• Title/Summary/Keyword: $N_2$N

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Effect of Copper Content on the Microstructural Properties of Mo-Cu-N Films (Copper 함량에 따른 Mo-Cu-N 박막의 미세구조 변화에 대한 연구)

  • Shin, Jung-Ho;Choi, Kwang-Soo;Wang, Qi-Min;Kim, Kwang-Ho
    • Journal of the Korean institute of surface engineering
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    • v.43 no.6
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    • pp.266-271
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    • 2010
  • Ternary Mo-Cu-N films were deposited on Si wafer substrates with various copper contents by magnetron sputtering method using Mo target and Cu target in $Ar/N_2$ gaseous atmosphere. As increasing $N_2$ pressure, the microstructure of Mo-N films changed from ${\gamma}-Mo_2N$ of (111) having face-centered-cubic (FCC) structure to $\delta$-MoN of (200) having hexagonal structure. Detailed the microstructures of the Mo-Cu-N coatings were studied by X-ray diffraction, scanning electron microscopy and field emission transmission electron microscope. The results indicated that the incorporation of copper into the growing Mo-N coating led to the $Mo_2N$ and MoN crystallites were more well-distributed and refined and the copper existed in grain boundary. Ternary Mo-Cu-N films had a composite microstructure of the nanosized crystal crystalline ${\gamma}-Mo_2N$ and $\delta$-MoN surrounded by amorphous $Cu_3N$ phase.

M.O. Studies of Configuration and Conformation (Part II) Configuration and Conformation of Ketimine isomers

  • Kim, Shi-Choon;Chun, Young-Gu;Lee, Ikchoon
    • Nuclear Engineering and Technology
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    • v.9 no.1
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    • pp.39-44
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    • 1977
  • The configuratior and conformation of N-methyl-C-phenylalkyl-ketimine isomers, Ph-CR=N$CH_3$ (R=H, $CH_3$, $CH_3$CH$_2$), have been studied from extended Huckel molecular orbital calculations. The result shows that the E-configuration of the C=N double bond is favored compared with that of the Z-configuration. The most preferable conformation of the phenyl ring rotamer in N-methyl-C-phenylaldimine and N-methyl-C-phenylmethylketimine are the coplanar forms with regard to the C=N plane, but the conformation of the $CH_3$CH$_2$-rotamer, in N-methyl-C-phenylethyl-ketimine, the gauche form (dihedral angle between C=N and $CH_3$CH$_2$- plane=90$^{\circ}$) is favored.

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Unusual Acute Encephalitis Involving the Thalamus: Imaging Features

  • Sam Soo Kim;Kee-Hyun Chang;Kyung Won Kim;Moon Hee Han;Sung Ho Park;Hyun Woo Nam;Kyu Ho Choi;Woo Ho Cho
    • Korean Journal of Radiology
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    • v.2 no.2
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    • pp.68-74
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    • 2001
  • Objective: To describe the brain CT and MR imaging findings of unusual acute encephalitis involving the thalamus. Materials and Methods: We retrospectively reviewed the medical records and CT and/or MR imaging findings of six patients with acute encephalitis involving the thalamus. CT (n=6) and MR imaging (n=6) were performed during the acute and/or convalescent stage of the illness. Results: Brain CT showed brain swelling (n=2), low attenuation of both thalami (n=1) or normal findings (n=3). Initial MR imaging indicated that in all patients the thalamus was involved either bilaterally (n=5) or unilaterally (n=1). Lesions were also present in the midbrain (n=5), medial temporal lobe (n=4), pons (n=3), both hippocampi (n=3) the insular cortex (n=2), medulla (n=2), lateral temporal lobe cortex (n=1), both cingulate gyri (n=1), both basal ganglia (n=1), and the left hemispheric cortex (n=1). Conclusion: These CT or MR imaging findings of acute encephalitis of unknown etiology were similar to a combination of those of Japanese encephalitis and herpes simplex encephalitis. In order to document the specific causative agents which lead to the appearance of these imaging features, further investigation is required.

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On the Tensor Product of m-Partition Algebras

  • Kennedy, A. Joseph;Jaish, P.
    • Kyungpook Mathematical Journal
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    • v.61 no.4
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    • pp.679-710
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    • 2021
  • We study the tensor product algebra Pk(x1) ⊗ Pk(x2) ⊗ ⋯ ⊗ Pk(xm), where Pk(x) is the partition algebra defined by Jones and Martin. We discuss the centralizer of this algebra and corresponding Schur-Weyl dualities and also index the inequivalent irreducible representations of the algebra Pk(x1) ⊗ Pk(x2) ⊗ ⋯ ⊗ Pk(xm) and compute their dimensions in the semisimple case. In addition, we describe the Bratteli diagrams and branching rules. Along with that, we have also constructed the RS correspondence for the tensor product of m-partition algebras which gives the bijection between the set of tensor product of m-partition diagram of Pk(n1) ⊗ Pk(n2) ⊗ ⋯ ⊗ Pk(nm) and the pairs of m-vacillating tableaux of shape [λ] ∈ Γkm, Γkm = {[λ] = (λ1, λ2, …, λm)|λi ∈ Γk, i ∈ {1, 2, …, m}} where Γk = {λi ⊢ t|0 ≤ t ≤ k}. Also, we provide proof of the identity $(n_1n_2{\cdots}n_m)^k={\sum}_{[{\lambda}]{\in}{\Lambda}^k_{{n_1},{n_2},{\ldots},{n_m}}}$ f[λ]mk[λ] where mk[λ] is the multiplicity of the irreducible representation of $S{_{n_1}}{\times}S{_{n_2}}{\times}....{\times}S{_{n_m}}$ module indexed by ${[{\lambda}]{\in}{\Lambda}^k_{{n_1},{n_2},{\ldots},{n_m}}}$, where f[λ] is the degree of the corresponding representation indexed by ${[{\lambda}]{\in}{\Lambda}^k_{{n_1},{n_2},{\ldots},{n_m}}}$ and ${[{\lambda}]{\in}{\Lambda}^k_{{n_1},{n_2},{\ldots},{n_m}}}=\{[{\lambda}]=({\lambda}_1,{\lambda}_2,{\ldots},{\lambda}_m){\mid}{\lambda}_i{\in}{\Lambda}^k_{n_i},i{\in}\{1,2,{\ldots},m\}\}$ where ${\Lambda}^k_{n_i}=\{{\mu}=({\mu}_1,{\mu}_2,{\ldots},{\mu}_t){\vdash}n_i{\mid}n_i-{\mu}_1{\leq}k\}$.

ON CHARACTERIZATIONS OF SET-VALUED DYNAMICS

  • Chu, Hahng-Yun;Yoo, Seung Ki
    • Bulletin of the Korean Mathematical Society
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    • v.53 no.4
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    • pp.959-970
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    • 2016
  • In this paper, we generalize the stability for an n-dimensional cubic functional equation in Banach space to set-valued dynamics. Let $n{\geq}2$ be an integer. We define the n-dimensional cubic set-valued functional equation given by $$f(2{{\sum}_{i=1}^{n-1}}x_i+x_n){\oplus}f(2{{\sum}_{i=1}^{n-1}}x_i-x_n){\oplus}4{{\sum}_{i=1}^{n-1}}f(x_i)\\=16f({{\sum}_{i=1}^{n-1}}x_i){\oplus}2{{\sum}_{i=1}^{n-1}}(f(x_i+x_n){\oplus}f(x_i-x_n)).$$ We first prove that the solution of the n-dimensional cubic set-valued functional equation is actually the cubic set-valued mapping in [6]. We prove the Hyers-Ulam stability for the set-valued functional equation.

DIVISOR FUNCTIONS AND WEIERSTRASS FUNCTIONS ARISING FROM q-SERIES

  • Kim, Dae-Yeoul;Kim, Min-Soo
    • Bulletin of the Korean Mathematical Society
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    • v.49 no.4
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    • pp.693-704
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    • 2012
  • We consider Weierstrass functions and divisor functions arising from $q$-series. Using these we can obtain new identities for divisor functions. Farkas [3] provided a relation between the sums of divisors satisfying congruence conditions and the sums of numbers of divisors satisfying congruence conditions. In the proof he took logarithmic derivative to theta functions and used the heat equation. In this note, however, we obtain a similar result by differentiating further. For any $n{\geq}1$, we have $$k{\cdot}{\tau}_{2;k,l}(n)=2n{\cdot}E_{\frac{k-l}{2}}(n;k)+l{\cdot}{\tau}_{1;k,l}(n)+2k{\cdot}{\sum_{j=1}^{n-1}}E_{\frac{k-1}{2}(j;k){\tau}_{1;k,l}(n-j)$$. Finally, we shall give a table for $E_1(N;3)$, ${\sigma}(N)$, ${\tau}_{1;3,1}(N)$ and ${\tau}_{2;3,1}(N)$ ($1{\leq}N{\leq}50$) and state simulation results for them.

Preparation of N'-Substituted Anilino-N-Methyl-N-Nitorsoureas as Candidate Antitumor Agents

  • Kim, Jack-C;Kim, Yeon-Gweon;Min, Byoung-Tack;Park, Jin-Il
    • Archives of Pharmacal Research
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    • v.17 no.6
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    • pp.420-423
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    • 1994
  • Various N'-substituted anilino-N-methyl-N'-nitrosoureas(2a-n) were easily prepared from the reaction of substituted phenylhydraines $(3, 4-CH_3, {\;} 3-, {\;} 4-OCH_3, {\;} 3-, {\;} 4-F, {\;} 3, {\;} 4-Cl, {\;} 4-Br, {\;} 2-, {\;} 3-, {\;} 4-NO_2, 4-(NO_2)_2)$ with methyl isocyanate, followed by the nitrosation with 99% HCOOH and dry sodium lnitrite powder. Surprisingly, of these series of analogus, the anilino-nitrocosureas substituted with eletron-withdrawing nitro groups (2k-a) showed significantly low $ED_{30}$ values of $1.4-3.4 {\mu}g/ml.$ In addition, none of these copounds subtituted with electron-donating groups exhibited cytotoxicities.

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First-principles Study on the Half-metallicity and Magnetism for the Heusler Based Compounds of N(2-0.5n)O0.5nKCa (n=0~4) (호이슬러 구조 기반의 N(2-0.5n)O0.5nKCa (n = 0~4) 화합물의 반쪽금속성 및 자성에 대한 제일원리 연구)

  • Bialek, Beata;Lee, Jae Il
    • Journal of the Korean Magnetics Society
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    • v.23 no.6
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    • pp.179-183
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    • 2013
  • The half-metallicity and magnetism for compounds of the $N_{(2-0.5n)}O_{0.5}nKCa$ (n = 0~4), which was based on the $d^0$ Heusler half-metals of $N_2KCa$ and $O_2KCa$, were investigated by means of first-principles band calculation method. From the calculated total magnetic moments and the density of states, we found that these three compounds have the half-metallicity. The magnetic moments of the N and O atoms in these compounds were considerably increased compared to those of pure $N_2KCa$ and $O_2KCa$. The K atoms have a large negative magnetic moments. The relationship between the value of magnetic moments for each atom and density of states are discussed.

MO Studies of Configuration and Conformation (XV). Through-Space and Through-Bond Interactions In Ethylene Diamine (배치와 형태에 관한 분자궤도론적 연구 (제15보). 에틸렌 디아민의 Through-Space 및 Through-Bond 상호작용)

  • Ikchoon Lee;Chang Kook Sohn;Chang Hyun Song
    • Journal of the Korean Chemical Society
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    • v.26 no.2
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    • pp.65-72
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    • 1982
  • STO-3G level computations were performed on n-propylamine, n-propylamine radical and cis-and trans-ethylene diamines in order to investigate structural contributions of (n${\pi}$/m) and (n-${\sigma}^*$) structures to the energy variations accompanying the conformational changes. It was found that (5${\pi}$/5) and (4${\pi}$/4) structures had attractive and repulsive nonbonded interactions, respectively, which were approximately additive. anti(n-${\sigma}^*$) structures had more stabilzing hyperconjugative interactions than syn(n-${\sigma}^*$) structures, but due to the large internuclear repulsion the net effect was destabilizing inthe former in contrast with the net stabilizing contribution in the latter. Moreover it was found that the stabilizing ${\pi}$-nonbond structure, (5${\pi}$/5) was always cooperatively reinforced by the more stabilizing anti(n-${\sigma}^*$) interaction, whereas the destabilizing (4${\pi}$/4) structure was accompanied by the less stabilizing syn(n-${\sigma}^*$) interaction. This type of cooperativity was found general through-bond interaction of the terminal lone pair lobes split the energy levels into two, $n_+ = \frac{1}{\sqrt{2}}(n_1 + n_2)$ and $n_- = \frac{1}{\sqrt{2}}(n_1 - n_2)$, the latter being the lower level, which can be shown using simple overlap patterns of the two lobes with a common vicinal ${\sigma}^*$ orbital.

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An Analytic Study on the Relations between the Ziegler-Nichols Tuning Methods for Controllers (지글러-니콜스 제어파라미터 조정법 (1), (2)의 연관성에 대한 해석적 연구)

  • 강인철;최순만;최재성
    • Journal of Advanced Marine Engineering and Technology
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    • v.26 no.2
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    • pp.219-225
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    • 2002
  • Parameter tuning methods by Ziegler-Nichols for PID controllers are generally classified into Z-N(1) and Z-N(2). The purpose of this paper is to describe what relations exist between the methods of Z-N(1) and Z-N(2), or how Z-N(1) can be originated from Z-N(2) by analyzing one loop control system composing of P or PI controller and time delay process. In this paper, for the first step to seek mutual relations, the simple formulas of Z-N(2) are transformed into those composing of the same parameters as Z-N(1) which is derived from the analysis of frequency characteristics. Then, the approximation of the actual ultimate frequency is proposed as important premise in the translation between Z-N(1) and (2). Such equalization and approximation brings a simple approximated formula which can explain how Z-N(1) is originated from the Z-N(2) in the form of formula.