• 제목/요약/키워드: $S_N2$

검색결과 18,076건 처리시간 0.049초

An improved bonferroni-type inequality

  • Lee, Min-Young
    • 대한수학회보
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    • 제32권2호
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    • pp.329-336
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    • 1995
  • Let $A_1, A_2, \ldots, A_n$ be a sequence of events on a given probability space and let $m_n$ be the number of those A's which occur. Put $S_{0,n} = 1$ and $$ S_{k,n} = \Sigma P(A_i_1 \cap A_i_2 \cap \cdots \cap A_i_k), (a \leq k)$$ where the summation is over all subscripts satisfying $1 \let i_1 < i_2 < \cdots < i_k \leq n$.

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P-Aminobenzaldehyde Cyclohexylthiosemicarbazone의 결정 및 분자구조 (The Crystal and Molecular Structure of P-Aminobenzaldehyde Cyclohexylthiosemicarbazone)

  • 구정회;김종희;박영자
    • 대한화학회지
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    • 제25권6호
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    • pp.343-350
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    • 1981
  • P-Aminobenzaldehyde cyclohexylthiosemicarbazone의 결정 및 분자구조를 Computer controlled four circle diffractometer에 의한 X-선 회절방법으로 해명하였다. 결정은 공간군 C2/c의 단사형계에 속하며 단위세포 상수는 a = 12.488(2), b = 12.276(4), c = 19.997(6)${\AA}$, ${\beta}=103.55(3)^{\circ}$이고 z = 8이다. 구조는 중원자법과 Fourier 방법으로 규명하였으며 full-matrix 최소자승법으로 정밀화하였다. 최종 R값은 2712개의 회절반점에 대하여 0.058이었다. 분자는 N(2)-N(3)결합에대하여 C(8)-S는 trans, C(8)-N(1)은 cis형으로 놓여 있으며 N(1)과 N(3) 원자들이 분자내 수소결합을 만들고 있다. 의자모양의 cyclohexane 고리는 benzene 고리와 $40.7^{\circ}$의 면각을 이루고 있다. 결정내의 분자들은 수소 결합들로 모여져 있는데 $N(2)-H{\ldots}S$ 수소결합이 분자들을 이합체 꼴을 만들며 이들 분자들을 $N-H{\ldots}N$ 수소결합들이 이어주고 있다.

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Genetic and Antigenic Characterization of Swine H1N2 Influenza Viruses Isolated from Korean Pigs

  • Jo, Su-Kyoung;Kim, Hyun-Soo;Cho, Sung-Whan;Seo, Sang-Heui
    • Journal of Microbiology and Biotechnology
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    • 제17권5호
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    • pp.868-872
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    • 2007
  • H1N2 influenza viruses are circulating in pigs worldwide and cause considerable economic losses to the pig industry. We genetically analyzed the genes of our isolates from Korean pigs, and compared the antigenicity of our isolates with swine H1N2 viruses isolated from pigs in the U.S.A. In addition, we serologically surveyed the infection rate of swine H1N2 viruses in pigs. We found that H1N2 isolates from Korean pigs are genetically more related to swine H1N2 viruses isolated from pigs in the U.S.A. than those in European countries. When antigenicity was compared, our isolates were weakly reacted to antibodies against swine H1N2 viruses isolated from pigs in the U.S.A. The serological surveillance using sera from pigs in Korea showed that about 46% was positive for H1N2 viruses. Our results suggest that swine H1N2 viruses are widespread in Korean pigs, and the development of a vaccine against H1N2 viruses may help to control their infection in pigs.

유도결합 $Cl_2/CHF_3, Cl_2/CH_4, Cl_2/Ar $플라즈마를 이용한 InGaN 건식 식각 반응 기구 연구

  • 이도행;김현수;염근영;이재원;김태일
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 1999년도 제17회 학술발표회 논문개요집
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    • pp.249-249
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    • 1999
  • GaN과 같은 III-nitride 반도체 관한 식각 기술의 연구는 blue-emitting laser diode(LD)를 위한 경면(mirror facet)의 형성뿐만아니라 새로운 display 용도의 light emitting diodes (LED), 고온에서 작동되는 광전소자 제조 등에도 그 중요성이 증대되고 있다. 최근에는 III-nitride 물질의 높은 식각속도와 미려하고 수직한 식각형상을 이루기 위하여 ECR(Electron Cyclotron Resonance)이나 ICP(Inductively Coupled Plasma)와 같은 고밀도 플라즈마 식각과 CAIBE(Chemically assisted ion beam etching)를 이용한 연구가 진행되고 있다. 현재 제조되어 지고 있는 LED 및 LD와 같은 광소자의 구조의 대부분은 p-GaN/AlGaN/InGaN(Q.W)/AlGaN/n-GaN 와 같은 여러 층의 형태로 이루어져 있다. 이중 InGaN는 광소자나 전자소자의 특성에 영향을 주는 가장 중요한 부분으로써 현재까지 보고된 식각연구는 undoped GaN에 대부분 집중되고 있고 이에 비해 소자 특성에 핵심을 이루는 InGaN의 식각특성에 관한 연구는 미흡한 상황이다. 본 연구에서는 고밀도 플라즈마원인 ICP 장비를 이용하여 InGaN를 식각하였고, 식각에는 Cl2/CH4, Cl2/Ar 플라즈마를 사용하였다. InGaN의 식각특성에 영향을 미치는 플라즈마의 특성을 관찰하기 위하여 quadrupole mass spectrometry(QMS)와 optical emission spectroscopy(PES)를 사용하였다. 기판 온도는 5$0^{\circ}C$, 공정 압력은 5,Torr에서 30mTorr로 변화시켰고 inductive power는 200~800watt, bias voltage는 0~-200voltage로 변화시켰으며 식각마스크로는 SiO2를 patterning 하여 사용하였다. n-GaN, p-GaN 층 이외에 광소자 제조시 필수적인 InGaN 층을 100% Cl2로 식각한 경우에 InGaN의 식각속도가 GaN에 비해 매우 낮은 식각속도를 보였다. Cl2 gas에 소량의 CH4나 Ar gas를 첨가하는 경우와 공정압력을 감소시키는 경우 식각속도는 증가하였고, Cl2/10%Ar 플라즈마에서 공정 압력을 감소시키는 경우 식각속도는 증가하였고, Cl2/10%CHF3 와 Cl2/10%Ar 플라즈마에서 공정압력을 15mTorr로 감소시키는 경우 InGaN과 GaNrks의 선택적인 식각이 가능하였다. InGaN의 식각속도는 Cl2/Ar 플라즈마의 이온에 의한 Cl2/CHF3(CH4) 플라즈마에서의 CHx radical 형성에 의하여 증가하는 것으로 사료되어 진다.

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THE JUMP NUMBER OF THE PRODUCT OF GENERALIZED CROWNS

  • Bae, Deok-Rak;Kim, Jong-Youl;Lee, Jeh-Gwon
    • 대한수학회보
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    • 제36권2호
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    • pp.411-417
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    • 1999
  • in this paper, we determine the jump number of the product of generalized crowns: s(${S_n}^k \times {S_m}^l$) = 2(m+1)(n+k)+2(m-2)(n-2)-1.

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Liquid Chromatographic Resolution of Racemic $\alpha$-Amino Acid Derivatives on an Improved $\pi$-Acidic Chiral Stationary Phase Derived from (S)-Leucine

  • 현명호;이승준;류재정
    • Bulletin of the Korean Chemical Society
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    • 제19권10호
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    • pp.1105-1109
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    • 1998
  • A chiral stationary phase derived from (S)-N-(3,5-dinitrobenzoyl)leucine N-phenyl N-alkyl amide (CSP 2) was applied in separating the two enantiomers of various π-basic aromatic derivatives of leucine N-propyl amide in order to evaluate π-basic aromatic groups as an effective derivatizing group for the resolution of a-amino acids. Subsequently N-(3,5-dimethoxybenzoyl) group was found to be very effective as a π-basic aromatic derivatizing group. Based on these results, N-(3,5-dimethoxybenzoyl) derivatives of various a-amino N-propyl amides, N,N-diethyl amides and esters were resolved on the CSP derived from (S)-N-(3,5-dinitrobenzoyl) leucine N-phenyl N-alkyl amide (CSP 2) and the resolution results were compared with those on the CSP derived from (S)-N-(3,5-dinitrobenzoyl)leucine N-alkyl amide (CSP 1). The enantioselectivities exerted by CSP 2 were much greater than those exerted by CSP 1. In addition, racemic N-(3,5-dimethoxybenzoyl)-a-mino N,Ndiethyl amides were resolved much better than the corresponding N-(3,5-dimethoxybenzoyl)-a-mino N-propyl amides and esters on both CSPs. Based on these results, a chiral recognition mechanism utilizing the π-π donor-acceptor interaction and the two hydrogen bondings between the CSP and the analyte was proposed.

경남지역 양액재배용 지하수의 이온 분포특성 (Ionic Characteristics of the Ground Water for Hydroponics in Kyeongnam Area)

  • 이영한;전성건;황연현;조강희;신원교
    • 생물환경조절학회지
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    • 제7권3호
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    • pp.246-252
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    • 1998
  • 1995년 경남지역에서 양액재배 원수로 사용되고 있는 77개 농가의 지하수 중의 무기성분 농도를 분석한 결과는 다음과 같다. 지하수의 깊이는 10~500m, pH는 6.2~8.4, EC는 0.11~1.44dS/m이었다. 1 liter당 무기성분의 평균함량은 N $H_{4}$-N 0.3mg, N $O_{3}$-N 3.1mg, P $O_{4}$$^{3-}$ 0.5mg, $Ca^{2+}$ 25.4mg, $Mg^{2+}$ 11.5mg, $Na^{+}$ 21.7mg, C $l^{-}$ 42.6mg, S $O_{4}$$^{2-}$ 72.5mg였다. 지하수의 pH와 $Mg^{2+}$(0.34$^{**}$ ), $Ca^{2+}$(0.33$^{**}$ ) 및 EC(0.29$^{**}$ ) 사이에 유의적인 정(+)의 상관을 보였다. 또한 EC와 $Na^{+}$(0.68$^{**}$ ), $Ca^{2+}$(0.67$^{**}$ ), S $O_{4}$$^{2-}$(0.62$^{**}$ ), $Mg^{2+}$(0.60$^{**}$ ), N $H_{4}$-N(0.36$^{**}$ ), C $l^{-}$(0.53$^{**}$ ) 및 $K^{+}$(0.26$^{**}$ ) 간에도 유의적인 정(+)의 상관을 보였다..

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청주지역 산성 가스상물질과 미세입자의 계절 변동 특성 (A Seasonal Variation of Acidic Gases and Fine Particle Species in Chongju Area)

  • 강병욱;이학성;김희강
    • 한국대기환경학회지
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    • 제13권5호
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    • pp.333-343
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    • 1997
  • The cyclone/annular denuder system/filter pack sampling system (ADS) was used to collect the acidic air pollutants in Chongju city. The data set was collected on fifty -eight different days with 24 hour sampling period from October 27, 1995 through August 25, 1996. The chemical species measured were HN $O_3$, HN $O_2$, S $O_2$ and N $H_3$ in the gas phase, and PM2.5( $d_{p}$ <2.5 ${\mu}{\textrm}{m}$), S $O_4$$^{2-}$, N $O_3$$^{[-10]}$ and N $H_4$$^{+}$ in the Particulate Phase. Mean concentrations measured for this study were: 0.45 $\mu\textrm{g}$/㎥ for HN $O_3$, 3.39 $\mu\textrm{g}$/㎥ for HN $O_2$, 26.4 $\mu\textrm{g}$/㎥ for S $O_2$, 3.83$\mu\textrm{g}$/㎥ for N $H_3$, 44.2 $\mu\textrm{g}$/㎥ for P $M_{2.5}$, 8.22 $\mu\textrm{g}$/㎥ for S $O_4$$^{2-}$, 3.63 $\mu\textrm{g}$/㎥ for N $O_3$$^{[-10]}$ , and 2.84 $\mu\textrm{g}$/㎥ for N $H_4$$^{- }$. HN $O_3$ and N $H_3$ were higher during the summer. However, HN $O_2$ and S $O_2$ were higher during the fall and winter. P $M_{2.5}$ , S $O_4$/ sup 2-/ and N $H_4$$^{+}$ were not showed seasonal variations, but N $O_3$$^{[-10]}$ was higher in the winter.ter.r.

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大氣中의 酸性降下物의 增加에 따른 Ctenidium molluscum 등 4 종 蘇類의 窒酸還元酵素 活性 (Natrate reductase activity of 4 mosses including ctenidium molluscum in relation to increasing acidic deposition from atmosphere)

  • Ihm, Byung-Sun;Lee, Jeom-Sook
    • The Korean Journal of Ecology
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    • 제15권4호
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    • pp.355-363
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    • 1992
  • Nitrate reductase activity(NRA) and induced NRA were compared in 4 species of moss ctenidium molluscum, homalothecium, tortella tortusa and neckera crispa collected from limestone in england. the NRA and dry weight of the c. molluscum were also measured after spraying with acidic deposition adjusted to ph 5.6, 4.6, 3.6 and 2.8 with one of two molar ratios of nitric to sulfuric acid, i.e. 1:0(N alone) and 1:2(1N+2S) for 20 days. All 4 species showed high NR leavels in the upper part of cut shoots and occurred maximum inducation of NRA within 6h. c. molluscum had the highest NRA levels among 4 species. after daily spraying of acidic deposition, NRA of c. molluscum was increased much more largely at ph 6 and ph 3.6 derived from N alone than from 1N+2S. However that was decreased at ph 2.8 derived both from N alone and 1N+2S . Decline of dry weight had occurred at ph 3.6 and 2.8 derived both from N alone and 1N+2S. Whereas substantial fertilization effect was observed at ph 4.6 derived from N alone. the data suggest that c. molluscum are able to utilize nitrate more effectivery than any other species, and NRA induction are more sensitive than growth response to nitrogen content of acidicdeposition in a short- term. however toxic effects was detected at high $NO_3$ supply and low phacidic deposition.

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고질소 Fe-l8Cr-l8Mn-2Mo-0.9N 강의 미끄럼 마멸 기구 (Sliding Wear Mechanism of the High-Nitrogen Austenitic 18Cr-l8Mn-2Mo-0.9N Steel)

  • 김승덕;김성준;김용석
    • 소성∙가공
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    • 제15권2호
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    • pp.112-117
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    • 2006
  • Sliding wear mechanism of a high nitrogen austenitic 18Cr-18Mn-2Mo-0.9N steel has been investigated. Dry sliding wear tests of the steel were carried out at various loads of IN-10N under a constant sliding speed condition of 0.15m/s against AISI 52100 bearing steel balls. Solution ($1050^{\circ}C$) and isothermal aging ($900^{\circ}C$) heat treatments were performed on the steel and the effect of the heat treatments on the wear was investigated. Wear rates of the solution-treated steel specimen remained low until 5N load, and then increased abruptly at loads above 5N. The rates of isothermally aged specimens were low and increased gradually with the applied load. Worn surfaces, their cross sections, and wear debris of the steel specimens were examined with a scanning electron microscopy. Phases of the heat-treated specimen and the wear debris were identified using XRD. The transformed phase underneath a sliding track was investigated and analyzed using a TEM. Effects of the phase transformation during the wear and $Cr_{2}N$ precipitates formed during the isothermal aging on the wear of the austenitic steel were discussed.