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http://dx.doi.org/10.5012/bkcs.2010.31.12.3745

Palladium(II) p-Tolylamide and Reaction with CO2 to Generate a Carbamato Derivative  

Seul, Jung-Min (Department of Chemistry, Dongguk University)
Park, Soon-Heum (Department of Chemistry, Dongguk University)
Publication Information
Bulletin of the Korean Chemical Society / v.31, no.12, 2010 , pp. 3745-3748 More about this Journal
Abstract
Pd(II) p-tolylamide Pd(2,6-$(Ph_2PCH_2)_2C_6H_3$)(NH($C_6H_4Me$-p)) (1) was metathetically prepared by the reaction of Pd(2,6-$(Ph_2PCH_2)_2C_6H_3$)Cl with NaNH($C_6H_4Me$-p). Treatment of 1 with carbon dioxide affords the palladium(II) carbamate Pd(2,6-$(Ph_2PCH_2)_2C_6H_3$)(OC(O)NH($C_6H_4Me$-p)) (2), quantitatively. Complex 2 reacts with HX (X = Cl, OTf) to give Pd(2,6-$(Ph_2PCH_2)_2C_6H_3$)X, $NH_2$(p-Tol) and $CO_2$. Reaction of the palladium(II) carbamate with MeI produced Pd(2,6-$(Ph_2PCH_2)_2C_6H_3$)I along with generation of methyl N-tolylcarbamate MeOC(O)NH($C_6H_4Me$-p), exclusively.
Keywords
Palladium arylamide; Palladium carbamate; Insertion of $CO_2$; Methyl N-aryl carbamate;
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