• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1993.05a
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• pp.3-5
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• 1993

It is very important that a spectrum of reflectance is in accord wi th a spectrum of absorbance for a effective heating. Therefore. the objective of this study was to achieve a technical composite for material plan which PTC thermistor increase a radiation property of far-infrared and keep a characteristic of R-T The Ceramic speciman studies had the composition $BaTiO_3$ with additive of 1.67 $Al_2O_3$, 3.75 $SiO_2$, 1.25 $TiO_2$, 0.15 $Sb_2O_3$ and 0.00-0.182 $MnO_2$. $MnO_2$ amounts of additives was both increase on the anomalous resistivity-temperature characteristics and high efficiency on the radiation properties bodies of far-infrared. This result shows that specimens produced high emissivity(average 0.8) of far-infrared at 4.5-15$[{\mu}m]$ by measuring a characteristic of IR and R-T.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.16 no.5
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• pp.181-188
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• 2006

Rutile single crystals grown by skull melting method were cut parallel and perpendicular to growth axis, and both sides of the cut wafers (${\phi}5.5mmx1.0mm$) were then polished to be mirror surfaces. The black wafers were changed into pale yellow color by annealing in air at 1200 and $1300^{\circ}C$ for $3{\sim}15\;and\;10{\sim}50$ hours, respectively. After annealing, structural and optical properties were examined by specific gravity (S.G), SEM-electron backscattered pattern (SEM-EBSP), X-ray diffraction (XRD), FT-IR transmittance spectra, laser Raman spectroscopy (LRS), photoluminescence (PL) and X-ray photoelectron spectroscopy (XPS). These results are analyzed increase of weight in air, decrease of weight in water and specific gravity, shown secondary phase of needle shape, diffusion of oxygen ion and increase of $Ti^{3+}$. From the above results, we suggest that the skull melting method grown rutile single crystals contain defect centers such as $O_v,\;Ti^{3+},\;O_v-Ti^{3+}$ interstitials and $F^+-H^+$.

• Applied Chemistry for Engineering
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• v.23 no.3
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• pp.253-258
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• 2012

The effects of active sites and valence states were investigated over $Pd/TiO_2$ catalyst on simultaneous oxidation of $CH_4$ and CO. The Pd species (PdO) crystallite size increased with increasing Pd loadings, which results in enhancement of the activity of $CH_4$ oxidation. Different results from the activity of $CH_4$ and CO oxidation were shown to be dependent on the Pd valence state on the surface of the catalyst prepared through a thermal treatment. XRD and $H_2-TPR$ analysis confirmed that $Pd^{2+}$species was predominated in the calcination catalyst, while $Pd^0$species was predominated in the reduction catalyst. Additionally, it could be found that the valence state of Pd was a more important factor on the catalytic activity than that of factors as the surface area and pore volume. The reaction mechanism of $CH_4$ and CO followed by the valence state of Pd could be identified using FT-IR analysis.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.425-425
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• 2011

The photocatalytic decomposition of toluene gas was investigated with $TiO_2$ on nano-diamond powder (NDP) under UV irradiation. Atomic layer deposition (ALD) was used for the growth of $TiO_2$ on the NDP. The structure and surface properties of catalysts were characterized by X-ray Diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS) and Transmission Electron Microscopy (TEM). The photocatalytic activity for the toluene decomposition was evaluated by measuring the concentration change of toluene and $CO_2$ gas with gas chromatography (GC)-flame ionization detector (FID) system. The photocatalytic activities of $TiO_2$/NDP catalysts were compared with that of P-25. The rate of initial photocatalytic decomposition of toluene for the $TiO_2$/NDP catalysts was relatively lower when compared to P-25. The photocatalytic activity of P-25 was rapidly decreased with time, whereas, the deactivation of $TiO_2$/NDP catalysts was less pronounced. Therefore, as the reaction time increased, the photocatalytic activity of $TiO_2$/NDP catalysts became higher than that of P-25. The intermediates such as benzaldehyde or benzoic acid, etc were more easily adhered to the active site on the P-25 surface during reaction, resulting in easier deactivation of P-25. These results could be confirmed using FT-IR spectroscopy. We suggest that the NDP used as substrate can reduce the deactivation of $TiO_2$ on the surface.

• Journal of the Korean Ceramic Society
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• v.37 no.4
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• pp.308-313
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• 2000

Hydrous titanium oxide particles with anatase phase were prepared from 0.05 mol TiCl4 solution using NH4HCO3 as precipitant by the droopping precipitant method. The sequential change of pH is completed by a sudden and steep increase in a pH value of the range of 6~7 to which the concentration of adsorbed OH- and H+ ions on TiO2 surface is equal. Rutile phase started precipitating with anatase phase as an increase of reaction temperature above 6$0^{\circ}C$ in aqueous 0.05mol TiCl4 solution and its specific surface area was found to decrease from 452 $m^2$/g($25^{\circ}C$) to 164$m^2$/g(8$0^{\circ}C$). Specific surface area decreased rapidly when anatase powders precipitated at 4$0^{\circ}C$ were heat-treated at temperature higher 40$0^{\circ}C$. FT-IR result confirmed that it was due to the decrease of OH species within hydrous titanium oxides. The loss of ethanol after illumination of the powder heated at $600^{\circ}C$ and $700^{\circ}C$ for 4 h was 66 and 68.8%, respectively.

• Applied Chemistry for Engineering
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• v.23 no.6
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• pp.614-617
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• 2012

Ti-containing zeolite was synthesised and used in the epoxidation of di-cyclopentadiene (DCPD). Among various Ti-zeolite catalysts, Y contained Ti-zeolite showed the highest yield in the epoxidation of DCPD. The study was also investigated in terms of the Ti content in the catalysts, $H_2O_2$/substrate ratio, reaction temperature and applied time. The reaction conditions significantly influenced on both the catalytic activity and selectivity. In addition, Ti structure in the zeolite was analyzed using IR and UV-vis spectroscopy.

• Korean Journal of Optics and Photonics
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• v.13 no.4
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• pp.363-369
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• 2002

We have designed conductive transparent filters using a low-emissivity coating such as [dielectric|Ag|dielectric] for display applications. The design is the repetition of [$TiO_{2}$|Ti|Ag |$TiO_{2}$] to increase the transmittance in the visible and decrease the transmittance in the near IR. The conductive transparent filters are deposited by a radio frequency(RF) magnetron sputtering system. The optical, structural and electrical properties of the filters were investigated and the optical spectra are compared with simulated spectra. The thickness of the deposited Ag films is above 13 ㎚ to increase the conductivity and that of $TiO_{2}$ films is 24 ㎚ to increase the transmittance in the visible range. Ti blockers are employed to prevent the Ag films from being oxidized by an oxygen gas during the reactive sputtering process. Also, it is shown that the thicker Ti film is necessary as the period increases. Finally, a filter with repetition of the basic structure three times shows the better cut-off near infrared(NIR) and the sheet resistance as low as 2Ω/□ which is enough to shield an unnecessary electromagnetic waves for a display panel.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.26 no.3
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• pp.428-435
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• 2002

Pyroelectric $Pb(Zr_{0.3}Ti_{0.7})O_3$ (PZT30/70) thin film IR detectors has been fabricated and characterised. The PZT30/70 thin film was deposited onto $Pt/Ti/Si_3N_4/SiO_2/Si$ substrate by the sol-gel process. Four different substrate conditions were studied for their effects on the pyroelectric responses of the IR detectors. The substrate conditions were the combinations of the Si etching and the Pt/Ti patterning. In the Si etched substrate, the $Si_3N_4/SiO_2$ composite layer was used as silicon etch-stop, and was used as the membrane to support the PZT pyroelectric film element as well. The measured pyroelectric current and voltage responses of detectors fabricated on the micro-machined thin $Si_3N_4/SiO_2$ membrane were two orders higher than those of the detectors on the bulk-silicon. For detectors on the membrane substrate, the Pt/Ti patterned detectors showed a 2-times higher pyroelectric response than that of not-patterned detectors. On the other hand, the pyroelectric response of the detectors on the not-etched Si substrate was almost the same, regardless of the Pt/Ti patterning. It was also found that the rise time strongly depended on the substrate thickness: the thicker the substrate was, the longer the rise-time.

• Applied Chemistry for Engineering
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• v.27 no.1
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• pp.16-20
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• 2016

In this work, we describe the synthesis and infrared light reflecting characteristics of $TiO_2$/mica hybrid composites. $TiO_2$/mica composite materials were obtained by the hydrolysis and condensation reaction of titanium isopropoxide in an aqueous solution of acetic acid in the presence of mica particles. Amorphous phase of $TiO_2$ on the surface of mica was converted to the crystalline rutile phase via anatase phase by heat treatment ($600-1000^{\circ}C$, 1-3 h) of $TiO_2$/mica composite materials, and the size of crystals was controlled by heat treatment conditions. Physicochemical properties of mica and $TiO_2$/mica composites were investigated using FE-SEM, ED-XRF, and PXRD. The solar reflectance of $TiO_2$/mica composites in the near IR region (780~2,500 nm) measured using a diffuse reflectance NIR spectrophotometer was 88.6%, which is rather higher than that of calcined pure mica (86.6%). Therefore, $TiO_2$/mica composites can be used as NIR light reflective pigments.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.35 no.2
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• pp.165-171
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• 2022

The SiO₂/TiO₂ multilayer thin films used for narrow band pass filter were fabricated using E-beam evaporation method. The narrow band pass filter was used to enhance the resolution of spectroscopy and sensor applications with near infrared (NIR) light source. The narrow band pass filter with multilayer thin films were designed with Essential Macleod program. The multilayers of SiO₂/TiO₂ with 32 layers were deposited on the silicon encapsulation of IR with peak wavelength (λ_p) of 660 nm and NIR LEDs with λ_p of 830 nm, 880 nm, and 955 nm. After NIR light passed through the narrow band pass filter, the full width of half maximum of 33.4~48.6 nm became narrow to 20~24 nm owing to the absorption of photons with short or long wavelength of designed band of 20 nm. The SiO₂/TiO₂ band pass filter fabricated in this study can be used for sensor, optoelectronics, and NIR spectroscopy applications.