• Title/Summary/Keyword: 'B' Film

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Deposition Of $TiB_2$ Films by High Density Plasma Assisted Chemical Vapor Deposition (고밀도 플라즈마 화학 증착 장치를 이용한 $TiB_2$ 박막 제조)

  • Lee S. H.;Nam K. H.;Hong S. C.;Lee J. J.
    • Journal of Surface Science and Engineering
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    • v.38 no.2
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    • pp.60-64
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    • 2005
  • The ICP-CVD (inductively coupled plasma chemical vapor deposition) process was applied to the deposition of $TiB_2$ films. For plasma generation, 13.56 MHz r.f. power was supplied to 2-turn Cu coil placed inside chamber. And the gas mixture of $TiCl_4,\;BCl_3,\;H_2$ and Ar was used for $TiB_2$ deposition. $TiB_2$ films with high hardness (<40 GPa) were obtained at extremely low deposition temperature $(250^{\circ}C)$, and the films hardness increased with ICP power and gas flow ratio of $TiCl_4/BCl_3$. The film structure was changed from (100) preferred orientation to random orientation with increasing RF power. It is supposed that the enhanced hardness of films was caused by a strong Ti-B chemical bonding of stoichiometric $TiB_2$ films and film densification induced by high density plasma.

Carbon Monoxide Sensor Based on a B2HDDT-doped PEDOT:PSS Layer

  • Memarzadeh, R.;Noh, Hui-Bog;Javadpour, S.;Panahi, F.;Feizpour, A.;Shim, Yoon-Bo
    • Bulletin of the Korean Chemical Society
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    • v.34 no.8
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    • pp.2291-2296
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    • 2013
  • An efficient carbon monoxide (CO) sensor was developed based on poly(3,4-ethylenedioxy)thiophenepoly(styrenesulfonate) (PEDOT:PSS) modified with a new pyrimidine-fused heterocyclic compound, bis(2-hydroxyphenyl)dihydropyrido[2,3-d:6,5-d]dipyrimidine-tetraone (B2HDDT). B2HDDT remains stable in the polymer matrix through interactions with functional groups of the polymer. It created prominent sites that captured CO gas, and the experimental parameters, including the amount of doped B2HDDT in the PEDOT:PSS film, were optimized. The sensor probe was also examined to verify its reliability for detecting CO in the presence of atmospheric gases in a discriminating manner. NMR, AFM, and FT-IR spectra were obtained to evaluate the structure and morphology of the B2HDDT-doped PEDOT:PSS (PEDOT:PSS/B2HDDT) film. The content of 35 vol % B2HDDT (7.0 mM) in PEDOT:PSS provided the largest response factor (${\Delta}R/R_o$) for the CO gas. The sensor response was reproducible, with a relative standard deviation < 5% (n = 5). The detection limit was determined to be $0.44{\pm}0.05$ vol %.

Structural and Dielectric Properties of BST-MgO with $B_2O_3-Li_2CO_3$ Thick Films ($B_2O_3-Li_2CO_3$가 첨가된 BST-MgO 후막의 구조 및 유전 특성)

  • Kang, Won-Seok;Kim, Jae-Sik;Koh, Jung-Hyuk;Lee, Young-Hie
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.19-20
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    • 2007
  • At first the $Ba_{0.5}Sr_{0.5}TiO_3$-MgO powder with $B_2O_3-Li_2CO_3$ were made by the Sol-Gel method. The thick films of BST-MgO with $B_2O_3-Li_2CO_3$ were fabricated on the $Al_2O_3$ substrates coated with Pt by the screen printing method. The structural and dielectric properties of the BST-MgO thick film with $B_2O_3-Li_2CO_3$, addition were investigated. The structure of the BST-MgO with $B_2O_3-Li_2CO_3$ thick films were dense and homogeneous with no pores. The dielectric constant was increased and dielectric loss was decreased with increasing the sintering temperature.

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Process Improvement and Effect for Enteric Tablet Coating Using Aqueous System (수계 장용 정제 코팅에 관한 공정개선 및 효과)

  • Jeong, Noh-Hee;Shin, Kang-Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.22 no.3
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    • pp.234-240
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    • 2005
  • In this study, we have prepared three kinds of enteric tablet coating formulations for prevention the crack incidence and enhanced process improvement of enteric tablet using aqueous system. we determined the mechanical strength of three formulatons on the enteric film-coating process. The compared experiment of one-layer and two-layer (A), (B) coating treated having placebo tablets without breakline and logo. In result, the breaking force time of two-layer (B) film strength was found to increase 0.8min than two-layer (A). We confirmed the half reduction of working hour and the simplification in the one-layer coating process, and the coating troubles was solved as setting up a dehumidifier in inlet of coater. In result, we recovered that optimum running capacity(g/kg) of dehumidifier is 10g/kg and below.