• Title/Summary/Keyword: $SiH_2Cl_2

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Compazrison of Water Qualities and Biotic Effects of Three River Waters in Taegu Area (대구지방 하천의 수질특성과 수생물에 미치는 영향 비교)

  • Lyu, Seung-Won;Seung-Dal Song
    • Journal of environmental and Sanitary engineering
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    • v.5 no.1
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    • pp.7-13
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    • 1990
  • The water environmental characters of the Nakdong River, Geumho River and Sin Stream, both before-flood (Aug. 24) and after-flood (Sept. 8), have been compared, and their effects on the growth of Spirodela polyrhiza Shleiden have been examined. Before the flood, the concentrations of most of the chemical components of the Geumho River were similar to those of the Sin Stream; (COD, 19.6~21.4; alkalinity, 177~183; $NH_4\;^+$, 20.7~24.4; $NO_3\;^-$, 3.9~4.3; $PO_\;4^{3-}$, 3.4~3.7; $Mg^{2+}$, 42; $Ca^{2+}$, 68.5~69.7; $Cl^-$, 90~92; $SiO_2$, 10.4~11.2; , 11~32; LAS, 3.0~3.8; , 0.007~0.010ppm) but much higher than those of the Nakdong River (30~40 fold for $NH_4\;^+$, , $PO_\;4^{3-}$ and LAS, and 2~5 fold for COD, alkalinity, $NO_3\;^-$, $Mg^{2+}$, Cl- and ). Especially in the Geumho River, Secchi disk transparency was very low (17cm) and DO was not detected. The flood caused significant increases in some chemical components: $NH_4\;^+$, 1.0;$NO_3\;^-$, 9.6; , 12.8 and , 5.4 ppm in the Nakdong River; DO, 1.0; $NO_2\;^-$, 0.92; $NO_3\;^-$, 22.2 and $SiO_2$, 17.6ppm in the Geumho River; DO, 3.0; $NO_2\;^-$, 1.4; $NO_3\;^-$, 22.2; SiO2$SiO_2$, 19.2 and , 25.0ppm in the Sin Stream. General species diversity index (H) of phytoplankton community in the Nakdong River, Geumho River and Sin Stream before flood was 3.1, 2.7 and 1.6, respectively. After the flood, the phytoplankton growth was highly sparse in each river water, hence indices have no significance. The growth of S. polyrhiza was enhanced in Geumho River water (max. RGR=26%/day), while it ceased within 7days in Nakdong River water.

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Growth of semi-polar (1-101) InGaN/GaN MQW structures on $8^{\circ}$ off -axis (100) patterned Si substrate by MOVPE ($8^{\circ}$-off (100) Si 기판위의 반극성을 가지는 (1-101) InGaN/GaN 다중양자우물 구조의 MOVPE 성장)

  • Han, Y.H.;Jean, H.S.;Hong, S.H.;Kim, E.J.;Lee, A.R.;Kim, K.H.;Ahn, H.S.;Yang, M.;Tanikawa, T.;Honda, Y.;Yamaguchi, M.;Sawaki, N.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.1
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    • pp.1-5
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    • 2009
  • In this study, we performed growth of InGaN/GaN multi quantum well (MQW) structures on semi-polar (1-10]) GaN facet on 8-degree off oriented stripe patterned (100) Si substratcs by MOVPE. The structural and optical properties of the InGaN/GaN multi quantum well (MQW) structures grown on (1-101) GaN stripe depend on $NH_3$ flow rate, TMI flow rate and growth temperature are characterized by cathodoluminescence (CL) and scanning electron microscopy (SEM). With the decrease of $NH_3$ flow rate, the threading dislocation of (1-101) GaN is considerably reduced. We could control the transition wavelength of InGaN/GaN MQW structures from 391.5 nm to 541.2 nm depend on the growth conditions.

Growth of Transferable Polycrystalline Si Film on Mica Substrate (운모기판을 이용한 다결정 Si 전이막 성장 연구)

  • Park Jin Woo;Eom Ji Hye;Ahn Byung Tae;Jun Young Kwon
    • Korean Journal of Materials Research
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    • v.14 no.5
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    • pp.343-347
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    • 2004
  • We investigated the growth feasibility of polycrystalline Si film on mica substrate for the transfer of the layer to a plastic substrate. The annealing temperature was limited up to $600^{\circ}C$ because of crack development in the mica substrate. Amorphous Si film was deposited on mica substrate by PECVD and was crystallized by furnace annealing. During the annealing, bubbles were formed at the Si/mica interface. The bubble formation was avoided by the Ar-plasma treatment before amorphous Si deposition. A uniform and clean polycrystalline Si film was obtained by coating $NiCl_2$ on the amorphous Si film and annealing at $500^{\circ}C$ for 10 h. The conventional Si lithography was possible on the mica substrate and the devices fabricated on the substrate could be transferred to a plastic substrate.

The Hydrochemistry of ChusanYongchulso Spring, Cheonbu-ri, Buk-myeon, Northern Ulleung Island (울릉도 북면 천부리 추산 용출소의 수질화학적 특성)

  • Lee, Byeong Dae;Cho, Byong Wook;Choo, Chang Oh
    • The Journal of Engineering Geology
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    • v.28 no.4
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    • pp.565-582
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    • 2018
  • We investigated the hydrochemical properties of ChusanYongchulso Spring located in Buk-myeon, Ulleung Island, focusing on the formation and characteristics of aquifers in and around the Nari caldera. Abundant pumice with high permeability and numerous fractures (including faults and joints) that formed as a result of caldera subsidence are widely distributed in the subsurface, favoring the formation of aquifers. Because of the presence of porous pyroclastic rocks with a high internal surface area, the water type of the springs is characterized by $NaHCO_3$, with upper stream waters and the upper spring being characterized by $NaHCO_3$ and NaCl, respectively. Components with a high coefficient of determination with EC are $HCO_3$, Na, F, Ca, Mg, Cl, $SiO_2$, and $SO_4$. The high concentrations of Na and Cl might be attributable to the main lithologies in the area, given that alkaline volcanic rocks are distributed extensively across Ulleung Island. Eh and pH, which are considered to be important indicators of water-rock interaction, are unrelated to most components. According to the results obtained from factor analysis, the variance explained by factor 1 is 54% and by factor 2 is 25.8%. Components with a high loading on factor 1 are F, Na, EC, Cl, $HCO_3$, $SO_4$, $SiO_2$, Ca, $NO_3$, and Mg, whereas components with a high loading on factor 2 are Mg and Ca, along with K, $NO_3$, and DO with negative loadings. It is suggested that the high concentrations of Na, Cl, F, and $SO_4$ are closely related to the presence of fine-grained alkaline pyroclastic rocks with high permeability and porosity, which favorintensewater-rock interaction. However, a wide-ranging investigation that encompasses methods such as geophysical prospecting and geochemical analysis (including isotope, trace-element, and tracer techniques) will be necessary to gain a better understanding of the groundwater chemistry, aquifer distribution, and water cycling of Ulleung Island.

Influence of Fluxing Agents in Sr3SiO5:Eu2+ Phosphors for Fabrication of Warm White Light Emitting Diodes (따뜻한 백색 LED의 제조를 위한 Sr3SiO5:Eu2+ 형광체에서의 융제 첨가 영향)

  • Kim, Hyun-Ho;Chung, Kang-Sup;Lee, Seoung-Won;Kim, Byoung-Gyu
    • Journal of the Korean Ceramic Society
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    • v.49 no.1
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    • pp.105-110
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    • 2012
  • In this paper, a yellow phosphor $Sr_3SiO_5:Eu^{2+}$ that emits efficiently at the 450 nm excitation for warm white LED is studied. In addition, the effects of various flux $BaF_2$, $NH_4Cl$ on the emission spectra were investigated. The samples were synthesized through conventional solid state reaction under reducing atmosphere of 95% $N_2$-5% $H_2$ mixture at the high temperature. All phosphors showed a excitation band from 450 nm and broad band emission peaking at region of 580 nm. The optimal concentration of $BaF_2$ flux is 3 wt% for $Sr_3SiO_5$ with doping 0.05mol Eu phosphors fired in a reductive atmosphere. The phosphor showed highest emission peaking at 582 nm.

CVD 및 CVR에 의한 SiC 코팅기술 개발

  • Yu, In-Geun;Yun, Yeong-Hun;Park, Lee-Hyeon;An, Mu-Yeong;Gu, Deok-Yeong;Jo, Seung-Yeon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.203-203
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    • 2012
  • 국제핵융합실험로(ITER)는 2020년경에 제작 설치가 완료될 예정이다. 이 장치에 한국도 시험블랑켓 모듈(Test Blanket Module: TBM)을 장착할 예정이다. 한국은 ITER 참여국 중 유일하게 지름 1 mm의 흑연 페블에 SiC를 코팅한 중성자 반사 재료를 채택한 것이 특징이다. 중성자 반사재료를 이용하게 되면 독성이 강한 중성자 증배재인 Be의 양을 줄일 수 있다. SiC 코팅은 여러 가지 방법이 알려져 있지만, 지름 1 mm 내외의 흑연 페블에 SiC를 골고루 코팅하기 위해서는 여러 가지 기술이 가미되어야 한다. 본 연구에서는 CVD 및 CVR법을 이용해 SiC를 코팅했으며, CVD의 경우 전구체 물질로 $CH_3SiCl_3$가 사용되었으며, 캐리어 가스로는 $H_2$를 사용했다. 그리고 CVR에서는 평균입도 10 ${\mu}m$$SiO_2$를 사용했으며, $1,750^{\circ}C$에서 2시간 노출시켰다. 이렇게 얻어진 SiC 코팅은 XRD, EDS, FE-SEM 등을 활용한 여러 가지 분석으로 확인할 수 있었다.

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Characteristics of Reverse Flux by using Direct Omosis in RO Membrane Process (역삼투막 공정에서 Direct Osmosis의 역방향 Flux 기초특성)

  • Kang, Il-Mo;Dock-Ko, Seok
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.3
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    • pp.399-405
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    • 2011
  • In a desalination technology using RO membranes, chemical cleaning makes damage for membrane surface and membrane life be shortened. In this research cleaning technology using direct osmosis (DO) was introduced to apply it under the condition of high pH and high concentration of feed. When the high concentration of feed is injected to the concentrate side after release of operating pressure, then backward flow occurred from treated water toward concentrated for osmotic pressure. This flow reduces fouling on the membrane surface. Namely, flux of DO was monitored under pH 3, 5, 10 and 12 conditions at feed concentrations of NaCl 40,000 mg/L, 120,000 mg/L and 160,000 mg/L. As a result, DO flux in pH 12 increased about 21% than pH 3. DO cleaning was performed under the concentrate NaCl 160,000 mg/L of pH 12 during 20 minutes. Three kinds of synthetic feed water were used as concentrates. They consisted of organic, inorganic and seawater; chemicals of SiO2 (200 mg/L), humic acid (50 mg/L) sodium alginate (50 mg/L) and seawater. As a result, fluxes were recovered to 17% in organic fouling, 15% in inorganic fouling and 14% of seawater fouling after cleaning using DO under the condition of concentrate NaCl 160,000 mg/L of pH 12.

Selective Contact Hole Filling by electroless Ni Plating (무전해 Ni 도금에 의한 선택적 CONTACT HOLE 충전)

  • 우찬희;권용환;김영기;박종완;이원해
    • Journal of the Korean institute of surface engineering
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    • v.25 no.4
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    • pp.189-206
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    • 1992
  • The effect of activation and electroless nickel plating conditions on contact properties was investi-gated for selective electroless nickel plating of Si wafers in order to obtain an optimum condition of con-tact hole filling. According to RCA prosess, p-type silicon (100) surface was cleaned out and activated. The effects of temperature, DMAB concentration, time, and strirring were investigated for activation of p-type Si(100) surface. The optimal activation condition was 0.2M HF, 1mM PdCl2, 2mM EDTA,$ 70^{\circ}C$, and 90sec under ultrasonic vibration. In electroless nickel plating, the effect of temperature, DMAB concentra-tion, pH, and plating time were studied. The optimal plating condition found was 0.10M NiSO4.H2O, 0.11M Citrate, pH 6.8, $60^{\circ}C$, 30minutes. The contact resistance of films was comparatively low. It took 30minutes to obtain 1$\mu\textrm{m}$ thick film with 8mM DMAB concentration. The film surface roughness was improved with decreasing temperature and decreasing pH of the plating solution. The best quality of the film was obtained at the condition of temperature $60^{\circ}C$ and pH 6.0. The micro-vickers hardness of film was about 800Hv. Plating rate of nickel on the hole pattern was slower than that of nickel on the line pattern.

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Properties of Zeolite A Synthesized by Natural Bentonite (천연 벤토나이트로부터 합성된 제올라이트 A의 특성)

  • Lee, Jae-Yeong;Jo, Seung-Rae;Lee, Hong-Gi;Sim, Mi-Ja;Lee, Ju-Seong;Kim, Sang-Uk
    • Korean Journal of Materials Research
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    • v.5 no.8
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    • pp.1035-1039
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    • 1995
  • Synthetic zeolite was prepared by using of natural bentonite from Kampo area and the application of detergent builder was investigated. The optimum synthetic condition was SiO$_2$/Al$_2$O$_3$= 2, Na$_2$O/A1$_2$O$_3$=1, H$_2$O/A1$_2$O$_3$=30 at 90$^{\circ}C$ for 3hr and it was found by XRD analysis that the zeolite synthesized under this condition was type A. When the zeolite A synthesized under the optimum condition was contacted with 40$^{\circ}$Dh CaCl$_2$solution at 30$^{\circ}C$ for 15min, the cation exchange capacity was 264.9mg CaO/g-zeolite. And the whiteness of the sample was 89% and the mean particle size was 9.95$\mu\textrm{m}$.

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Hydrochemical Properties of the Onyang Hot Spring Waters (온양지역 온천수의 수리화학적 특성)

  • Yun, Uk;Cho, Byong Wook;Lee, Cholwoo
    • The Journal of Engineering Geology
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    • v.26 no.4
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    • pp.561-570
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    • 2016
  • For the investigation of hydrochemical changes in hot spring waters from the Onyang hot spring area, we analyzed water chemistry of 24 hot spring waters in 2011 and 2016. The results showed that there is no significant change in temperature and properties of the hot spring waters. The relationship of 2016 between temperature and $SiO_2$ and F reveals a positive trend ($r^2=0.60$, 0.47), and the relationship between temperature and Ca, Mg, Cl, $SO_4$, $HCO_3$, EC reveals a negative trend ($r^2=0.50$, 0.11, 0.50, 0.63, 0.23, 0.51). The relationship between temperature and pH is a positive trend, while the one between temperature and DO is a negative trend, indicating that the source is from deep groundwater. When plotted on Piper diagram, most of which are $Na-HCO_3$ but several hot waters are classified as the $Na(Ca)-HCO_3$, indicating inflow of shallow groundwater was occurred.