• The Korean Journal of Ceramics
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• 제5권2호
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• pp.125-130
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• 1999

After $SnO_2$ fine powder by precipitation method, Ca as crystallization inhibitor and Pd as catalyst were added to $SnO_2$ raw material by various methods. Thick film device was fabricated on the alumina substrate by mixing ethylene glycol and such mixed powders. The sensing characteristics of the device for methane gas were investigated. The most excellent gas sensing property was shown by the thick film device fabricated by Method 3 in which Ca and Pd doped $SnO_2$ powder is prepared by mixing $SnO_2$ powder, 0.1 wt% Ca acetate and 1 wt% $PdCl_2$ in deionized water and by calcining the mixture, after $Sn(OH)_4$ is dried at $110^{\circ}C$ for 36h. The sensitivity of the sensor fabricated with $SnO_2$-0.1 wt%Ca acetate-1wt%$PdCl_2$ powder heat-treated at $700^{\circ}C$ for 1h was about 86% for 5,000 ppm methane in air at $350^{\circ}C$ of the operating temperature. Response time and recovery were also excellent.

• 센서학회지
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• 제17권5호
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• pp.361-368
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• 2008

Nanosized $SnO_2$ particles were synthesized by homogeneous precipitation method using tin chloride ($SnCl_4{\cdot}5H_{2}O$) and urea ($CO(NH_2)_2$). The powders were heated at $500^{\circ}C$ and $600^{\circ}C$ for 2h. The crystal structure, microstructure, thermal behavior, specific surface area were analyzed using XRD, FE-SEM, TGA and BET, respectively. The initial resistance and the $H_2$ sensing properties were measured as a function of ${Sb_2}{O_3}$ and Pd doping concentrations. The resistance was decreased with the addition of ${Sb_2}{O_3}$ and the sensitivity for $H_2$ gas was increased with the addition of Pd. Thus, the optimum $H_2$ gas sensing property was obtained in the 0.25.mol% ${Sb_2}{O_3}$ and 1.w% added $SnO_2$ powders.

• Bulletin of the Korean Chemical Society
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• 제26권2호
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• pp.278-280
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• 2005

To obtain cytochrome $c_3$ labeled with a stable isotope, the conditions of cultivation and the composition of medium for DvMF were examined. The growth of DvMF was steady and reproducible under purging with $N_2$ and under pH control. DvMF was able to go on a defined medium without natural products. The composition of medium containing a small amount of $NH_4C$l as sole nitrogen source was established. Then, uniformly $^{15}N$labeled cytochrome $c_3$ was obtained during the culture of DvMF in a defined medium with $^{15}NH_4$Cl; it was confirmed by $^1H-^{15}N$ HMQC.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1989년도 하계종합학술대회 논문집
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• pp.295-298
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• 1989

Using the anisotropic etching characteristics or $N_2H_4-H_2O$ solution, Si diaphragm was fabricated for the integrated sensor. The optimal composition and temperature of the solution in Si etching process was established to be 50mol% $N_2H_4$ in water at $105{\pm}2^{\circ}C$ for both higher etch rate(=$2.6{\mu}m/min$) and better surface quality of etched {100} planes. Under the optimal etching condition, the electrochemical etch stop technique was employed to form Si diaphragm for pressure sensor and diaphragm thickness was exactly controlled to $20{\pm}2{\mu}m$.

• 대한화학회지
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• 제36권2호
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• pp.218-222
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• 1992

시티딘은 장미조직이 가지고 있는 시티딘 디아미나제에 의해 우리딘과 암모니아 기체를 생성한다. 이 장미조직 50mg을 암모니아 기체감응센서에 고정시켜 장미조직센서를 제조하고, 수용액 중의 시티딘을 정량하는데 최적 실험조건을 조사하였다. pH8.4, 온도 37$^{\circ}C$, 0.2M 인산 완충용액을 사용하였을 때 시티딘의 농도가 $7.0 {\times}10^{-4}$에서 $1.0{\times}10^{-2}$M까지 직선이었고, 53mV/decade의 감응기울기를 나타내었다. 검출한계는 $3.0 {\times} 10^{-4}$ M 상대표준편차는 3.4%였다. 또한 이 조직센서는 선택성이 탁월하였다.

• 한국세라믹학회지
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• 제36권3호
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• pp.237-243
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• 1999

스크린 프린팅법을 이용하여 NOX 감지용 WO3 후막형 가스센서를 제조하였다. 본 실험에서는 감지막의 소성 온도에따른 감도변화 및 Ru을 첨가함으로써 감도의 증진을 중점적으로 조사하였다. 또한 NO2 50 ppm하에서 CO, H2, CH4 그리고 i-C4H10등의 가스에 대하여 cross sensitivity를 조사하였다. WO3 가스센서는 소성온도 50$0^{\circ}C$, 작동온도 30$0^{\circ}C$에서 최대감도를 얻었다. 순수한 WO3에 Ru(0.004 wt%)을 첨가시 NO2 및 NO 가스에 대한 감도가 크게 증진되었다. 그러나 순수한 WO3 센서는 Ru(0.004 wt%)이 첨가된 WO3 센서보다 더 우수한 cross sensitivity를 보였다.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2005년도 춘계학술발표대회 논문집
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• pp.25-28
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• 2005

The optical fiber is known for the proper sensor which can accomplish the structural health monitoring, Fiber Bragg Grating sensors are being studied more than any other fiber optic sensors due to good multiplexing capabilities. But because the signal stability of FBG sensors can be influenced by the strain gradient, it needs to analyze signal of FBG sensors. Particularly acoording to strain gradient induced by structural geometry or cracks, the spectrum peak of the FBG sensor signal can be split easily. In this paper, the spectrum analysis of the FBG sensor signal was performed and the region of embedment of FBG sensors was determined in $H_2$ pressure vessel by numerical method.

• 한국균학회지
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• 제23권4호통권75호
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• pp.354-358
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• 1995

용존 유기물의 농도를 BOD로 신속히 측정하여 폐수처리 공정에 feed back할 수 있는 Yeast BOD sensor 를 제작하여 BOD 측정의 거동을 조사하였다. BOD sensor의 감응도는 yeast의 활성이 가장 높은 pH 7.0 및 온도 $30^{\circ}C$에서 가장 높게 나타났다. Sensor에 충전되는 효모의 양도 감응도에 영향을 미치며 투석막 단위면적당 $ 0.14\;mg/cm^2$가 최적의 균체량이었다. 오염물질의 종류에 따라 BOD sensor의 출력 신호가 다르게 나타났으며 각각의 오염물질 속에 효모균를 전처리 시킨 후 sensor에 충전할 경우 sensor 의 감응도가 크게 증가하였다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1997년도 하계학술대회 논문집 C
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• pp.1304-1307
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• 1997

A hydrogen gas sensor utilizing Pt/$SnO_2$ system was fabricated by the pressed pellet method. The crystal structure, direction of the crystal, crystal size and microstructure between the catalyst and the support ($SnO_2$) were characterized with Electron Diffraction Analysis, Transmission Electron Microscopy, Scanning Electron Microscopy. After the reactor with a Pt/$SnO_2$ sample was run with a flow rate of 30sccm (a mixture of $0.5%H_2$ in $N_2$) for a while, the resistance of $SnO_2$ was saturated, but the $SnO_2$ kept absorbing $H_2$ gas. $H_2$ gas sensing properties of Pt/$SnO_2$ were investigated at several temperatures. As a result, it was observed that Pt/$SnO_2$ has high sensitivity at $300^{\circ}C$ and $400^{\circ}C$.

• 센서학회지
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• 제17권4호
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• pp.295-302
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• 2008

$TiO_2,\;ZrO_2$, and $SiO_2$ were added in the concentration of 1 - 3 wt.% to improve long-term stability for the $SnO2$ thick film gas sensor. Short-term sensor resistances up to 90 h were measured to investigate the stabilization time of initial resistance in air. Long-term resistance drifts in air and in gas to 5000 ppm methane for the sensors annealed at $750^{\circ}C$ for 1 h and continuously heated at an operating temperature of $400^{\circ}C$ were also measured up to 90 days at an interval of 1 day. The long-term drifts in methane sensitivity for the three metal oxide-doped $SnO2$ sensors are closely related to methane sensitivity level, catalytic activity, and long-term drift in sensor resistance in air. Those stabilities are mainly discussed in terms of oxidation state and catalytic activity.