• Title/Summary/Keyword: 감응특성

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Electrochemical Properties of PAN-based Carbon Fibers Tow Electrode Using Organic/inorganic Nanocomposite and Its Application of Non-enzymatic Sensor (유/무기 나노 복합체를 이용한 PAN계 탄소섬유 토우 유연 전극의 전기화학적 특성 평가 및 비효소 전기화학 센서의 활용)

  • Min-Jung Song
    • Korean Chemical Engineering Research
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    • v.62 no.3
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    • pp.233-237
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    • 2024
  • This study is about the fabrication of a flexible electrode based on PAN-based carbon fibers tow using organic/inorganic nanocomposite and its application of non-enzymatic sensor. The organic/inorganic nanocomposite was composed of the conductive polymer polyaniline (PANI) and the metal oxide CuO. And glucose was used as the target of the electrochemical sensor. Commercialized CFTs were pretreated through heat treatment for desizing and electrochemical oxidation for activation. This nanocomposite was sequentially synthesized on the pretreated CFT surface using electrochemical polymerization and electrochemical deposition. Finally, the CFT/PANI/CuO NPs electrode was obtained. The electrochemical properties and sensing performance of the CFT/PANI/CuO NPs electrode were analyzed using chronoamperometry (CA), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The sensitivity of the CFT/PANI/CuO NPs electrode was about 8.352 mA/mM (in a linear range of 0.445~6.674 mM) and 3.369 mA/mM (in a linear range of 6.674~50 mM), respectively. So, the CFT/PANI/CuO NPs electrode exhibited the enhanced sensing performances due to unique properties such as small peak potential separation, low electron transfer resistance, and large specific surface area.

Preparation and Characterization of L-Arginine Containing Poloxamer Hydrogels for Solubilization and Sustained Release of Amphotericin B (Amphotericin B의 가용화 및 방출지속화를 위한 아르기닌 함유 폴록사머 하이드로젤의 제조 및 특성분석)

  • Shin, Baek-Ki;Baek, Eun-Jung;Kim, Ye-Tae;Jeong, Ji-Woong;Nho, Young-Chang;Lim, Youn-Mook;Park, Jong-Seok;Huh, Kang-Moo;Park, Jeong-Sook
    • Polymer(Korea)
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    • v.34 no.5
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    • pp.459-463
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    • 2010
  • Amphotericin B (AmB) is anti-fungal agent for the treatment of systemic fungal infections, but its poor solubility has limited clinical applications. In this study, a new gel formulation made up of L-arginine as solubilizer, thermosensitive Poloxamer 407 (P 407), and adhesive carbopol was designed for effective solubilization and delivery of AmB. The aqueous solubility of AmB was enhanced up to 2.6 mg/mL by addition of L-arginine. Aqueous P 407 solutions of more than 20% w/v showed thermo-induced sol-gel-sol phase transition. The phase transition behavior was affected by the presence of AmB and L-arginine, and the phase transition range was broadened by addition of carbopol. In vitro drug release was improved by the solubilizing effect of L-arginine, and the presence of mucoadhesive carbopol prolonged the release rate as a function of concentration.

Breeding of Purple Flower-colored Dwarf 'Jiknyeo' from Hybridization of Campanula punctata Lam. × Campanula punctata Lam. var. rubriflora Mak. (애기초롱꽃(Campanula punctata Lam.)과 자주초롱꽃(C. punctata Lam. var. rubriflora Mak.)의 교잡을 통한 자주색 꽃을 가진 왜성 초롱꽃 '직녀' 육성)

  • Choi, Nam-Hee;Kim, Gyeong-Hee;Lim, Mi-Young;Kim, Zhoo-Hyeon;Jeong, Byoung-Ryong
    • Horticultural Science & Technology
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    • v.30 no.3
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    • pp.338-341
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    • 2012
  • Campanula, native to Korea, is potentially an attractive potted or bedding plant. Experiments were conducted to produce a $F_1$ hybrid plant for a reduced plant height, 'Jiknyeo', by a conventional cross breeding between C. punctata Lam. and C. punctata Lam. var. rubriflora Mak. The crossing was carried out in July 2001 and the seeds were harvested in October 2001. Seeds were stored for two months at $5^{\circ}C$ for vernalization, and then were sown in March 2002. The $F_1$ hybrid have a purple flower color, and decreased plant height, leaf length, leaf width, and peduncle length. Each flower maintained freshness for a period of 20 days on the average. The whole flowering period of a plant was four months. The plant has flowering characteristics of an indeterminate inflorescence, prefers low humidity during the whole cultivation period, and requires low temperature in winter for flower bud differentiation.

The Detection of Magnetic Properties in Blood and Nanoparticles using Spin Valve Biosensor (스핀밸브 바이오 센서를 이용한 혈액과 나노입자의 자성특성 검출)

  • Park, Sang-Hyun;Soh, Kwang-Sup;Ahn, Myung-Cheon;Hwang, Do-Guwn;Lee, Sang-Suk
    • Journal of the Korean Magnetics Society
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    • v.16 no.3
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    • pp.157-162
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    • 2006
  • In this study, a high sensitive giant magnetoresistance-spin valve (GMR-SV) bio-sensing device with high linearity and very low hysteresis was fabricated by photolithography and ion beam deposition sputtering system. Detection of the Fe-hemoglobin inside in a red blood and magnetic nanoparticles using the GMR-SV bio-sensing device was investigated. Here a human's red blood includes hemoglobin, and the nanoparticles are the Co-ferrite magnetic particles coated with a shell of amorphous silica which the average size of the water-soluble bare cobalt nanoparticles was about 9 nm with total size of about 50 nm. When 1 mA sensing current was applied to the current electrode in the patterned active GMR-SV devices with areas of $5x10{\mu}m^2 $ and $2x6{\mu}m^2 $, the output signals of the GMRSV sensor were about 100 mV and 14 mV, respectively. In addition, the maximum sensitivity of the fabricated GMR-SV sensor was about $0.1{\sim}0.8%/Oe$. The magnitude of output voltage signals was obtained from four-probe magnetoresistive measured system, and the picture of real-time motion images was monitored by an optical microscope. Even one drop of human blood and nanopartices in distilled water were found to be enough for detecting and analyzing their signals clearly.

Persistence and degradation of herbicide molinate in paddy-soil environment (논토양 환경 중 제초제 molinate의 잔류성과 분해특성)

  • Park, Byung-Jun;Park, Hyeon-Ju;Lee, Byung-Moo;Ihm, Yang-Bin;Choi, Ju-Hyeon;Ryu, Gab-Hee
    • The Korean Journal of Pesticide Science
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    • v.9 no.1
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    • pp.60-69
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    • 2005
  • The herbicide molinate has been detected with high frequency in the main river during the growing season in Korea. To elucidate the exposure of molinate in agricultural environment, the persistence and the degradation characteristics of molinate were investigated in paddy ecosystems. The half-lives of molinate were 4.1 days with soil aquatic system, and 4.2 days in only aquatic system. Initial dissipation rate of molinate in water was greater with soil aquatic system than that of only aquatic system. Photolysis of molinate was occurred about 31.0% of molinate treated in pure water, when irradiated at 5,530 $J/cm^2$ by the xenon lamp, but its hydrolysis was stable. For the accelerated photolysis of molinate in aqueous solution, several photosensitizers were screened, showing that the hydroperoxide($H_2O_2$) and acetone were prominent among the chemical tested. When hydroperoxide and zinkoxide(ZnO) were used as photosensitizer, their photolysis were accelerated greater than 98% and 58% in aqueous solution, respectively. Elution rate of molinate as granular formulations in aqueous system was more than 90% in 30 hour at $35^{\circ}C$. Molinate concentration pattern in paddy water was rapidly decrease from treatment till 7 days in paddy rice field and its half-lives were 3.7 days($Y=1.9258{\times}e^{-0.1865X}$(r=-0.9402)).

온라인 협동조합의 공생마케팅 전략-웹기반 사진앨범협동조합 (주)와이드스쿨 사례-

  • 김창호
    • Distribution Business Review
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    • no.3
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    • pp.155-170
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    • 2003
  • 본 연구는 기본적으로 온라인과 오프라인의 통합마케팅을 절명하고 이에 관한 경험적 사례를 개발하기 위한 목적으로 진행되었다. 앨범서비스 영역의 공생적 기반 위에 전개되는 온 -오프라인의 경험적 사례를 개발하고 바람직한 마케팅방향 방향을 제시하였다. 본 연구는 문헌연구와 사례연구를 병행하여 연구를 진행하였다. 사례는 인터넷 기반의 앨범서비스를 제공하기 위한 (주)와이드스쿨이다. 온-오프라인의 협력적 통합마케팅의 전략을 전개하기 위해서는 무엇보다도 온 -오프라인의 뚜렷한 목표를 절정하고 성장방향에 대한 비전을 공유하고 나아가 온 -오프라인의 사명을 감당하는 것이다. 즉, 실천적으로는 \circled1 항상 고객 (customer)기반의 의사결정을 이루며 \circled2 철저한 협력적 돕는 경쟁(competition) 의식과 \circled3 구성원 자신의 일에 대한 자신감(confidence)을 지니고 \circled4 실천을 위한 용기(courage)를 가지고 \circled4 혁신하여 변화(change)를 선도하는 것이다. 온라인(on line)으로 표현되는 인터넷환경은 모든 영역에 변화를 요구하고 있다. 온라인에 관한 연구는 크게 온라인시장의 경쟁(competition)에 관한 연구와, 온라인 소비자(consumer)에 관한 연구 그리고 온라인 시장 참가기업(company)에 관한 연구로 구분된다(이석규 ; 2001). 이중 기업에 관한 연구의 중심에는 e-biz의 수익모텔에 관한 연구가 주류를 이루고 았다(David et al, 1999) 특히 오프라인기업의 경우 어떠한 형태방법으로 온라인 환경에 부응하며 기존의 마케팅활동과 연계할 것인가는 매우 중요한 문제다. 즉 기존의 오프라인기업이 온라인도구변화에 적응하고 이를 전략적으로 활용하기 위해서는 무엇보다도 오프라인과 온라인의 통합에 관한 형태와 전략 등을 명확히 이해하고 적용하는 것이 중요하다. 개수가 감소하는 것과는 상당히 다른 분포이다. 따라서 우리의 관측 결과는 2001년 사자자리 유성우의 극대 시간 전후 2시간에 적어도 0등급 이하의 밝은 유성이 상대적으로 많이 발생하였을 것으로 해석된다. 이런 밝은 유성의 빈도는 유성우 특성 연구에 중요한 의미를 가진다. 그러나 표준성만을 이용해 결정된 유성 등급은 유성의 지속 시간에 대한 불확실성과 전천 카메라 감응도의 비선형성에 의한 불확실성을 내포하고 있음을 지적해 둔다.umn chromatography)를 사용하였고 일련의 정제 과정을 통하여 배양액 중의 L-lactic acid 정제 수율은 약 85% 정도로 나타났으며 HPLC로 분석한 결과 99.7%의 순도를 확인할 수 있었다.경향을 나타내며 유입휫수와 $Dst_{min}$ 사이에는 높은 상관관계(0.83)가 있었다. 둘째, 주상기간 중 자기폭풍의 크기가 클수록 플럭스 비 ($f_{max}/f_{ave}$는 대체로 증가하는 경향을 나타냈다. 그리고 75~113keV 에너지 채널에서의 $Dst_{min}$ 값과 플럭스 비의 상관계수는 0.74로서 가장 높았으며 나머지 에너지 채널 역시 비교적 높은 상관관계를 나타냈다. 셋째, 주상기간 중 총 에너지 유입률 지수와 $Dst_{min}$ 사이에 높은 상관관계가 확인되었다. 특히 환전류를 구성하는 주요 입자의 에너지 영역(75~l13keV)에서 가장 높은(0.80) 상관계수를 기록했다. 넷째, 회복기 중에 일어나는 입자들의 유입은 자기폭풍의 지속시간을 연장시키는 경향을 보이며 큰 자기폭풍일수록 현저했다. 주상에서 관측된 이러한 특성은 서브스톰 확장기 활동이 자기폭풍의 발달과 밀접한 관계가 있음을 시사한다.se that were all low in two aspects, named "the Nonsignificant group".

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One-component Room Temperature Vulcanizing-Type Silicone Rubber-Based Solid-State Carbonate Ion Selective Electrode (단일 조성 실온 경화형 실리콘러버를 지지체로 사용한 고체상 탄산이온선택성 전극의 개발)

  • Kim, Mi-Kyoung;Yoon, In-Jun;Cho, Sung-Ho;Shin, Hye-Ra;Han, Jong-Ho;Ha, Jeong-Han;Nam, Hak-Hyun;Cha, Geun-Sig
    • Journal of the Korean Chemical Society
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    • v.48 no.3
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    • pp.266-272
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    • 2004
  • We developed a miniaturized solid-state carbonate ion-selective electrode (carbonate ISE) based on one-component room temperature vulcanizing type silicone rubber 730 (730 RTV) without adding plasticizer to the matrix. The optimized carbonate ion selective membrane is prepared with 85.8 wt% of 730 RTV, 11.1 wt% of trifluoroacetyl-p-decylbenzene (TFADB), and 3.1 wt% of tridodecyl-methylammonium chloride (TDMACl). This carbonate ISE exhibited excellent potentiometric properties (i.e., slope: 26.3 mV/dec; selectivity: $logKT^{pot}_{CO_{2},Cl^-}$= -4.00 and $logKT^{pot}_{TCO_{2},Sal^-}$=1.69); and detection limit for $TCO_2:\;4.0{\times}10^{-4}M$). In addition, the early potentiometric properties of the solid-state sensor with optimized membrane composition were not deteriorated for more than 60 days.

Magnetoresistance of $[FeNi/Cu/CoFe(Co)/Cu]_N$ Spin-Valve Multilayers ($[FeNi/Cu/CoFe(Co)/Cu]_N$ Spin-Valve 다층박막의 자기저항 특성)

  • 김미양;이정미;최규리;오미영;이장로
    • Journal of the Korean Magnetics Society
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    • v.9 no.1
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    • pp.41-47
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    • 1999
  • $Buffer/[NiFe/Cu/CoFe(Co)/Cu]_N$ spin valve multilayers prepared by dc magnetron sputtering on a corning glass substrate using NiFe and CoFe(Co) posses different coercivities. Dependence of magnetoresistance on the type and thickness of buffer layer, thickness of Cu, NiFe, stacking number of multilayer, substrate temperature and annealing temperature in the form $[NiFe/Cu/CoFe(Co)/Cu]_N$ spin-valve multilayers were investigated. To evaluate effect of magnetoresistance for this samples, X-ray diffraction analysis, vibrating sample magnetometer analysis, and magnetoresistance measurement (4-probe method) were performed the maximum magnetoresistance ratio and coercivity were 7.5 % and 140 Oe, respectively for $Cr-50{\AA}/[NiFe-20{\AA}/Cu-{\AA}/Co-20{\AA}/Cu-50{\AA}]_10$ at substrate temperature of 9$0^{\circ}C$. Magnetoresistance slope maintained 0.25%/Oe until 15$0^{\circ}C$ of annealing temperature, and then decreased to 0.03%/Oe at 20$0^{\circ}C$. It was confirmed that the main factor of thermal stability was deteriorating of soft magnetic properties in the NiFe layer.

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Effects of Multi-layer and TiCl4 Treatment for TiO2 Electrode in Dye-sensitized Solar Cell (염료감응 태양전지의 TiO2 전극의 다중층 및 TiCl4 처리에 따른 효과)

  • Kim, Gyeong-Ok;Kim, Ki-Won;Cho, Kwon-Koo;Ryu, Kwang-Sun
    • Applied Chemistry for Engineering
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    • v.22 no.2
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    • pp.190-195
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    • 2011
  • To investigate the photon-trapping effect and scattering layer effect of $TiO_2$ multi-layer in dye-sensitized solar cell (DSSC) and the degree of recombination of electrons at the electrode treated $TiCl_4$, we formed electrodes of different conditions and obtained the most optimal electrode conditions. To estimate characteristics of the cell, IV curve, UV-Vis spectrophotometer, electrochemical impedance spectroscopy (EIS) and incident photon-to-current conversion efficiency (IPCE) were measured. As a result, we confirmed that the multi-layer's efficiency was higher than that of monolayer in the IV curve and the performance of $TiCl_4$ treated electrode was increased according to decreasing the impedance of EIS. Among several conditions, the efficiency of the cell with scattering layer is higher than that of a layer with the base electrode about 19%. Because the light scattering layer enhances the efficiency of the transmission wavelength and has long electron transfer path. Therefore, the value of the short circuit current increases approximately 10% and IPCE in the maximum peak also increases about 12%.

The Concept of Divine Beings Coined by Jeungsan Kang Il-Sun (증산 강일순의 신명(神明)사상)

  • Kim, Tak
    • Journal of the Daesoon Academy of Sciences
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    • v.35
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    • pp.109-145
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    • 2020
  • Jeungsan, Kang Il-Sun (hereafter, Jeungsan)'s perspective on divine beings can be characterized by the philosophical notion of divinity, which recognizes a variety of divine entities. Jeungsan insisted that all things embrace divine entities. Furthermore, he claimed that the backgrounds of all incidents were influenced by these gods. Jeungsan thought that the universe consists of the heavenly realm, the earthly realm and the underground realm. He insisted that there were many gods in each realm. And Jeungsan defined his times as the era of divine beings, which meant that the age was a time for divine beings to actively interact with one another and take the lead in world affairs. Divine beings were briskly involved in human affairs and could either reciprocate gratitude or attain revenge. They were also divine beings that could change the acts and perception of humans as well as judge human acts. However, Jeungsan predicted that by the time the paradisiacal land of immortals was established in the Later World, divine beings would instead run errands for humans. In addition, he forecast that divine beings would be entities likely to harbor grievances just like humans, yet they would ultimately become perfected beings in the Later World. Jeungsan further suggested a multitude of various concepts such as the mutual relationship wherein the realm of divine beings and the realm of humanity interrelate with each other, the mutual responses and functions between them, mutual itineration, co-existence, and the homogeneity of divine beings and humans, which described how both have the same innate characteristics. Jeungsan proposed the concept that 'Divinity is an existential state experienced after one's death." In this regard, he is the one who formulated a new perspective of divinity. Moreover, Jeunsan stressed the immortality of humans (continuity or eternality) and the co-existence of divine beings and humans. He emphasized that divinity is intrinsically immanent and the realm of divine beings has a hierarchical system that maintains order and is akin to that of the human realm. Jeungsan recognized a revolutionary change and perspective based on humanity by suggesting a unique view of humanity. In other words, he was a religious figure who introduced an ingenious view of divinity and dramatically transformed this pattern of reasoning. In conclusion, Jeungsan re-interpreted traditional views of divinity in Korea and systemized them into a new concept of divinity in an ingenious way.