• Title/Summary/Keyword: $N_2$N

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The Roles of Hydrogen Bonds in 2,9-(N,N-Dimethylethylenediaminomethyl)-1,10-phenanthroline Molecule as a New Ligand Compound of Artificial DNase (인공 DNase의 리간드 화합물로써 2,9-(N,N-Dimethylethylenediaminomethyl)-1,10-phenanthroline 분자내 수소결합들의 역할)

  • Sung, Nack-Do;Park, Kyeng-Yong
    • Applied Biological Chemistry
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    • v.48 no.4
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    • pp.326-330
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    • 2005
  • In the catalytic hydrolysis of 2',3'-cAMP by the Cu(II) complexes of 2,9-(N,N-dimethylethylenediamino)-1,10-phenanthroline (A) and 2,9-(N,N-dimethylethylenediaminomethyl)-1,10-phenanthroline (B) that are designed as a new ligand molecule of artificial DNase, due to the four intramolecular H-bonds forming between amino groups of ligand molecule and phosphoryl group of 2',3'-cAMP. It is anticipated that Cu(II) complexes of (A) and (B) are able to promote a rate that is as much as seventy thousand times faster than the catalytic hydrolysis rate of 2',3'-cAMP by Cu(II) complexes of 2,9-dimethyl-o-phenanthroline.

Development and Luminescent Characteristics of $CaSiN_2$ Based Phosphors ($CaSiN_2$를 모체로 하는 형광체의 개발 및 발광 특성)

  • Lee, Soon-Seok;Lim, Sung-Kyoo
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.36D no.10
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    • pp.31-36
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    • 1999
  • The $CaSiN_2:Eu$ and $CaSiN_2:Tb$ phosphors were synthesized and analyzed to develop new nitride compound phosphors. $Ca_3N_2$, $Si_3N_4$ and $EuF_3$(or $TbF_3$) powders were mixed, cold-pressed, and sintered to synthesize $CaSiN_2:Eu$ and $CaSiN_2:Tb$ phosphors. Photoluminescence(PL) and electroluminescence(EL) characteristics of the synthesized phosphors were measured and found to be similar to general emission spectra of 뗘 and Tb ion, respecticely. Threshold voltage($V_{th)$) and luminance of the $CaSiN_2:Eu$ TFEL device fabricated by sputtering were 90 V and 1.62 $cd/m^2$ at 280 V, respectively. The charge-voltage(Q-V) and transferred charge-phosphor field($Q_t-F_p$) characteristics of the TFEL devices were also measured.

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Breakdown Characteristics of Ar/$N_2$ and Kr/$N_2$ Gas Mixtures with Pressure Variation (압력변화에 따른 Ar/$N_2$및 Kr/$N_2$ 혼합가스의 절연파괴 특성)

  • 이상우;이동인;이광식;김인식;김이국;배영호
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2001.11a
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    • pp.187-191
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    • 2001
  • In this paper, the ac breakdown characteristics of Ar/$N_2$and Kr/$N_2$gas mixtures with gas pressure range of 58.8~137.3[kPa] under uniform and non-uniform fields were investigated. Summarizing the experimental results, the breakdown voltages of Ar/$N_2$ gas mixtures were decreased with decreasing the mixture ratio of pure $N_2$gas. In case of Ar(85%)/$N_2$(15%) and Ar(70%)/$N_2$(30%) gas mixtures comparing to the pure Ar gas, the breakdown voltages under uniform field were increased about 1.8 and 2.2 times, and under non-uniform field were increased about 1.1 and 1.3 times at the pressure of 101.3[kPa]. Also, in case of Kr(85%)/$N_2$(15%) and Kr(70%)/$N_2$(30%) gas mixtures comparing to the pure Kr gas, the breakdown voltages under uniform field were increased about 1.7 and 2.0 times, and under non-uniform field were increased about 1.0 and 1.2 times.

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Modified Baby-Step Giant-Step Algorithm for Discrete Logarithm (최단 보폭-최장 보폭 이산대수 알고리즘의 변형)

  • Lee, Sang-Un
    • Journal of the Korea Society of Computer and Information
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    • v.18 no.8
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    • pp.87-93
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    • 2013
  • A baby-step giant-step algorithm divides n by n blocks that possess $m={\lceil}\sqrt{n}{\rceil}$ elements, and subsequently computes and stores $a^x$ (mod n) for m elements in the 1st block. It then calculates mod n for m blocks and identifies each of them with those in the 1st block of an identical elemental value. This paper firstly proposes a modified baby-step giant-step algorithm that divides ${\lceil}m/2{\rceil}$ blocks with m elements applying $a^{{\phi}(n)/2}{\equiv}1(mod\;n)$ and $a^x(mod\;n){\equiv}a^{{\phi}(n)+x}$ (mod n) principles. This results in a 50% decrease in the process of the giant-step. It then suggests a reverse baby-step giant step algorithm that performs and saves ${\lceil}m/2{\rceil}$ blocks firstly and computes $a^x$ (mod n) for m elements. The proposed algorithm is found to successfully halve the memory and search time of the baby-step giant step algorithm.

ON A PERMUTABLITY PROBLEM FOR GROUPS

  • TAERI BIJAN
    • Journal of applied mathematics & informatics
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    • v.20 no.1_2
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    • pp.75-96
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    • 2006
  • Let m, n be positive integers. We denote by R(m,n) (respectively P(m,n)) the class of all groups G such that, for every n subsets $X_1,X_2\ldots,X_n$, of size m of G there exits a non-identity permutation $\sigma$ such that $X_1X_2{\cdots}X_n{\cap}X_{\sigma(1)}X_{/sigma(2)}{\cdots}X_{/sigma(n)}\neq\phi$ (respectively $X_1X_2{\cdots}X_n=X_{/sigma(1)}X_{\sigma(2)}{\cdots}X_{\sigma(n)}$). Let G be a non-abelian group. In this paper we prove that (i) $G{\in}P$(2,3) if and only if G isomorphic to $S_3$, where $S_n$ is the symmetric group on n letters. (ii) $G{\in}R$(2, 2) if and only if ${\mid}G{\mid}\geq8$. (iii) If G is finite, then $G{\in}R$(3, 2) if and only if ${\mid}G{\mid}\geq14$ or G is isomorphic to one of the following: SmallGroup(16, i), $i\in$ {3, 4, 6, 11, 12, 13}, SmallGroup(32, 49), SmallGroup(32, 50), where SmallGroup(m, n) is the nth group of order m in the GAP [13] library.

Effects of Deposition Parameters on TiN Film by Plasma Assisted Chemical Vapor Deposition(II) -Influence of TiCl4, N2 inlet Fraction on the TiN Deposition- (플라즈마 화학증착법(PACVD)에 의한 TiN증착시 증착변수가 미치는 영향(II) -TiCl4, N2의 입력분율을 중심으로-)

  • Rhee, B.H.;Shin, Y.S.;Kim, M.I.
    • Journal of the Korean Society for Heat Treatment
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    • v.2 no.4
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    • pp.11-18
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    • 1989
  • To investigate the influence of $TiCl_4$, $N_2$ inlet fraction on the TiN layer, TiN film was deposited onto the STC3 and STD11 steel from gas mixtures of $TiCl_4/N_2/H_2$ by the radio frequency plasma assisted chemical vapor deposition. The films were deposited at various $TiCl_4$, $N_2$ inlet fractions. The results showed that the film thickness was increased with $TiCl_4$ inlet fraction. However, while the thickness was increased with $N_4$ inlet fraction under 0.4 the thickness was decreased with increasing $N_2$ inlet fraction over 0.4. The density of deposited films was varied as $TiCl_4$, $N_2$ inlet fraction and its maximum value was about $5.6g/cm^3$. The contents of chlorine were increased with increasing $TiCl_4$ inlet fraction and nearly constant with increasing $N_2$ inlet fraction.

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INJECTIVE AND PROJECTIVE PROPERTIES OF REPRESENTATIONS OF QUIVERS WITH n EDGES

  • Park, Sangwon
    • Korean Journal of Mathematics
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    • v.16 no.3
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    • pp.323-334
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    • 2008
  • We define injective and projective representations of quivers with two vertices with n arrows. In the representation of quivers we denote n edges between two vertices as ${\Rightarrow}$ and n maps as $f_1{\sim}f_n$, and $E{\oplus}E{\oplus}{\cdots}{\oplus}E$ (n times) as ${\oplus}_nE$. We show that if E is an injective left R-module, then $${\oplus}_nE{\Longrightarrow[50]^{p_1{\sim}p_n}}E$$ is an injective representation of $Q={\bullet}{\Rightarrow}{\bullet}$ where $p_i(a_1,a_2,{\cdots},a_n)=a_i,\;i{\in}\{1,2,{\cdots},n\}$. Dually we show that if $M_1{\Longrightarrow[50]^{f_1{\sim}f_n}}M_2$ is an injective representation of a quiver $Q={\bullet}{\Rightarrow}{\bullet}$ then $M_1$ and $M_2$ are injective left R-modules. We also show that if P is a projective left R-module, then $$P\Longrightarrow[50]^{i_1{\sim}i_n}{\oplus}_nP$$ is a projective representation of $Q={\bullet}{\Rightarrow}{\bullet}$ where $i_k$ is the kth injection. And if $M_1\Longrightarrow[50]^{f_1{\sim}f_n}M_2$ is an projective representation of a quiver $Q={\bullet}{\Rightarrow}{\bullet}$ then $M_1$ and $M_2$ are projective left R-modules.

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A Study on the Fabrication and Structural Evaluation of AlN Thin Films

  • Han, Seung-Oh;Han, Chang-Suk
    • Journal of the Korean Society for Heat Treatment
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    • v.23 no.2
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    • pp.69-74
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    • 2010
  • AlN thin films were deposited by using a two-facing-targets type sputtering system (TFTS), and their deposition characteristics, microstructure and texture were investigated. Total gas pressure was kept constant at 0.4 Pa and the partial pressures of nitrogen, $PN_2$ (($N_2$ pressure)/($Ar+N_2$ pressure)) varied from 0 to 0.4 Pa. The texture of the film cross-sections and surface morphology were observed by field emission scanning electron microscope (FE-SEM). The crystallographic orientation of the films were analyzed by X-ray diffraction (XRD). Deposition of AlN film depends on $N_2$ partial pressure. The best preferred oriented AlN thin films can be deposited at a nitrogen partial pressure of $PN_2$ = 0.52. As-deposited AlN films show preferred orientation and columnar structure, and the grAlN size of AlN films increases with increasing sputtering current.

High Temperature Stability of Sintered Bulk CrN (CrN 소결체의 고온 안정성)

  • Choi, J.H.;Lee, D.B.
    • Journal of Surface Science and Engineering
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    • v.40 no.1
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    • pp.39-43
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    • 2007
  • The pure CrN powders oxidized to $Cr_2O_3$ noticeably above $850^{\circ}C$ in air. When these powders were sintered into bulk samples at $1500^{\circ}C$ under 40 atm of $N_2$ pressure, the CrN phase partly changed into the $Cr_2N$ phase, owing to the partial loss of nitrogen from CrN. When the bulk sample was heated at $1000-1200^{\circ}C$ for 100 hr under vacuum, the CrN phase also progressively changed into $Cr_2N$. At the same time, a relatively thin $Cr_2O_3$ layer formed on the bulk sample due to the reaction of chromium with residual oxygen in vacuum.

Wear Characteristics of Coated $Si_3N_4$-TiC Ceramic Tool (Coated $Si_3N_4$-TiC Ceramic 공구의 마모 특성)

  • 김동원;권오관;이준근;천성순
    • Tribology and Lubricants
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    • v.4 no.2
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    • pp.44-51
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    • 1988
  • Titanium carbide(TiC), Titanium nitride(TiN), and Titanium carbonnitride(Ti(C,N)) films were deposited on $Si_3N_4$-TiC composite cutting tools by chemical vapor deposition(CVD) using $TiCl_4-CH_4-H_2$, $TiCl_4-N_2-H_2$, and $TiCl_4-CH_4-N_2-H_2$ gas mixtures, respectively. The experimental results indicate that TiC coatings compared with TiN coatings on $Si_3N_4$ -TiC ceramic have an improved microstructural property, good thermal shock resistance, and good interfacial bonding. However TiN coatings compared with TiC coatings have a low friction coefficient with steel and good chemical stability. It is found by cutting test that coated insert compared with $Si_3N_4$-TiC ceramic have a superior flank and crater wear resistance. And multilayer coating compared with monolayer coating shows a improved wear resistance.