• 제목/요약/키워드: $NO_x$ sensor

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Frbrication and characteristics of NO$_{2}$ Gas sensor using the phthalocyanines (프탈로시아닌을 이용한 NO$_{2}$ 가스센서의 제작 및 특성)

  • 전춘배;박효덕;이덕동
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.32A no.7
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    • pp.85-93
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    • 1995
  • In this study, phthalocyanine thin films were prepared by vacuum sublimation method and investigated sensing characteristics of the films. The phthalocyannies used for the prepaation of the NO$_{x}$ sensors were metal-free Pc(H$_{2}$Pc) and metal Pc(CuPc, CoPc, PbPc). And the substrate temperatures maintained during the fomation of Pc films were varied between R.T. and 200$^{\circ]C$, and the base pressure was 5${\times}10^{6}$ torr. The relationships between NO$_{2}$ sensing properties and SEM analyses as a function of substrate temperatures during the formation of the films were investigated. Among the Pc films, PbPc film showed the best sensing characteristics. Particularlly, the PbPc films prepared at 70$^{\circ]C$ of the substrage temperature showen good sensitivity of 85% to 1ppm NO$_{2}$ gas at operating temperature 190$^{\circ]C$ and response time was about 24 seconds.

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The Effect of Exhaust Gas Recirculation (EGR) on Combustion Stability, Engine Performance and Exhaust Emissions In a Gasoline Engine

  • Jinyoung Cha;Junhong Kwon;Youngjin Cho;Park, Simsoo
    • Journal of Mechanical Science and Technology
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    • v.15 no.10
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    • pp.1442-1450
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    • 2001
  • The EGR system has been widely used to reduce nitrogen oxides (NO$\_$x/) emission, to improve fuel economy and suppress knock by using the characteristics of charge dilution. However, as the EGR rate at a given engine operating condition increases, the combustion instability increases. The combustion instability increases cyclic variations resulting in the deterioration of engine performance and emissions. Therefore, the optimum EGR rate should be carefully determined in order to obtain the better engine performance and emissions. An experimental study has been performed to investigate the effects of EGR on combustion stability, engine performance,70x and the other exhaust emissions from 1.5 liter gasoline engine. Operating conditions are selected from the test result of the high speed and high acceleration region of SFTP mode which generates more NO$\_$x/ and needs higher engine speed compared to FTP-75 (Federal Test Procedure) mode. Engine power, fuel consumption and exhaust emissions are measured with various EGR rate. Combustion stability is analyzed by examining the variation of indicated mean effective pressure (COV$\_$imep/) and the timings of maximum pressure (P$\_$max/) location using pressure sensor. Engine performance is analyzed by investigating engine power and maximum cylinder pressure and brake specific fuel consumption (BSFC)

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Fabrication and NOx Gas Sensing Properties of LaMeO3 (Me = Cr, Co) by Polymeric Precursor Method (Polymeric Precursor법에 의한 LaMeO3 (Me = Cr, Co)의 제조 및 NOx 가스 검지 특성)

  • Lee, Young-Sung;Shimizu, Y.;Song, Jeong-Hwan
    • Korean Journal of Materials Research
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    • v.21 no.8
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    • pp.468-475
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    • 2011
  • [ $LaMeO_3$ ](Me = Cr, Co) powders were prepared using the polymeric precursor method. The effects of the chelating agent and the polymeric additive on the synthesis of the $LaMeO_3$ perovskite were studied. The samples were synthesized using ethylene glycol (EG) as the solvent, acetyl acetone (AcAc) as the chelating agent, and polyvinylpyrrolidone (PVP) as the polymer additive. The thermal decomposition behavior of the precursor powder was characterized using a thermal analysis (TG-DTA). The crystallization and particle sizes of the $LaMeO_3$ powders were investigated via powder X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and particle size analyzer, respectively. The as-prepared precursor primarily has $LaMeO_3$ at the optimum condition, i.e. for a molar ratio of both metal-source (a : a) : EG (80a : 80a) : AcAc (8a) inclusive of 1 wt% PVP. When the as-prepared precursor was calcined at $700^{\circ}C$, only a single phase was observed to correspond with the orthorhombic structure of $LaCrO_3$ and the rhombohedral structure of $LaCoO_3$. A solid-electrolyte impedance-metric sensor device composed of $Li_{1.5}Al_{0.5}Ti_{1.5}(PO_4)_3$ as a transducer and $LaMeO_3$ as a receptor has been systematically investigated for the detection of NOx in the range of 20 to 250 ppm at $400^{\circ}C$. The sensor responses were able to divide the component between resistance and capacitance. The impedance-metric sensor for the NO showed higher sensitivity compared with $NO_2$. The responses of the impedance-metric sensor device showed dependence on each value of the NOx concentration.

Fault Diagnosis for Electric Chassis System

  • Ryu, Seong-Pil;Kwak, Byung-Hak;Park, Young-Jin;Jung, Hun-Sang
    • 제어로봇시스템학회:학술대회논문집
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    • 2001.10a
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    • pp.116.1-116
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    • 2001
  • In the near future, drive-by-wire systems will replace mechanical systems of vehicles. Since there would be no mechanical redundancy in the x-by-wire subsystem, it needs to improve the reliability of the system using fault diagnosis of sensors and actuators. This paper proposes a Kalman filter based fault diagnosis method for the vehicle with the drive-by-wire system, which includes steer-by-wire, brake-by-wire and throttle-by-wire systems. We will show that the proposed method is successful in fault detection and isolation for single sensor/actuator faults of the vehicle system.

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Control Measures for Air Pollutant Emissions from In-Use Light-Duty Diesel Vehicles Regarding their Emission Control Technologies (배출허용기준 대응기술을 고려한 국내 소형 경유 운행차의 대기오염물질 관리 방안)

  • Lee, Taewoo;Park, Hana;Park, Junhong;Jeon, Sangzin;Kim, Jeongsoo;Choi, Kwangho
    • Journal of Korean Society for Atmospheric Environment
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    • v.30 no.4
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    • pp.327-338
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    • 2014
  • The objective of this study is to enhance the effectiveness of Korean Inspection and Maintenance (I/M) program. Three main tasks are: to measure pollutant emissions of in-use light-duty diesel vehicles (LDVs); to evaluate the validity of existing smoke control scheme for low-smoke-emitting vehicles, which have diesel particulate filters, DPF, to meet stringent Euro-5 emission limits; and to assess the necessity and the benefit of $NO_x$ inspection, which is not involved in current I/M program. We measured second-by-second smoke, particulate and gaseous emissions of 27 LDVs using opacity smoke meter, photo-acoustic soot sensor, and portable emissions measurement system, respectively, under the Korean I/M test driving cycle, KD-147. We find that the DPF plays a key role in controlling soot, which can be considered as black carbon contained in particulate matter. Thus, from an I/M perspective, we believe smoke inspection strategies for Euro-5 diesel vehicles should be more focused on the capability of detecting DPF malfunctions or failures, in order to keep DPF properly functional. Fleet averaged distance-specific $NO_x$ emissions are consistently higher than corresponding emission limits, and the values are similar among pre-Euro-3, Euro-3, and Euro-4 vehicle fleets. These findings indicate that the $NO_x$ inspection should be incorporated into current I/M program in order to manage urban $NO_x$ emissions. This research allows the Korean I/M program keep pace with developments in vehicle technologies, as well as the increased emphasis on $NO_x$ with respect to air quality and human health.

Fabrication and Characterization of TFT Gas Sensor with ZnO Nanorods Grown by Hydrothermal Synthesis (수열합성법으로 성장시킨 ZnO 나노 로드기반 TFT 가스 센서 제조 및 특성평가)

  • Jeong, Jun-Kyo;Yun, Ho-Jin;Yang, Seung-Dong;Park, Jeong-Hyun;Kim, Hyo-Jin;Lee, Ga-Won
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.4
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    • pp.229-234
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    • 2017
  • In this study, we fabricated a TFT gas sensor with ZnO nanorods grown by hydrothermal synthesis. The suggested devices were compared with the conventional ZnO film-type TFTs in terms of the gas-response properties and the electrical transfer characteristics. The ZnO seed layer is formed by atomic-layer deposition (ALD), and the precursors for the nanorods are zinc nitrate hexahydrate ($Zn(NO_3)_2{\cdot}6H_2O$) and hexamethylenetetramine ($(CH_2)6N_4$). When 15 ppm of NO gas was supplied in a gas chamber at $150^{\circ}C$ to analyze the sensing capability of the suggested devices, the sensitivity (S) was 4.5, showing that the nanorod-type devices respond sensitively to the external environment. These results can be explained by X-ray photoelectron spectroscopy (XPS) analysis, which showed that the oxygen deficiency of ZnO nanorods is higher than that of ZnO film, and confirms that the ZnO nanorod-type TFTs are advantageous for the fabrication of high-performance gas sensors.

Examination on the variation of ride comfort for korean high speed train through on-line test (시운전 시험을 통한 한국형 고속열차의 승차감 변화추세에 관한 연구)

  • Kim, Young-Guk;Mok, Jin-Yong;Kim, Seog-Won;Park, Chan-Kyeong;Kim, Ki-Hwan;Park, Tae-Won
    • Journal of Sensor Science and Technology
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    • v.14 no.3
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    • pp.144-149
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    • 2005
  • In this paper, we introduce the variation of ride characteristics for HSR 350x(Korea High Speed Train project) through on-line test during about 3 years. The concept of term "ride comfort" is equivocal. Generally it is evaluated as the vehicle vibration. The ride comfort for HSR 350x has been assessed by statistical method according to UIC 513R. The testing results show that HSR 350x has no problems from the viewpoint of the comfort ride on the high speed line and conventional line and that 1st and 2nd suspensions play an important role in the ride characteristics for high speed train.

Diagnostic accuracy of digital images for detection of artificial chemical proximal caries (화학적 인공 인접면 치아우식증의 디지털 영상 진단능 평가)

  • Park Geum-Mee;Nah Kyung-Soo
    • Imaging Science in Dentistry
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    • v.33 no.2
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    • pp.91-95
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    • 2003
  • Purpose : To compare the diagnostic accuracy of proximal caries detection between Kodak Insight film and the Biomedisys CDX2000HQ digital (CCD) sensor. Materials and Methods: 156 proximal surfaces of extracted teeth, 78 of which had chemical artificial caries, were used in this study. Four observers interpreted the radiographs using a five-point confidence rating scale to record their diagnoses. The results were analyzed by receiver operating characteristic curves, ANOVA and Kappa values. Result: Analysis using receiver operating characteristic curves revealed the areas under each curve which indicated a diagnostic accuracy of 0.951 in Insight and 0.952 in CDX2000HQ digital sensor. ANOVA revealed no significant differences between the two images with respect to caries detection. Kappa values indicated that the mean intra-observer agreement was 0.85 and inter-observer agreement 0.71 in conventional radiography. In digital radiography, the mean intra-observer agreement was 0.84 and inter-observer agreement 0.72. Conclusion: The results suggest that no significant difference exists between the two modalities for artificial caries detection and that CDX2000HQ was as good as Insight film for this purpose.

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Research Progress in Membrane and Catalyst for Highly Selective Chemiresistive Gas Sensors (저항변화식 가스센서 선택성 향상을 위한 멤브레인 및 촉매 연구동향)

  • Jang, Ji-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.1
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    • pp.11-17
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    • 2022
  • Direct exposure to toxic and hazardous gases has always been considered as the most pervasive problem worldwide, leading to a gradual increase in the number of asthma patients due to NOx/SOx gases inhaling and exposure to 50 ppm formaldehyde gases. Therefore, the development of accurate gas sensors is a key issue for resolving these problems. To address such issues, the development of membranes for selective filtering of target molecules as well as nanocatalyst for enhancing the sensing selectivity is highly crucial. In this review, the research progress for porous membrane materials (e.g. MOFs, and graphene) and nanocatalyst technology for the development of selective and accurate gas sensors will be discussed.

Comparative study on the radiopacity of different resin-based implant cements (레진계 임플란트용 시멘트의 방사선 불투과성에 대한 비교연구)

  • Han, Kyeong-Hwan;Cheon, Ho-Young;Kim, Min-Su;Shin, Sang-Wan;Lee, Jeong-Yol
    • The Journal of Korean Academy of Prosthodontics
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    • v.52 no.2
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    • pp.97-104
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    • 2014
  • This study was aimed to compare the radiopacity of four kinds of currently available resin based implant cements using digital radiography. Materials and Methods: Four resin-based implant cements((Estemp $Implant^{TM}$ (Spident, Incheon, Korea), $Premier^{(R)}$Implant (Premier, Pennsylvania, USA), $Cem-Implant^{TM}$ (B.J.M lab, Or-yehuda, Israel), $InterCem^{TM}$ (SCI-PHARM, California, USA)) and control group (Elite Cement $100^{TM}$ (GC, Tokyo, Japan) ) were mixed and cured according to the manufacturer's instructions on the custom made split-type metal mold. A total of 150 specimens of each cement were prepared and each specimen (purity over 99%) was placed side-by-side with an aluminum step wedge for image taking with Intraoral X-ray unit (Esx, Vatech, Korea) and digital X-ray sensor (EzSensor, Vatech, Korea). For the evaluation of aluminum wedge equivalent thickness (mm Al), ImageJ 1.47 m (Wayne Rasband, National Institutes of Health, USA) and Color inspector 3D ver 2.0 (Interaktive Visualisierung von Farbraumen, Berlin, Germany) programs were used. Result: Among the 5 cements, Elite cement $100^{TM}$ (control group) showed the highest radio-opacity in all thickness. In the experimental group, $InterCem^{TM}$ had the highest radio-opacity followed by $Premier^{(R)}$ Implant $Cement^{TM}$, $Cem-Implant^{TM}$ and Estemp $Implant^{TM}$. In addition, $InterCem^{TM}$ showed radio-opacity that met the ISO No. 4049 standard in all the tested specimen thickness. Cem-Implant on 0.5 mm thickness showed radiopacity that met the ISO No. 4049 standard. Conclusion: Among the implant resin-based cements tested in the study, $Premier^{(R)}$ Implant Cement and Estemp $Implant^{TM}$ did not show appropriate radio-opacity. Only $InterCem^{TM}$ and $Cem-Implant^{TM}$ 0.5 mm specimen had the proper radiopacity and met the experiment standard.