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Studies on the Interaction of Biocides and Ethylsilicate Consolidants for Stone Monument (석조문화재 살생물제와 에틸실리게이트 강화제의 상호작용에 관한 연구)

  • Do, Jin-Young;Yun, Yun-Kyung;Lee, Tae-Jong;Kyung, Hye-Sun
    • Journal of Conservation Science
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    • v.21
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    • pp.73-88
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    • 2007
  • In this paper, the interaction between five biocides(commercial) and two ethylsilicate consolidants for stone monuments, reacted in different sequence, has been studied. Through the structures, weight and gelation time of mixture of biocides and consolidants have been evaluated the reactivity of biocide alone, the reactivity of consolidants and biocides, the reactivity of consolidants and dried biocide, and the reactivity of ethylsilicate gel and biocides. The tested biocides show quite different properties from those of consolidants; after evaporation, some biocides are remained white salt crystals, another need the long time for evaporation and one biocide shows pale brown color. The results have shown an interaction of the tested products each other in some application sequences of the products. When the application of liquid state biocides with consolidants, it was noted that some biocide seem to interfere with the formation of gel due to reaction of consolidants and water and salts in biocides. In the reaction of ethylsilicate with dried biocides have shown a heterogenous gel(transparent layer with ethylsilicate alone and white layer which is mixed biocide and ethylsilicate) and many cracks in product due to the different shrinkage, thus the products don't play a role as consolidants. There is no change in structures and color in reaction of the gas state biocide and ethylsilicate gel.

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Assessment of Durability of Stone Monument Using Specimens from Old Stone Quarry (고대 채석장 부지의 시료를 이용한 석조문화재 내구성 평가)

  • Park, Hyeong Dong;Shin, Gi Hye;Aboushook, M.
    • 한국문화재보존과학회:학술대회논문집
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    • 2001.11a
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    • pp.19-24
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    • 2001
  • This study mainly reports preliminary results from site investigation of the Great Pyramids and Sphinx in Egypt and sampling works where conducted in the same limestone beds in Mokattam quarry in Cairo. Analyses of composition of samples showed similar result to those of limestone in Giza and thus such samples can be easily used for further experimental work without disturbing real monuments. Future work will be concentrated on the change of engineering properties of samples before and after artificial weathering and the change of digital image acquired from the colored surface of monuments.

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Deterioration of the Rock-carved Seated Buddha at Golguram Hermitage, Gyeongju and Effect of the Ethylsilicate Consolidant (경주 골굴암 마애여래좌상 구성암석의 손상과 에틸실리케이트 암석강화제의 효과)

  • Do, Jin Young
    • Journal of the Mineralogical Society of Korea
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    • v.30 no.2
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    • pp.71-81
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    • 2017
  • Rock properties and the effects of chemicals that were used for conservation were studied for effective conservation treatment of Seated Buddha rock carving, which is composed of grayish white tuff, at Golguram Hermitage, Gyeongju. The rocks contain 3-5% montmorillonite, a swelling mineral and reacting with water, the d spacing of swelling minerals was increased (1.54-2.69%). On the one hand, the physical properties of the rock samples, such as surface hardness, water absorption rate, and porosity improved after the application of ethyl silicate-based stone strengthener. On the other, the interlayer of swelling minerals decreased and greater the of swelling mineral content, the greater is the extent of swelling (4.23-12.12%). When the ethyl silicate-based stone strengthener was applied after pretreatment with a swelling inhibitor, the physical properties were similar to those of the stone strengthener alone. There was no interlayer spacing change of swelling minerals due to swelling inhibition treatment; however, when the stone strengthener was applied after the swelling inhibitor, interlayer changes were similar to those when only the stone strengthener was treated (4.10-11.85%). Though the peak intensity of swelling minerals in X-ray diffraction pattern decreased, the effect of the swelling inhibitor was almost negligible. Therefore, it is not appropriate to use ethyl silicate-based stone strengthener for Golgulam rock containing swelling minerals and supplementing them with a swelling inhibition system is not effective. Because weathering rapidly progresses when swelling minerals contact moisture, for now, measures to prevent water contact, such as expansion of the canopy, are needed in the lower and side parts of the carving.

Measurement of Crack Depth and Weathering Degree Using Ultrasonic Velocity and Deterioration Evaluation of the Unhyungung Stone Water Container (운현궁수조의 손상평가와 초음파 속도를 이용한 풍화도 및 균열심도 측정)

  • Chun, Yu-Gun;Lee, Chan-Hee;Jo, Seung-Nam;Jo, Yeong-Hoon;Park, Gi-Jung;Yang, Pil-Seung
    • Journal of Conservation Science
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    • v.24
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    • pp.1-11
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    • 2008
  • The Unhyungung Water Container in the possession of the Seoul Museum of History in Korea is consisted of a calcareous marble developed laminated bedding and numerous argillaceous veinlets. This monument should need to conservation treatment because of black discoloration and seriously numerous cracks. Vertical and horizontal cracks in the monument are developed following stratification and argillaceous veinlets that are relatively low coherence between the rock materials. We have proved that the material inducing discoloration on the surface is carbon which is formed by deposited organic matters. As the result of the ultrasonic measurements, although highly surface weathering degree, the physical properties of the Unhyungung Water Container is confirmed slightly weathered state. The depths of cracks in the monument are calculated at maximum 60mm in some cracks completely penetrating into the wall and at minimum 9mm in the other crack. The cracks, developed following veinlet, are revealed that there penetrate from an outer wall to an inside wall for the monument. And most depths of cracks, developed following stratification, are calculated 20 to 30mm. This result will offer a significant data for conservation of the Unhyungung Water Container.

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A Study on the Use Planning of Geomorphic Resources within Biseulsan(Mt. Biseul), in Daegu City (대구 비슬산지 내 지형자원의 활용방안에 관한 연구)

  • Jeon, Young-Gweon;Son, Myoung-Won
    • Journal of the Korean association of regional geographers
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    • v.10 no.1
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    • pp.53-66
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    • 2004
  • There are various granite landforms including block stream(natural monument No. 435) within Mt. Biseul, in Daegu city. The Daegyunsa(temple) and community of rhododendron around the summit of the mountain provide visitors many objects o( interest in cultural & ecological heritage. This paper aimed to develope nature trails of various type according to visitor's characteristics. 1) Various granite landforms develope along with the main path up the mountain(block stream-gnamma-exfoliation-poligonal cracking-talus-core stone-sheeting joint-tor-free face-high flat summit). 2) The explanatory note on terminology, origin, characteristics of geomorphic resources are developed in this paper for the first time. 3) In Consideration of the path line of flow of visitor, the best field study sites and the most effective nature trails are designed for visitor. 4) Three nature tails are designed for visitor according to the type and the length of visitor's stay.

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Art and Science Revaluation on Literary Outwards of Kim SaKat related with Gossi Cave in Youngworl (영월하동 고씨동굴과 난고 김삿갓 시선의 문학외적 학술평가)

  • Soh, Dea-Wha
    • Journal of the Speleological Society of Korea
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    • no.79
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    • pp.17-30
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    • 2007
  • Gossi-cave, which is Natural monument No. 219, originally was called Norigok-cave, but happened Imjin-Japanese war, aborigine and Gossi family took refuse to Norigok-cave. Japanese soldiers set fire to this cave, in result lots of people had been died. And then, this cave was called Gossi-cave because Gossi family only survived during the war. Stalactite, Stone pillar that was created from four hundred million ago Harmonized with the others. The length is 6.3km in 1969.6.4. this cave was appointed natural monument as a result of investigating Korean Speleological Society. Kim SaKat a Master Poet(1807-1863) : A Genius with wit and eccentric conduct, a poet who wrote a refined poems with his own dramatic path of life destructed the format of Chines poem and created a new folk literature. He is Kim SaKat - a wizard of poet Kim Sakat - a poet wearing conical bamboo hat. Kim Sakat was born in 1807, in the latter part of Chosun period, his antonym was Kim Byung-Yun. He passed the state examination in the first place when he was 20. Two years later, he set out his life as a wanderer when he realized his winning composition was a criticism on his grandfather.

Removal Methods of Paint Pollutants on the Stone Cultural Heritage using Poultices (습포제를 이용한 석조문화재의 페인트 오염물 제거기법 연구)

  • Lee, Joo-Wan;Ham, Chul-Hee;Kim, Sa-Dug;Lee, Chan-Hee
    • Journal of Conservation Science
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    • v.25 no.4
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    • pp.421-430
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    • 2009
  • This research was carried out focusing on the urgent treatment and related studies for paint scribbling on Samjeondobi Monument (Historic Sites No. 101) in 2007. Before the preliminary test, the paint lacquer used on the surface of Samjeondobi Monument was analyzed. The paint lacquer turned out to be the paint lacquer spray composed of $Pb_3O_4$ used for the red pigment in the market. It was proved that the poultice used with the organic solvent was the best way to remove the paint pollutants following the preliminary test for the removal of paint pollutants which was performed with various removal methods by the laser, etc. However, the removing the paint pollutants was found in difficulty in contrast to the preliminary tests because the paint on the spot was hardened so rapidly over time that there was difference from the situation of the laboratory. For that problem, the poultice method with ethylene dichloride of main component from Remover (goods in the market) was the most efficient, therefore the pollutants were removed with the solution of alkyds resin and nitrocellulose and the rest part was removed by the $Laponite^{(R)}$ RD.

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Influence of the Soluble Salt on the Exfoliation of the Stone Monument (수용성염이 석조문화재 표면 박리현상에 미치는 영향)

  • Do, Jin-Young;Lim, Kwon-Woong
    • Journal of Conservation Science
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    • v.22
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    • pp.121-134
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    • 2008
  • The mechanism of stone exfoliation and its cause in relation to chemical weathering by soluble salt were studied. Chemical, mineralogical and physical analysis was performed in exfoliation samples from stone monuments. The representative salt is gypsum in the exfoliation samples. In order to understand the salt reaction, stone samples(tuff and granite) were treated with two type of the salt, gypsum and sodium sulfate, which have different solubility. The capillary water uptakes are slight increased in impregnated with Na2SO4 and weathering simulation of two rock types. It means that the rock is deteriorated in the near of the surface by $Na_2SO_4$. $CaSO_4{\cdot}2H_2O$ bring out the thicker exfoliation than $Na_2SO_4$ because it is penetrated into the deeper zone and amount of accumulated salt is more abundant in the inner part than in the near of the surface. The exfoliation was formed in the tuff by salt treatment and 30cycle of weathering simulation, but there are not significant symptoms of exfoliation in the granite by same condition. This result was caused by the different capillary water uptakes and porosity of the rocks. In the tuff, salt solutions are penetrated into the inner part due to its high capillary water uptakes and porosity but the granite, which has low value relatively, can be formed thinner exfoliation.

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Studies on the Relationship between Bacteria and Soluble Salts on Surface Layer of Stone Monument (석조문화재 표면 수용성 염과 서식세균의 상관관계 연구)

  • Yun, Yun-Kyung;Do, Jin-Young;Kim, Tae-Hyung;Seong, Hyun-Jeong;Choi, Ji-Sook
    • Journal of Conservation Science
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    • v.21
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    • pp.59-72
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    • 2007
  • The relationship between soluble salts and microbial growth on stone surface was investigated. Samples from deteriorated surface layers of several stone monuments were collected, and the soluble salts in samples were chemically analysed. According to the results of chemical analyses, $Na_2SO_4$, $CaSO_4$ $2H_2O$, and NaCl and so on were added to isolation media. As a result of preliminary experiments, 15 bacteria were selected. They are all Gram positives and fourteen of them were rods. Every bacteria could grow not only in media without salts, but also in media with $CaCO_3$, $CaSO_4$ $2H_2O$, and $Ca(OH)_2$. Three bacteria, Bl6, B56, and B6l, secreted viscous substances in these $Ca^{2+}$ added media. $CaCl_2$ $2H_2O$ was the most hygroscopic among 11 soluble salts, but it seemed to interfere with bacterial growth. Ammonium ion was the inhibitor, too.

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The Epigraph Reading Method using a Visualization Technique based on Morphological Characteristics of the Letters (각자된 글자의 형태적 시각화를 이용한 금석문 판독방법)

  • Choi, Won-Ho;Ko, Sun-Woo
    • The Journal of the Korea Contents Association
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    • v.17 no.1
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    • pp.740-749
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    • 2017
  • The epigraphy is a text or a picture engraved on metal or stone. One of advantages of rubbing of ancient inscription has been used in epigraphic field is simple. But the rubbing is not an optimal method in viewpoints of resolution and noise to decode the inscribed characters. In this study, we proposed a new research method that increases the possibility of a reading by reflecting the 3D characteristics of the engraved letters. The proposed techniques apply 3D scanning technology to obtain three-dimensional and high quality data of each of the letters in the epigraphy and use Ambient Occlusion visualization techniques to express the shade according to the 3D form of the letters. Research result enhances the readability of the letters that removed the damaged and worn information from the letters information of surface. This research contributes to narrow the scope of a particular letter and read to the controversial letters on the Pohang Jungsoengri Silla Stone Monument(Korea's national treasure number 318).