• 한국세라믹학회지
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• 제32권12호
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• pp.1331-1336
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• 1995

The glass-ceramics for ferro-electric were made from compositions of 70PbO.16TiO2.8SiO2.4B2O3.2AlPO4 (wt%) and 67.5PbO.20TiO2.8.5SiO2.2B2O3.2AlPO4 (wt%). The crystallization kinetics for PbTiO3 crystalline phase formation from glass was studied using non-isothermal DSC techniques. The values of activation energy, ΔE using variables of heating rate and temperature were calculated at various reaction fractions obtained from peak area over DSC. The results indicated that activation energy was lowest at 60% reaction fractions and the activation energy of glass containing 20.0 wt% TiO2 is higher than that of glass containing 16.0 wt% TiO2. The crystallization mechanism was three dimensional growth (n=4).

• 한국세라믹학회지
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• 제39권2호
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• pp.153-158
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• 2002

습식법에 의하여 제조된 $Al_2O_3$-1∼11 wt% $TiO_2$계 복합체를 1350$^{\circ}C$, 1450$^{\circ}C$ 에서 2시간 열처리 한 후 이에 대한 기계적 물성변화 및 미세구조를 조사하였다. 그 결과, $TiO_2$ 첨가량이 3 wt%였을 때의 복합체가 bulk density도 높고 기공율도 낮은 치밀한 미세구조를 이루었으며 이 때 young's modulus는 35.5 GPa, 곡강도값은 68.7 MPa로서 다른 $TiO_2$ 첨가량에 비하여 우수한 물성을 나타내었다. $TiO_2$ 첨가량이 증가할 수록 많은 양의 aluminium titanate의 합성으로 인해 열팽창 계수는 낮은 값을 나타내었다.

• 대한전기학회논문지
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• 제44권8호
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• pp.1068-1074
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• 1995

Effect of (Zn$_{1}$3/Nb$_{2}$3/) $O_{2}$ addition on the phase changes and microwave dielectric properties of BaTi $O_{3}$-3Ti $O_{2}$ ceramics were investigated. Addition of (Zn$_{1}$3/Nb$_{2}$3/) $O_{2}$ to BaTi $O_{3}$-3Ti $O_{2}$ resulted in the formation of Ba $Ti_{4}$$O_{9}$, $Ba_{2}$ $Ti_{9}$ $O_{20}$, Ba(Zn$_{1}$3/Nb$_{2}$3/) $O_{3}$, and Ti $O_{2}$ phases. Ba $Ti_{4}$$O_{9}$ phase was gradually transformed to $Ba_{2}$ $Ti_{9}$ $O_{20}$. This was identified by XRD and microstructure. As the Ba $Ti_{4}$$O_{9}$ phase transformed to $Ba_{2}$ $Ti_{9}$ $O_{20}$ phase, the dielectric constant increased to 37.5. Q*f$_{o}$ value was 40000 at x=0.04, and the temperature coefficient of resonant frequency was +10ppm/.deg. C.C.. C.C.

• 전기화학회지
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• 제18권4호
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• pp.156-160
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• 2015

파이로프로세싱 전해환원은 사용후핵연료의 재활용을 위해 우라늄산화물을 금속으로 전환하는 공정으로 핵물질을 사용하기 이전에 대체 금속산화물을 이용한 실험을 통해 환원 장치의 성능을 평가하고 개선한다. 본 연구에서는 전해환원 장치 개발을 위한 대체 금속산화물로 타이타늄 산화물(TiO와 $TiO_2$)을 선정하고 $650^{\circ}C$의 $Li_2O$-LiCl 용융염에서의 용해도 및 전해환원 특성을 평가하였다. 1.0 wt.% $Li_2O$-LiCl 용융염에서 TiO와 $TiO_2$의 침지 실험을 통해 두 산화물 모두 염에 일부 용해됨을 확인하였는데, $TiO_2$(2100 ppm)가 TiO(156 ppm)에 비해 더 높은 용해도를 보였다. 1.0 wt.% $Li_2O$-LiCl 용융염에서 TiO와 $TiO_2$의 전해환원을 각각 수행하여 Ti 금속을 성공적으로 제조하였다. 그러나 염 내 용해도가 낮은 TiO는 환원에 사용된 백금 양극 표면에서 Ti이 검출되지 않은 반면 $TiO_2$의 백금 표면에서는 Ti이 검출되었다.

• 산업기술연구
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• 제21권A호
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• pp.273-278
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• 2001

In this study, we prepared nano-sized $TiO_2$ particles for various process variables by the diffusion flame reactor and we collected $TiO_2$ particles by thermophoresis. It is found that the size of $TiO_2$ particles increases, as the flame temperature or the inlet $TiCl_4$ concentration increase or the total gas flow rate decreases. We investigated the photo-degradation of phenol wish the prepared $TiO_2$ particles. We found the optimum amounts of $TiO_2$ photocatalysts for our experimental apparatus and investigated the photo-degradation efficiencies of phenol, changing the process variables such as size of $TiO_2$ photocatlysts, phase ratio of rutile/anatase, concentration of phenol, input ratio of $O_2$. Degradation efficiencies of phenol were almost 95% in 15 minutes for the standard conditions of our experiments.

• 한국재료학회지
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• 제18권7호
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• pp.389-393
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• 2008

Nano-sized $TiO_2$-60 wt% SrO composite powders were synthesized by a sol-gel method using titanium isopropoxide and $Sr(OH)_2\;{\cdot}\;8H_2O$ as precursors. 3, -5, -7 wt%Ag spot-coated $TiO_2$-60 wt% SrO composite powders were synthesized by a Ag electroless deposition method using $TiO_2$-60 wt% SrO composite powders calcined at $1050^{\circ}C$, which mainly exhibited the $SrTiO_3$phase. However, a small number of rutile $TiO_2$, $Sr_2TiO_4$ and $SrO_2$ phases were also detected. In the Ag spot-coated powders synthesized by electroless deposition, nano-sized particles about 5-25 nm in diameter adhered to the $TiO_2$-60 wt% SrO composite powders. The photocatalytic activity of Ag spot-coated $TiO_2$-SrO and $TiO_2$-SrO composite powders for degradation of phenol showed that all of $TiO_2$-SrO composite powders were highly active under UV light irradiation. 7 wt%Ag spot-coated $TiO_2$-60wt.%SrO composite powders had a relatively higher photocatalytic activity than did $TiO_2$-SrO composite powders under visible light.

• 한국재료학회지
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• 제22권7호
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• pp.352-357
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• 2012

$SnO_2$-mixed and Sn-doped $TiO_2$ nanoparticles were synthesized via a hydrothermal process. $SnO_2$-mixed $TiO_2$ nanoparticles prepared in a neutral condition consisted of anatase $TiO_2$ nanoparticles(diamond shape, ~25 nm) and cassiterite $SnO_2$ nanoparticles(spherical shape, ~10 nm). On the other hand, Sn-doped $TiO_2$ nanoparticles obtained under a high acidic condition showed a crystalline phase corresponding to rutile $TiO_2$. As the Sn content increased, the particle shape changed from rod-like(d~40 nm, 1~200 nm) to spherical(18 nm) with a decrease in the particle size. The peak shift in the XRD results and a change of the c-axis lattice parameter with the Sn content demonstrate that the $TiO_2$ in the rutile phase was doped with Sn. The photocatalytic activity of the $SnO_2$-mixed $TiO_2$ nanoparticles dramatically increased and then decreased when the $SnO_2$ content exceeded 4%. The increased photocatalytic activity is mainly attributed to the improved charge separation of the $TiO_2$ nanoparticles with the $SnO_2$. In the case of Sn-doped $TiO_2$ nanoparticles, the photocatalytic activity increased slightly with the Sn content due most likely to the larger energy bandgap caused by Sn-doping and the decrease in the particle size. The $SnO_2$-mixed $TiO_2$ nanoparticles generally exhibited higher photocatalytic activity than the Sn-doped $TiO_2$ nanoparticles. This was caused by the phase difference of $TiO_2$.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1995년도 추계학술대회 논문집
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• pp.22-24
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• 1995

The electrical conductivity of TiO$_2$doped ZnO was investigated by means of complex impedance measurement and voltage-current source and meaurement unit. The e1ectrical conductivity of TiO$_2$added ZnO was increased with increasing the concentration of TiO$_2$. The calculated relative dielectric constant was decreased with increasing the concentration of TiO$_2$. The increase of electrical conductivity seems to be the effect of TiO$_2$donor doping.

• 공업화학
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• 제21권3호
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• pp.291-294
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• 2010

최근 고효율 염료감응형 태양전지를 위한 다층구조의 $TiO_2$ 전극에 대한 연구가 관심을 받고 있다. 본 연구에서는 입자의 크기가 작고 큰 $TiO_2$로 이루어진 다층구조의 $TiO_2$ 전극에 대해 연구하였다. 나노구조를 갖는 $TiO_2$ 분말은 $TiCl_4$를 가수분해하여 합성하였다. 크기가 7.6 nm 및 18 nm인 $TiO_2$ 분말은 소성온도를 조절하여 얻었다. 다층구조를 갖는 $TiO_2$ 전극이 단락전류(Jsc)에 큰 영향을 미치는 것을 확인하였으며, 또한 다층구조를 갖는 $TiO_2$ 전극이 각각의 입자만을 사용한 염료감응형 태양전지 보다 변환효율이 증가함을 확인하였다.

• 한국전기전자재료학회논문지
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• 제23권9호
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• pp.681-684
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• 2010

The $TiO_2$/ZnS/Ag/ZnS/$TiO_2$ multilayered structure for the transparent electrodes in plasma display panel was designed by essential macleod program (EMP) and the multilayered film was deposited on a glass substrate by direct-current (DC)/radio-frequency (RF) magnetron sputtering system. During film deposition process, the Ag layer in $TiO_2$/Ag/$TiO_2$ structure became oxidized and the filter characteristic was degraded easily. In this study, ZnS layer was adopted as a diffusion blocking layer between $TiO_2$ and Ag to prevent the oxidation of Ag layer efficiently in $TiO_2$/ZnS/Ag/ZnS/$TiO_2$ structure. Based on the AES depth profiling analysis, the Ag layer was effectively protected by the ZnS layer as compared with the $TiO_2$/Ag/$TiO_2$ multilayered films without ZnS as an antioxidant layer. The 3 times stacked $TiO_2$/ZnS/Ag/ZnS/$TiO_2$ films have low sheet resistance of $1.22{\Omega}/{\square}$ and luminous transmittance was as high as 62% in the visible ranges.