• Title/Summary/Keyword: (Mn, Zn)ferrite

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The Electromagnetic and Thermal Properties of Magnetic Core Materials for the Power Line Communication as the function of Additives (첨가제에 따른 전력선 통신용 자심 재료의 전자기적 특성 및 발열거동)

  • 오영우;이혜연;김현식;허정섭;민복기;김종령
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.2
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    • pp.61-66
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    • 2003
  • The electromagnetic properties and thermal behavior of Mn-Zn ferrite cores used for the blocking filter in he Power Line Communication(PLC) application were investigated as the function of additives. The highest density and permeability of 4.98 g/㎤) and 8,221 respectively were obtained to the specimen with composition of MnO 24 mol%, ZnO 25 mol% and Fe$_2$O$_3$ 51 mol% added MnO$_3$ 400 ppm, SiO$_2$ 100 ppm and CaO 200 ppm since the uniform grains were organized and the microstructures were compacted through reduction of pores. The permeability was increased up to 13,904 as temperature of specimen increased to 11$0^{\circ}C$, however, it was decreased precipitously under 100 over 11$0^{\circ}C$. The exothermic behavior was observed in the frequency range from 1 kHz to 1 MHz that the maximum temperature of specimens became 102$^{\circ}C$ at 1 MHz. In the consequence, the Mn-Zn ferrite core developed by this research will maintain the stable electromagnetic properties since the temperature of ferrite core rose to 93$^{\circ}C$ in the range of 10 kHz to 450 kHz bandwidth qualified for PLC.

A Study on Multi-Layered EM Wave Absorber Using Natural Lacquer as a Binder

  • Choi, Dong-Han;Kim, Dong-Il;Choi, Chang-Mook;Li, Rui
    • Journal of Navigation and Port Research
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    • v.30 no.9
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    • pp.767-772
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    • 2006
  • Generally, a silicone rubber and a chlorinated polyethylene(CPE) have been used as a binder for the development of high-performance composite EM(Electro Magnetic) wave absorbers. In this paper, the EM wave absorption performance of natural lacquer, which is newly proposed as a binder was investigated. The prepared MnZn ferrite EM wave absorbers are mixed with natural lacquer showed excellent EM wave absorption characteristics compared with MnZn ferrite EM wave absorbers which are mixed with the conventional binders. MnZn ferrite EM wave absorbers mixed with natural lacquer were prepared and their absorption ability was also investigated The EM wave absorbers are fabricated in different proportions of MnZn, or NiZn ferrite and natural lacquer, and their reflection coefficients are measured. The permittivity and permeability are calculated by using the measured reflection coefficients. The EM wave absorption abilities are calculated according to different thicknesses of the EM wave absorbers.

A Study on Multi-Layered EM Wave Absorber Using Natural Lacquer as a Binder

  • Choi, Dong-Han;Kim, Dong-Il;Choi, Chang-Mook;Li, Rui
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • v.1
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    • pp.157-161
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    • 2006
  • Generally, a silicone rubber and a chlorinated polyethylene(CPE) have been used as a binder for the development of high-performance composite EM(Electro Magnetic) wave absorbers. In this paper, the EM wave absorption performance of natural lacquer, which is newly proposed as a binder was investigated. The prepared MnZn ferrite EM wave absorbers are mixed with natural lacquer showed excellent EM wave absorption characteristics compared with MnZn ferrite EM wave absorbers which are mixed with the conventional binders. MnZn ferrite EM wave absorbers mixed with natural lacquer were prepared and their absorption ability was also investigated. The EM wave absorbers are fabricated in different proportions of MnZn, or NiZn ferrite and natural lacquer, and their reflection coefficients are measured. The permittivity and permeability are calculated by using the measured reflection coefficients. The EM wave absorption abilities are calculated according to different thicknesses of the EM wave absorbers.

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Nickel Substitution Effects on Nano-sized Co, Mn and MnZn Ferrites Synthesized by Sol-gel Method

  • Choi, Won-Ok;Kwon, Woo Hyun;Chae, Kwang Pyo;Lee, Young Bae
    • Journal of Magnetics
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    • v.21 no.1
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    • pp.40-45
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    • 2016
  • Nickel substituted nano-sized ferrite powders, $Co_{1-x}Ni_xFe_2O_4$, $Mn_{1-x}Ni_xFe_2O_4$ and $Mn_{1-2x}Zn_xNi_xFe_2O_4$ ($0.0{\leq}x{\leq}0.2$), were fabricated using a sol-gel method, and their crystallographic and magnetic properties were subsequently compared. The lattice constants decreased as quantity of nickel substitution increased, while the particle size decreased in $Co_{1-x}Ni_xFe_2O_4$ ferrite but increased for the $Mn_{1-x}Ni_xFe_2O_4$ and $Mn_{1-2x}Zn_xNi_xFe_2O_4$ ferrites. For the $Co_{1-x}Ni_xFe_2O_4$ and $Mn_{1-x}Ni_xFe_2O_4$ ($0.0{\leq}x{\leq}0.2$) ferrite powders, the $M{\ddot{o}}ssbauer$ spectra could be fitted as the superposition of two Zeeman sextets due to the tetrahedral and octahedral sites of the $Fe^{3+}$ ions. However, the $M{\ddot{o}}ssbauer$ spectrum of $Mn_{0.8}Zn_{0.1}Ni_{0.1}Fe_2O_4$ consisted of two Zeeman sextets and one single quadrupole doublet due to the ferrimagnetic and paramagnetic behavior. The area ratio of the $M{\ddot{o}}ssbauer$ spectra could be used to determine the cation distribution equation, and we also explain the variation in the $M{\ddot{o}}ssbauer$ parameters by using this cation distribution equation, the superexchange interaction and the particle size. The saturation magnetization decreased in the $Co_{1-x}Ni_xFe_2O_4$ and $Mn_{1-2x}Zn_xNi_xFe_2O_4$ ferrites but increased in the $Mn_{1-x}Ni_xFe_2O_4$ ferrite with nickel substitution. The coercivity decreased in the $Co_{1-x}Ni_xFe_2O_4$ and $Mn_{1-2x}Zn_xNi_xFe_2O_4$ ferrites but increased in the $Mn_{1-x}Ni_xFe_2O_4$ ferrite with nickel substitution. These variations could thus be explained by using the site distribution equations, particle sizes and spin magnetic moments of the substituted ions.

Properties and defects of Mn-Zn Ferrite single crystals grown by the modified process (연속 성장법으로 성장된 Mn-Zn Ferrite 단결정 특성 및 결함)

  • 정재우;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.1 no.2
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    • pp.23-33
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    • 1991
  • Mn - Zn Ferrite has the natural characteristics of incongruent melting and the zinc oxide evaporation while the crystal is being grown. As a result of these, it comes into existence to be a non-uniform distribution of cations along the crystal growth axis and also Pt particles are usually precipitated into the crystals in Bridgman method since the melt zone is maintained for a long time in the crucible. These have bad effects on the magnetic properties of ferrites. But, to overcome these faults and then acquire the better single crystals. new modified growth method was developed and the growth factors were investigated as following: melt height in the crucible, surface tension and density of melt, the behavior of melt at interface, the shapes of crucible and solid -liquid interface, powder feeding rate, and the crystal growing speed. In additon, when we analyzed the compositional fluctuations of grown crystals, they were supressed within 1.5 mol% $Fe_20_3$, 2 mol% MnO, ZnO respectively with comparing to initial composition of crystal and the microstructures of crystals on the(110) plane were observed by optical microscope through the chemical etching technique and the magnetic properties were determined.

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Fabrication of Mn-Zn Ferrite by Hot Petroleum Drying Method (석유증발 건조방법에 의한 Mn-Zn Ferrite의 제조에 관한 연구)

  • 변수일
    • Journal of the Korean Ceramic Society
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    • v.16 no.2
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    • pp.69-76
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    • 1979
  • This study attempted to characterize the powder and sintered specimen of Mn-Zn ferrite that was prepared by Hot Petroleum Drying Method. The results of the experiment were as follows: 1. The mixed sulfate powder prepared by Hot Petroleum Drying Method was homogeneous and very reactive. The ferrite formation of this powder occurred at lower temperature than the one prepared by Sulfate Dry Mixing Method. 2. The calcined oxide powder prepared by Hot Petroleum Drying Method was found to be agglomerated, and therefore it was very difficult to compact this powder. 3. The sintered density was 4.95g/㎤, 97% of the theoretical density, when the specimen was prepared by Hot Petroleum Drying method, calcined at 90$0^{\circ}C$ in air for 3h, sintered at 1,30$0^{\circ}C$ in air for 3h, and then cooled in nitrogen. 4. The discontinuous grain growth occurred at lower temperature in the specimen prepared by Hot Petroleum Dyring Method than in the one prepared by Sulfate Dry Mixing Method. The discontinuous grain growth was considered to be due to the presence of liquid formed by addition of CaO and $SiO_2$.

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Microstructural Evoluation from the Oxidation-Reduction of Mn-Zn Ferrite Single Crystal (망간징크 페라이트 단결정의 산화-환원반응에 따른 미세구조의 변화)

  • 윤상영;김문규
    • Journal of the Korean Ceramic Society
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    • v.27 no.5
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    • pp.652-660
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    • 1990
  • Oxidation of Mn-Zn ferrite was made in air at various temperatures ranging from 400$^{\circ}C$ to 1150$^{\circ}C$. Subsequent reduction fo these oxidized samples was also made in air at 1300-1350$^{\circ}C$ where the spinel phase of Mn-Zn ferrite is stable. Morphological observation revealed that the shape of precipitated hematite was plate or lath type on the close-packed habit plane of {111} ferrite which has a definite orientation relationship. The growth of precipitates showed the behavior fo parabolic dependence of the oxidating time. An apparent activation energy for the growth was found to be 125${\pm}$3Kcal/mol. The fact that pores are observed along the precipitates illustrates the oxidation to occur dominantly by the counterdiffusion of cations and ction vacancies. For the reductio reaction pores are found to form at the site once occupied by the precipitates and at the surface. This observation illustrates that the oxygen volitalization from interior region to the surface is the dominant process for the reduction reaction.

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A Study on Composite EM Absorber's Absorption Characteristics Using Natural Lacquer by Binder (옻을 지지재로 사용한 복합형 전자파 흡수체의 흡수 특성에 관한 연구)

  • Choi, Dong-Han
    • Proceedings of the Korea Electromagnetic Engineering Society Conference
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    • 2003.11a
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    • pp.622-629
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    • 2003
  • Generally, a silicone rubber and a chloride polyethylene(CPE) have been used for the development of high-performance composite EM(ElectroMagnetic) wave absorber. In this study, the EM wave absorption abilities for natural lacquer which is newly suggested in this study as a binder for composite EM wave absorber were investigated to develop an improved EM wave absorber In addition, MnZn ferrite composite EM wave absorber mixed with the natural lacquer were prepared and their absorption ability was also investigated. MnZn ferrite composite EM wave absorber which employs the natural lacquer as a binder showed an improved EM wave absorption characteristics in comparison with the conventional binder such as a silicone rubber and a chloride polyethylene(CPE). The matching frequency and the absorption ability of EM wave absorber mixed with natural lacquer can be controled the change of the thickness of them.

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A Study on the EM Wave Absorber for the Electromagnetic Environment of Indoor Wireless LAN (실내 무선 LAN 전자파 환경 대책용 전파 흡수체에 관한 연구)

  • Yoon, Sang-Gil;Kim, Dong-Il;Lee, Dae-Hee;Choi, Chang-Mook
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.18 no.11
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    • pp.1224-1230
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    • 2007
  • Recently, wireless LAN are often applied in home or office because of its various of convenience. Frequency rage of wireless LAN specified by IEEE 802.11a is at 5.2 GHz and IEEE 802.11b is 2.4 GHz. But in offices with wireless LAN devices, reflection of waves against walls, ceilings, floors and desks made of metal creates multipath problems that reduce communication speed and lose data. These problems can be solved by using EM wave absorber. In this paper, we designed and fabricated EM wave absorbers using MnZn-ferrite, sendust, carbon and CPE(Chlorinated Polyethylene). The EM wave absorber with the ratio of MnZn-Ferrite : sendust : CPE=64 : 16 : 20 wt.% has thickness of 3.7 mm and absorption ability more than 17 dB at 2.4 GHz and the EM wave absorber with the ratio of MnZn-ferrite : carbon : CPE=40 : 15 : 45 wt.% has thickness of 3.8 mm and absorption ability more than 23 dB at 5.2 GHz.