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Influence of Carbonation for Chloride Diffusion in Concrete (탄산화 복합환경시 염소이온 확산에 관한 연구)

  • Oh Byung-Hwan;Lee Sung-Kyu;Lee Myung-Kue;Jung Sang-Hwa
    • Journal of the Korea Concrete Institute
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    • v.17 no.2 s.86
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    • pp.179-189
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    • 2005
  • Corrosion of steel due to chloride attack is a major concern in reinforced concrete structures which are located in the marine environments. In this case, Fick's 2nd law has been used for the prediction of chloride diffusion related with service life of concrete structures. However, those studies were confined mostly to the single deterioration due to chloride only, although actual environment is rather of combined type. The purpose of the present study is, therefore, to explore the influences of carbonation to chloride attack in concrete structures and to investigate the validity of Fick's law to chloride attack combined carbonation. The test results indicate that the chloride ion profiles from Fick's law using the diffusion coefficient of immersion tests is not reflected the effect of separation of chloride ions in carbonation region but valid in sound region in case of combined action. On the other hand, the chloride ion profiles from Fick's law using the diffusion coefficient of Tang and Nilsson's method coincide with test results under dry-wet condition but not under combined condition. The results of present study may Imply that the new method for the measurement of diffusion coefficient is required to predict the chloride ion profiles in case of combined action at early.

Study on Decline of Trees by Acid Rainfall (산성 강우에 의한 수목의 쇠퇴현상(I) - 음이온을 중심으로 -)

  • Lee, Chong-Kyu;Hwang, Jin-Hyoung;Kim, Jong-Kab
    • The Korean Journal of Ecology
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    • v.27 no.6 s.122
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    • pp.347-353
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    • 2004
  • This study was carried out to analyze pH, Electrical conductivity(EC), cation and anion on rainfall and throughfall raining at industrial area(Onsan and Nongso of Ulsan city), suburban area(Myeongsek-myeon of Jinju city) and rural area(Haman and Changyoung-gun), and to investigate $SO_2\;and\;NO_2$ concentration in the air of industrial area and rural area, and to survey degree of decline of Pinus thunbergii growing at each area. The rainfall pH was higher than the throughfall pH at the all surveyed areas. The rainfall pH and throughfall pH was $4.76{\sim}5.15\;and\;4.64{\sim}4.98,\;4.95{\sim}5.30\;and\;4.87{\sim}5.13,\;5.29{\sim}5.76\;and\;5.12{\sim}5.73$ at the industrial area, suburban area and rural area, respectively. The EC of rainfall and throughfall was $13.64{\sim}17.22\;and\;41.60{\sim}103.59,\;4.18{\sim}8.65\;and\;17.02{\sim}23.89,\;4.09{\sim}6.65\;and\;13.75{\sim}21.44$ at the industrial area, suburban area and rural area, respectively. Generally EC at the industrial area was higher than those of suburban area and rural area. In the correlation analysis among Degree of decline on Pinus thunbergii and ingredients of rainfall, it showed that there was a negative correlation between Degree of decline and pH. There was a positive correlation between pH and $Cl^-$ respectively.

Chemical Properties of Precipitation in Related to Wind Direction in Busan, Korea, 2009 (풍향에 따른 2009년 부산지역 강수의 화학적 특성)

  • Jung, Woon-Seon;Park, Sung-Hwa;Lee, Dong-In;Kang, Deok-Du;Kim, Dongchul
    • Journal of the Korean earth science society
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    • v.35 no.2
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    • pp.104-114
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    • 2014
  • The variation of acidity, conductivity, and ion components in precipitation depending on the dominant wind direction was investigated from January, 2009 to December 2009 in Busan, Korea. Both southwesterly and northeasterly winds were dominant in Busan area. The volume-weighted mean acidity showed pH 7, and the high conductivity indicated 200 ${\mu}scm^{-1}$ in westerly wind. The volume-weighted mean equivalent concentration showed higher value of $K^+$ and $Cl^-$ in all wind directions. The composition ratio of $NO{_3}^-/SO{_4}^{2-}$ showed over 3 in northerly wind. The neutralization factors have been found to have higher value for potassium ion in northeasterly, easterly, southwesterly, and westerly winds compared with different wind directions, which indicated significant neutralization of acidic components over the region by potassium. Also, the concentration of sea salt has been found over 800 ${\mu}sm^{-3}$ in northeasterly and southwesterly winds. Air masses passing through Manchuria, Inner Mongolia plateau, China, and Russia in spring, autumn, and winter covered Busan, Korea in northerly, westerly, and northwesterly winds. However, air masses passing through the ocean in summer covered Busan, Korea in easterly, northeasterly, and southwesterly winds. Therefore, the variation of acidity, conductivity, and ionic components contained in precipitation shows each seasonal characteristics with prevailing wind systems between the continental and coastal area in Busan, Korea.

Model Optimization for Sea Surface Wind Simulation of Strong Wind Cases (강풍 사례의 해상풍 모의를 위한 모형의 최적화)

  • Heo, Ki-Young;Lee, Jeong-Wook;Ha, Kyung-Ja;Jun, Ki-Cheon;Park, Kwang-Soon
    • Journal of the Korean earth science society
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    • v.29 no.3
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    • pp.263-279
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    • 2008
  • This study is concerned with the optimization of models using MM5 and WRF mesoscale numerical models to simulate strong sea surface winds, such as that of typhoon Shanshan on 17 September 2006, and the Siberian high event on 16 December 2006, which were selected for displaying the two highest mean wind speeds. The model optimizations for the lowest level altitude, physical parameters and horizontal resolution were all examined. The sea surface wind values obtained using a logarithmic function which takes into account low-level stability and surface roughness were more accurate than those obtained by adjusting the lowest-level of the model to 10 m linearly. To find the optimal parameters for simulating strong sea surface winds various physical parameters were combined and applied to the model. Model grid resolutions of 3-km produced better results than those of 9-km in terms of displaying accurately regions of strong wind, low pressure intensities and low pressure mesoscale structures.

Cretaceous Pterosaur Tracks in Daegok-ri, Ulju-gun, Ulsan: Spatio-temporal Distribution of Pterosaur in the Korean Peninsula (울산 울주군 대곡리에서 산출된 백악기 익룡 발자국: 한반도 익룡의 시공간적 분포)

  • Ha, Sujin;Chae, Yong-Un;Lim, Jong Deock;Kim, Cheong-Bin;Lim, Hyoun Soo;Kim, Kyung Soo
    • Journal of the Korean earth science society
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    • v.39 no.5
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    • pp.458-472
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    • 2018
  • Pterosaur tracks were discovered recently in the Daegok-ri dinosaur tracksite (Ulsan Metropolitan City Cultural Properties No. 13), Ulju-gun, Ulsan. Those tracks were reported as being the first in the Cretaceous deposits of Ulsan area. This tracksite is located relatively far from the Gyeongsangnam-do coastal area where pterosaur tracks were reported intensively, and there are stratigraphic differences. This study described the pterosaur tracks and trackway of the Daegok-ri tracksite and discussed the spatio-temporal distribution of the Cretaceous pterosaurs in the Korean Peninsula. The pterosaur footprints founded in Daegok-ri can be classified as Pteraichnus ichnosp., followed by the morphological characteristics. Based on the distribution of the pterosaur tracks on the Korean Peninsula including the Daegok-ri pterosaur tracks, it was estimated that the Cretaceous pterosaurs on the Korean Peninsula had survived approximately for 40 million years from 120 Ma (i.e., Early Cretaceous) to 80 Ma (i.e., Late Cretaceous) and inhabited in various sedimentary environments regardless of the basin size and the specific sedimentary environments. Furthermore, the occurrence of the sauropod, ornithopod, theropod, pterosaurs, birds, and crocodyliforms tracks/trackways in the Daegok-ri area represented that the Cretaceous vertebrate ichnodiversity was fairly high.

Changes of the Protein Contents of Seafood Cooking Drips by Gamma Irradiation (감마선 조사에 의한 수산 자숙액의 단백질 함량 변화)

  • Choi, Jong-Il;Kim, Hyun-Joo;Sung, Nak-Yun;Byun, Eui-Baek;Kim, Jae-Hun;Chun, Byung-Soo;Ahn, Dong-Hyun;Cho, Kook-Yeon;Byun, Myung-Woo;Lee, Ju-Woon
    • KSBB Journal
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    • v.23 no.6
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    • pp.489-493
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    • 2008
  • Although the seafood cooking drips were the byproducts from the fishery industry and being wasted, it had many nutrients including proteins. In this study, the effect of a gamma irradiation on the cooking drips from Hizikia fusiformis, Enteroctopus dofleni and Thunnus thynnus were investigated. The cooking drips were extracted with 70% ethanol solution, and the extracts were analysed for the protein concentration by three different methods of Lowry, BCA and Kjeldahl. The extracts were irradiated with different doses and the protein contents were compared with respect to the absorbed doses. Total content of the proteins was increased with increasing irradiation dose. The change of protein pattern in the irradiated cooking drips was also confirmed by SDS-PAGE analysis. These results shown that the proteins in cooking drips could be unfolded or aggregated by the irradiation. Therefore, gamma irradiation could be considered as an effective method for extracting useful proteins.

An Empirical Analysis on the Presumption of Public Apartment's Construction Cost in Housing Land Development Project (택지개발사업의 공공주택건설공사비 추정의 실증적 분석)

  • Kim, Seong-Hee
    • Korean Journal of Construction Engineering and Management
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    • v.12 no.2
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    • pp.81-88
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    • 2011
  • Providers haven't recently had a flexible construction cost estimation system to meet various needs of consumers about public housing. So the subject of this study is to estimate construction cost reasonably in early project stage of public housing and then develop reliable means which is able to support construction cost management and establish a adequate funding investment plan as a provider. In this study, Regression analysis was performed by the case on 20 public apartment complex which were designed from the first half of 2007 to the first half of 2008. A total construction cost of construction, civil engineering, machinery, elevator, land scape, electricity and communication work was used as one sample for increasing explanation and representativeness of the case. In addition, The total construction cost which is devided into design, contract and completion cost was variously analysed for increasing relevance of model and actual utilization. The result of estimation model based on a total construction cost set up completion and design cost showed that error rate is within 2%, which is a excellent result. The estimation model of the construction cost developed by this study is expected to estimate approximate construction cost which is adjacent real construction cost in early stage of the project by using some data.

Mixed Carbon/Polypyrrole Electrodes Doped with 2-Naphthalenesulfonic Acid for Supercapacitor (2-Naphthalenesulfonic Acid로 도핑된 혼합카본/폴리피롤을 이용한 Supercapacitor용 전극)

  • Jang, In-Young;Kang, An-Soo
    • Korean Chemical Engineering Research
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    • v.43 no.3
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    • pp.425-431
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    • 2005
  • New type of supercapacitor using high surface area activated carbons mixed with high conductivity polypyrrole (Ppy) has been prepared in order to achieve low impedance and high energy density. Mixed carbons of BP-20 and MSP-20 were used as the active electrode material, and polypyrrole doped with 2-naphthalenesulfonic acid (2-NSA) and carbon black (Super P) as conducting agents were added to activated carbons in order to enhance good electric conductivity. Electrodes prepared with the activated electrode materials and the conducting agents were added to a solution of organic binder [P(VdF-co-HFP) / NMP]. The ratio of optimum electrode composition was 78 : 17 : 5 wt.% of (MSP20 : BP-20=1 : 1), (Super P : Ppy=10 : 7) and P(VdF-co-HFP) respectively. The performance of unit cell with addition of 7 wt% Ppy have shown specific capacitance of 28.02 F/g, DC-ESR of $1.34{\Omega}$, AC-ESR of $0.36{\Omega}$, specific energy of 19.87 Wh/kg and specific power of 9.77 kW/kg. With addition of Ppy, quick charge-discharge of unit cell was possible because of low ESR, low charge transfer resistance and quick reaction rate. And good stability up to 500 chargedischarge cycles were retained about 80% of their original capacity. It was concluded that the specific capacitance originated highly from compound phenomena of the pseudocapacitance by oxidation-reduction of polypyrrole and the nonfaradaic capacitance by adsorption-desorption of activated carbons.

An Analysis on the Plan of Revitalizing Investment for Developing Countries on the Development Project Applying System Dynamics (시스템 다이내믹스를 이용한 개발도상국 진출 및 투자개발형 사업 활성화 지원정책 분석)

  • Kim, Jae-Won;Ahn, Byung-Ju;Lee, Yoon-Sun;Kim, Jae-Jun
    • Proceedings of the Korean Institute Of Construction Engineering and Management
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    • 2007.11a
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    • pp.513-518
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    • 2007
  • Domestic construction companies are interested in finding a larger market abroad because of declining the amount of orders placed and competing the amount of orders received. Recently, the Development project including the finance offer by builder is becoming more common and broad in the flow of the world market in construction from underdeveloped countries to the advanced countries. If the construction companies revitalized because of being active in the Middle East market don't appropriately cope with the situation, they will be probably depressed. The support policies helped revitalization of the development project are examined in this study. The purpose of this study is basic data how to be influenced by the situation of market abroad, policies revitalized development project and extending market. The policies revitalized development project and the relationship of many variables near the market abroad are analyzed applying the System Dynamics as hopeful market abroad which have a circumstance finding a larger market.

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An Analysis of Best Practices for Efficient Utility Relocation and an Inquiry into the Applicability of SUE (효율적인 지하지장물 이설을 위한 모범사례분석 및 SUE 적용에 관한 연구)

  • Lee, Seung-Hyun;Baek, Seung-Ho;Tae, Yong-Ho;Ahn, Bang-Ryul;Park, Hyeon-Yong
    • Proceedings of the Korean Institute Of Construction Engineering and Management
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    • 2007.11a
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    • pp.971-976
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    • 2007
  • In the U.S., utility damages or utility delay caused by conflicts during the underground utility relocation is one of the weighty problem in the construction industry. Also, in domestic case, delay and additional cost caused by underground utility(i.e, electricity, communication, gas, water supply and sewerage) relocation has been happened so that there is an increase of claims for responsibility between owners and contractors. However, there is insufficient survey for the recent circumstance of additional cost for delay and design changes caused by utility relocation and shortage of enough research for solving and analyzing of causes and their ripple effect. This research presents a result of the study about the best practices of FHWA(Federal Highway Administration), SHAs(State Highway Agencies) and the utility companies managing utility relocation. Also, it presents the basic concept of SUE(Subsurface Utility Engineering), the most reliable tool of FHWA presented, and investigates the developing status about SUE in Korea. At the end of this paper, this research proposes a practical and more applicable study about the efficient utility relocation focusing on local industry.

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