) as well as the amount of the pores within the bonding heterogeneous. Reports on carbonation mechanism shows that the pores of cement-based materials are filled up by the progress of carbonation. Therefore, this study aims at an estimation of the period for optimum carbonation reforming appropriate for the thickness of the bonding heterogeneous of recycled aggregate, based on carbonation mechanism, with a view to improving the product quality by means of filling up the pores of the bonding heterogeneous of recycled aggregate. This study drew the carbonation depth according to the passage of age by calculating the bonding ratio and bonding thickness of the bonding heterogeneous as against the particle size distribution of recycled aggregate as well as by chemical quantitative analysis according to the age of accelerated carbonation of mock-up samples imitating bonding heterogeneous. Based on the correlation between the age of accelerated carbonation and carbonation depth, this study also proposed the estimated period of carbonation reforming of recycled aggregate appropriate for the thickness of the bonding heterogeneous.