• Title/Summary/Keyword: $Fe_{16}N_2$

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백두산 화산군 환경과 동굴 암석의 년대측정 및 성분분석

  • 김경훈
    • Journal of the Speleological Society of Korea
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    • v.34 no.35
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    • pp.32-42
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    • 1993
  • The Paektu-san mountains are geographically situated in the Korea strait to the north of the main peninsula, coordinated between the longitudes of W(127$^{\circ}$15'~128$^{\circ}$00')and E(128$^{\circ}$15'~129$^{\circ}$00'), and between the latitudes of S(41$^{\circ}$15'~42$^{\circ}$00') and N(42$^{\circ}$10'~42$^{\circ}$40'). The volcanic group of the Paektu-san mountains can be devided into 2 main kinds of volcanos by the method investigation, The ashes are mainly made of tremolite, trachte, basalt and pumice, or, a little quartz, labradorite and volcanic glass. These sorts, ratios and forms of the rocks are respectively similar. The Haeven lake is surrounded by 19 peaks. The central volcanic cone is a secant cone in shape, with an altitude of the 1800m to 2749,2m (Chang-kun-bong), an average diameter of 10km, and a shape of an ellipse seen high from the plane. They say there were several eruptions in 1668, 1700 and 1702 A. D. The crystal structure of the rock sample collected at the cave of Mt. Paektu-san is monoclinic. The quantitative analysis of the rock samples in the cave is done by using XRF this time. The chemical compositions by XRF fundamamental parameter analysis is : SiO$_2$: 50.72Wt%, TiO = 2.422Wt%, $Al_2$O$_3$= 17.65Wt%, Fe$_2$O$_3$= 9.371Wt%, CaO = 8.711Wt%, MgO = 4.l19Wt%, MnO = 0.l15Wt%, $K_2$O = 1.369Wt%, Na$_2$O : 3.028Wt% and P$_2$O$_{5}$ = 0.365Wt%. The K-Ar age of the rock sample is also determined to be 0.16Ma. This paper describes some problems experienced in dating young volcanic rocks, and then discusses chemical compositions, X-ray fluorescence analyses and the age of the formation of a lava tunnel such as in Mt. Paektu-san.n.

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The characteristics of Pt thin films prepared by DC magnetron sputter (DC Magnetron Sputter로 제조된 Pt 박막의 특성)

  • Na, Dong-Myong;Kim, Young-Bok;Park, Jin-Seong
    • Journal of Sensor Science and Technology
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    • v.16 no.2
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    • pp.159-164
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    • 2007
  • Thin films of platinum were deposited on a $Al_{2}O_{3}/ONO(SiO_{2}-Si_{3}N_{4}-SiO_{2})/Si$-substrate with an 2-inch Pt(99.99 %) target at room temperature for 20, 30 and 60 min by DC magnetron sputtering, respectively X-ray diffract meter (XRD) was used to analyze the crystallanity of the thin films and field emission scanning electron microscopy (FE-SEM) was employed for the investigation on crystal growth. The densification and the grain growth of the sputtered films have a considerable effect on sputtering time and annealing temperatures. The resistance of the Pt thin films was decreased with increasing deposition time and sintering temperature. Pt micro heater thin film deposited for 60 min by DC magnetron sputtering on an $Al_{2}O_{3}$/ONO-Si substrate and annealed at $600^{\circ}C$ for 1 h in air is found to be a most suitable micro heater with a generation capacity of $350^{\circ}C$ temperature and 645 mW power at 5.0 V input voltage. Adherence of Pt thin film and $Al_{2}O_{3}$ substrate was also found excellent. This characteristic is in good agreement with the uniform densification and good crystallanity of the Pt film. Efforts are on progress to find the parameters further reduce the power consumption and the results will be presented as soon as possible.

Optimization of MOF-235 Synthesis by Analysis of Statistical Design of Experiment (통계학적 실험계획법 해석을 통한 MOF-235 합성 최적화)

  • Chung, Mingee;Yoo, Kye Sang
    • Applied Chemistry for Engineering
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    • v.30 no.5
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    • pp.615-619
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    • 2019
  • Statistical design of experiments was performed to optimize MOF-235 synthesis process. Concentrations of terephthalic acid (TPA), iron (III) chloride hexahydrate, N,N-dimethylformamide (DMF) and ethanol were important factors to develop the crystal structure of MOF-235. MOF-235 was synthesized with various concentrations of the listed chemicals above and the crystallinity was measured by XRD. The effect of the composition on the synthesis of MOF-235 was evaluated using a statistical analysis. For the variance analysis using F-test, the concentration of ethanol showed the greatest effect on the crystallinity and TPA the least influential. A regression model for predicting the crystallinity of MOF-235 was derived and the prediction results for two synthetic variables were presented using contour plots. Finally, the crystallinity was predicted by a mixture method with $FeCl_3$, ethanol and DMF.

Fertilizer and Organic Inputs Effects on CO2 and CH4 Emission from a Soil under Changing Water Regimes (토양 수분 변동 조건에서 시비 및 유기물 투입에 따른 CO2와 CH4 방출 특성)

  • Lim, Sang-Sun;Choi, Woo-Jung;Kim, Han-Yong
    • Korean Journal of Environmental Agriculture
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    • v.31 no.2
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    • pp.104-112
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    • 2012
  • BACKGROUND: Agricultural inputs (fertilizer and organic inputs) and water conditions can influence $CH_4$ and $CO_2$ emission from agricultural soils. This study was conducted to investigate the effects of agricultural inputs (fertilizer and organic inputs) under changing water regime on $CH_4$ and $CO_2$ emission from a soil in a laboratory incubation experiment. METHODS AND RESULTS: Four treatments were laid out: control without input and three type of agricultural inputs ($(NH_4)_2SO_4$, AS; pig manure compost, PMC; hairy vetch, HV). Fertilizer and organic inputs were mixed with 25 g of soil at 2.75 mg N/25 g soil (equivalent to 110 kg N/ha) in a bottle with septum, and incubated for 60 days. During the first 30-days incubation, the soil was waterlogged (1 cm of water depth) by adding distilled water weekly, and on 30 days of incubation, excess water was discarded then incubated up to 60 days without addition of water. Based on the redox potential, water regime could be classified into wetting (1 to 30 days), transition (31 to 40 days), and drying periods (41 to 60 days). Across the entire period, $CH_4$ and $CO_2$ flux ranged from 0 to 13.8 mg $CH_4$/m/day and from 0.4~1.9 g $CO_2$/m/day, and both were relatively higher in the early wetting period and the boundary between transition and drying periods. During the entire period, % loss of C relative to the initial was highest in HV (16.4%) followed by AS (8.1%), PMC (7.5%), and control (5.4%), indicating readily decomposability of HV. Accordingly, both $CH_4$ and $CO_2$ fluxes were greatest in HV treatment. Meanwhile, the lower $CH_4$ flux in AS and PMC treatments than the control was ascribed to reduction in $CH_4$ generation due to the presence of oxidized compounds such as ${SO_4}^{2-}$, $Fe^{3+}$, $Mn^{4+}$, and ${NO_3}^-$ that compete with precursors of $CH_4$ for electrons. CONCLUSION: Green manure such as HV can replace synthetic fertilizer in terms of N input, however, it may increase $CH_4$ emission from soils. Therefore, co-application of green manure and livestock manure compost needs to be considered in order to achieve satisfactory N supply and to mitigate $CH_4$ and $CO_2$ emission.

A Study on Deep Levels in Rapid Thermal Annealed PICTS Semi-Insulating InP(100) by PICTS (PICTS 방법에 의한 급속열처리시킨 반절연성 InP(100)에서 깊은준위에 관한 연구)

  • 김종수;김인수;이철욱;이정열;배인호
    • Electrical & Electronic Materials
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    • v.10 no.8
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    • pp.800-806
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    • 1997
  • The behavior of de levels in rapid thermal annealed Fe-doped semi-insulating InP(100) was studied by photoinduced current transient spectrocopy(PICTS). In bulk InP, T2(Ec-0.24 eV), T3(Ec-0.30 eV) and T5(Ec-0.62 eV) traps were observed. After annealing the T2 trap was annihilated at 20$0^{\circ}C$ and recreated at 35$0^{\circ}C$. T3 trap was not affected below 40$0^{\circ}C$. With increasing temperature the concentration of T5 trap reduced and it was annihilated at 30$0^{\circ}C$. However the T1(Ec-0.16 eV) and T4(Ec-0.42 eV) traps were began to appear at 40$0^{\circ}C$and these concentrations were increased with annealing temperature. The T1 and T4 traps seem to be related to the isolated phosphorus vacancy( $V_{p}$) and $V_{p}$-indium antisite( $V_{p}$- $P_{in}$ ) or $V_{p}$-indium interstitial( $V_{p}$-I $n_{I}$) respectiely.respectiely.

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The Study on Scattering of Chromosomes in Cells -Scattering of Chromsomes by Treatment with Potassium Ferricyanide Solution under Light- (세포내 염색체의 분산에 관한 연구 -적혈염용액의 광조사 처리에 의한 염색체의 분산-)

  • 김종호
    • Journal of Plant Biology
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    • v.17 no.3
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    • pp.113-117
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    • 1974
  • In counting chromosome number and karyotype study, it is necessary to let chromosomes on metaphase by pretreatment before fixation. For this purpose, colchicine, or 8-oxyquinoline are generally used. The author found out that chromosomes could be scattered by illuminating cyanoferrate complex solution in which root-tips were sunk. As materials, 8 sorts of plant such as Allium fisturosum, allium tuberosum Rottler, Triticum vulgare were used. Their root-tips were sunk on the bottom of beaker in potassium ferricyanide solution $3{\times}10-4M$ and illuminated through the solution by sterilizing lamp for 1~2 hours in dark room, keeping 10 cm distance from light source to the surface of solution and 2cm depth of solution. Then again, they were illuminated to the light which was somewhat weaker intensity than the former (distance, 16cm; depth, 3cm) for 1.5~2 hours after immersed in 1/100N-HCl and washed in water for each 5minutes. By such methods chromosomes could be scattered. About the mechanism of scattering, it is supposed that CN and Fe(CN)x ions $(x {\leq}5)$ which were gradually produced in the process of photodissociation acted together on the scattering of chromosomes.

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The physicochemical properties of kenaf(Hibiscus cannabinus L.) as mushroom culture media source (버섯배지 재료로서 케나프의 이화학성 분석)

  • Kang, Chan-Ho;Yoo, Young-Jin;Seo, Sang-Young;Choi, Kyu-Hwan;Lee, Ki-Kwon;Song, Young-Ju;Kim, Chung-Kon
    • Journal of Mushroom
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    • v.13 no.3
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    • pp.207-211
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    • 2015
  • To investigate the usefulness of Kenaf(Hibiscus cannabinus L.) as mushroom culture media source, we analyze physical condition and contents of nutritional components. The water absorption rate of Kenaf bast was 578% and it was 95% higher than that of poplar sawdust's. This was caused by Kenaf's porous cellular structure. so it could give more moisture and oxygen to cultured mushroom. Total carbon contents of Kenaf was 91.4%, it was quite higher than that of poplar sawdust, wheat bran and rice bran. Total nitrogen content was 1.76% and C/N ratio was 51.9. The content of NFE(Nitrogen free extract) was 46.6% and it was similar with rice bran. Cellulose content was higher than poplar but lignin content was lower. specially hemicellulose and pectin complex which more digestible carbon source to mushroom was 3.7% higher than poplar. Mineral component and amino acid contents were also maintained high compared with poplar. Fe was 4.2 times, P 3.2 times, K 2.2 times more and Ca was higher 16 mg/kg than poplar. The content of amino acid was quite more higher than poplar sawdust but lower than chaff. Consequently Kenaf had a good trait for basic support material in mushroom culture media and also had a good character as nutritional source.

Effect of Potassium on Rice Plant Growth on an Akiochi Soil (추락답토양(秋落沓土壤)에 생육(生育)한 수도(水稻)에 대(對)한 가리(加里)의 효과)

  • Park, Y.D.;Kim, Y.S.;Park, C.S.
    • Korean Journal of Soil Science and Fertilizer
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    • v.3 no.1
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    • pp.11-16
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    • 1970
  • In application of manganese and silica to Akiochi soil, growth of rice plant with potassium was remarkably increased, but the growth without potassium was stunted and the number of the tiller was relatively reduced in comparison with that receiving potassium. The minus potassium plant developed tiny brown spots on the leaves and color of the leaves was dark green. They had smaller leaves and shorter stem while heading advanced. Roots with potassium were long and thick, and new ones developed, while roots without K were very poor, the branch and hair roots very thin, and severe root rot was observed. With minus potassium treatment, the root rot of Jin Heung(commercial variety) was more severe than Nonglim 6(Akiochi resistant). Growth of plant without potassium was very poor, and potassium content of the plant was very low, while nitrogen, phosphorus, silica, iron and manganese contents were higher than potassium supplied plant. Application of $Mn+SiO_2$ to Akiochi soil lowered iron content of plant, and iron content of the plant were also reduced by application of potassium. From the results obtained it can be concluded that root damage of minus potassium plant grown in Akiochi soil supplied $Mn+SiO_2$ was caused by potassium deficiency. Potassium, and $Mn+SiO_2$ applications lowered iron content in the plant grown on Akiochi soil.

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Effect of Ultrathin Film HfO2 by Atomic Layer Deposition on the Propreties of ZnS:Cu,Cl Phosphors (ZnS:Cu,Cl 형광체의 특성에 미치는 원자층 증착 초박막 HfO2의 영향)

  • Kim, Min-Wan;Han, Sand-Do;Kim, Hyung-Su;Kim, Hyug-Jong;Kim, Hyu-Suk;Kim, Suk-Whan;Lee, Sang-Woo;Choi, Byung-Ho
    • Korean Journal of Materials Research
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    • v.16 no.4
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    • pp.248-252
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    • 2006
  • An investigation is reported on the coating of ZnS:Cu,Cl phosphors by $HfO_2$ using atomic layer deposition method. Hafnium oxide films were prepared at the chamber temperature of $280^{\circ}C$ using $Hf[N(CH_3)_2]_4\;and\;O_2$ as precursors and reactant gas, respectively. XPS and ICP-MS analysis showed the surface composition of coated phosphor powder was hafnium oxide. In FE-SEM analysis, the surface morphology of uncoated phosphors became smoother and clearer as the number of ALD cycle increased from 900 to 1800. The photoluminescence intensity for coated phosphors showed $7.3{\sim}13.4%$ higher than that of uncoated. The effect means that the reactive surface is uniformly coated with stable hafnium oxide to reduce the dead surface layer without change of bulk properties and also its absorptance is almost negligible due to ultrathin(nano-scaled) films. The growth rate is about $1.1{\AA}/cycle$.

Changes in Agricultural Irrigation Water Quality in Nam River (남강 농업용수의 시기별 수질변화)

  • Lee, Young-Han;Kim, Jong-Gyun;Lee, Han-Saeng;Cho, Dong-Jin;Cho, Ju-Sik;Shin, Yon-Kyo
    • Korean Journal of Environmental Agriculture
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    • v.16 no.3
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    • pp.259-263
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    • 1997
  • To investigate chemical changes of agricultural water in Nam river used for the basic information. Samples were collected from seven sites along the Nam river and were analyzed for inorganic content from April to September in $1994{\sim}1995$. Average value of analyzed inorganic concentrations at seven sampling sites were pH 7.9, COD 7.3mg/l, $NO_3-N$ 1.2mg/l, $Na^+$ 6.2mg/l, $Cl^-$ 14.8mg/l, EC 0.13dS/m, $PO_4\;^{3-}$ 0.21mg/l, $K^+$ 2.6mg/l, $Ca^{2+}$ 10.8mg/l,$Mg^{2+}$ 2.9mg/l, $SO_4\;^{2-}$ 10.5mg/l, $Fe^{3+}$ and $Zn^{2+}$ 0.02mg/l. The monthly average value of COD, $NO_3-N$, $Na^+$ and $Cl^-$ showed highest peak in July $8.4{\sim}11.6$, $1.1{\sim}1.7$, $5.4{\sim}13.1$ $18.9{\sim}27.9mg/l$. The highest region of average COD, $NO_3-N$, $Na^+$ and $Cl^-$ were Weola pumping station, $8.8{\sim}11.3$, $1.6{\sim}2.4$, $9.0{\sim}10.2$ and $21.7{\sim}23.0mg/l.$ The ionic $copmposition({\Sigma}A/{\Sigma}C)$ : ratio between total equivalant of anions and canon) of Nam river was higher at Weola pumping station than other topography. The EC was positively correlated with $K^+$, $Ca^{2+}$, $Mg^{2+}$, $Na^+$, $Cl^-$ and $SO_4\;^{2-}$.

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