• Title/Summary/Keyword: $CO_2$ injection

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Review of the CO2 Geological Storage Using Nanoparticle-stabilized CO2 Foam (나노입자기반 CO2 폼을 이용한 CO2 지중저장에 대한 기술적 고찰)

  • Son, Han Am
    • Economic and Environmental Geology
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    • v.53 no.2
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    • pp.213-220
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    • 2020
  • When CO2 foam is injected into the saline aquifer, the relative permeability of CO2 decreases and its viscosity increases, thereby reducing mobility in porous media and ultimately improving CO2 storge with enhanced sweep efficiency. In general, surfactants were used to fabricate CO2 foam. Recently, nanoparticles have been used to form stable foam than surfactant. This paper introduces CO2 storage technology using nanoparticle stabilized CO2 foam. If the surface of the hydrophilic nanoparticles is partially modified into a CO2-philic portion, the particles have an affinity for CO2 and water, thus forming a stable CO2 foam even in deep saline aquifers under high temperature and high salinity conditions, thereby it can be stored in the pores of the rock. In terms of economics, injection method using nanopaticle-stabilized CO2 foam is more expensive than the conventional CO2 injection, but it is estimated that it will have price competitiveness because the injection efficiency is improved. From an environmental point of view, it is possible to inject chemical substances such as surfactants and nanomaterials into aquifers or reservoirs for specific purposes such as pollutant removal and oil production. However, some studies have shown that nanoparticles and surfactants are toxic to aquatic animals, so environmentally proven substances should be used. Therefore, further research and development will be needed to study the production and injection of nanoparticle-stabilized CO2 foam that are environmentally safe and economically reasonable.

Review on Ocean Carbon Sequestration through Direct Injection (심층 분사를 통한 해양 이산화탄소 격리 기술 소개)

  • Park, Young-Gyu;Choi, Sang-Hwa;Matsumoto, Katsumi;Lee, Jung-Suk;Gang, Seong-Gil;Hwang, Jin-Hwa
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.10 no.2
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    • pp.118-124
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    • 2007
  • The oceans could absorb almost all the anthropogenic carbon dioxide the mankind has been producing eventually, but in the nature the air-sea $CO_2$ exchange occurs very slowly and to lower the atmospheric $CO_2$ concentration substantially $CO_2$ must be injected to the interior of the ocean directly. If we inject $CO_2$ collected at the major $CO_2$ sources into the international waters in the Philippine Sea or east of Japan, we could store the $CO_2$ in the oceans effectively for a few hundred years. When $CO_2$ is dissolved into the water, PH drops. The creatures adapted to the deep oceans where environment is very stable could be affected by even a small change in pH significantly. If, therefore, we are to inject $CO_2$ into the oceans, we must assess the effect of $CO_2$ injection in the marine ecosystem beforehand. Only when the damage to the marine ecosystem is smaller than the benefit from the $CO_2$ injection, $CO_2$ injection is effective.

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SPRAY AND COMBUSTION CHARACTERISTICS OF HYDROCARBON FUEL INJECTED FROM PRESSURE-SWIRL NOZZLES

  • Laryea Gabriel Nii;No Soo-Young
    • Journal of ILASS-Korea
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    • v.9 no.4
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    • pp.31-37
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    • 2004
  • This paper presents spray and combustion characteristics of hydrocarbon fuel injected from pressure-swirl nozzles. Three commercial nozzles with orifice diameters of 0.256, 0.308 and 0.333mm and injection pressures ranging from 0.7 to 1.3 MPa were selected f9r the experiments. Spray characteristics such as breakup length. spray angle and drop size (SMD) were analyzed using photo image analyses and Malvern Panicle Size Analyzer. The drop size was measured with and without a blower at the same measuring locations. The flame length and width were measured using photo image analyses. The temperature distribution along the axial distance and the gas emission such as CO, $CO_2\;and\;NO_x$ were studied. The breakup length decreased with an increase in injection pressure for each nozzle but increased with an increase in nozzle orifice diameter. The spray angle increased and SMD decreased with an increase in injection pressure. The flame with an increased linearly with an increase in injection pressure and in nozzle orifice diameter. The flame temperature increased with an increase in injection pressure but decreased along the axial distance. The maximum temperatures occurred closer to the burner exit and flame at axial distance of 242mm from the diffuser tip. The experimental results showed that the level of CO decreased while that of $CO_2\;and\;NO_x$ increased with an increase in injection pressure and nozzle orifice diameter.

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Combustion Emission Characteristics on the Effect of Secondary Air Injection in Model Gas Turbine Combustor (모형 가스터빈 연소기의 2차공기 주입에 따른 연소배출특성)

  • 김규성;임경달;이도형
    • Journal of Ocean Engineering and Technology
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    • v.14 no.3
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    • pp.84-89
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    • 2000
  • The purpose of this study is to investigate the combustion emission characteristics by the effect of secondary air injection and variation of the excess air ratio in combustion field of model gas turbine combustor. For this purpose, mean temperature, CO, $CO_2$, $O_2$ and HC concentrations were measured by changing excess air ratio and secondary air injection. As a result of this study, mean temperature was decreased and CO, HC emission increased by increasing the excess air ratio of secondary air. Therefore, this results showed the secondary air injection effected strongly on the flame structure and combustion emission characteristics.

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Potentiometric Determination of L-Malate Using Ion-Selective Electrode in Flow Injection Analysis Syste

  • Kwun, In-Sook;Lee, Hye-Sung;Kim, Meera
    • Preventive Nutrition and Food Science
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    • v.4 no.1
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    • pp.79-83
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    • 1999
  • A potentiometric biosensor employing a CO3-2 ion-selective electrode(ISE) and malic enzyme immobilization in al flow injection analysis (FIA) system was constructed. Analytical parameters were optimized for L-malate determination . The CO3-2 -ISE-FIA system was composed of a pump, an injector, a malic enzyme (EC1.1.1.40) reactor, a CO3-2 ion-selective electrode, a pH/mV meter and a recorder. Cofactor NADP was also injected with substrate for theenzyme reaction into the system. Optimized analytical parameters for L-malate determination in the CO3-2 ISE-FIA system were as follows ; flow rate, 14.5ml/hr ; sample injection volume, 100ul; enzyme loading in the reactor, 20 units ; length of the enzyme reactor , 7 cm ; tubing length form the enzyme reactor to the detector as a geometric factor in FIA, 15 cm . The response time for measuring the entire L-malate concentration range (10-2 ~10-5 mol/L ; 4 injections )was <15minutes . In this CO3-2 -ISE-FIA system, the potential differences due to th eformation of CO3-2 by the reaction of malic enzyme on L-malate were correlated to L-malate concentration in the range of 10-2 ~10-5mol/L ; the detection limit was 10-5 mol/L. This potentionmetric CO3-2 ISE--FIA system was found to be useful for L-malate measurement.

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Effects of Die Temperature and CO2 Gas Injection on Physical Properties of Extruded Brown Rice-Vegetable Mix (사출구 온도와 CO2 가스주입이 현미·야채류 압출성형물의 물리적 특성에 미치는 영향)

  • Gil, Sun-Kook;Ryu, Gi-Hyung
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.42 no.11
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    • pp.1848-1856
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    • 2013
  • This study is designed to examine the change in physical properties of extruded brown rice-vegetable mix at different temperatures and $CO_2$ gas injections. Moisture content and screw speed were fixed to 27% and 100 rpm respectively. Die temperatures and $CO_2$ gas injections were adjusted to 60, 80, $100^{\circ}C$ and 0, 150 mL/min, respectively. The ratio of ${\alpha}$-brown rice, brown rice and sugars (oligosaccharides and palatinose) was fixed to 25, 50 and 16%, respectively. Green tea, tomato and pumpkin powder were blended individually at 9%. Specific mechanical energy (SME) input decreased as die temperature for each vegetable addition increased. All extrudates decreased in density and breaking strength, but increased in specific length and water soluble index as $CO_2$ gas injection increased. Elastic modulus decreased as the die temperature and $CO_2$ gas injection increased. Extruded green tea mix with $CO_2$ gas injection at 150 mL/min was larger pore size and higher amount of pore than the tomato and pumpkin extrudates with $CO_2$ gas injection. Cold extrusion with $CO_2$ gas injection at $60^{\circ}C$ die temperature could be applicable for making Saengsik (uncooked food).

Combustion Control through the DME Injection Timing in the Hydrogen-DME Partially Premixed Compression Ignition Engine (DME 분사 시기 조절을 통한 수소-DME 부분 예혼합 압축착화 연소 제어)

  • Jeon, Jeeyeon;Bae, Choongsik
    • Journal of the Korean Society of Combustion
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    • v.18 no.1
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    • pp.27-33
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    • 2013
  • Hydrogen-dimethy ether(DME) partially premixed compression ignition(PCCI) engine combustion was investigated in a single cylinder compression ignition engine. Hydrogen and DME were used as low carbon alternative fuels to reduce green house gases and pollutant. Hydrogen was injected at the intake manifold with an injection pressure of 0.5 MPa at fixed injection timing, $-210^{\circ}CA$ aTDC. DME was injected directly into the cylinder through the common-rail injection system at injection pressure of 30 MPa. DME inejction timing was varied to find the optimum PCCI combustion to reduce CO, HC and NOx emissions. When DME was injected early, CO and HC emissions were high while NOx emission was low. As the DME injection was retarded, the CO and HC emissions were decreased due to high combustion efficiency. NOx emissions were increased due to the high in-cylinder temperature. When DME were injected at $-30^{\circ}CA$ aTDC, reduction of HC, CO and NOx emissions was possible with high value of IMEP.

Laboratory study of $CO_2$ migration in water-saturated anisotropic sandstone, based on P-wave velocity imaging (P-파 속도 영상화에 근거한 물로 포화된 이방성 사암에서의 $CO_2$ 이동에 관한 실험 연구)

  • Xue, Ziqiu;Lei, Xinglin
    • Geophysics and Geophysical Exploration
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    • v.9 no.1
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    • pp.10-18
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    • 2006
  • We measured the changes in P-wave velocity that occur when injecting $CO_2$ in gaseous, liquid, and supercritical phases into water-saturated anisotropic sandstones. P-wave velocities were measured in two cylindrical samples of Tako Sandstone, drilled along directions normal and parallel to the bedding plane, using a piezo-electric transducer array system. The velocity changes caused by $CO_2$ injection are typically -6% on average, with maximum values about -16% for the case of supercritical $CO_2$ injection. P-wave velocity tomograms obtained by the differential arrival-time method clearly show that $CO_2$ migration behaviour is more complex when $CO_2$ flows normal to the bedding plane than when it flows parallel to bedding. We also found that the differences in P-wave velocity images were associated both with the $CO_2$ phases and with heterogeneity of pore distribution in the rocks. Seismic images showed that the highest velocity reduction occurred for supercritical $CO_2$ injection, compared with gaseous or liquid $CO_$ injection. This result may justify the use of the seismic method for $CO_2$ monitoring in geological sequestration.

Spin injection and transport properties of Co/Au/Y$Ba_2$$Cu_3$$O_y$ tunnel junctions

  • Lee, Kiejin;Kim, Sunmi;Ishibashi, Takauki;Cha, Deokjoon
    • Progress in Superconductivity
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    • v.3 no.1
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    • pp.70-73
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    • 2001
  • We report the spin injection and transport properties of three terminal devices of Co/Au/$YBa_2$$Cu_3$$O_{y}$(F/N/S) tunnel junctions by injection of spin-polarized quaiparticles using a cobalt ferromagnetic injector. The observed current gain depends on the thickness of Au interlayer and is directly related to the nonequilibrium magnetization due to spin relaxation effects. The tunnel characteristic of a F/N/S tunnel junctions exhibited a zero bias conductance peak (ZBCP). The suppression of the ZBCP was observed due to the suppression of Andreev reflection at the interface, which is due to the spin scattering processes at the interface between a ferromagnetic and a d-wave superconductor.r.

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The Performance Evaluation of In-situ Carbonation Mortar Using Gaseous CO2 (기체 CO2를 사용한 In-situ 탄산화 모르타르 성능평가)

  • Changgun Park;Deukhyun Ryu;Seongwoo Choi;Kwangwoo Wi;Seungmin Lim
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.3
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    • pp.226-233
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    • 2023
  • In this study, two phases were conducted to investigate the direct injection of gaseous CO2 into cement mortar. The aim was to advance carbon capture, utilization, and storage (CCUS) technology by harnessing industrial waste CO2 from the domestic ready-mixed concrete industry. In the first phase, the factors influencing the physical properties of cement mortar when using gaseous CO2 were identified. This included a review of materials to achieve physical properties comparable to a reference formulation. As a result of this phase, it was confirmed that traditional approaches, such as adjusting the water-to-cement ratio, had limitations in achieving the desired physical properties. Consequently, the second phase focused on the optimization of CO2-injected mortar. This involved studying the CO2 application and mixing method for cement mortar. Changes in properties were observed when gaseous CO2 was injected into the mortar. The optimal injection quantity and time to enhance the compressive strength of mortar were determinded. As a result, this study indicated that an extra mixing time exceeding 120 seconds was necessary, compared to conventional mortar. The optimal CO2 injection rate was identified as 0.1 to 0.2 % by weight of cement, taking both flowability and compressive strength performance into account. Increasing the CO2 injection time did not further enhance strength. For this approach to be employed as a CCUS technology, additional studies are required, including a microstructural analysis evaluating the amount of immobilized CO2.