• Title/Summary/Keyword: $PM_{2.5}$ concentrations

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Mass Concentration and Ion Composition of Size-segregated Particulate Matter during the Non-Asian Dust Storm of Spring 2007 in Iksan (익산지역에서 봄철 비황사기간 중 입경별 대기먼지농도와 이온조성)

  • Kang, Gong-Unn;Kim, Nam-Song;Lee, Hyun-Ju
    • Journal of Environmental Health Sciences
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    • v.34 no.4
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    • pp.300-310
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    • 2008
  • In order to further determine the mass concentration and ion composition of size-segregated particulate matter (PM) during the non-Asian dust storm of spring, $PM_{2.5}$ (fine particle), $PM_{10-2.5}$ (coarse particle), and $PM_{over-10}$ (PM with an aerodynamic diameter larger than $10{\mu}m$) were collected using a MCI (multi-nozzle cascade impactor) sampler of a three-stage filter pack in the spring season of 2007 in the Iksan area. During the sampling period from 5 April to 21 April, a total of 34 samples for size-segregated PM were collected, and then measured for PM mass concentrations by gravimetric measurements and for water-soluble inorganic ion species by using ion chromatography. Average mass concentrations of $PM_{2.5}$, $PM_{10-2.5}$, $PM_{over-10}$ were $35.4{\pm}11.5{\mu}g/m^3$, $13.3{\pm}5.5{\mu}g/m^3$ and $9.5{\pm}4.7{\mu}g/m^3$, respectively. On average, $PM_{2.5}$ accounted for 74% of $PM_{10}$. Compared with the literature from other areas in Korea, the measured concentration of $PM_{2.5}$ were relatively high. Water-soluble inorganic ion fractions in $PM_{2.5}$, $PM_{10-2.5}$, and $PM_{over-10}$ were found to be 47.8%, 28.5%, and 14.7%, respectively. Among the water-soluble inorganic ion species, $SO_4^{2-}$, $NO_3^-$ and $NH_4^+$ were the main components in $PM_{2.5}$, while $NO_3^-$ dominantly existed in both $PM_{10-2.5}$ and $PM_{over-10}$. Non-seasalt $SO_4^{2-}$ (nss-$SO_4^{2-}$ and $NO_3^-$ were found to mainly exist as the neutralized chemical components of $(NH_4)_2SO_4$ and $NH_4NO_3$ in fine particles.

Sampling and Analysis of Acidic Air Pollutants Using an Annular Denuder System during the Summer Season in Chongju City (디누더 측정기를 이용한 여름철 청주시의 산성오염물질 측정과 분석)

  • 이학성;강병욱
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.4
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    • pp.441-448
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    • 1996
  • The cyclone/annular denuder system/filter pack sampling system (ADS) was used to collect the acidic air pollutants in Chongju city. The data set was collected on nine different days with 24 hour sampling period from July 27 through August 27, 1995. The chemical species measured were $HNO_3, HNO_2, SO_2 and NH_3$ in the gas phase, and $PM_{2.5}(d_P<2.5 \mum), SO_4^{2-}, NO_3^- and NH_4^+$ in the particulate phase. Mean concentrations measured from this study were: $0.90 \mug/m^3 for HNO_3, 1.27 \mug/m^3 for HNO_2, 10.9 \mug/m^3 for SO_2, 4.82 \mug/m^3 for NH_3, 27.5 \mug/m^3 for PM_{2.5}, 5.24 \mug/m^3 for SO_4^{2-}, 1.22 \mug/m^3 for NO_3^-, and 1.64 \mug/m^3 for NH_4^+$. The fine particle $(PM_{2.5})$ mass measured for the ADS samples was slightly higher than the fine particle mass measured for the corresponding dichotomous sampler. For the wind coming from Chongju industrial complex the concentrations of acidic air pollutants measured were higher when compared with other directions. Specially, $SO_2 and PM_{2.5}$ concentrations for the wind coming from Chongju industrial complex were 3.6 and about 2 times, respectively, higher than those of other wind directions. High correlations were observed between $PM_{2.5} and fine particle's ion components $(r=0.82 with SO_4^{2-}, r=0.76 with NO_3^- and r=0.89 with NH_4^+). NH_4^+ and SO_4^{2-}$ was also highly correlated (r=0.97).

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Forecasting daily PM10 concentrations in Seoul using various data mining techniques

  • Choi, Ji-Eun;Lee, Hyesun;Song, Jongwoo
    • Communications for Statistical Applications and Methods
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    • v.25 no.2
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    • pp.199-215
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    • 2018
  • Interest in $PM_{10}$ concentrations have increased greatly in Korea due to recent increases in air pollution levels. Therefore, we consider a forecasting model for next day $PM_{10}$ concentration based on the principal elements of air pollution, weather information and Beijing $PM_{2.5}$. If we can forecast the next day $PM_{10}$ concentration level accurately, we believe that this forecasting can be useful for policy makers and public. This paper is intended to help forecast a daily mean $PM_{10}$, a daily max $PM_{10}$ and four stages of $PM_{10}$ provided by the Ministry of Environment using various data mining techniques. We use seven models to forecast the daily $PM_{10}$, which include five regression models (linear regression, Randomforest, gradient boosting, support vector machine, neural network), and two time series models (ARIMA, ARFIMA). As a result, the linear regression model performs the best in the $PM_{10}$ concentration forecast and the linear regression and Randomforest model performs the best in the $PM_{10}$ class forecast. The results also indicate that the $PM_{10}$ in Seoul is influenced by Beijing $PM_{2.5}$ and air pollution from power stations in the west coast.

Regional Trends in Short-Term High Concentrations of Criteria Pollutants from National Air Monitoring Stations (측정망 자료를 이용한 환경기준 대기오염물질의 권역별 단기 고농도 변화 추이)

  • Ghim, Young Sung;Kim, Chan Hyuk
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.5
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    • pp.545-552
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    • 2013
  • While attainment rates for $SO_2$ and CO approached 100%, those for $PM_{10}$, $NO_2$, and $O_3$ have been low during the past decade. The attainment rates for 24-h $PM_{10}$ and 8-h $O_3$ have been only 1~3% and 5~12%, respectively, since the standards were strengthened in 2007. Variations in the 99th percentiles of 24-h $PM_{10}$, 8-h $O_3$, and 24-h $NO_2$, which are used as criteria for determining exceedance of standards, were examined by region. Because the analysis was based on short-term high-concentrations, the effects of Asian dust were observed for $PM_{10}$. Accordingly, it is necessary to specify whether exceptional events such as Asian dust will be included or not in determining the exceedances of standards. While variations in $NO_2$ were not large, there was an increasing trend in $O_3$. In the Yeongnam region, the increasing rate of $O_3$ concentrations was small although the decreasing rate of $NO_2$ was the greatest. In the Gangwon region, $NO_2$ concentrations were almost unchanged, but $O_3$ concentrations experienced a significant increase. Regional management strategies targeting short-term high concentrations of criteria pollutants analogous to the Special Act for the greater Seoul area will aid in improving attainment rates.

Urban Air Quality Model Inter-Comparison Study (UMICS) for Improvement of PM2.5 Simulation in Greater Tokyo Area of Japan

  • Shimadera, Hikari;Hayami, Hiroshi;Chatani, Satoru;Morikawa, Tazuko;Morino, Yu;Mori, Yasuaki;Yamaji, Kazuyo;Nakatsuka, Seiji;Ohara, Toshimasa
    • Asian Journal of Atmospheric Environment
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    • v.12 no.2
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    • pp.139-152
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    • 2018
  • The urban model inter-comparison study (UMICS) was conducted in order to improve the performance of air quality models (AQMs) for simulating fine particulate matter ($PM_{2.5}$) in the Greater Tokyo Area of Japan. UMICS consists of three phases: the first phase focusing on elemental carbon (UMICS1), the second phase focusing on sulfate, nitrate and ammonium (UMICS2), and the third phase focusing on organic aerosol (OA) (UMICS 3). In UMICS2/3, all the participating AQMs were the Community Multiscale Air Quality modeling system (CMAQ) with different configurations, and they similarly overestimated $PM_{2.5}$ nitrate concentration and underestimated $PM_{2.5}$ OA concentration. Various sensitivity analyses on CMAQ configurations, emissions and boundary concentrations, and meteorological fields were conducted in order to seek pathways for improvement of $PM_{2.5}$ simulation. The sensitivity analyses revealed that $PM_{2.5}$ nitrate concentration was highly sensitive to emissions of ammonia ($NH_3$) and dry deposition of nitric acid ($HNO_3$) and $NH_3$, and $PM_{2.5}$ OA concentration was highly sensitive to emissions of condensable organic compounds (COC). It was found that $PM_{2.5}$ simulation was substantially improved by using modified monthly profile of $NH_3$ emissions, larger dry deposition velocities of $HNO_3$ and $NH_3$, and additionally estimated COC emissions. Moreover, variability in $PM_{2.5}$ simulation was estimated from the results of all the sensitivity analyses. The variabilities on CMAQ configurations, chemical inputs (emissions and boundary concentrations), and meteorological fields were 6.1-6.5, 9.7-10.9, and 10.3-12.3%, respectively.

A quantitative study of the transfer of colostral immunoglobulins to the newborn Korean native calf (한우 송아지의 초유섭취에 의한 수동면역 획득 상태)

  • Kim, Doo;Han, Hong-ryul
    • Korean Journal of Veterinary Research
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    • v.29 no.2
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    • pp.75-81
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    • 1989
  • The levels of the serum and colostral total protein and immunoglobulins of the Korean native cows immediately after parturition and colostrum-conferred passive immune status of the Korean native calves were studied, and the results obtained were summerized as follows: The mean total protein, total immunoglobulin, IgG, IgM, and IgA concentrations in sera of 10 Korean native cows immediately after parturition were $6.8{\pm}0.4g/dl$, $24.39{\pm}3.41mg/ml$, $19.49{\pm}2.70mg/ml$, $4.56{\pm}1.14mh/ml$, and $0.35{\pm}0.08mg/ml$ respectively. And the mean total protein, total immunoglobulin, IgG, IgM, and IgA concentrations in colostrum were $15.0{\pm}1.1g/dl$, $116.13{\pm}23.07mg/ml$, $101.51{\pm}22.59mg/ml$, $9.46{\pm}1.99mg/ml$, and $5.17{\pm}1.59mg/ml$ respectively. The mean concentrations of total protein and immunoglobulins in colostrum were 2.1 times to 14.8 times higher than those in serum. The mean concentrations of total protein, total immunoglobuln, IgG, IgM, and IgA in sera from 211 Korean native calves at 2 days old were $6.7{\pm}0.9g/dl$, $35.74{\pm}9.56mg/ml$, $29.06{\pm}8.07mg/ml$, $4.91{\pm}2.99mg/ml$, and $1,9{\pm}0.99mg/ml$ respectively. Although the calves had been suckled the dam's colostrum, each of calves was considerably various in levels of serum total protein and immunoglobulins and 16.1 percent of the calves were in a state of hypoglobulinemia.

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The Effect of Dust Emissions on PM10 Concentration in East Asia (황사 배출량이 동아시아 지역 PM10 농도에 미치는 영향)

  • Choi, Dae-Ryun;Koo, Youn-Seo;Jo, Jin-Sik;Jang, Young-Kee;Lee, Jae-Bum;Park, Hyun-Ju
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.1
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    • pp.32-45
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    • 2016
  • The anthropogenic aerosols originated from the pollutant emissions in the eastern part of China and dust emitted in northwestern China in Yellow sand regions are subsequently transported via eastward wind to the Korean peninsula and then these aerosols induce high $PM_{10}$ concentrations in Korean peninsula. In order to estimate air quality considering anthropogenic and dust emissions, Comprehensive Air-quality Model with extension (CAMx) was applied to simulate $PM_{10}$ concentration. The predicted $PM_{10}$ concentrations without/with dust emissions were compared with observations at ambient air quality monitoring sites in China and Korea for 2008. The predicted $PM_{10}$ concentrations with dust emissions could depict the variation of measured $PM_{10}$ especially during Yellow sand events in Korea. The comparisons also showed that predicted $PM_{10}$ concentrations without dust emissions were under-predicted while predictions of $PM_{10}$ concentrations with dust emission were in good agreement with observations. This implied that dust emissions from desert and barren soil in southern Mongolia and northern China minimized the discrepancies in the $PM_{10}$ predictions in East Asia. The effect of dust emission on annual $PM_{10}$ concentrations in Korea Peninsula for year 2008 was $5{\sim}10{\mu}g/m^3$, which were about 20% of observed annual $PM_{10}$ concentrations.

Assessment of Airborne Bacteria and Particulate Matters Distributed in Seoul Metropolitan Subway Stations (서울시 일부 지하철역 내 분포하는 부유 세균 및 입자상 오염물질 평가)

  • Kim, Ki-Youn;Park, Jae-Beom;Kim, Chi-Nyon;Lee, Kyung-Jong
    • Journal of Environmental Health Sciences
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    • v.32 no.4 s.91
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    • pp.254-261
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    • 2006
  • In activity areas of subway workers and passengers in Seoul metropolitan subway lines 1-4, mein concentrations of airborne bacteria were relatively higher in workers' bedroom and station precinct whereas concentrations of particulate matters, $PM_{10}$ and $PM_{2.5}$, were relatively higher in platform, inside train and driver's seat as compared with other activity areas. This result indicates that little correlation between airborne bacteria and particulate matters was found, which assumed that most airborne particulate matters distributed in subway consisted of mainly inorganic dust like a metal particles. Mean concentrations of $PM_{10}$ and $PM_{2.5}$ in station precinct and platform exceeded the threshold limit value ($PM_{10}:150{\mu}g/m^3,\;PM_{2.5}:65{\mu}g/m^3$) but those in station office and ticket office were below it. The genera identified in all the activity areas of subway over 5% detection rate were Staphylococcus, Micrococcus, Bacillus and Corynebacterium, of which Staphylococcus and Micrococcus covered over 50% of total airborne bacteria and were considered as predominant genera distributed in subway.

The Plasma Concentrations and Systemic Toxicity of Lidocaine after Maximal or Supramaximal Recommended Doses of Epidural Administration (경막외 Lidocaine의 최대사용량과 혈중농도에 대한 고찰)

  • Park, Han-Suk;Chung, Chan-Jong;Chin, Young-Jhoon
    • The Korean Journal of Pain
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    • v.12 no.1
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    • pp.36-42
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    • 1999
  • Background: The current maximal recommended doses of lidocaine are 7 mg/kg with $5\;{\mu}g/ml$ of epinephrine. But in clinical practice, sometimes more doses of lidocaine are required to produce adequate regional anesthesia. Method: Twenty-two healthy women patients were divided into two groups and pretreated with valium 5 mg p.o., morphine 5 mg i.m., and midazolam 2 mg i.v. before operation. Of these, 7 mg/kg of 2% lidocaine with $5\;{\mu}g/ml$ of epinephrine were given to 11 patients epidurally. Initial 3 ml of epinephrine mixed lidocaine was given as a test dose and remaining doses were given 5 ml/30 sec with 3 min intervals. Radial arterial blood were drawn at 5, 10, 15, 20, 30, 45, 60, 90, 120 min to measure plasma lidocaine concentrations. After confirming all of the peak plasma concentrations of 7 mg/kg lidocaine were absolutely under $5\;{\mu}g/ml$, the other 11 patients were given 10 mg/kg of 2% lidocaine with $5\;{\mu}g/ml$ of epinephrine epidurally and blood samplings were taken according to the same method of 7 mg/kg group. The peak plasma concentration ($C_{max}$), time to reach to $C_{max}$ ($T_{max}$), time to reach to $T_4$, maximal sensory block level, systemic toxicity, and vital sign changes were investigated. Result: $C_{max}$ was significantly higher in 10 mg/kg group ($5.1{\pm}1.3\;{\mu}g/ml$) than 7 mg/kg group($3.3{\pm}0.5\;{\mu}g/ml$), but $T_{max}$ ($10.5{\pm}2.7$ min vs $10.9{\pm}3.1$ min) was not different. Time to reach $T_4$ was significantly shorter in 10 mg/kg group ($9.5{\pm}2.7$ min) than 7 mg/kg group ($12.7{\pm}3.2$ min) but maximal sensory block level ($T_{3.7{\pm}0.7}$ vs $T_{2.7{\pm}1.0}$) was not different. In four patients of 10 mg/kg group, peak plasma concentrations exceeded $5\;{\mu}g/ml$, but no systemic toxicities appeared. No significant vital sign changes were observed. Conclusion: The current maximal recommended doses of lidocaine, merely based on body weight are not always appropriate. Further studies are needed to determine more precise guideline of maximal doses that include various pharmacokinetic components.

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