• Title/Summary/Keyword: $SO_X$

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Estimation of air pollutant emissions from heavy industry sector in North Korea (북한의 중공업 부문 대기오염물질 배출량 추정)

  • Lee, Young Won;Kim, Yong Pyo;Yeo, Min Ju
    • Particle and aerosol research
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    • v.17 no.4
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    • pp.133-148
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    • 2021
  • This study aims to estimate the amount of air pollutants emitted from heavy industry facilities in North Korea. To compare the emission in 2017 from the heavy industry sector in North Korea with South Korea, the heavy industry sector was classified with the South Korean classification (Matching Heavy Industry sector) and air pollutant emissions by Matching Heavy Industry sector in North Korea were estimated. The CO, NOx and SOx emissions of Matching Heavy Industry sector in North Korea are 22%, 73%, and 31% of the emission in South Korea, respectively. The air pollutant emissions in the Matching Heavy Industry sector in North Korea for CO, NOx and SOx were 0.6%, 124%, and 24% of the total air pollutant emission in North Korea estimated from EDGAR, respectively. As for the distribution of emissions by administrative district of the Matching Heavy Industry sector in North Korea, NOx was concentrated in the western part of North Korea, and CO and SOx emissions were concentrated in Hamgyong-bukto.

Characteristic of Water-soluble Components of PM10 at Taean and Gangneung Sites in Summer Season (태안과 강릉지역 여름철 PM10의 수용성 성분 특성)

  • Park, Seung-Shik;Ko, Jae-Min;Chung, Chang-Hoon
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.3
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    • pp.291-302
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    • 2011
  • [ $PM_{10}$ ]measurements were made at two coastal sites, i.e., Taean and Gangneung, for summer to examine the characterization of water-soluble organic carbon (WSOC) and inorganic ionic species, and to investigate their difference between the sites. The fractions of three major inorganic water-soluble components ($NO_3^-$, $SO_4^{2-}$, and $NH_4^+$) at Taean and Gangneung sites were 30.6% (16.2~62.0%) and 25.6% (13.0~52.5%) of the $PM_{10}$, respectively. $SO_4^{2-}$ is the most dominant species of water-soluble ions at both sites, accounting for up to 20.5% (9.1~44.9%) and 16.3% (5.5~34.2%) of their respective PM10 mass concentrations. Using the paired T-test, $PM_{10}$ (p<0.01), $NO_3^-$ (p<0.05), $SO_4^{2-}$ (p<0.01), $NH_4^+$ (p<0.001), and WSOC (p<0.05) concentrations exhibited strong fluctuations on a daily basis between Taean and Gangneung sites. Relationship between the concentrations of $SO_x$ ($SO_4^{2-}+SO_2$) and CO indicates that the slopes of $SO_x$ /CO were 0.007 and 0.019 in the Taean and Gangneung sites, respectively. The smaller $SO_x$/CO slope in the Taean site could be related to the aged air with wet scavenging of $SO_x$ during transport. The correlation between the concentrations of CO and WSOC suggests that WSOC observed in the Gangneung ($R^2$=0.82) be transported from combustion-related sources, while the WSOC at the Taean site could be formed through atmospheric processing of primary volatile organic species during transport.

Bonding and Electronic Considerations in the Apex Bridged $M_2(OR)_6L_x(\mu-X)$ Complexes (M = Mo ; R = -t-Bu, -i-Pr ; L = Py ; x = 0 or 2 ; X = CO, SO$_2$, HCCH, H, and Cl)

  • Ko, Jae-Jung
    • Bulletin of the Korean Chemical Society
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    • v.9 no.3
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    • pp.121-126
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    • 1988
  • The molecular interaction of $Mo_2(OR)_4({\mu}-OR)_2$$ unit has been studied for carbonyl and acetylene ligands by means of extended Huckel calculations. We have extended the extended Hckel calculations to unknown apex bridged $Mo_2(OR)_6({\mu}-X)$ complexes (X = $SO_2$H, and Cl) in order to compare the stability of the complexes. In the $C_2H_2$and H apex bridged complexes, one finds a relatively small HOMO-LUMO gap. However, both complexes are stabilized due to Jahn-Teller distortion. The stability of both complexes is comparable to that of $Mo_2(OR)_6(CO)$ complex. The comparisons and predictions in the stability of known and unknown complexes are the subject of this study.

2 Liquid Phase Purification Characteristics for Sulfur-Iodine Thermochemical Hydrogen Production (황-요오드 열화학 수소체조 공정에서 2 액상 정체 특성)

  • Lee, Kwang-Jin;Cha, Kwang-Seo;Kang, Young-Han;Park, Chu-Sik;Bae, Ki-Kwang;Kim, Young-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.69-72
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    • 2007
  • The objective of this work was to study the properties of purification of two liquid phase for exclusion of impurities in each phase. The experiments for process variables were carried out in the temperature range($H_{2}SO_{4}$ phase: $413{\sim}513$ K, $HI_{x}$ phase: $353{\sim}453$ K) and in the $N_{2}$ flow rate range($H_{2}SO_{4}$, $HI_{x}$ phase: $50{\sim}200$ mL/min). As the results, it is appeared that the principles of $H_{2}SO_{4}$ phase purification was due to stripping, evaporation and reverse bunsen reaction and $HI_{x}$ phase purification was due to stripping and reverse bunsen reaction. In purification of $H_{2}SO_{4}$ phase, the concentration rate of $H_{2}SO_{4}$ phase was controled by temperature but the temperature had few effects on yield of $H_{2}SO_{4}$. In purification of $HI_{x}$ phase, we observed products of side reactions($H_{2}S$, S) over 433 K. The purity of $HI_{x}$ phase was increased with increasing $N_{2}$ flow rate because impurites were decreased with increasing conversion of reverse reaction.

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Relationship of Electricity Consumption and Emission Rate of Acidic Gases (전력소비와 산성가스 배출량과의 관계)

  • 정일록;김대곤
    • Journal of environmental and Sanitary engineering
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    • v.10 no.3
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    • pp.131-138
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    • 1995
  • As the energy consumption increases continuously, the emission amount of air pollutants is growing, and after all it can influence the global environment as welt as the regional atmosphere. So, the clean energy which emits less air pollutants should be developed and widely used to reduce emission of pollutants. Electricity, known for clean energy in the side of consumption, is not actually clean in the process of generation. Electric power is generated using fossil fuels which produce acidic gases like $SO_{2}$, $NO_{x}$, etc. The emission rates of $SO_{2}$, $NO_{x}$, $CO_{2}$ are 2g,0.78g and 1 l0g per electric power generating Ikwh. If one light(60 watt bulb) be turned off at each house for a month electricity will be saved about 1.Skillion kwh a year. This is almost the same as 4,170 tons of $SO_{2}$ and $NO_{x}$. As a result the economization of electricity will be one of the effective strategy to reduce the air pollution and to keep our life clean and comfortable.

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Study on the Co-firing of Sewage Sludge to a 80 kWth-scale Pulverized Coal Combustion System (80 kWth급 미분탄 연소 시스템에서 하수슬러지 혼소시 연소 특성 연구)

  • Chae, Taeyoung;Lee, Jaewook;Lee, Youngjae;Yang, Won
    • Clean Technology
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    • v.25 no.1
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    • pp.74-80
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    • 2019
  • Thermochemical treatment of sewage sludge is an energy-intensive process due to its high moisture content. To save the energy consumed during the process, the hydrothermal carbonization process for sewage sludge can be used to convert sewage sludge into clean solid fuel without pre-drying. This study is aimed to investigate co-firing characteristics of the hydrothermally carbonated sewage sludge (HCS) to a pulverized coal combustion system. The purpose of the measurement is to measure the pollutants produced during co-firing and combustion efficiency. The combustion system used in this study is a furnace with a down-firing swirl burner of a $80kW_{th}$ thermal input. Two sub-bituminous coals were used as a main fuel, and co-firing ratio of the sewage sludge was varied from 0% to 10% in a thermal basis. Experimental results show that $NO_x$ is 400 ~ 600 ppm, $SO_x$ is 600 ~ 700 ppm, and CO is less than 100 ppm. Experimental results show that stable combustion was achieved for high co-firing ratio of the HCS. Emission of $NO_x$ and $SO_x$ was decreased for higher co-firing ratio in spite of the higher nitrogen contents in the HCS. In addition, it was found that the pollutant emission is affected significantly by composition of the main fuel, regardless of the co-firing ratios.

FIXED POINTS OF ROTATIVE LIPSCHITZIAN MAPS

  • Park, Sehie;Yie, Sangsuk
    • Bulletin of the Korean Mathematical Society
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    • v.23 no.2
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    • pp.155-160
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    • 1986
  • Let X be a closed convex subset of a Banach space B and T:X.rarw.X a lipschitzian rotative map, i.e., such that ∥Tx-Ty∥.leq.k∥x-y∥ and ∥T$^{n}$ x-x∥.leq.a∥Tx-x∥ for some real k, a and an integer n>a. We denote by .PHI. (n, a, k, X) the family of all such maps. In [3], [4], K. Goebel and M. Koter obtained results concerning the existence of fixed points of T depending on k, a and n. In the present paper, the main results of [3], [4] are so strengthened that some information concerning the geometric estimations of fixed points are given.

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