• 한국재료학회지
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• 제14권11호
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• pp.813-820
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• 2004

The electrolytic reduction of spent oxide fuel involves the liberation of oxygen in a molten LiCl electrolyte, which is a chemically aggressive environment that is very corrosive for typical structural materials. So, it is essential to choose the optimum material for the process equipment handling molten salt. In this study, corrosion behavior of Haynes 263, 75, and Inconel X-750, 718 in molten salt of $LiCl-Li_{2}O$ under oxidation atmosphere was investigated at $650^{\circ}C\;for\;72\sim360$ hours. At $3\;wt\%\;of\;Li_{2}O$, Haynes 263 alloy showed the highest corrosion resistance among the examined alloys, and up to $8\;wt\%\;of\;Li_{2}O$, Haynes 75 exhibited the highest corrosion resistance. Corrosion products were formed $Li(Ni,Co)O_2,\;LiNiO_2\;and\;LiTiO_2\;and\;Cr_{2}O_3$ on Haynes 263, $Cr_{2}O_3,\;NiFe_{2}O_4,\;LiNiO_2,\;Li_{2}NiFe_{2}O_4,\;Li_{2}Ni_{8}O_10$ and Ni on Haynes 75, $Cr_{2}O_3,\;(Al,Nb,Ti)O_2,\;NiFe_{2}O_4,\;and\;Li_{2}NiFe_{2}O_4$ on Inconel X-750 and $Cr_{2}O_3,\;NiFe_{2}O_4\;and\;CrNbO_4$ on Inconel 718, respectively. Haynes 263 showed local corrosion behavior and Haynes 75, Inconel X-750, 718 showed uniform corrosion behavior.

• 한국세라믹학회지
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• 제31권12호
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• pp.1437-1442
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• 1994

Self propagating synthesis and thermal explosion of combustion reactions were applied to Al/K2Cr2O7/Al2O3 system as the first stage for a production of magnesia-chromium refractory. Several factors related to products made by two combustion reactions were considered and properties of products were characterised. Two processes were required to preheat upto at least 80$0^{\circ}C$ for the thermal explosion and the self propagating synthesis. These processes were so violent and explosive that alumina as diluent was added to the system in order to absorb the reaction heat and reduce the reaction rate. The products consisted of crystal phases of KAl5O8, Cr2O3, Al2O3, K2CrO4, and K2Al2O4.3H2O. The amount of KAl5O8 and K2Al2O4.3H2O crystal phases of products were decreased with further addition of alumina.

• 한국세라믹학회지
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• 제48권4호
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• pp.298-302
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• 2011

This study developed a pigment by doping Cr to Pyrochlore-type stannate crystals and investigated the chromogenic relationship in a glaze. Crystal phases of the pigment according to firing temperatures were analyzed by XRD, and the doping relationship was analyzed by Raman Spectroscopy. Color and reflection rate of the pigment were measured by UV-vis Spectrophotometer. Consequently, stannate characteristic band appeared at 307, 408, 505 and $755cm^{-1}$ until 0.1 mole substitution of $Cr_2O_3$. However, as amount of $Cr_2O_3$ increased, the stannate characteristic peak was decreased and shift happened at the left hand side due to Cr-dope. In composition of 0.12~0.14 mole substituted, the unreacted $Cr_2O_3$ stannate characteristic peak, which was not engaged, was shown. This result shows the maximum limit of solid solution was 0.1 mole $Cr_2O_3$. The color of the glaze, which was produced by adding 6 wt% of $Y_2Sn_{1.94}Cr_{0.06}O_7$ pigment in a lime or a lime-magnesia glaze and fired the mixture at $1260^{\circ}C$, was grayish pink with $L^*$ 70.29, $a^*$ 5.68 and $b^*$ 6.27. It showed gray with $L^*$ 68.82, $a^*$ 3.07and $b^*$ 8.13 for $Y_2Sn_{1.9}Cr_{0.1}O_7$.

• 한국표면공학회지
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• 제40권5호
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• pp.219-224
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• 2007

The corrosion characteristics of Fe-18Cr-10Ni steels were studied between $600^{\circ}C$ and $1000^{\circ}C$ in Ar+(0.2, 1)%$SG_2$ gas for up to 300 hr in order to employ Fe-18Cr-10Ni steels in the coal-fired power plants. The corrosion resistance of Fe-18Cr-10Ni steels was good due mainly to the high amount of Cr, which formed $Cr_2O_3$ from the initial corrosion stage. Fe in the steels corroded to mainly $Fe_2O_3$ and $Fe_3O_4$. Ni was not susceptible to corrosion under the current corrosion condition. Relatively thin, single-layered scales formed.

• 한국세라믹학회지
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• 제46권6호
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• pp.615-620
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• 2009

The present research was performed to determine the optimal firing condition and holding time for malayaite crystal, which is responsible for the stable pink-red coloration in glaze at high temperatures, using Cr$Cl_3$ as chromophore for the synthesis of $Cr_2O_3-SnO_2-CaO-SiO_2$ system pigments. The malayaite crystal was influenced by the raw materials used for synthesis, firing temperature, and holding time. Thus there are differences in the crystal phase and in the coloration according to the condition of synthesis. When Cr$Cl_3$ was used as chromophore, the pigment could be synthesized at lower temperatures, because Cr$Cl_3$ melts at $1500{^{\circ}C}$, which is much lower than the temperature at which $Cr_2O_3$ melts (higher than $2435{^{\circ}C}$). And the employed Cr ion showed a change in oxidation state. When a mineralizer was used to improve the employment of malayaite and the Cr ion, and the low temperature was maintained at which the malayaite crystal is produced, the production of malayaite crystal was promoted and the employment of chromophore was also promoted in the oxidation state of Cr (IV). The results of the experiment showed that the optimal firing condition was 18 h of holding time at $800{^{\circ}C}$, using Cr$Cl_3$ as chromophore, followed by 2 h at the raised temperature of $1150{^{\circ}C}$. The change in coloration of the Cr (IV) employed by malayaite showed a very rich color of red. Thus it was possible to effectively synthesize sphene-pink pigments with more red tint at a low temperature.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2012년도 춘계학술발표회 논문집
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• pp.167-168
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• 2012

Films of CrN, $Cr_{40}Zr_9N$, and $Cr_{31}Zr_{16}N$ were deposited on a steel substrate by closed field unbalanced magnetron sputtering, and their oxidation behaviors at $700^{\circ}C$ and $800^{\circ}C$ for up to 60h in air were investigated. All the deposited films were composed of the CrN phase. Zirconium atoms in $Cr_{40}Zr_9N$ and $Cr_{31}Zr_{16}N$ films partially dissolved in the CrN phase. They advantageously refined the columnar structure, reduced the surface roughness, and increased the microhardness. The CrN film displayed relatively good oxidation resistance, owing to the formation of the highly protective $Cr_2O_3$ on its surface. The $Cr_{40}Zr_9N$ and $Cr_{31}Zr_{16}N$ films oxidized to $Cr_2O_3$ as the major phase and ${\alpha}-ZrO_2$ as the minor one. They oxidized primarily by the inward transport of oxygen. The addition of Zr could not increase the oxidation resistance of the CrN film, because the formed $ZrO_2$ that was intermixed in the $Cr_2O_3$-rich oxide layer was oxygen permeable, and developed the compressive stress in the oxide scale owing to the volume expansion during its formation.

• 한국세라믹학회지
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• 제39권1호
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• pp.79-85
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• 2002

플라즈마 용사코팅법을 이용하여 산화몰리브덴이 첨가된 크로미아 용사코팅층을 제조하여 MoO$_3$첨가에 따른 마찰, 마멸특성을 조사하였다. 상온 마찰, 마멸특성에 대한 실험을 위하여 왕복동 마멸시험장치를 사용하였다. 마멸시험후 마멸면의 물리적 변화와 화학적 조성의 변화를 SEM와 XPS를 통하여 살펴보았다. 산화몰리브덴이 첨가된 코팅층에서 마찰계수의 감소를 관찰할 수 있었다. 그러나 마멸량의 경우 산화몰리브덴이 첨가되지않은 크로미아 코팅층에서 가장 낮은 값을 나타내었다. 산화몰리브덴이 첨가된 코팅의 마멸된 표면에 마탈, 마멸에 유리한 보호막의 형성이 광범위하게 일어남을 알 수 있었다. 이러한 보호막에 산화몰리브덴이 MoO$_3$의 형태로 존재하는 것을 XPS분석을 통하여 알 수 있었다. 보호막에 산화몰리브덴의 존재가 마찰계수를 감소시키는 것으로 생각된다.

• Bulletin of the Korean Chemical Society
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• 제11권4호
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• pp.318-323
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• 1990

The bis(malonato)diaquochromate(III) ion, $Cr(C_3H_2O_4)_2^-$ in acidic solution hydrolyzes to give $Cr(C_3H_2O_4)^{+}.$ This reaction is catalyzed by ferric ion and the rate law for this cation catalyzed-aquation in a $HClO_4/NaClO_4$ medium, $I = 1.00 M, is-d[Cr(C_3H_2O_4)_2^-]/dt = ({\kappa}_1[Fe^{3+}] + {\kappa}_2[H^+])[Cr(C_3H_2O_4)_2^-]$ where ${\kappa}_1(25^{\circ}C) = 4.72×10^{-5} M^{-1}sec^{-1} ({\Delta}H^{\neq} = 22.5 Kcal/mol, {\Delta}S^{\neq} = - 2.58 eu) and {\kappa}_2(25^{\circ}C) = 4.75{\times}10^{-5} M^{-1}sec^{-1} ({\Delta}H^{\neq} = 21.2 Kcal/mol, {\Delta}S^{\neq} = - 7.13 eu).$ Rapid preequilibrium association of basic Cr-bound oxygen with $Fe^{3+},$ followed by rate-determining ring opening, is proposed to account for the ${\kappa}_1,$ hydrolysis pathway.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2004년도 하계학술대회 논문집 C
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• pp.1631-1633
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• 2004

The surge current characteristics of ZnO-$Pr_6O_{11}$-CoO-$Cr_2O_3-Dy_2O_3$-based varistors were investigated with various $Dy_2O_3$ contents. The sintered density decreased in the range of $5.2{\sim}4.6g/cm^3$ with increasing $Dy_2O_3$ content. The incorporation of $Dy_2O_3$ markedly enhanced the nonlinear properties of varistors above 10 times in nonlinear exponent, compared with the varistor without $Dy_2O_3$. The varistor ceramics doped with 0.5 mol% $Dy_2O_3$ exhibited the highest electrical stability. However, the remainder varistors resulted in thermal runaway due to low density of varistor ceramics. The clamping voltage ratio exhibited a minimum value of 2.03 in 1.0 mol% $Dy_2O_3$ at surge current of 100 A(8/20 ${\mu}s$).

• Elastomers and Composites
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• 제50권1호
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• pp.7-12
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• 2015

The $BaCrO_4$ nanoparticles were synthesized from a 0.1 M $K_2CrO_4$ and 0.1 M $BaCO_3$ solution with stirring for 10 h. The product was washed several times with acetone and heated to $700^{\circ}C$ for 6 h. At that time, the color of mixture was a greenish yellow. The graphene/$BaCrO_4$ nanocomposites were prepared with graphene and $BaCrO_4$ nanoparticles by stirring in tetrahydrofuran and heated in an electric furnace at $700^{\circ}C$ for 2 h. The $BaCrO_4$ nanoparticles, graphene/$BaCrO_4$ and heated graphene/$BaCrO_4$ nanocomposites were characterized by X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The graphene/$BaCrO_4$ nanocomposites and heated graphene/$BaCrO_4$ nanocomposites were evaluated as a photocatalyst and discussed about kinetics study for the degradation of organic dyes, such as methylene blue and rhodamine B under ultraviolet light irradiation at 254 nm.