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Investigation of Liquid Phase Ammonia Removal Efficiency by Chemo-biological Process of Zeolites and Klebsiella pneumonia sp. (제올라이트와 Klebsiella pneumonia sp.을 이용한 화학-생물학적 액상 암모니아의 제거 효율 연구)

  • Park, Min Seob;Choi, Kwon-Young
    • Applied Chemistry for Engineering
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    • v.28 no.6
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    • pp.685-690
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    • 2017
  • Ammonia is a useful substance which is widely used in various industries. It is generally released by the decomposition of agricultural wastes and known to have toxic effects on human beings. Due to the common usage, it is possible to cause water pollution through either direct or indirect leakage. Such cases, it is preferable to use the adsorption capacity of zeolite to rapidly remove ammonium ions, but it is not sufficiently removed by the adsorption only. In this paper, the removal efficiency of ammonium ion through both the adsorption capacities of commercial synthetic zeolites and the biological mechanism of microorganisms were compared. In addition, microorganisms were immobilized on the zeolite in order to enhance the removal efficiency by applying a chemo-biological process. As a result, the standard commercial zeolite showed 67~81% of the removal efficiency in 2~4 hours at a 100 ppm concentration of ammonium, whereas the selected microorganism Klebsiella pneumoniae subsp. Pneumoniae showed up to 97% within 8 hours. When the microorganism was immobilized on the zeolite, the highest removal efficiency of approximately 98.5% were observed within 8 hours.

An Estimation of Direct and Indirect GHG-AP Integrated Emissions from Energy Sector in Seoul (2010) (서울시 에너지부문 직·간접 온실가스-대기오염 통합 배출량(2010) 산정)

  • Jung, Jaehyung;Kwon, O-Yul
    • Journal of Korean Society for Atmospheric Environment
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    • v.30 no.2
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    • pp.150-160
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    • 2014
  • Greenhouse gas (GHG) and Air Pollution (AP) emission inventories have been constructed and estimated independently up-to-date in Seoul. It causes difficulty in GHG and AP integrated management due to a difference in emission inventories. In this study, we constructed GHG and AP integrated emission inventories for direct and indirect sources in Seoul during the year 2010 in Energy activities for estimating GHG and AP emissions were derived from IPCC guideline, guidelines for local government greenhouse inventories, air pollutants calculation manual, and Indirect Emission Factors (IEF) reported by Korea Power Exchange. The annual GHG emission was estimated as 50,530,566 $tonCO_{2eq}$, of which 54.8% resulted from direct sources and the remaining 45.2% from indirect sources. Among direct sources, transportation sector emitted the largest GHG, accounting for 47.3% of the total emission from direct sources. As with indirect sources, purchased electricity sector only emitted 98.6% of the total emission from indirect sources. The annual AP emission was estimated as 283,701 tonAP, of which 85.9% was contributed by the combined AP emissions of transportation and fugitive sectors. Estimation of individual air pollutant showed that the largest source were transportation sector for CO, $NO_x$, TSP, $PM_{10}$ and NH3, non-energy sector for $SO_x$, and fugitive sector for VOCs. This study found some limitations in estimating GHG and AP integrated emissions, such as nonconforming emission inventories between GHG and AP, and no indirect AP emission factor of purchased electricity, and so on. Those should be further studied and improved for more effective GHG and AP integrated management.

Analysis of Performance and Energy Saving of a SOFC-Based Hybrid Desiccant Cooling System (건물용 연료전지 기반 하이브리드 제습냉방시스템 성능 및 에너지 절감 분석)

  • IN, JUNGHYUN;LEE, YULHO;KANG, SANGGYU;PARK, SUNGJIN
    • Journal of Hydrogen and New Energy
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    • v.30 no.2
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    • pp.136-146
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    • 2019
  • A solid oxide fuel cell (SOFC) based hybrid desiccant cooling system model is developed to study the effect of fuel utilization rate of the SOFC on the reduction of energy consumption and $CO_2$ emission. The SOFC-based hybrid desiccant cooling system consists of an SOFC system and a Hybrid desiccant cooling system (HDCS). The SOFC system includes a stack and balance of plant (BOP), and HDCS. The HDCS consists of desiccant rotor, indirect evaporative cooler, electric heat pump (EHP), and heat exchangers. In this study, using energy load data of a commercial office building and SOFC-based HDCS model, the amount of ton of oil equivalent (TOE) and ton of $CO_2$ ($tCO_2$) are calculated and compared with the TOE and $tCO_2$ generation of the EHP using grid electricity.

Recent changes in springtime discharge and nutrient fluxes to the vicinity of the Korean Peninsula (2012-2021) (봄철 한반도 연안으로 유입되는 하천 유량과 영양염류 유출량 변화량 (2012-2021))

  • Ye Na Kim;Jong Hun Kam
    • Proceedings of the Korea Water Resources Association Conference
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    • 2023.05a
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    • pp.145-145
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    • 2023
  • 육지의 영양염류는 강수를 통해 강을 따라 바다로 흐른다. 연안 수질과 생태계를 효과적으로 관리하기 위해 수계를 통해 연안으로 배출되는 육상 영양염류 유출의 변화를 연구하는 것이 중요하다. 그러나 제한적인 수량과 수질 동시 관측자료로 인해 한반도 연안으로 유입되는 영양염량 변화에 대한 연구는 매우 제한적이다. 따라서 본 연구에서는 한반도 내륙에서 주변 연안 지역으로 유출되는 영양염류의 유출량과 그 변화량을 추정 및 분석하고 유출량에 대한 수량과 수질 변화의 기여도를 정량적으로 조사하였다. 2012-2021년 봄철(3-5월)에 한반도 연안 주변의 75개의 하천 지점에서 측정된 수질 농도 및 유량 관측 데이터와 한반도 연안 375지점에서 측정된 해양 수질 농도 데이터를 사용하였다. 더불어 22개의 해안지역 하천 유량 관측소와 근접한 수질 관측자료를 통해, 총 질소(TN), 총 인(TP), 클로로필a의 봄철 영양염류 유출 총량을 추정하고 그 변화량을 평가하였다. 그리고 영양염류 유출 변화량을 모델 수식으로 분해하여 유출 총량 변화량에 대한 하천 유량과 영양염류 농도 변화의 상대적인 기여도를 분석하였다. 분석결과는 연간 봄철 TN, TP, 클로로필a 유출 총량의 변화율이 영양염류의 농도 (각각 19%, 48%, 5%)보다는 하천 유량 (각각 84%, 51%, 91%)에서 더 많은 영향을 받았음을 보여주었다. 한반도 연안을 서해, 남해, 동해로 나누어 영양염류 유출 총량을 분석한 결과, 한반도 전체 유출량에서 서해의 가장 큰 기여도를 확인하였다. 또한 한반도 내륙에서 유출된 영양염류 총량이 연안의 수질에 끼치는 영향을 조사하고자 내륙 하천과 연안의 수질 간의 상관관계를 조사하여 간접적으로 파악하였다. 본 연구는 분석적인 접근을 통해 하천과 연안 수질 환경에서 수문학적인 연결고리의 중요성을 강조하고, 영양염류 유출 변화가 해안에 서식하는 생태계와 양식산업 생산성에 미치는 잠재적인 영향을 강조하였다.

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Operating Optimization and Economic Evaluation of Multicomponent Gas Separation Process using Pressure Swing Adsorption and Membrane Process (압력 순환 흡착과 막 분리공정을 이용한 다성분 기체의 분리공정 조업 최적화 및 경제성 평가)

  • Kim, Hansol;Lee, Jaewook;Lee, Soobin;Han, Jeehoon;Lee, In-Beum
    • Korean Chemical Engineering Research
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    • v.53 no.1
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    • pp.31-38
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    • 2015
  • At present, carbon dioxide ($CO_2$) emission, which causes global warming, is a major issue all over the world. To reduce $CO_2$ emission directly, commercial deployment of $CO_2$ separation processes has been attempted in industrial plants, such as power plant, oil refinery and steelmaking plant. Besides, several studies have been done on indirect reduction of $CO_2$ emission from recycle of reducing gas (carbon monoxide or hydrogen containing gas) in the plants. Unlike many competing gas separation technologies, pressure swing adsorption (PSA) and membrane filtration are commercially used together or individually to separate a single component from the gas mixture. However, there are few studies on operation of sequential separation process of multi-component gas which has more than two target gas products. In this paper, process simulation model is first developed for two available configurations: $CO_2$ PSA-CO PSA-$H_2$ PSA and $CO_2$ PSA-CO PSA-$H_2$ membrane. Operation optimization and economic evaluation of the processes are also performed. As a result, feed gas contains about 14% of $H_2$ should be used as fuel than separating $H_2$, and $CO_2$ separation should be separated earlier than CO separation when feed gas contains about 30% of $CO_2$ and CO. The simulation results can help us to find an optimal process configuration and operation condition for separation of multicomponent gas with $CO_2$, CO, $H_2$ and other gases.

Estimation of C Storage and Annual $CO_2$ Uptake by Street Trees in Gyeonggi-do (경기도 도시가로수의 탄소저장량과 연간 이산화탄소 흡수량 산정)

  • Park, Eun-Jin;Kang, Kyu-Yi
    • Korean Journal of Environment and Ecology
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    • v.24 no.5
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    • pp.591-600
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    • 2010
  • We estimated and compared C storages and annual $CO_2$ uptakes by 9 dominant tree species planted along the streets. DBH and age by tree species were measured in the sites selected considering the planting status and distributions of tree species, and biomass, C storage, growth rate, and annual $CO_2$ uptake were estimated for each species. As a result, L. tulipifera, M. glyptostroboides, P. occidentalis were classified into fast-growing group, P. serrulata, G. biloba, Z. serrata, S. japonica, A. palmatum showed intermediate growth rates, and P. densiflora was slow-growing. Average C storage per tree was 205kgC/tree and ranged from 518kgC/tree(L. tulipifera) to 41kgC/tree(P. densiflora). Average annual $CO_2$ uptake by urban street trees over their lifespan ranged from $7.6kgCO_2$/tree/y to $99.1kgCO_2$/tree/y and L. tulipifera was the greatest, followed by glyptostroboides and P. occidentalis, and P. densiflora was the lowest. Total annual $CO_2$ uptake by all street trees in Gyeonggi-do, estimated based on the annual $CO_2$ uptake by each species, was as small as approximately 0.67% of that by forest in Gyeonggi-do. However, urban trees are still important because forest area continues to decrease and urbanization occurs annually in Gyeonggi-do, and should be managed considering their multi-functional aspects, including mitigation of heat island effect and building energy saving(indirect $CO_2$ uptake).

Carbon control and environmental policy in the U.K. : A reappraisal of strategies for the green state (영국의 탄소규제와 환경정책 : 녹색국가 전략의 재평가)

  • Choi, Byung-Doo;Shin, Hae-Ran
    • Journal of the Korean association of regional geographers
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    • v.19 no.2
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    • pp.301-323
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    • 2013
  • The government of the UK since the 1990, especially under the new Labour Party, has pursued sustainable development or carbon control as a core strategy for its national development. The seemingly prominent environmental policy for 'greening the government' of the UK as well as considerable achievements in energy and environment indices have attracted much attentions of policy makers and researchers for the 'low carbon green growth' in Korea. This paper tries to see the character of carbon control and environmental policy in the UK not merely as the integrating or mainstreaming policy but a new strategy for national development, that is, for the 'ecologically modernized' state, eco-state, or green state. It defines the environmental policy for carbon control in the UK as the strategy for the green state which has provided it as a principal guide for integrating national policies as a whole, and which has pursued it through market-dependent neoliberal measures. From this point of view, this paper introduces the development process of carbon control and environmental policy mainly under the new Labour Party government in the UK, and gives a reappraisal of both its policy and of energy-environment indices.

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Interaction Between Plants and Rhizobacteria in Phytoremediation of Heavy Metal- Contaminated Soil (중금속 오염 토양의 식물상 복원에 있어 식물과 근권세균의 상호작용)

  • Koo So-Yeon;Cho Kyung-Suk
    • Microbiology and Biotechnology Letters
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    • v.34 no.2
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    • pp.83-93
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    • 2006
  • In heavily industrialized areas, soil sites are contaminated with high concentrations of heavy metals. These pollutants are highly accumulated to the human body through the food web and cause serious diseases. To remove heavy metals from the soil, a potential strategy is the environmental friendly and cost effective phytoremediation. For the enhancement of remediation efficiency, the symbiotic interaction between the plant and plant growth-promoting rhizobacteria (PGPR) has been attended. In this review, the interaction of the plant and PGPR in the heavy metal-contaminated soil has been reviewed. The physicochemical and biological characteristics of the rhlzosphere can influence directly or indirectly on the biomass, activity and population structure of the rhizobacteria. The root exudates are offered to the soil microbes as useful carbon sources and growth factors, so the growth and metabolism of rhizobacteria can be promoted. PGPR have many roles to lower the level of growth-inhibiting stress ethylene within the plant, and also to provide iron and phosphorus from the soil to plant, and to produce phytohormone such as indole acetic acid. The plant with PGPR can grow better in the heavy metal contaminated soil. Therefore higher efficiency of the phytoremediation will be expected by the application of the PGPR.

A study on the promotion for rail transport in Ui-Wang ICD (의왕 ICD 철도수송 활성화 방안에 대한 연구)

  • Yun, Dong-Hee;Lee, Yong-Sang
    • Proceedings of the KSR Conference
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    • 2010.06a
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    • pp.1603-1614
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    • 2010
  • As the Kyoto protocol and Bali road-map, our country is expected to be included to the emission reduction controlled country of greenhouse gas, so we are now urgent situation to take an action in the level of government. In this research, environment friendly rail logistics and combined transport were treated to meet with the green growth policy of our government. Major problems of Ui-wang ICD suggested in this research are short of yards, unutilized public CY, inconvenience use by non-share holders. It is necessary to improve rail logistic infrastructure, that is, additional expansion of yard, direct operation by KORAIL and regular unloading system are needed. such improvement can not be solved just by the endeavor of business body. Rail logistic infra & Integrated freight terminal has a tendency of SOC, which require tremendous amount of investment, so there are some limit in doing by private sector itself, now it's time to do by the government level. The improvement of rail logistic infrastructure in the level of government is possible by the policy of environment friendly green logistic support which is related with Logistic Policy Basic Law, so government should prepare detailed directives to activate Integrated freight terminal.

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Detection of Aflatoxin $M_1$ in Human and Porcine Urine and Its Risk Assessment (인축의 뇨 중 aflatoxin $M_1$의 오염분석 및 위해성 평가)

  • Kim, Hyun-Jung;Kwak, Bo-Yeon;Shon, Dong-Hwa
    • Korean Journal of Food Science and Technology
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    • v.41 no.2
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    • pp.215-219
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    • 2009
  • To conduct a risk assessment of $AFB_1$ intake, $AFM_1$, which is a metabolite of $AFB_1$ in the human and porcine urine, was determined by competitive direct ELISA (cdELISA). The detection limit of cdELISA using anti-$AFM_1$ antibody and $AFB_1$-HRP conjugate was 10 pg/mL. The recoveries of $AFM_1$ were 117-167% after the addition of $AFM_1$ in the human urine in a range of 3-100 pg/mL. 165 samples (95.5%) of those obtained from 172 persons evidenced measurable levels of urinary $AFM_1$. The detected $AFM_1$ ranges were 0-11.6 pg/mL and the average level of $AFM_1$ contamination was 2.74${\pm}$ 1.89 pg/mL. The estimated amount of $AFM_1$ excretion in the human urine was 3.97 ng/day and the estimated $AFB_1$ intake amount was 79.4 ng/day. The probable daily intake (PDI) of $AFB_1$ by the subjects was estimated to be 1.28 ng/kg bw/day, which was higher than the tolerable daily intake (TDI, 0.15 ng/kg bw/day). In the case of porcine urine, the $AFM_1$ ranged between 0.97-26.7 pg/mL and the average contaminated $AFM_1$ was 10.62${\pm}$4.39 pg/mL. The estimated amount of $AFM_1$ excretion in the porcine urine was 27.6 ng/day, and the estimated $AFB_1$ intake amount was 551 ng/day.