• Title/Summary/Keyword: $PaO_2$

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Characterization of Poly(ether-block-amide)s Prepared from Oligomeric Polyamide 12 via Dispersion Polymerization (분산중합에 의한 폴리아미드 12 올리고머의 제조와 그를 이용한 Poly(ether-block-amide)의 특성)

  • Kim, Doo-Hyeon;Lee, Ji-Hun;Kim, Hyung-Joong
    • Polymer(Korea)
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    • v.36 no.4
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    • pp.513-518
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    • 2012
  • Polyamide 12 (PA12) oligomers (oPA1) were prepared by dispersion polymerization of ${\omega}$-amino carboxylic acid and dibasic acid in a dispersion medium, thermally stable hydrocarbon liquid paraffin, YK-D130 (a step polymerization). The molecular weight and various properties of other oligomeric PAs (oPA2) obtained by bulk polymerization without the medium were compared with those of oPA1s. The oPA1s showed lighter white color and narrower molecular weight distribution than oPA2s at the same molecular weight. Moreover elastomeric poly(ether-block-amide) (PEBA)s were synthesized with oPA1 and oPA2 as hard segments and poly(tetramethylene glycol) (PTMG) as a soft segment. The molecular weight distribution, and mechanical property of the PEBA originated from the both oligomeric PAs were characterized.

Changes in Physicochemical and Organoleptic Qualities of 'Niitaka' Pears during Controlled Atmosphere Storage (CA저장 중 신고 배의 이화학적 및 관능적 품질특성 변화)

  • Chung, Hun-Sik;Kim, Sung-Hwan;Chang, Eun-Ha;Youn, Kwang-Sup;Seong, Jong-Hwan;Choi, Jong-Uck
    • Korean Journal of Food Science and Technology
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    • v.35 no.5
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    • pp.865-870
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    • 2003
  • The effects of storage atmosphere on the physicochemical and organoleptic properties of Asian pears (Pyrus pyrifolia Nakai cv. Niitaka) were investigated. The pears were stored at $0^{\circ}C$ for up to 8 months under CA conditions (3 kPa $O_2$+1 kPa $CO_2$, 1 kPa $O_2$+5 kPa $CO_2$, 1 kPa $O_2$+1 kPa $CO_2$) controlled by a static system or air (21 kPa $O_2$+0 kPa $CO_2$). CA conditions retarded the loss of weight, flesh firmness, organoleptic properties (appearance, aroma, sweetness, texture), and the development of injuries in the fruits during storage. Low $O_2$ plus high $CO_2$ conditions maintained the highest flesh firmness. In addition, low $O_2$ reduced injuries more than the other conditions. Skin color (lightness, chroma, hue), soluble solids, titratable acidity, pH and vitamin C were unaffected by storage atmosphere.

Relationship between In Vitro Maturation and Plasminogen Activator Activity on Porcine Cumulus-Oocytes Complexes Exposed to Oxidative Stress

  • Sa, Soo-Jin;Park, Chun-Keun;Cheong, Hee-Tae;Son, Jung-Ho;Kim, Myung-Jick;Cho, Kyu-Ho;Kim, Du-Wan;So, Kyoung-Min;Kim, In-Cheul
    • Reproductive and Developmental Biology
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    • v.35 no.3
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    • pp.221-225
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    • 2011
  • This study was undertaken to evaluate the relationship between in vitro maturation and plasminogen activators (PAs) activity on porcine cumulus-oocytes complexes (COCs) exposed to oxidative stress. When COCs were cultured in maturation medium with hydrogen peroxide ($H_2O_2$), the proportion of the germinal vesicle breakdown (GVBD) and oocytes maturation were decrease with addition of $H_2O_2$, and were significantly (p<0.05) lower in medium with 0.1 mM $H_2O_2$ than control group. Also, the rate of degenerated oocytes was increased in as $H_2O_2$ concentration in eased. When COCs were cultured for 48 h, three plasminogen-dependent lytic bands were observed: tissue-type PA (tPA); urokinase-type PA (uPA); and tPA-PA inhibitor (tPA-PAI). PA activity was quantified using SDS-PAGE and zymography. When $H_2O_2$ concentration was increased, tPA and tPA-PAI activities also increased in porcine oocytes cultured for 48 h, but not uPA. In other experiment, embryos were divided into three groups and cultured in (1) control medium, (2) control medium with 1.0 mM $H_2O_2$ and (3) control medium with 1.0 mM $H_2O_2$ along with catalase in concentrations of 0.01, 0.1, and 1.0 mg/ml, respectively. $H_2O_2$ decreased the rate of GVBD and maturation in porcine COCs but catalase revealed protective activity, against oxidative stress caused by $H_2O_2$. In this experiment, tPA and tPA-PAI activities were higher in media with 1.0 mM $H_2O_2$ alone. Increasing concentration of catalase decreased tPA and tPA-PAI activities in porcine oocytes. These results indicate that the exposure of porcine follicular oocytes to ROS inhibits oocytes maturation to metaphase-II stage and increase the oocytes degeneration. Also, we speculated that increased ROS level may trigger tPA and tPA-PAI activities in porcine oocytes matured in vitro.

Nocturnal Arterial Oxygen Saturation Monitoring in Patients with Respiratory Disease (호흡기 질환 환자들에서 야간 동맥혈 산소포화도 감시 성적)

  • Choi, In-Seon;Yang, Jae-Beom;Kim, Young-Chul;Chung, Ik-Joo;Kang, Yu-Ho;Koh, Yeoung-Il;Park, Sang-Seon;Lee, Min-Su;Park, Kyung-Ok
    • Tuberculosis and Respiratory Diseases
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    • v.41 no.2
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    • pp.103-110
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    • 1994
  • To find out the predictors of nocturnal arterial oxygen desaturation in patients with respiratory diseases, transcutaneous oxygen saturation($StcO_2$) monitoring studies using a pulse oximeter were performed during sleep in 20 patients. $StcO_2$ was decreased more than 4% from the baseline value in 18 patients(90%) and more than 10%("Desaturator") in 8(40%). Five of the seven patients(71.4%) with awake $PaO_2$<60mmHg and three of the thirteen patients(23.1%) with awake $PaO_2{\geq}60mmHg$ were "desaturators". The awake $PaO_2/FIO_2$ and $PaO_2/PAO_2$ could distinguish "desaturator" from "nondesaturator", and $PaO_2,\;SaO_2$ or $StcO_2$ could not. These results suggest that the nocturnal oxygen desaturation depends on the severity of the underlying disease rather than the baseline $PaO_2$. Anthropomorphic and lung function factors could not separate between "desaturator" and "non-desaturator", and about a quater of patients with a wake $PaO_2{\geq}60mmHg$ developed significant desaturation. Therefore, it is necessary to monitor the nocturnal arterial oxygen saturation in patients with respiratory diseases regardless of their severity of airflow obstruction or awake $PaO_2$.

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Effect of Hollow Sphere Size on Heat Shield Properties of hollow TiO2/polyacrylate Composites (중공구의 크기에 의한 hollow TiO2/polyacrylate 복합체의 열차단 특성)

  • Kim, Jong Seok
    • Applied Chemistry for Engineering
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    • v.32 no.6
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    • pp.690-694
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    • 2021
  • Carbon spheres (CS) were fabricated using glucose as a precursor in the hydrothermal method. Hollow TiO2 (H-TiO2) spheres with 200 nm, 500 nm, and 1,200 nm were synthesized by CS/TiO2 core-shell particles via a sol-gel and calcination method. H-TiO2 spheres with nano and micron sizes were characterized using FE-SEM, HR-TEM, and X-ray diffraction. The CIE color coordinate, solar reflectance, and heat shield temperatures of H-TiO2/polyacrylate (PA) composite film were investigated using a UV-Vis-NIR spectrometer and homemade heat insulation temperature measuring device. H-TiO2/PA composites exhibit excellent thermal insulation since the hollow structure filled with dry air has low thermal conductivity and near infrared light reflecting performance. The thermal insulation increased with increasing the hollow sphere (HS) size on H-TiO2/PA composites. The PA composite film mixed with H-TiO2 filled with 1200 nm HS reduced the heat shield temperature by 26 ℃ compared to that of the transparent glass counterpart.

The Effect of Body Positioning on Physiologic Index in Patients with Unilateral Lung Disease (편측성 폐질환 환자의 체위변경이 생리적 지표에 미치는 영향)

  • Cho, Jee Yeon;Lee, Hyang Yeon
    • Korean Journal of Adult Nursing
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    • v.12 no.1
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    • pp.122-133
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    • 2000
  • The purpose of this study was to identify the effect of body positioning on $PaO_2$, $SpO_2$, systolic blood pressure, diastolic blood pressure, pulse, and respiration(above all defined physiologic index), of patients with unilateral lung disease. The subjects for this study were eleven patients admitted to I.C.U. of K.H.M.C. with a diagnosis of unilateral lung disease confirmed by chest X-ray and the attending doctor, from January 30th. to April 20th. 1999. A quasi-experimental repeated-measures cross-over design was used to compare three body positions(semi-Fowler's, lateral decubitus with good lung dependent, and lateral decubitus with diseased lung dependent). Each subject spent 30 minutes in semi-Fowler's position and 2 hours in good lung dependent position and diseased lung dependent position. Starting in the semi-Fowler's position, then in the lateral position with the good lung dependent or the diseased lung dependent as assigned in random order. Thirty minutes after each positioning, arterial blood sample was analyzed. Measurements of all physiologic index were recorded at the specified intervals(0, 30, 60 90, and 120 minutes) in good lung dependent and diseased lung dependent position. Statistical comparison of $PaO_2$ value was done using the Wilcoxon Signed Rank Test, and Multivariate repeated-measures analysis of variance was performed to analyse the within-subject effect of two dependent position for 2 hours on the five dependent variables: (1) $PaO_2$ (2) $SpO_2$ (3) systolic blood pressure (4) diastolic blood pressure (5) pulse. The results obtained were as follows: 1. The $PaO_2$ value in the good lung dependent position was significantly higher than the $PaO_2$ value in the diseased lung dependent position(Z=-2.8451, p=.002). 2. The $PaO_2$ value in the good lung dependent position was significantly higher than the $PaO_2$ value in the semi-Fowler's position (Z=-2.6673, p=.003). 3. The difference between the $PaO_2$ value in the semi-Fowler's position and the $PaO_2$ value in the diseased lung dependent position was not significant(Z=-1.2448, p=.10). 4. There were no statistically significance in the trends of physiologic index in the good lung dependent position and the diseased lung dependent position. From the results, it may be concluded that the good lung dependent position is the most effective position for patients with unilateral lung disease that improve oxygenation. Identification of positioning over time may be need further studies.

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Effect of Irrigation and Fertigation Treatments on Growth and Yield in Spring Potato Cultivation (봄 감자 재배 시 관수 및 관비 처리가 생육 및 수량에 미치는 영향)

  • Kim, Jong Hyuk;Rho, Il Rae
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.67 no.2
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    • pp.121-130
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    • 2022
  • This study was conducted to determine the suitable amount of irrigation and fertigation for the growth and yield of spring potatoes (Solanum tuberosum L.). To investigate the effect of soil moisture content on the growth and yield of potato, five irrigation treatments were performed based on soil moisture tension: -10 kPa, -20 kPa, -30 kPa, -40 kPa, and non-irrigation. The growth and yield among the irrigation treatments was the best in the -10 kPa treatment, where the yield increased by 47% compared to the non-irrigation treatment. To determine the standard of additional fertilizer for fertigation cultivation of spring potatoes, seven treatments were performed, including a control (basic fertilization without additional fertilizer), compound fertilizer (NPK) based on 0.5 times the standard amount of fertilizer (NPK 0.5; N-P2O5-K2O: 2.5-2.2-3.25 kg/10a), NPK 0.8 (N-P2O5-K2O: 4-3.5-5 kg/10a), and NPK 1.2 (N-P2O5-K2O: 6-5.3-7.8 kg/10a), and potassium fertilizer of 2 kg (K 2), 5 kg (K 5), and 7 kg (K 7). The growth and yield among the fertilization treatments was highest in the K 5 treatment, where the yield increased by approximately 27% compared to the control. Therefore, this study suggests that irrigation with -10 kPa or fertigation with K 5 during the tuber initiation and tuber filling stage could increase the yield of spring potatoes.

Improvement on the Passivation Effect of PA-ALD Al2O3 Layer Deposited by PA-ALD in Crystalline Silicon Solar Cells (결정질 실리콘 태양전지를 위한 PA-ALD Al2O3 막의 패시베이션 효과 향상 연구)

  • Song, Se Young;Kang, Min Gu;Song, Hee-Eun;Chang, Hyo Sik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.10
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    • pp.754-759
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    • 2013
  • Aluminum oxide($Al_2O_3$) film deposited by atomic layer deposition (ALD) is known to supply excellent surface passivation properties on crystalline Si surfaces. Since $Al_2O_3$ has fixed negative charge, it forms effective surface passivation by field effect passivation on the rear side in p-type silicon solar cell. However, $Al_2O_3$ layer formed by ALD process needs very long process time, which is not applicable in mass production of silicon solar cells. In this paper, plasma-assisted ALD(PA-ALD) was applied to form $Al_2O_3$ to reduce the process time. $Al_2O_3$ synthesized by ALD on c-Si (100) wafers contains a very thin interfacial $SiO_2$ layer, which was confirmed by FTIR and TEM. To improve passivation quality of $Al_2O_3$ layer, the deposition temperature was changed in range of $150{\sim}350^{\circ}C$, then the annealing temperature and time were varied. As a result, the silicon wafer with aluminum oxide film formed in $250^{\circ}C$, $400^{\circ}C$ and 10 min for the deposition temperature, the annealing temperature and time, respectively, showed the best lifetime of 1.6ms. We also observed blistering with nanometer size during firing of $Al_2O_3$ deposited on p-type silicon.

Microfiltration/ultrafiltration polyamide-6 membranes for copper removal from aqueous solutions

  • El-Gendi, Ayman;Ali, Sahar;Abdalla, Heba;Saied, Marwa
    • Membrane and Water Treatment
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    • v.7 no.1
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    • pp.55-70
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    • 2016
  • Microfiltration/ultrafiltration (MF/UF) Adsorptive polyamide-6 (PA-6) membranes were prepared using wet phase inversion process. The prepared PA-6 membranes are characterized by scanning electron microscopy (SEM), porosity and swelling degree. In this study, the membranes performance has examined by adsorptive removal of copper ions from aqueous solutions in a batch adsorption mode. The $PA-6/H_2O$ membranes display sponge like and highly porous structures, with porosities of 41-73%. Under the conditions examined, the adsorption experiments have showed that the $PA-6/H_2O$ membranes had a good adsorption capacity (up to 120-280 mg/g at the initial copper ion concentration ($C_0$) = 680 mg/L, pH7), fast adsorption rates and short adsorption equilibrium times (less than 1.5-2 hrs) for copper ions. The fast adsorption in this study may be attributed to the high porosities and large pore sizes of the $PA-6/H_2O$ membranes, which have facilitated the transport of copper ions to the adsorption. The results obtained from the study illustrated that the copper ions which have adsorbed on the polyamide membranes can be effectively desorbed in an Ethylene dinitrilotetra acetic acid Di sodium salt ($Na_2$ EDTA) solution from initial concentration (up to 92% desorption efficiency) and the PA-6 membranes can be reused almost without loss of the adsorption capacity for copper ions. The results obtained from the study suggested that the $PA-6/H_2O$ membranes can be effectively applied for the adsorptive removal of copper ions from aqueous solutions.

Intrinsic Reactivity of NO and $N_2$O gas with Korean Anthracites (국내산 무연탄과 NO, $N_2$O 기체의 고유반응 특성)

  • 박영철
    • Journal of Energy Engineering
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    • v.8 no.2
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    • pp.279-284
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    • 1999
  • Thermal analyses were conducted in a thermogravimetric analyzer by isothermal technique in order to characterize the Korean anthracites-nitrogen oxides reaction. The tested coal sample was Dogae anthracites and compared with SP-1 graphite. Carbon-NO and carbon-N$_2$O reactions were carried out with respect to isothermal reaction temperatures (550$^{\circ}C$-900$^{\circ}C$) and reactant gas partial pressures (5 kPa∼20 kPa). In NO reaction, measured reaction orders of NO concentration and activation energy were 0.45∼0.96 and 39∼l12 kJ/mol, respectively. In N$_2$O reaction, measured reaction orders of N$_2$O concentration and activation energy were 0.62∼0.87 and 190∼215.3 kJ/mol, respectively. Compared the Korean anthracites-nitrogen oxides reaction with the combustion reaction, the reaction rate in the oxidation below 700$^{\circ}C$ decreases in the order O$_2$>NO>N$_2$O. But above 700$^{\circ}C$, the reaction rate of N$_2$O is faster than that of NO.

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