• Title/Summary/Keyword: $N_2O$ emission factor

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Developing N2O Emission Factor in Red Pepper Fields to Quantify N2O Emission of Agricultural Field

  • Kim, Gun-Yeob;Park, Woo-Kyun;Lee, Jong-Sik;Jeong, Hyun-Cheol;Lee, Sun-Il;Choi, Eun-Jung;Kim, Pil-Joo;Seo, Young-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.47 no.6
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    • pp.598-603
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    • 2014
  • The level of nitrous oxide ($N_2O$), a long-lived greenhouse gas, in atmosphere has increased mainly due to anthropogenic sources, especially application of nitrogen fertilizers. Quantifying $N_2O$ emission in the agricultural field is essential to develop National inventories of greenhouse gases (GHGs) emission. The objective of this study was to develop emission factor to estimate direct $N_2O$ emission from agricultural field by measuring $N_2O$ emissions in the red pepper cultivating field from 2010 to 2012. Emission factor of $N_2O$ calculated from accumulated $N_2O$ emission, nitrogen fertilization rate, and background $N_2O$ emission was $0.0086{\pm}0.00043kg$ $N_2O-N\;kg^{-1}$ N resulted from three year experiment of the research sites. More extensive studies need to be conducted to develop $N_2O$ emission factors for other upland crops in the various regions of Korea because $N_2O$ emission is influenced by many factors including climate characteristics, soil properties, and agricultural practices.

The Development of N2O Emission Factor at Killn Type Pyrolysis Melting Facility (외열킬른형 열분해용융시설의 N2O 배출계수 개발)

  • Yun, Hyun-Ki;Lee, Dae Kyeom;Cho, Changsang;Kang, Seongmin;Yoon, Young joong;Jeon, Youngjae;Jeon, Eui Chan
    • Journal of Climate Change Research
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    • v.8 no.3
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    • pp.231-237
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    • 2017
  • In this study, the $N_2O$ emission factor of the facility was developed by measuring the kiln type pyrolysis melting facility. This used PAS (Photoacoustic Spectroscopy) method and measured the $N_2O$ emission concentration. From March 2016 to April 2016, it was measured over a total of two times and $N_2O$ concentrations were measured continuously for 24 hours using a 24 hour continuous measuring instrument (LSE-4405). The measured $N_2O$ emission concentration of the pyrolysis melting facility was 0.263 ppm on average and the emission concentration distribution in the range of 0.013~0.733 ppm was obtained. Therefore, the $N_2O$ emission factor of the kiln-type pyrolysis melting facility was estimated to be $0.829gN_2O/ton$-Waste. As a result of comparing the $N_2O$ emission factor of the thermal kiln type pyrolysis melting facility and the previous study, previous studies were about 18 times higher. It is estimated that this is due to the difference of furnace temperature, oxygen concentration and denitrification facilities. It is considered that the study of the emission factor of pyrolysis melting facility is an important factor in improving the credibility of greenhouse gas inventory in waste incineration sector.

Assessment of N2O Emission Factor of Autumn Chinese Cabbage Fields at Three Different Geographical Location in South Korea

  • Kim, Gun-Yeob;Park, Woo-Kyun;Jeong, Hyun-Cheol;Lee, Sun-il;Kim, Pil-Joo;Seo, Young-Ho;Na, Un-sung
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.3
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    • pp.163-169
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    • 2015
  • The level of nitrous oxide ($N_2O$), a long-lived greenhouse gas, in atmosphere has increased mainly due to anthropogenic sources, especially application of nitrogen fertilizers. Quantifying $N_2O$ emission in the agricultural field is essential to develop national inventories of greenhouse gases (GHGs) emission. The objective of this study was to develop an emission factor to estimate the direct $N_2O$ emission from an agricultural field cultivated with the Chinese cabbage during autumn season in 2010-2012. Emission factor of $N_2O$ calculated over three years experiment using accumulated $N_2O$ emission, nitrogen fertilization rate, and background $N_2O$ emission was $0.0058{\pm}0.00254kg\;N_2O-N\;kg^{-1}\;N$. More extensive studies need to be conducted to develop $N_2O$ emission factors for other upland crops in the various regions of Korea because $N_2O$ emission is influenced by many factors including climate characteristics, soil properties, and agricultural practices as well as crop species.

Nitrous Oxide Emissions from Red Pepper, Chinese Cabbage, and Potato Fields in Gangwon-do, Korea

  • Seo, Youngho;Kim, Gunyeob;Park, Kijin;Kim, Kyunghi;Jung, Yeong-Sang
    • Korean Journal of Soil Science and Fertilizer
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    • v.46 no.6
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    • pp.463-468
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    • 2013
  • The level of nitrous oxide ($N_2O$), a long-lived greenhouse gas, in atmosphere has increased mainly due to anthropogenic source, especially application of nitrogen fertilizers. Quantifying $N_2O$ emission from agricultural field is essential to develop national inventories of greenhouse gases (GHGs) emission. The objective of the study was to develop emission factor to estimate direct $N_2O$ emission from agricultural field in Gangwon-do, Korea by measuring $N_2O$ emissions from potato (Solanum tuberosum), red pepper (Capsicum annum L.), and Chinese cabbage (Brassica campestris L.) cultivation lands from 2009 to 2012. Accumulated $N_2O$ emission was $1.48{\pm}0.25kg$ $N_2O-N\;ha^{-1}$ for red pepper, $1.27{\pm}0.27kg$ $N_2O-N\;ha^{-1}$ for potato, $1.49{\pm}0.06kg$ $N_2O-N\;ha^{-1}$ for Chinese cabbage cultivated in spring, and $1.14{\pm}0.22kg$ $N_2O-N\;ha^{-1}$ for fall Chinese cabbage. Emission factor of $N_2O$ calculated from accumulated $N_2O$ emission, nitrogen fertilization rate, and background $N_2O$ emission was $0.0051{\pm}0.0016kg$ $N_2O-N\;ha^{-1}$ N for cropland in Gangwon province. More extensive study is deserved to be conducted to develop $N_2O$ emission factor for upland crops in Korea through examining the emission factors from various regions and crops because $N_2O$ emission is influenced by many factors including climate characteristics, soil properties, and agricultural practices.

Assessment of Integrated N2O Emission Factor for Korea Upland Soils Cultivated with Red Pepper, Soy Bean, Spring Cabbage, Autumn Cabbage and Potato

  • Kim, Gun-Yeob;Na, Un-Sung;Lee, Sun-Il;Jeong, Hyun-Cheol;Kim, Pil-Joo;Lee, Jong-Eun;Seo, Young-Ho;Lee, Jong-Sik;Choi, Eun-Jung;Suh, Sang-Uk
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.6
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    • pp.720-730
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    • 2016
  • Greenhouse-gas emission factors are widely used to estimate emissions arising from a defined unit of a specific activity. Such estimates are used both for international reporting to the United Nations Framework Convention on Climate Change (UNFCCC) and for myriad national and sub-national reporting purposes (for example, European Union Emissions Trading Scheme; EU ETS). As with the other so-called 'Kyoto protocol GHGs', the Intergovernmental Panel on Climate Change (IPCC) provides a methodology for national and sub-national estimation of $N_2O$ emissions, based on the sector from which the emissions arise. The objective of this study was to develop a integrated emission factor to estimate the direct $N_2O$ emission from an agricultural field cultivated with the red pepper, soy bean, spring cabbage, autumn cabbage and potato in 2010~2012. Emission factor of $N_2O$ calculated using accumulated $N_2O$ emission, N fertilization rate, and background $N_2O$ emission over three year experiment was $0.00596{\pm}0.001337kg$ $N_2O-N(N\;kg)^{-1}$. More extensive studies need to be conducted to develop $N_2O$ emission factors for other upland crops in the various regions of Korea because $N_2O$ emission is influenced by many factors including climate characteristics, soil properties, and agricultural practices.

The Development of N2O Emission Factor at Municipal Solid Waste Incinerator (도시고형폐기물 소각시설의 N2O 배출계수 개발)

  • Ko, Jae Churl;Choi, Sang Hyun
    • Clean Technology
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    • v.25 no.1
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    • pp.40-45
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    • 2019
  • In this study, nitrous oxide ($N_2O$) emission concentration was measured 3 times continuously for 24 hours from August 27, 2018 to October 22, 2018 and non-dispersive infrared (NDIR) spectrometer was used to calculate $N_2O$ concentration of exhaust gas from municipal solid waste (MSW) incinerator. As a result of $N_2O$ emission characteristics, it is estimated that $N_2O$ emission concentration is due to the difference of furnace temperature, oxygen concentration rather than the chemical component of waste. The measured $N_2O$ emission concentration of MSW incinerator was obtained in the range of 53.6 ~ 59.5 ppm and the total average concentration was measured 55.6 ppm. Therefore, the amount of $N_2O$ emissions calculated from the $N_2O$ concentration was $98.05kg\;day^{-1}$ on average and the amount of $N_2O$ distribution in the range of $90.41{\sim}108.44kg\;day^{-1}$ was obtained. As a result, the $N_2O$ emission factor of the MSW incinerator was estimated to be $1,066.13g_{N_2O}\;ton_{waste^{-1}}$. The estimated $N_2O$ emission factor of the MSW incinerator was 20 times higher than calculated emission factor used in the Tier 2 method. Consequently, it is considered that the method of calculating the amount of $N_2O$ emission in the MSW incineration facilities using waste type and incineration amount needs to be supplemented to ensure accuracy.

A Revised Estimate of N2O Emission Factor for Spring Chinese cabbage fields in Korea (국내 봄배추 재배지의 아산화질소 배출계수 개발에 관한 연구)

  • Kim, Gun-Yeob;Park, Woo-Kyun;Jeong, Hyun-Cheol;Lee, Sun-il;Choi, Eun-Jung;Kim, Pil-Joo;Seo, Young-Ho;Na, Un-sung
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.17 no.4
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    • pp.326-332
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    • 2015
  • Greenhouse-gas emission factors are widely used to estimate emissions arising from a defined unit of a specific activity. Such estimates are used both for international reporting to the United Nations Framework Convention on Climate Change (UNFCCC) and for a myriad of national and subnational reporting purposes. The Intergovernmental Panel on Climate Change (IPCC) provides a methodology for national and sub-national estimation of known greenhouse gas emissions including $N_2O$ for each sector from which the emissions arise. The objective of this study was to develop an emission factor to estimate the direct $N_2O$ emission from an agricultural field cultivated with Chinese cabbage during spring season in 2010-2012. An estimated emission factor of $N_2O$ calculated over three years from field experiment accounting for cumulative $N_2O$ emission, nitrogen fertilization rate, and background $N_2O$ emission was $0.0056{\pm}0.00254$ (95% CI) Kg $N_2O-N/kg$ N. More extensive studies are needed to develop $N_2O$ emission factors for other upland crops in various regions of Korea because $N_2O$ emission is influenced by many factors including climate characteristics, soil properties agricultural practices and crop species.

Evaluation of indirect N2O Emission from Nitrogen Leaching in the Ground-water in Korea (우리나라 농경지에서 질소의 수계유출에 의한 아산화질소 간접배출량 평가)

  • Kim, Gun-Yeob;Jeong, Hyun-Cheol;Kim, Min-Kyeong;Roh, Kee-An;Lee, Deog-Bae;Kang, Kee-Kyung
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.6
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    • pp.1232-1238
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    • 2011
  • This experiment was conducted to measure concentration of dissolved $N_2O$ in ground-water of 59 wells and to make emission factor for assessment of indirect $N_2O$ emission at agricultural sector in agricultural areas of Gyeongnam province from 2007 to 2010. Concentrations of dissolved $N_2O$ in ground-water of 59 wells were ranged trace to $196.6{\mu}g-N\;L^{-1}$. $N_2O$ concentrations were positively related with $NO_3$-N suggesting that denitrification was the principal reason of $N_2O$ production and $NO_3$-N concentration was the best predictor of indirect $N_2O$ emission. The ratio of dissolved $N_2O$-N to $NO_3$-N in ground-water was very important to make emission factor for assessment of indirect $N_2O$ emission at agricultural sector. The mean ratio of $N_2O$-N to $NO_3$-N was 0.0035. It was greatly lower than 0.015, the default value of currently using in the Intergovernmental Panel on Climate Change (IPCC) methodology for assessing indirect $N_2O$ emission in agro-ecosystems (IPCC, 1996). It means that the IPCC's present nitrogen indirect emission factor ($EF_{5-g}$, 0.015) and indirect $N_2O$ emission estimated with IPCC's emission factor are too high to use adopt in Korea. So we recommend 0.0034 as national specific emission factor ($EF_{5-g}$) for assessment of indirect $N_2O$ emission at agricultural sector. Using the estimated value of 0.0034 as the emission factor ($EF_{5-g}$) revised the indirect $N_2O$ emission from agricultural sector in Korea decreased from 1,801,576 ton ($CO_2$-eq) to 964,645 ton ($CO_2$-eq) in 2008. The results of this study suggest that the indirect Emission of nitrous oxide from upland recommend 0.0034 as national specific emission factor ($EF_{5-g}$) for assessment of indirect $N_2O$ emission at agricultural sector.

Development of Non-CO2 Greenhouse Gas Emission Factors for the B-C Oil Fired Boiler Power Plants (B-C유 화력발전소 보일러의 Non-CO2 온실가스 배출계수 개발 연구)

  • Lee, See-Hyung;Kim, Jin-Su;Kim, Ok-Hun;Lee, Jeong-Woo;Lee, Seong-Ho;Jeon, Eui-Chan
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.1
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    • pp.41-49
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    • 2011
  • The power plants are one of the GHG major source among the sectors of fossil fuel combustion, therefore information of its emission factors is very essential to the establishing control strategies for the greenhouse gas emissions. The $CH_4$ and $N_2O$ concentration from power plants were measured using GC-FID and GC-ECD. The results showed that $CH_4$ emission factor was 0.33 kg/TJ and $N_2O$ emission factor was 0.88 kg/TJ. The $CH_4$ and $N_2O$ emission factors developed in this study were compared with those for IPCC default value and other countries emission factors. The results showed that $CH_4$ emission factor was lower than IPCC default value and Finnish emission factor, but higher than Japanese emission factor. $N_2O$ emission factor was higher Japanese emission factor and IPCC default emission factor however lower than Finnish emission factor. More research is needed on our own emission factors of various energy-consuming facilities in order to stand on a higher position in international negotiations regarding the treaties on climate changes.

Comparison of N2O Emissions by Greenhouse Gas Emission Estimation Method (온실가스 배출량 산정 방법에 따른 N2O 배출량 비교)

  • Kang, Soyoung;Cho, Chang-Sang;Kim, Seungjin;Kang, Seongmin;Yoon, Hyeongi;Jeon, Eui-Chan
    • Journal of Climate Change Research
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    • v.6 no.3
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    • pp.175-184
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    • 2015
  • In this study GC and PAS were used to calculate $N_2O$ concentration of exhaust gas from Wood Chip combustion system. Fuel supplied to the incinerator was collected and analyzed and then the analysis result was used to calculate $N_2O$ emissions. Tier 3 and Tier 4 Method were used to calculate the $N_2O$ emissions. Plant's Specific emission factor of $N_2O$ by Tier 3 Method was 0.35 kg/TJ, while default emission factor of Wood?Wood Waste proposed by 2006 IPCC G/L was 4 kg/TJ. So the $N_2O$ emission factor of this study was 3.65 kg/TJ lower compared to the IPCC G/L. The total emissions calculated by Plant's specific emission factor was 4.22 kg during the measuring period, but by Tier 4 Method it was 7.88 kg. This difference in emissions was caused by the difference of continuous measuring and intermittent sampling. It would be necessary to apply continuous measuring to calculate emissions of $Non-CO_2$ gas whose the density distribution is relatively high. However currently, according to the target management guideline of greenhouse gas and energy, the continuous measuring method to calculate greenhouse gas emission is applied only to $CO_2$. Therefore for reliable greenhouse gas emission calculation it would be necessary to apply continuous measuring to calculate $Non-CO_2$ gas emission.