• 제목/요약/키워드: $NH_2Cl$

검색결과 879건 처리시간 0.026초

오르토 치환 아닐린과 요오드 사이의 착물에 관한 연구 (The Complexes of Iodine with Ortho-Substituted Anilines in Carbon Tetrachloride)

  • 이부영;최상업
    • 대한화학회지
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    • 제15권6호
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    • pp.312-317
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    • 1971
  • 아닐린, o-톨루이딘, o-에틸아닐린, o-클로로아닐린등과 $I_2$사이의 상호작용을 자외선 분광광도법으로 조사한 결과 $CCl_4$ 용액내에서 아닐린 또는 상기 o-치환 아닐린과 $I_2$ 사이에 1:1 착물이 형성됨을알았다. 이들 착물의 실온에서의 형성상수를 구한 결과 다음과 같은값을 얻었다. $C_6H_5NH_2{\cdot}I_2,\;12.8lmole^{-1};\;o-CH_3C_6H_4NH_2{\cdot}I_2,\;9.31l mole^{-1};\;o-C_2H_5C_6H_4NH_2{\cdot}I_2,\;3.15l mole^{-1};\;o-ClC_6H_4NH_2{\cdot}I_2,\;0.576 l mole^{-1}$. 본 실험결과를 전 실험의 결과와 비교하면 $I_2{\cdot}$아민 착물의 안정도가 다음 순으로 감소함을 알 수 있다. $C_6H_5N(C_2H_5)_2 >C_6H_5N(CH_3)_2 >C_6H_5NH_2 >o-CH_3C_6H_4NH_2 >o-C_2H_5C_6H_4NH_2 >o-ClC_6H_4NH_2$ 이들 착물의 상대적 안정도는 치환기의 유발효과와 입체효과에 의하여 설명될 수 있다.

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사각평면형 백금(Ⅱ) 착물의 트란스효과에 대한 분자궤도함수론적 해석 (MO Interpretation for the trans Effect of Square Planar Type Pt(Ⅱ) Complexes)

  • 박병각;이상협;여환진;조이영
    • 대한화학회지
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    • 제32권5호
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    • pp.495-500
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    • 1988
  • trans-[$PtNH_3Cl_2L$] (L = $H_2O$, $NH_3$, $Cl^-$, $Br^-$, $I^-$, $CH_3$$PH_3$)형 백금(Ⅱ)착물계열의 트란스효과를 설명하기 위해 필자들이 수정한 확장 Huckel MO법을 사용했다. 계산에 의하면 L이 보다 좋은 트란스배향리간드일수록 L의 트란스자리에 있는 Pt-N의 결합의 reduced overlap population(ROP)은 감소했다. 즉 이 사실은 보다 좋은 트란스배향리간드 일수록 트란스 효과가 증대되었다. 따라서 일반적인 trans-[$PtTL_2X$] 착물의 트란스효과를 양자화학적으로 설명할 수 있었다.

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토양에의 고농도 Na 및 Cl 염류가 토마토의 생육 및 무기성분 흡수에 미치는 영향 (Effect of High Concentrations of Sodium or Chloride Salts in Soil on the Growth of and Mineral Uptake by Tomatoes)

  • 강경희;권기범;최영하;김회태;이한철
    • 생물환경조절학회지
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    • 제11권3호
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    • pp.121-126
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    • 2002
  • 본 연구는 토양에의 고농도 Na 및 Cl 염류처리가 토마토의 생육과 무기성분 흡수, 광합성 속도 및 수분 포텐셜에 미치는 효과를 검토코자 수행되었다. 초장, 생체중, 건물중 등 생육은 대조구에 비해 모든 염 처리구에서 억제되었으나, 토양의 pH와 EC와는 관계가 없었다. 토마토의 생육억제 효과는 Na계열에서는 Cl, SO$_4$, CO$_3$, PO$_4$, NO$_3$ 순으로, 그리고 Cl 계열에서는 Na, K, Mg, NH$_4$, Ca순으로 컸으며, Na 계열이 Cl 계열보다 컸다. 토마토의 수량은 대조구보다 모든 염 처리구에서 30%~10%적었으며,특히 NaCl처리구에서 더욱 적었다. 엽록소 함량, 광합성 속도, 기공전도도는 대조구에 비해 염 처리구에서 낮았다. 무기양분 함량은 대조구보다 모든 염류에서 낮았다. N 함량은 NaNO$_3$, NH$_4$Cl 및 대조구가 11% 내외로 가장 높았으나 Na 계열에서는 NaCl 및 NaHCO$_3$ 처리구가, Cl 계열에서는 KCI 처리구가 5.5~6.0% 내외로 낮았다. K 함량은 Cl 계열보다 Na 계열이 적었으며, 특히 NaCl과 $Na_2$SO$_4$ 처리구에서 더욱 낮았다. Mg 및 Ca 함량은 대조구보다 낮았으며, NaCl과 KCl 처리에서 매우 낮아 Na 및 K 이온과 상당한 길항관계를 보였다 전반적으로 각 이온의 흡수는 KCl및 NaCl처리구에서 가장 낮은 경향이었다.

연속강우시 산성우의 이온농도 변화에 관한 조사연구 (A Study on Ion Concentration Change of Acid Rain by the Succeeding Raintall)

  • 박경렬;김대선
    • 한국환경보건학회지
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    • 제16권2호
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    • pp.11-20
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    • 1990
  • To investigate ionic characteristics of acid rain by the succeeding rainfall. bulk precipitation was collected every each 5mm rainfall from march to october 1990 at Dae Jeon area. pH, sulfate nitrate, chloride, ammonium ion was measured and analyzed. The result was as follows: 1. The weighted average pH of rain was 5.1$\pm$ 0.72(4.15~7.6) and rain pH less than 5.5 was appeared 51.3% 2. Average ion concentrations of sulfate, nitrate, chloride and ammonium ion was 125.12 $\mu$eq/l, 62.38 $\mu$eq/l, 31.95 $\mu$eq/l, 66.6 $\mu$eq/l and rates of each anions was 57%, 28.4%, 14.6% and rate of sulfate by nitrate was 2 times. 3. There is no correlations time interval of rainfall and Ion concentration change. 4. From initial to 15mm rainfall, each ion concentrations were decreased. and average concentration of pH, SO$^{-2}_{4}$, Cl ion concentration was increased in the succeeding rainfall 5. Only sulfate ion was correlated by the simple regression analysis with pH except NO$^{-}_{3}$, Cl$^{-}$ and NH$_{4}^{+}$ Cl$^{-}$ correlation coefficient was very high at the multiple regression analysis with pH. 6. Simple & multiple correlation coefficient among anions and NH$^{+}_{4}$ was very high especially N$^{+}_{4}$ and SO$^{2-}_{4}$ at simple regression analysis and SO$^{-2}_{4}$ and NO$_{3}^{-}$, Cl$^{-}$, NH$_{4}^{-}$ at multiple regression analysis.

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1994년 수도권 지역에서의 시정과 미세 입자상물질 화학조성과의 관계해석 (Chemical Composition of Fine Aerosol Associated with Visibility Degradation in Seoul Metropolitan Area in 1994)

  • 한진석;김병곤;김신도
    • 한국대기환경학회지
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    • 제12권4호
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    • pp.377-387
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    • 1996
  • This study was carried out to monitor the visibility including measurement and analysis of the various parameters such as particle size distribution, chemical composition, and meteorotical conditions to understand the characteristics and causes of this phenomenon. According to the analysis of intensive sampling, $SO_4^{2-}, NO-3^-, Cl^-, NH_4^+$ ion concentration increased together with the mass concentration around 1 $\mu$m in the case of low visibility. $(NH_4)_2SO_4, NH_4NO_3$, and $NH_4Cl$ were thought to be the major components of fine particles. The statistical analysis showed that the scattering effect of particle was 81.2%, the absorption effect was 14.9%. Therefore, these effects were the major factors to reduce the visibility. In conclusion, the visibility was reduced by the fine particle of sulfate (18.6%), nitrate (14.2%), organic carbon (10.8%), element carbon (25.8%), and residual (24.8%) during this study.

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경산시 지하수의 수질특성에 관한 연구 (A Study on the Characteristics of Groundwaters in Gyeongsan City)

  • 송성숙;박병윤;이부용
    • 한국환경과학회지
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    • 제16권6호
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    • pp.677-682
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    • 2007
  • This study was performed to provide the basic information on characteristics of groundwater pollution in Gyeongsan city. Forty two groundwater samples were collected, and pH, DO, COD, $NH_3-N,\;NO_3^--N$, T-N, $PO_4^{3-}-P$, Cl, Ca, Mg, hardness, evaporate residues and others were investigated. And, ANOVA analyses were carried out to reveal the differences in water pollution indicator values of by industry, commerce/residence and agriculture areas. The results were as follows. 1. The mean values of pH, DO, COD, $NH_3-N,\;NO_3^--N$, T-N, $PO_4^{3-}-P$, Cl, evaporate residues, Ca and hardness were 6.9, $7.9mg/\ell,\;0.4mg/\ell,\;2.44mg/\ell,\;2.73mg/\ell,\;6.06mg/\ell,\;0.82mg/\ell,\;32.72mg/\ell,\;381.67mg/\ell,\;41.53mg/\ell,\;177.17mg/\ell$, respectively. 2. As groundwater became deeper, the values of Cl, Ca, Mg, Na, hardness and evaporate residues remarkably increased, but those of COD, $NH_3^--N,\;NO_3^--N,\;NO_2^-N$, T-N decreased. 3. The values of COD, Cl, Ca, Mg, Na, hardness and evaporate residues were very high in industrial area, and those of $NH_3-N,\;NO_2^--N$, T-N were very high in commercial/residential area, and those of $NO_3^--N$ were a little high in agricultural area. 4. The correlations between depth and each value of Mg, Na, Fe, hardness and evaporate residues were highly positive, and those between DO and each value of Mg, Cu, Fe, hardness and evaporate residues were highly negative. 5. According to ANOVA analyses, the differences in three area groups (industry, commerce/residence and agriculture) on the values of $NH_3-N$, T-N, evaporate residues, hardness, Ca, Mg, K and Fe were significant at 1% level.

Structural and Optical Properties of the $(C_nH_{2n}_+_1NH_3)_2SnCl_4$ (n=2, 4, 6, 8, and 10) System

  • 인리주;요철현
    • Bulletin of the Korean Chemical Society
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    • 제19권9호
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    • pp.947-951
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    • 1998
  • $K_2NiF_4$-type layered compounds of the ($C_nH_{2n+1}NH_3)_2SnCl_4$ (n=2, 4, 6, 8, and 10) system have been synthesized from a stoichiometric mixture of $SnCl_2$ and alkyl ammonium salt using a low temperature solution technique under the inert atmosphere condition. Their crystal structures are assigned to the orthorhombic system by X-ray powder diffraction analysis. The a and b cell parameters show small changes. However, the c parameter is varied significantly according to the increment of alkyl chains of the organic layer which is located between inorganic layers in the compounds. The conformational phase transitions of the compounds are studied by the DSC in the temperature range of 300 to 500 K. FT-IR and Raman spectra are analyzed in the ranges of 1300 to 4000 cm-1 and of 50 to 360 $cm^{-1}$ with Ar-laser (λ=514.5 nm) excitation, respectively. Photoluminescence phenomena are observed for some compounds. The bond-length of Sn-Cl is determined by the EXAFS spectroscopic analysis.

Palladium(II) p-Tolylamide and Reaction with CO2 to Generate a Carbamato Derivative

  • Seul, Jung-Min;Park, Soon-Heum
    • Bulletin of the Korean Chemical Society
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    • 제31권12호
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    • pp.3745-3748
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    • 2010
  • Pd(II) p-tolylamide Pd(2,6-$(Ph_2PCH_2)_2C_6H_3$)(NH($C_6H_4Me$-p)) (1) was metathetically prepared by the reaction of Pd(2,6-$(Ph_2PCH_2)_2C_6H_3$)Cl with NaNH($C_6H_4Me$-p). Treatment of 1 with carbon dioxide affords the palladium(II) carbamate Pd(2,6-$(Ph_2PCH_2)_2C_6H_3$)(OC(O)NH($C_6H_4Me$-p)) (2), quantitatively. Complex 2 reacts with HX (X = Cl, OTf) to give Pd(2,6-$(Ph_2PCH_2)_2C_6H_3$)X, $NH_2$(p-Tol) and $CO_2$. Reaction of the palladium(II) carbamate with MeI produced Pd(2,6-$(Ph_2PCH_2)_2C_6H_3$)I along with generation of methyl N-tolylcarbamate MeOC(O)NH($C_6H_4Me$-p), exclusively.

The stimulatory effect of CaCl2, NaCl and NH4NO3 salts on the ssDNA-binding activity of RecA depends on nucleotide cofactor and buffer pH

  • Ziemienowicz, Alicja;Rahavi, Seyed Mohammad Reza;Kovalchuk, Igor
    • BMB Reports
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    • 제44권5호
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    • pp.341-346
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    • 2011
  • The single-stranded DNA binding activity of the Escherichia coli RecA protein is crucial for homologous recombination to occur. This and other biochemical activities of ssDNA binding proteins may be affected by various factors. In this study, we analyzed the effect of $CaCl_2$, NaCl and $NH_4NO_3$ salts in combination with the pH and nucleotide cofactor effect on the ssDNA-binding activity of RecA. The studies revealed that, in addition to the inhibitory effect, these salts exert also a stimulatory effect on RecA. These effects occur only under very strict conditions, and the presence or absence and the type of nucleotide cofactor play here a major role. It was observed that in contrast to ATP, ATP${\gamma}$S prevented the inhibitory effect of NaCl and $NH_4NO_3$, even at very high salt concentration. These results indicate that ATP${\gamma}$S most likely stabilizes the structure of RecA required for DNA binding, making it resistant to high salt concentrations.

이산화염소 가스분무에 의한 퇴비장 악취저감 효과 (Conducted to Verify the Effect of Chlorine Dioxide (ClO2) on Odor Reduction at a Compost Facility)

  • 송준익;전중환;이준엽;박규현;조성백;황옥화;김두환
    • 한국축산시설환경학회지
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    • 제18권sup호
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    • pp.1-6
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    • 2012
  • 본 연구는 양돈분뇨처리 퇴비사에서 발생하는 악취 제어를 위하여 이산화염소 가스를 이용한 악취 제어 효율을 검증하고자 하였다. 본 실험은 일반농장에서 실시하였으며 실험결과는 다음과 같다. 1. 퇴비사 내부 퇴비화 기계위에서의 암모니아 가스는 이산화염소 가스를 분무하기 전에는 550 ppm 전후로 측정되었으나, 이산화염소 가스 분무후 퇴비화 기계위에서의 암모니아 농도는 78 ppm 이하로 나타나 86% 이상 저감되었으며, 퇴비사 외부는 20 ppm ${\rightarrow}$ 5 ppm으로 저감되어 75% 저감되었다. 황화수소는 퇴비사 내부에서 3 ppm 검출되었으나 이산화염소 가스 분무후(1▼)는 거의 검출 되지 않았으며 퇴비사 외부는 거의 검출 되지 않았다. 2. 퇴비화 기계 가동시 퇴비사 내부에서의 이산화염소 가스분무 전후의 변화는 암모니아($NH_3$)는 분무전 420 ppm ${\rightarrow}$ 분무후는 35 ppm로 감소(83% 감소)하였고, 황화수소($H_2S$)는 분무전 210 ppb ${\rightarrow}$ 분무후 32 ppb로 감소(85% 감소) 효과가 있었다. 이상의 실험결과를 종합해 볼 때 퇴비사에 있어서 이산화염소 가스 분무에 의한 돈사 내외부에서 암모니아 등의 악취를 외부에 휘산시키는 농도를 저하시킬 수 있음을 알 수 있었다.