• 제목/요약/키워드: $O_2/N_2$ separation

검색결과 209건 처리시간 0.036초

Gas-Transport Properties through Various Cations Exchanged Sulfonated Poly(ether imide) Membranes

  • Rhim, Ji-Won
    • Korean Membrane Journal
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    • 제3권1호
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    • pp.51-58
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    • 2001
  • The surface of Poly(ether imide) (PEI) membranes has been sulfonated using CIS03H. The resulting membranes were characterized through the analysis of ESCA and contact angle measurements The sulfonated PEI membranes were exposed to gases of $O_2$, $N_2$, and $CO_2$ to measure the permeation rates and ideal separation factors. In addition, the diffusivities and solubilities of individual gases were measured. The diffusivity effect is more dominant than the solubility one on gas transports.

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열분해성 고분자 도입에 따른 탄소분자체막의 기체 투과 특성 (Carbon Molecular Sieve Membranes Derived from Thermally Labile Polymer Containing Polyimide and Their Gas Separation Properties)

  • Young Moo Lee;Youn Kook Kim;Ji Min Lee;Ho Bum Park
    • 멤브레인
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    • 제13권3호
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    • pp.182-190
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    • 2003
  • Polyvinylpyrrolidone을 포함하는 폴리이미드 전구체의 열분해 공정을 통해 탄소분자체막을 제조하였으며 열분해성 고분자를 포함하는 전구체를 통해 제조된 막의 구조 및 기체 투과 특성에 대해 연구 하였다. 열분해성 고분자를 포함하는 전구체의 열적 특성을 조사한 결과 열적으로 안정한 폴리이미드의 경우 $550^{\circ}C$에서 분해되는 것을 확인할 수 있었으며 열분해성 고분자의 경우 $400^{\circ}C$에서 분해가 시작되는 것을 TCA를 통해 확인하였다 제조된 탄소분자체막의 기체 투과 특성을 조사한 결과 최종 열분해 온도가 증가됨에 따라 기체 투과도는 감소하였으며 열분해성 고분자를 포함한 전구체로부터 제조된 탄소분자체막의 경우 기체 투과가 향상됨을 알 수 있었다. 열분해성 고분자를 함유하는 전구체로부터 $550^{\circ}C$에서 열분해를 통해 제조된 탄소분자체막의 경우 $O_2$ 투과도 808 Barrer $[10^{-10}cm^3 (STP)cm/cm^2scmHg]$$O_2$/$N_2$선택도 7을 나타내었다.

Resolution of Salbutamol Enantiomers in Human Urine by Reversed-Phase High Performance Liquid Chromatography after Derivatization with 2,3,4,6-Tetra-O-acetyl-${\beta}$-D-glucopyranosyl Isothiocyanate

  • Kim, Kyeong-Ho;Kim, Tae-Kyun
    • Archives of Pharmacal Research
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    • 제21권2호
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    • pp.217-222
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    • 1998
  • A stereospecific HPLC method has been developed for the resolution of the enantiomers of salbutamol in human urine. After solid-phase extraction and derivatization with 2,3,4,6-tetra-O-acetyl-$\beta$-D-glucopyranosyl isothiocyanate, the diastereomeric derivatives were resolved (Rs=1.83) on $5{\mu}m$ octadecylsilan column using 35% acetonitrile in 0.05M ammonium acetate buffer (pH=6) as a mobile phase with electrochemical detection. The diastereomeric derivatives were formed within 30 min. The detection limit of each enantiomer was 20 ng/ml (S/N=3).

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RI 폐기물 내 방사성요오드 분석을 위한 분리 및 회수 (Separation and Recovery for the Analysis of Radioiodine in RI Wastes)

  • 강상훈;한선호;이흥래;지광용;이인구
    • 방사성폐기물학회지
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    • 제5권4호
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    • pp.267-272
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    • 2007
  • RI 폐기물 내에 있는 낮은 방사능의 요오드의 함량을 결정하기 위해 산분해법과 BPGe 감마 선분광계를 이용하는 방법이 개발되었다. 분석에 앞서 모의시료인 제염지 내에 $^{131}I$이 일정량 첨가되었으며, 100 mL의 0.4 N $K_2Cr_2O_7$와 100 mL의 9 M $H_2SO_4$, 10 mL의 30% $H_3PO_3$, 1 mL의 $H_2O_2$를 넣고 산분해과정을 거치면서 증류된 용액을 응축하여 포집하였다. $CCl_4$의 용매추출에 의한 화학 분리과정을 거친 후 $AgNO_3$를 첨가해서 얻은 AgI 침전물을 여과하고 건조하여 측정하였다. 산분해 과정, 화학 분리과정, 여과 및 침전과정 등 세 단계로 나눠 회수율을 측정한 결과, 각각 94% 이상의 회수율을 나타냈으며, 본 연구의 측정조건에서 최소검출방사능은 0.6 Bq/g이었다.

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A Potent Anti-Complementary Acylated Sterol Glucoside from Orostachys japonicus

  • Yoon, Na-Young;Min, Byung-Sun;Lee, Hyeong-Kyu;Park, Jong-Cheol;Choi, Jae-Sue
    • Archives of Pharmacal Research
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    • 제28권8호
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    • pp.892-896
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    • 2005
  • In order to isolate substances that inhibit the hemolytic activity of human serum against eryth-rocytes, we have evaluated whole plants of the Orostachys japonicus species with regard to its anti-complement activity, and have identified its active principles following activity-guided isolation. A methanol extract of the O. japonicus, as well as its n-hexane soluble fraction, exhibited significant anti-complement activity on the complement system, which was expressed as total hemolytic activity. A bioassay-guided chromatographic separation of the constituents resulted in the isolation of three known compounds 1-3 from the active n-hexane fraction. The structure of these compounds were analyzed, and they were identified as hydroxyhopanone (1), $\beta-sitosteryl-3-O-\beta-D-glucopyranosyl-6'-O-palmitate$ (2), and $\beta-sitosteryl-3-O-\beta-D-glucopyranoside$ (3), respectively. Of these compounds, compound 2 exhibited potent anti-complement activity $(IC_{50}=1.0\pm0.1{\mu}M)$ on the classical pathway of the complement, as compared to tiliroside $(IC_{50}=76.5\pm1.1{\mu}M)$, which was used as a positive control. However, compounds 1 and 3 exhibited no activity in this system.

Liquid Membrane Permeation of Nitrogen Heterocyclic Compounds Contained in Model Coal Tar Fraction

  • Kim, Su-Jin;Kang, Ho-Cheol;Kim, Yong-Shik;Jeong, Hwa-Jin
    • Bulletin of the Korean Chemical Society
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    • 제31권5호
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    • pp.1143-1148
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    • 2010
  • We investigated the separation of nitrogen heterocyclic compound (NHC) contained in a model coal tar fraction comprising four kinds of NHC [indole (In), quinoline (Q), iso-quinoline (iQ), quinaldine (Qu)], three kinds of bicyclic aromatic compound (BAC) [1-methylnaphthalene (1MN), 2-methylnaphthalene (2MN), dimethylnaphthalene (DMN) mixture with ten structural isomers (DMNs; regarded as one component)], biphenyl (Bp) and phenyl ether (Pe) by liquid membrane permeation (LMP). A batch-stirred tank was used as the permeation unit. An aqueous solution of saponin and n-hexane were used as the liquid membrane and the outer oil phase, respectively. Yield and selectivity of individual NHC was much larger than that of BAC, Bp and Pe. Increasing the initial mass fraction of the saponin to the membrane solution ($C_{sap,0}$) and the initial volume fraction of O/W emulsion to total liquid in a stirred tank (${\phi}_{OW,0}$) resulted in deteriorating the yield of individual NHC, but increasing the stirring speed (N) resulted in improving the yield of each NHC. With increasing $C_{sap,0}$, the selectivity of each NHC based on DMNs increased. Increasing ${\phi}_{OW,0}$ and N resulted in decreasing the selectivity of individual NHC based on DMNs. At an experimental condition fixed, the sequence of the yield and selectivity in reference to DMNs for each NHC was Q > Qu = iQ > In. Furthermore, we compared LPM method with methanol extraction method in view of the separation efficiency (yield, selectivity) of NHC.

오존($O_3$)을 이용한 악취물질 처리시설의 적용사례 연구 (A Study on Installation of Treatment Equipment of Malodorous Substances using the $O_3$)

  • 김석택
    • 환경위생공학
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    • 제15권3호
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    • pp.70-74
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    • 2000
  • The technology of malodorous substances treatment was classified physical separation and chemical destruction. This study was carried out to investigate the characteristics of malodorous substances treatment with the change of operating conditions from the ozone generator. The major results of this study were as follows : Removal efficiency by additive ozone rate was measured $NH_3$:95%(ozone additive rate : 2), $H_2S$ : 97%(ozone additive rate:4), $CH_3SH$ : 96%(ozone additive rate : 3), $(CH_3)_2S_2$ : 97%(ozone additive rate:5), $(CH_3)_3N$ : 95%(ozone additive rate : 1), $CH_3CHO$ : 95%(ozone additive rate : 2), $C_6H_5CHCH_2$ : 95%(ozone additive rate : 2).

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Biguanide-Functionalized Fe3O4/SiO2 Magnetic Nanoparticles: An Efficient Heterogeneous Organosuperbase Catalyst for Various Organic Transformations in Aqueous Media

  • Alizadeh, Abdolhamid;Khodaei, Mohammad M.;Beygzadeh, Mojtaba;Kordestani, Davood;Feyzi, Mostafa
    • Bulletin of the Korean Chemical Society
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    • 제33권8호
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    • pp.2546-2552
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    • 2012
  • A novel biguanide-functionalized $Fe_3O_4/SiO_2$ magnetite nanoparticle with a core-shell structure was developed for utilization as a heterogeneous organosuperbase in chemical transformations. The structural, surface, and magnetic characteristics of the nanosized catalyst were investigated by various techniques such as transmission electron microscopy (TEM), powder X-ray diffraction (XRD), vibrating sample magnetometry (VSM), elemental analyzer (EA), thermogravimetric analysis (TGA), $N_2$ adsorption-desorption (BET and BJH) and FT-IR. The biguanide-functionalized $Fe_3O_4/SiO_2$ nanoparticles showed a superpara-magnetic property with a saturation magnetization value of 46.7 emu/g, indicating great potential for application in magnetically separation technologies. In application point of view, the prepared catalyst was found to act as an efficient recoverable nanocatalyst in nitroaldol and domino Knoevenagel condensation/Michael addition/cyclization reactions in aqueous media under mild condition. Additionally, the catalyst was reused six times without significant degradation in catalytic activity and performance.

Expanding the Limits of Membrane-Based Gas Separation Materials

  • Koros, William J.
    • 한국막학회:학술대회논문집
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    • 한국막학회 1995년도 제3회 심포지움 (분리막 연구의 최신동향)
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    • pp.21-22
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    • 1995
  • Gas separation science and technology is among the most rapidly growing areas involving membrane-based processes. Nitrogen enrichment of air, hydrogen recovery from a broad array of stream types, and removal of acid gases from natural gases are typical of the applications in this field. Great progress has been made in the discovery of guidelines optimization of polymer structures with simultaneously high permeabilities and selectivities for these important gas pairs. The development of thin-skinned asymmetric hollow fibers have also provided structures with extremely high permeation fluxes. Especially in the case of O$_{2}$/N$_{2}$ separations, the rate of improvements in new polymeric materials for gas separations appears to be slowing to a halt. Evidence will be presented, however, that the practical tradeoff between membrane permeability and selectivity has not been reached.

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Hydrophillic Interaction Chromatography-tandem Mass Spectrometry Method for Identification and Quantitation of 5-MeO-DIPT and its Metabolites in Rat Urine

  • Kim, Yoon;Kim, Un-Yong;In, Moon-Kyo;Lee, Jae-Ick;Kwon, Oh-Seung;Yoo, Hye-Hyun
    • Bulletin of the Korean Chemical Society
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    • 제32권4호
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    • pp.1158-1164
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    • 2011
  • 5-Methoxy-N,N-diisopropyltryptamine (5-MeO-DIPT), a psychoactive tryptamine derivative, is a hallucinogenic drug of abuse. In this study, 5-OH-DIPT and its metabolites were identified and the quantitative method was developed and validated by using hydrophilic interaction chromatography-tandem mass spectrometry (HILICMS/MS). Chromatographic separation was achieved on an Atlantis HILIC silica column ($5{\mu}m$, $100{\times}2.1\;mm$). The metabolites of 5-MeO-DIPT in rat urine were characterized via Q1 scanning and product ion scanning. As a consequence, 5-MeO-IPT, 5-OH-DIPT, 6-OH-5-MeO-DIPT and their glucuronide conjugates were detected and identified as the metabolites of 5-MeO-DIPT. Subsequently, a quantitative method for 5-MeO-DIPT and its major metabolites, 5-MeO-IPT and 5-OH-DIPT, was developed in multiple reactions monitoring (MRM) mode. The calibration curves for all analytes evidenced good linearity over the concentration range of 1-1000 ng/mL with linear correlation co-efficients ($r^2$) in excess of 0.99. The intra- and inter-day accuracy and precision were 92.2-110.2% and 1.5-9.9%, respectively.