• Title/Summary/Keyword: $CcH_2$

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Components in Chinese Cabbage (Brassica rapa ssp. campestris) as Affected by Soil pH: 6.9 vs. 7.6 (토양의 pH (6.9 vs. 7.6)에 의한 배추 (Brassica rapa ssp. campestris) 의 성분에 대한 영향)

  • Jo, Man-Hyun;Ham, In-Ki;Lee, Eun-Mo;Lee, Jo-Eun;Jiang, Nan;Lim, Yong-Pyo;An, Gil-Hwan
    • Korean Journal of Agricultural Science
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    • v.37 no.1
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    • pp.73-80
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    • 2010
  • Functional and nutritional components of 7 cultivars of Chinese cabbage (CC; Brassica rapa subspecies campestris) from China were analyzed to compare the effects of soil pH (6.9 vs. 7.6). The CC grew on the soil of pH6.9 (CC-6.9) contained significantly increased amounts (2.3~4-fold) of pectin, crude protein, vitamin C and vitamin E compared to the control. The contents of ash and minerals (Ca, Fe, Na, Zn, K and Mn) were also significantly increased in CC-6.9. However, CC-6.9 contained 16-75% lower contents of reducing sugars, cellulose and crude fat than CC-7.6. CC-7.6 contained more glucosinolates than CC-6.9; gluconasturtiin (20.68 vs. 0.84 $nmol{\cdot}g^{-1}$ wet wt) and gluconapin (202.55 vs. 0.15 $nmol{\cdot}g^{-1}$ wet wt). In conclusion, CC-6.9 had an improved texture (high pectin and low cellulose) and nutritional value (high in protein, Ca, Fe, Zn, vitamin C, and E), whereas CC-7.6 had better taste (high in reducing sugars) and anticancer functionality (high in glucosinolates).

Theoretical Investigation for the Structures and Binding Energies of H2O3 and Water (H2O) Clusters (H2O3과 물(H2O) 클러스터들의 분자구조와 열역학적 안정성에 대한 이론적 연구)

  • Seo, Hyun-il;Kim, Jong-Min;Song, Hui-Sung;Kim, Seung-Joon
    • Journal of the Korean Chemical Society
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    • v.61 no.6
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    • pp.328-338
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    • 2017
  • The density functional theory(DFT) and ab initio calculations have been applied to investigate hydrogen interaction of $H_2O_3(H_2O)_n$ clusters(n=1-5). The structures, IR spectra, and H-bonding energies are calculated at various levels of theory. The $trans-H_2O_3$ monomer is predicted to be thermodynamically more stable than cis form at the CCSD(T)/cc-pVTZ level of theory. For clusters, the geometries are optimized at the MP2/cc-pVTZ level of theory. The binding energy of $H_2O_3-H_2O$ cluster is predicted to be -6.39 kcal/mol at the CCSD(T)//MP2/cc-pVTZ level of theory after zero-point vibrational energy (ZPVE) and basis set superposition error (BSSE) correction. This result implies that $H_2O_3$ is a stronger proton donor(acid) than either $H_2O$ or $H_2O_2$. The average binding energies per $H_2O$ are predicted to be 8.25 kcal/mol for n=2, 7.22 kcal/mol for n=3, 8.50 kcal/mol for n=4, and 8.16 kcal/mol for n=5.

Effect of pre-planting liming fertilization in peatmoss based substrates on plug seeding growth of 'Red Madness' petunia and changes in soil chemical properties (피트모스 혼합상토에 기비로 혼합된 석회질 비료가 'Red Madness' 페튜니아 플러그 묘 생장과 상토화학성에 미치는 영향)

  • Lee, Poong-Ok;Lee, Jong-Suk;Choi, Jong-Myung
    • Korean Journal of Agricultural Science
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    • v.38 no.1
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    • pp.17-23
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    • 2011
  • This research was conducted to investigate the influence of application rate of liming fertilizers on changes in soil chemical properties and growth of 'Red Madness' petunia in plug production. To achieve this, dolomite (DO) with 0, 1.0, 3.5, 8.0 or 13.0 $g{\cdot}L^{-1}$ and calcium carbonate (CC) with 0, 2.0, 2.5, 3.0, 3.5, or 4.0 $g{\cdot}L^{-1}$ were incorporated into peatmoss + vermiculite (1:1, v/v) during the root substrates formulation. The treatments of 3.5 $g{\cdot}L^{-1}$ of DO and 2.5 or 3.0 $gL^{-1}$ of CC had acceptable ranges of pH and EC in soil solution such as 5.6~6.2 and 0.7~1.0 $dS{\cdot}m^{-1}$, respectively. The faster rising of pH was observed in root media containing CC rather than those of DO. This indicates that the solubility of CC is higher than DO. The soil Ca concentrations in all treatments of CC were 1.8 times as high as those of DO. The treatments of 3.5 or 8.0 $g{\cdot}L^{-1}$ of DO had the highest soil Mg concentrations, but all treatments of CC had lower soil Mg concentrations than control treatment indicating that additional application of Mg fertilizers are required. The elevated application rate of DO or CC resulted in the increase of fresh and dry weight. But plant heights were not influenced by application of liming fertilizers. The results of tissue analysis showed that application of DO or CC influenced the $PO_4{^-}P$, Ca and Mg contents, but not influenced the contents of other nutrients such as N, P, Fe, Mn, Zn and Cu.

Impact of Application Rates of Pre-planting Liming Fertilizers on Changes in Soil Chemical Properties and Growth of 'Melody Yellow' Pansy in Plug Production (팬지 'Melody Yellow'의 플러그 육묘시 석회질 비료의 시비수준이 토양화학성 변화와 식물생장에 미치는 영향)

  • Lee, Poong-Ok;Lee, Jong-Suk;Choi, Jong-Myung
    • Horticultural Science & Technology
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    • v.28 no.5
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    • pp.735-742
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    • 2010
  • Objective of this research was to investigate the influence of liming fertilizers on changes in soil chemical properties and growth of pansy 'Melody Yellow' in plug production. To achieve this, dolomite (DO) with 0, 1.0, 3.5, 8.0 or $13.0g{\cdot}L^{-1}$ and calcium carbonate (CC) with 0, 2.0, 2.5, 3.0, 3.5, or $4.0g{\cdot}L^{-1}$ in application rate were incorporated into peatmoss + vermiculite (1:1, v/v) during the formulation. The treatments of $3.5g{\cdot}L^{-1}$ of DO and 2.5 or $3.0g{\cdot}L^{-1}$ of CC had acceptable range of soil solution pH such as 5.6-6.2. Faster rising of pH was observed in root media containing CC rather than those of DO, indicating higher solubility of CC. The soil Ca concentrations in all treatments of CC were 2 times as high as those of DO. The treatments of 3.5 or $8.0g{\cdot}L^{-1}$ of DO had the highest soil Mg concentrations, but all treatments of CC had lower soil Mg concentrations than control indicating that additional applications of Mg fertilizers are required. The elevated application rate of DO or CC resulted in the increase of fresh and dry weight; however, plant heights were not influenced by application of liming fertilizers. The results of tissue analysis showed that application of DO or CC influenced the Ca and Mg contents, but did not influence the contents of other nutrients such as N, P, Fe, Mn, Zn and Cu.

Efficacy of Clomiphene Citrate Stimulated Cycle in Poor Responders in in vitro Fertilization (Poor Responder 환자에서 Clomiphene Citrate 주기와 Controlled Ovarian Hyperstimulation 주기의 체외수정 결과 비교)

  • Song, Ji-Hong;Koong, Mi-Kyoung
    • Clinical and Experimental Reproductive Medicine
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    • v.25 no.3
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    • pp.239-244
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    • 1998
  • The purpose of this study is compare IVF cycle outcome in poor responders between clomiphene citrate (CC) stimulated and controlled ovarian hyperstimulation (COH) protocol. A total of 94 patients responding poorly in previous IVF cycles (estradiol<600 pg/ml or less than 3 oocytes retrieved) subsequently underwent either COH (COH group: 122 cycles, 68 patients) or CC-stimulated cycles (CC group: 43 cycles, 26 patients). CC was administered for five consecutive days starting on cycle day 3 at a dose of 100 mg daily. Serial transvaginal ultrasound examination was done from cycle day 8. Urine was collected $3\sim4$ times before hCG injection for the detection of LH surge. The hCG was administered when serum estradiol reached greater than 150 pg/ml and mean follicle diameter>16 mm. In COH group, ovarian stimulation was done using short protocol (GnRH-a/FSH/HMG/hCG). No difference in age or number of transferred embryos was found between CC group and COH group. COH group had significantly (p<0.05) higher mean peak level of $E_2$ ($810{\pm}112$ vs $412{\pm}55$ pg/ml) and greater number of retrieved oocytes ($3.0{\pm}0.2$ vs $2.0{\pm}0.2$) than CC group. CC group had transferred embryos $(1.8{\pm}0.2)$ compared with $(2.1{\pm}0.2)$ in COH group. However, CC group had higher pregnancy rate than COH group per retrieval [26.9% (7/26) vs 6.2% (6/97)], or per transfer [31.8% (7/22) vs 7% (6/86)]. Although cycle cancellation rate in CC group (48.8%) was higher than that of COH group (21.3%), the pregnancy rate per cycle in CC group was still higher (16.3%) than COH group (4.9%). In addition, implantation rate in CC group was 17.5% (7/40), which was significantly (p<0.01) higher than 3.9% (7/180) in COH group. These data suggest that oocyte and embryo quality are lower in COH cycles of poor responders than CC cycles. We suggest that clomiphene citrate stimulated IVF cycle may be more efficient than COH IVF cycle in poor responders in terms of lower costs and higher pregnancy performance.

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Cultural Characteristics and Mechanism of Bacillus amyloliquefacien subsp. plantarum CC110 for Biological Control of Cucumber Downy Mildew (Bacillus amyloliquefaciens subsp. plantarum CC110균주의 오이 노균병 발생 억제기작 및 배양적 특성)

  • Lee, Sang Yeob;Weon, Hang Yeon;Kim, Jeong Jun;Han, Ji Hee
    • The Korean Journal of Pesticide Science
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    • v.17 no.4
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    • pp.428-434
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    • 2013
  • An isolate of Bacillus amyloliquefaciens subsp. plantarum CC110 was selected as an effective antagonist for biological control of cucumber downy mildew caused by Pseudoperonospora cubensis. Temperature range for growth of CC110 isolate was $7.5{\sim}55.0^{\circ}C$, and its optimal temperature at $36.6^{\circ}C$. pH range for growth of CC110 isolate was 4.5~9.5, and its optimal pH at 7.0. In this study, the most effective sources of carbon and nitrogen for growth of CC110 isolate were fructose and yeast extract, respectively. The volatile of CC110 isolate was found to be effective to control downy mildew on cucumber showing no diseased area whereas that of control was 13.2% using the I plate bioassay. The culture broth and cells of isolate CC110 cultured in TSB media for 48 hours at $28^{\circ}C$ inhibited occurrence of cucumber downy mildew. The cells and culture broth were transformed into sporangia of P. cubensis by in observation under light microscope and scanning electron microscope.

Biohydrogen production from engineered microalgae Chlamydomonas reinhardtii

  • Kose, Ayse;Oncel, Suphi S.
    • Advances in Energy Research
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    • v.2 no.1
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    • pp.1-9
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    • 2014
  • The green microalgae Chlamydomonas reinhardtti is well-known specie in the terms of $H_2$ production by photo fermentation and has been studying for a long time. Although the $H_2$ production yield is promising; there are some bottlenecks to enhance the yield and efficiency to focus on a well-designed, sustainable production and also scaling up for further studies. D1 protein of photosystem II (PSII) plays an important role in photosystem damage repair and related to $H_2$ production. Because Chlamydomonas is the model algae and the genetic basis is well-studied; metabolic engineering tools are intended to use for enhanced production. Mutations are focused on D1 protein which aims long-lasting hydrogen production by blocking the PSII repair system thus $O_2$ sensitive hydrogenases catalysis hydrogen production for a longer period of time under anaerobic and sulfur deprived conditions. Chlamydomonas CC124 as control strain and D1 mutant strains(D240, D239-40 and D240-41)are cultured photomixotrophically at $80{\mu}mol\;photons\;m^{-2}s^{-1}$, by two sides. Cells are grown in TAP medium as aerobic stage for culture growth; in logarithmic phase cells are transferred from aerobic to an anaerobic and sulfur deprived TAP- S medium and 12 mg/L initial chlorophyll content for $H_2$ production which is monitored by the water columns and later detected by Gas Chromatography. Total produced hydrogen was $82{\pm}10$, $180{\pm}20$, $196{\pm}20$, $290{\pm}30mL$ for CC124, D240, D239-40, D240-41, respectively. $H_2$ production rates for mutant strains was $1.3{\pm}0.5mL/L.h$ meanwhile CC124 showed 2-3 fold lower rate as $0.57{\pm}0.2mL/L.h$. Hydrogen production period was $5{\pm}2days$ for CC124 and mutants showed a longer production time for $9{\pm}2days$. It is seen from the results that $H_2$ productions for mutant strains have a significant effect in terms of productivity, yield and production time.

Properties of Optically Selected Supernova Remnants in M31

  • Lee, Jong Hwan;Lee, Myung Gyoon
    • The Bulletin of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.61.2-61.2
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    • 2013
  • We present a study of optically emitting supernova remnants (SNRs) in M31 based on $H{\alpha}$ and [S II] images in the Local Group Survey. Using these images, we have selected objects that have [S II]:$H{\alpha}$ > 0.4 and morphology for typical SNRs. We find 76 new SNRs. We have also inspected 233 SNR candidates presented in previous studies, confirming that only 80 of them are SNRs. Combining these, we produce a master catalog of 156 SNRs in M31. We classify these SNRs according to two types of criteria: the SNR progenitor types (Type Ia and core-collapse (CC) SNRs) and the morphological types. Type Ia and CC SNRs are 23% and 77%, respectively, of the total sample. Most of CC SNRs are concentrated along the spiral arms, while Type Ia SNRs are rather spread over the entire galaxy including the inner region. CC SNRs are brighter in $H{\alpha}$ and [S II] than Type Ia SNRs. The cumulative size distribution of the SNRs with 15 < D < 50 pc is well fitted by a power law with an index, ${\alpha}=2.53{\pm}04$. It indicates that most SNRs in M31 are in Sedov-Taylor phase. Properties of these SNRs show little variation depending on the galactocentric distance. The $H{\alpha}$ and [S II] surface brightness shows a good correlation with X-ray luminosity for the SNRs that are center-bright.

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Theoretical Study for the Structures and Binding Energies of HOOO-(H2O)n (n=1~5) Cluster (HOOO-(H2O)n (n=1~5) 클러스터의 구조와 에너지에 대한 이론적 연구)

  • Kim, Jong-Min;Hong, Sung-Yoon;Kim, Seung-Joon
    • Journal of the Korean Chemical Society
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    • v.59 no.5
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    • pp.387-396
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    • 2015
  • The DFT and ab initio calculations have been performed to elucidate hydrogen interaction of HOOO-(H2O)n (n=1~5) clusters. The optimized geometries, harmonic vibrational frequencies, and binding energies are predicted at various levels of theory. The trans conformer of HOOO monomer is predicted to be thermodynamically more stable than cis form at the CCSD(T) level of theory. For HOOO-(H2O)n clusters, the geometries are optimized at B3LYP/aug-cc-pVTZ and CAM-B3LYP/aug-cc-pVTZ levels of theory. The binding energy of HOOO-H2O cluster is predicted to be 6.05 kcal/mol at the MP2//CAM-B3LYP/ aug-cc-pVTZ level of theory after zero-point vibrational energy (ZPVE) and basis set superposition error (BSSE) correction. The average binding energy per H2O is increased according to adding a H2O moiety in HOOO-(H2O)n clusters up to 7.2 kcal/mol for n=5.

Atom Number Densities for Uranyl Nitrate Solution (질산우라늄용액의 구성원소별 원자수밀도)

  • Seung Gy Ro;Duck Kee Min;Jung-Kyoon Chon
    • Nuclear Engineering and Technology
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    • v.14 no.3
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    • pp.103-109
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    • 1982
  • An empirical formula for determining water content as functions of uranium concentration and nitric acid normalities in uranyl nitrate solutions has been derived from a least-squares analysis of experimental data, i.e., uranium concentration, nitric acid normalities and solution densities for a large number of UO$_2$(NO$_3$)$_2$ solutions. The formula derived is Q=1-0.3628C-0.0327H$^{+}$ where Q, C, and H$^{+}$ stand for water content (g/cc), uranium concentration (g/cc), ana nitric acid normality, respectively. Atom number densities and nuclear criticality for hypothetical uranyl nitrate solutions have been calculated by using the empirical formula, ana compared with the results obtained on the basis of uranium concentration, nitric acid normality, and solution density. The empirical formula derived in this study seems to be useful in uranium concentrations ranging from 0.295g/cc down to 0.004g/cc and nitric acid normality from 5.06 to 1.00..00.

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