• Title/Summary/Keyword: $Sol_0{^4}$

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Effect of Thin-Film Thickness on Electrical Performance of Indium-Zinc-Oxide Transistors Fabricated by Solution Process (용액 공정을 이용한 IZO 트랜지스터의 전기적 성능에 대한 박막 두께의 영향)

  • Kim, Han-Sang;Kyung, Dong-Gu;Kim, Sung-Jin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.8
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    • pp.469-473
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    • 2017
  • We investigated the effect of different thin-film thicknesses (25, 30, and 40 nm) on the electrical performance of solution-processed indium-zinc-oxide (IZO) thin-film transistors (TFTs). The structural properties of the IZO thin films were investigated by atomic force microscopy (AFM). AFM images revealed that the IZO thin films with thicknesses of 25 and 40 nm exhibit an uneven distribution of grains, which deforms the thin film and degrades the performance of the IZO TFT. Further, the IZO thin film with a thickness of 30 nm exhibits a homogeneous and smooth surface with a low RMS roughness of 1.88 nm. The IZO TFTs with the 30-nm-thick IZO film exhibit excellent results, with a field-effect mobility of $3.0({\pm}0.2)cm^2/Vs$, high Ion/Ioff ratio of $1.1{\times}10^7$, threshold voltage of $0.4({\pm}0.1)V$, and subthreshold swing of $0.7({\pm}0.01)V/dec$. The optimization of oxide semiconductor thickness through analysis of the surface morphologies can thus contribute to the development of oxide TFT manufacturing technology.

Synthesis of TiO2 Fine Powder by Sol-Gel Process and Reaction Mechanism(I): Hydrolysis of Titanium Isopropoxide (졸-겔법에 의한 TiO2 미분말 합성과 반응메카니즘(I): Titanium isopropoxide의 가수분해)

  • Myung, Jung-Jae;Chung, Yong-Sun;Kyong, Jin-Bum;Kim, Ho-Kun
    • Applied Chemistry for Engineering
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    • v.7 no.4
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    • pp.794-801
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    • 1996
  • $TiO_2$ fine powders were synthesized via hydrolysis reaction of titanium isopropoxide in isopropanol solvent and the reaction rates were studied by use of UV spectroscopic method. The reactions were controlled to proceed to pseudo-first-order reaction in the presence of excess water in isopropanol solvent. The rate constants which varied with temperature and concentration of water were calculated by Guggenheim method. Reactions using $D_2O$ were also carried out to determine the catalytic character of water. n value of water molecules in transition state and the thermodynamic parameters showed that the reaction proceeded by $S_N2$ mechanism. $TiO_2$ powders synthesized in this reaction were almost spheric forms and had average particle size of $0.3{\mu}m$ diameter.

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Preparation and Characterization of TPA Captured CL-SPEEK Polymer Composite Membranes for Water Electrolysis (수전해용 술폰화 폴리에테르 에테르 케톤과 고정된 TPA 고분자 복합막의 제조 및 특성)

  • CHA, JINSAN;YOON, YOUNGYO;KIM, MINJIN;KIM, BOYOUNG;MOON, SANG-BONG;CHUNG, JANG-HOON
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.1
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    • pp.17-23
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    • 2017
  • Polyether ether ketone (PEEK) composite including tungstophosphoric acid(TPA) membranes have been intensively investigated for polymer electrolyte membrane water electrolysis (PEMWE) and thus covalently linked sulfonated polyether ether ketone (CL-SPEEK) with captured TPA composite membranes were prepared and characterized. Sulfonated polyether ether ketone (SPEEK) was prepared in sulfonation of PEEK and was cross-linked with 1,4 diiodobutane. The carbonyl group of SPEEK was reduced with $NaBH_4$ and 3-isocyanatepropyltriethoxysilane (ICPTES) was added. The TPA captured composite was prepared in reaction of TPA with 3-mercaptopropyltrime thoxysilane (MPTMS). The polymer composite membranes showed better thermostability and electrochemical properties than SPEEK. The membranes were prepared by sol-gel casting method. The polymer composite membrane featured 0.1285 S/cm of proton conductivity at $80^{\circ}C$ and outstanding durability.

Synthesis and characterization of polyamide thin-film nanocomposite membrane containing ZnO nanoparticles

  • AL-Hobaib, A.S.;El Ghoul, Jaber;El Mir, Lassaad
    • Membrane and Water Treatment
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    • v.6 no.4
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    • pp.309-321
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    • 2015
  • We report in this study the synthesis of mixed matrix reverse osmosis membranes by interfacial polymerization (IP) of thin film nanocomposite (TFNC) on porous polysulfone supports (PS). This paper investigates the synthesis of ZnO nanoparticles (NPs) using the sol-gel processing technique and evaluates the performance of mixed matrix membranes reached by these aerogel NPs. Aqueous m-phenyl diamine (MPD) and organic trimesoyl chloride (TMC)-NPs mixture solutions were used in the IP process. The reaction of MPD and TMC at the interface of PS substrates resulted in the formation of the thin film composite (TFC). NPs of ZnO with a size of about 25 nm were used for the fabrication of the TFNC membranes. These membranes were characterized and evaluated in comparison with neat TFC ones. Their performances were evaluated based on the water permeability and salt rejection. Experimental results indicated that the NPs improved membrane performance under optimal concentration of NPs. By changing the content of the filler, better hydrophilicity was obtained; the contact angle was decreased from $74^{\circ}$ to $32^{\circ}$. Also, the permeate water flux was increased from 26 to 49 L/m2.h when the content of NPs is 0.1 (wt.%) with the maintaining of lower salt passage of 1%.

Preparation of Field Effect Transistor with $(Bi,La)Ti_3O_{12}$ Ferroelectric Thin Film Gate ($(Bi,La)Ti_3O_{12}$ 강유전체 박막 게이트를 갖는 전계효과 트랜지스터 소자의 제작)

  • Suh Kang Mo;Park Ji Ho;Gong Su Cheol;Chang Ho Jung;Chang Young Chul;Shim Sun Il;Kim Yong Tae
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2003.11a
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    • pp.221-225
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    • 2003
  • The MFIS-FET(Field Effect Transistor) devices using $BLT/Y_2O_3$ buffer layer on p-Si(100) substrates were fabricated by the Sol-Gel method and conventional memory processes. The crystal structure, morphologies and electrical properties of prepared devices were investigated by using various measuring techniques. From the C-V(capacitance-voltage) data at 5V, the memory window voltage of the $Pt/BLT/Y_2O_3/si$ structure decreased from 1.4V to 0.6V with increasing the annealing temperature from $700^{\circ}C\;to\;750^{\circ}C$. The drain current (Ic) as a function of gate voltages $(V_G)$ for the $MFIS(Pt/BLT/Y_2O_3/Si(100))-FET$ devices at gate voltages $(V_G)$ of 3V, 4V and 5V, the memory window voltages increased from 0.3V to 0.8V as $V_G$ increased from 3V to 5V.

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Appropriate Methods in Determining the Event Mean Concentration and Pollutant Removal Efficiency of a Best Management Practice

  • Maniquiz, Marla C.;Choi, Ji-Yeon;Lee, So-Young;Cho, Hye-Jin;Kim, Lee-Hyung
    • Environmental Engineering Research
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    • v.15 no.4
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    • pp.215-223
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    • 2010
  • This study attempted to develop and suggest a more appropriate method for the determination of event mean concentration (EMC) and pollutant removal efficiency of a stormwater best management practice (BMP) considering rainfall. The stormwater runoff and hydrologic data gathered from 22 storm events during a 28-month monitoring period on a swirl and filtration type of BMP were used to evaluate the developed methods. Based on the findings, the modified EMC method resulted in lower (average) values than the overall EMC, although the differences were not significant (P>0.05). By comparison, the developed 'Rainfall Occurrence Ratio' (ROR) method was most significantly correlated (r=0.967 to 988, P<0.009) with the other existing removal efficiency determination methods such as the 'Efficiency Ratio' (ER), 'Summation of Loads' (SOL) and 'Regression of Loads' (ROL) methods. In addition, the ROR method gave the highest efficiency values, with no significant differences with any of the pollutant parameters, unlike the other three methods. These results were obtained because the ROR method integrated both pollutant loading and rainfall, which are not considered by the other three methods. Therefore, this study proved the suitability of the modified EMC and ROR methods for application in other BMP monitoring studies.

Effects of Jakyakgamchotang Extract on the Trachea Smooth Muscle (작약감초탕(芍藥甘草湯) 및 구성약물(構成藥物)이 기관지평골근(氣管支平滑筋)에 미치는 영향(影響))

  • Kook Yoon-Bum;Lee Jang-Chun;Kim Hee-Soo
    • Herbal Formula Science
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    • v.10 no.2
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    • pp.143-158
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    • 2002
  • The purpose of the present study is to determine the effect of Jakyakgamchotang on histamine or acetylcholine induced tracheal smooth muscle contraction in rats and guinea pigs. Guinea pig(500g, male) and Sprague Dawley rats(250g, male) were killed by $CO_2$ exposure and a segment (4-5mm) of the thoracic trachea from each rat and guinea pig was cut into equal segments and mounted 'in pairs' in a tissue bath. Contractile force was measured with force displacement transducers under 0.5g loading tension. The dose of histamine(His) which evoked 50% of maximal response($ED_{50}$) was obtained from cumulative dose response curves for histamine($10^{-7}{\sim}10^{-4}M$). Contractions evoked by His($ED_{50}$) were inhibited significantly by Jakyakgamchotang. In guinea pig tracheal smooth muscle, the mean percent inhibition of histamine induced contraction was 90.8% (p〈0.001) after $100{\mu}l/ml$ Jakyakgamchotang. In rat tracheal smooth muscle, the mean percent inhibition of acetylcholine induced contraction was 22.1% (p〈0.05) after $100{\mu}l/ml$ Jakyakgamchotang. Propranolol indomethacin and methylene blue($10^{-7}M$) slightly but significantly attenuated the inhibitory effects of Jakyakgamchotang. These results indicate that Jakyakgamchotang can relax histamine or acetylcholine induced contraction of guinea pig and rat tracheal smooth muscle.

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Fabrication of bi-axially textured Ni tapes for YBCO coated conductors by a cold rolling process and heat treatment of Ni powder compacts (니켈 분말 성형체의 냉간압연과 열처리로 제조된 YBCO coated conductor용 양축 정렬된 니켈 테이프)

  • 이동욱;지봉기;임준형;정충환;주진호;박순동;전병혁;홍계원;김찬중
    • Progress in Superconductivity and Cryogenics
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    • v.4 no.2
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    • pp.16-20
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    • 2002
  • Bi-axially textured Ni tapes for YBCO coated conductors were Prepared by cold rolling and heat treatment of Ni Powder compacts. The Ni powder used in this study was 5 urn in particle size and 99.99 % in purity. The process of this study consists of filling of hi powder into a rubber mold, cold-isostatically Pressing and sintering of the powder compacts at 110$0^{\circ}C$ for 6h in 96 % Ar - 4 % H$_2$ atmosphere. The sintered compacts were cold rolled with a 5 % step reduction ratio into a 100 micron-thick tapes and then heat-treated at 100$0^{\circ}C$ for various time periods. The (200) texture of Ni tape was successfully developed through the recrystallization heat treatment of the cold rolled Ni tapes. At 100$0^{\circ}C$, the degree of texture of the heat-treated Ni tapes seems not to be significantly affected by the heat-treatment time. The short heat treatment of S min was sufficient to develop the complete (200) cube texture. The degree of in-Plane and out-of-plane texture of the prepared Ni tapes was 8-10$^{\circ}$. The heat treated Ni tapes consisted of equiaxed grains with a size 50-70 microns. and the AFM sol-face roughness was as smooth as 3 nm.

Diet Composition of Common Flying Squid Todarodes pacificus in the Coastal Waters of East Sea, Korea (한국 동해에 출현하는 살오징어(Todarodes pacificus)의 위내용물 조성)

  • Park, Hyun-Sol;Jin, Suyeon;Kim, So Ra;Kim, Jung Jin;Baeck, Gun Wook
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.54 no.6
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    • pp.1052-1057
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    • 2021
  • The diet composition of common flying squid Todarodes pacificus was studied using 1,084 specimens collected through trawl and jigging from June 2018 to June 2020 in the East Sea of Korea. The mantle length (ML) of the collected individuals ranged from 13.6 to 31.1 cm. Todarodes pacificus is a carnivore. In the study area, T. pacificus was observed feeding mainly on fish and cephalopods, in addition to small quantities of crustaceans. The calculated trophic level value for T. pacificus was 4.10. Small individuals (ML, <18.0 cm) mainly fed on cephalopods, while intermediate (ML, 18.0-23.0 cm) and large (ML, ≥23.0 cm) individuals fed mainly on fish and occasionally on cephalopods. Overall, as the body size of T. pacificus increased, the mean weight of the consumed prey increased (one-way ANOVA, P<0.05).

Study on the Performance Improvement of ZnO-based NO2 Gas Sensor through MgZnO and MgO (ZnO 기반 NO2 가스센서의 MgZnO와 MgO을 통한 성능 향상에 대한 연구)

  • So-Young, Bak;Se-Hyeong, Lee;Chan-Yeong, Park;Dongki, Baek;Moonsuk, Yi
    • Journal of Sensor Science and Technology
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    • v.31 no.6
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    • pp.455-460
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    • 2022
  • Brush-like ZnO hierarchical nanostructures decorated with MgxZn1-xO (x = 0.1, 0.2, 0.3, 0.4, and 0.5) were fabricated and examined for application to a gas sensor. They were synthesized using vapor phase growth (VPG) on indium tin oxide (ITO) substrates. To generate electronic accumulation at ZnO surface, MgZnO nanoparticles were prepared by sol-gel method, and the ratio of Mg and Zn was adjusted to optimize the device for NO2 gas detection. As the electrons in the accumulation layer generated by the heterojunction reacted faster and more frequently with the gas, the sensitivity and speed improved. When tested as sensing materials for gas sensors at 100 ppm NO2 at 300℃, these MgZnO decorated ZnO nanostructures exhibited an improvement from 165 to 514 times compared to pristine ZnO. The response and recovery time of the MgZnO decorated ZnO samples were shorter than those of the pristine ZnO. Various analyzing techniques, including field-emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray powder diffraction (XRD) were employed to confirm the growth morphology, atomic composition, and crystalline information of the samples, respectively.