• Title/Summary/Keyword: $CO_2$ Recovery

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Vacuum Stripping of $CO_2$ from Aqueous MEA Solutions Using PDMS-PE Composite Membrane Contactor (MEA 수용액으로부터 PDMS-PE 복합막 접촉기를 이용한 이산화탄소 감압탈거)

  • Kim, Jeong-Hoon;Ahn, Hyo-Seong;Kim, Jeong-Hoon
    • Membrane Journal
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    • v.22 no.1
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    • pp.46-53
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    • 2012
  • Low-temperature carbon dioxide stripping by a vacuum membrane stripping technology was studied as a substitute for the stripping process in a conventional aqueous amine process. Composite membranes with $5{\mu}m$ thickness of PDMS (polydimethylsiloxane) dense layer on a PE (polyethylene) support layer were prepared by a casting method and used as a membrane contactor for $CO_2$ stripping. Aqueous amine solutions of 30 wt% MEA (monoethanolamine) were used as absorbents. $CO_2$ flux was examined under various operating conditions by varying the vacuum pressure (60~360 mmHg (abs.)), stripping temperature ($25{\sim}80^{\circ}C$), $CO_2$ loading (0.5~0.7). $CO_2$ stripping flux increased with increasing temperature and $CO_2$ loading as well as decreasing vacuum pressure. PDMS-PE composite membrane has stability for vacuum stripping process compared with PTFE porous membrane.

Study on the Characteristics of Catalyst Reaction for Hydrogen Recovery from Nuclear Fusion Exhaust Gas (핵융합 배가스 중 수소 회수를 위한 촉매반응 특성 연구)

  • JUNG, WOOCHAN;JUNG, PILKAP;KIM, JOUNGWON;MOON, HUNGMAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.5
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    • pp.402-408
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    • 2015
  • In D-T fusion reaction, $D_2$ (duterium) and $T_2$(tritium) are used as fuel gas. The exhaust gas of nuclear fusion includes hydrogen isotopes $Q_2$ (Q means H, D or T), tritiated components ($CQ_4$ and $Q_2O$), CO, $CO_2$, etc. All of hydrogen isotopes should be recovered before released to the atmosphere. This study focused on the recovery of hydrogen isotopes from $CQ_4$ and $Q_2O$. Two kinds of experiments were conducted to investigate the catalytic reaction characteristics of SMR (Steam Methane Reforming) and WGS (Water Gas Shift) reactions using Pt catalyst. First test was performed to convert $CH_4$ into $H_2$ using 6% $CH_4$, 6% CO/Ar feed gas. In the other test, 100% CO gas was used to convert $H_2O$ into $H_2$ at various reaction conditions (reaction temperature, S/C ratio, GHSV). As a result of the first test, $CH_4$ and CO conversion were 41.6%, 57.8% respectively at $600^{\circ}C$, S/C ratio 3, GHSV $2000hr^{-1}$. And CO conversion was 72% at $400^{\circ}C$, S/C ratio 0.95, GHSV $333hr^{-1}$ in the second test.

A study on the fabrication of lithium carbonation powder by gas-liquid reaction using ultrasonic energy (탄산리튬 분말 제조에 있어서 초음파 에너지를 적용한 기액반응에 관한 연구)

  • Kim, Dae-Weon;Kim, Bo-Ram;Choi, Hee-Lack
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.2
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    • pp.55-60
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    • 2020
  • In the previous study, we reported the result to prepare lithium carbonate powder from various lithium-contained solution. Therefore, using the lithium hydroxide solution, it is conformed that the reaction could occur thermodynamically, and the recovery rate of lithium was 89.4 %. In this study, we carried out the experiment to prepare lithium carbonate powder through gas-liquid reactions with lithium hydroxide solution and CO2 gas using ultrasound energy. In case ultrasonic energy is applied to the reaction of lithium carbonate, the recovery rate of lithium at room temperature was approximately 83.8 %, and the recovery rate of lithium was greatly increased to approximately 99.9 % at 60℃ reaction temperature. And when ultrasonic energy is not applied, the particle size of lithium carbonate powder was 7.7 ㎛ in D50. But the particle size of lithium carbonate powder was significantly reduced to 8.4 ㎛ in D50 under the influence of ultrasonic.

Increase of Recovery Ratio by Two Stage Membrane Process (the Pressurized PVDF Membrane Followed by Submerged PE Membrane) (PVDF 가압식과 PE 침지식 분리막을 결합한 2단 막여과 공정의 성능검토 및 회수율 증대 방안 연구)

  • Kim, Junhyeon;Mun, Baeksu;Jang, Hong-Jin;Kim, Jinho;Kim, Byungseok
    • Membrane Journal
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    • v.23 no.1
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    • pp.45-53
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    • 2013
  • Membrane filtration processes are increasingly popular for drinking water treatment that requires high quality of water. But pre-treatment system (Coagulation/Flocculation/Sedimentation) requires increased footprint and installation cost. In addition, 5~10% of the concentrate are formed. In this study, the pressurized PVDF membrane (ECONITY Co., Ltd.) system was tested with surface water (Han River, South Korea) without pre-treatment. As a result, permeate flux was operated between 1 m/d and 2.4 m/d (at $25^{\circ}C$) without chemical cleaning for one year and membrane permeate turbidity was maintained stably under 0.05 NTU regardless of raw water turbidity. And we studied application of concetrate treatment of pressurized PVDF membrane by submerged PE membrane (ECONITY Co., Ltd.). As a result, we increased recovery of total treatment process to 99.5%.

Preparation of Asymmetric PES Hollow Fiber Gas Separation Membranes and Their $CO_2/CH_4$ Separation Properties (비대칭구조의 폴리이서설폰 기체분리용 중공사막의 제조 및 이를 이용한 $CO_2/CH_4$ 분리특성)

  • Park, Sung-Ryul;Ahn, Hyo-Seong;Kim, Jeong-Hoon
    • Membrane Journal
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    • v.21 no.4
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    • pp.367-376
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    • 2011
  • Huge amount of $CH_4$ mixtures has been emitted from landfills and organic wastes via anaerobic digestion. The recovery of high purity $CH_4$ from these gases has two merits: reduction of green house gases and production of renewable fuels. Membrane technology based on polymeric materials can be used in this application. In this study, asymmetric gas separation hollow fiber membranes were fabricated to develop the membrane-based bio-gas purification process. Polyethersulfone (PES) was chosen as a polymer materials because of high $CO_2$ permeability of 3.4 barrer and $CO_2/CH_4$ selectivity of 50[1]. Acetone was used as a non-solvent additive because of its unique swelling power for PES and highly volatile character. The prepared PES hollow fiber showed excellent separation properties: 36 GPU of $CO_2$ permeance and 46 of $CO_2/CH_4$ selectivity at optimized preparation conditions: 9wt% acetone content, 10cm air-gap and 4wt% PDMS coating processes. With the PES hollow fiber membranes developed, mixed $CO_2/CH_4$ test was done by changing various operating conditions such as pressures and feed compositions to meet the highest recovery of CH4 with 95% purity. High $CH_4$ recovery of 58 wt% was observed at 10 atm feed pressure for the 50 vol% of $CO_2$ in $CO_2/CH_4$ mixture.

Effects of Warm-up Performance on SI Engine with Exhaust Heat Recovery System (배기열 회수장치 적용에 따른 SI 엔진의 웜업 성능에 미치는 영향)

  • Park, Kyoun-Suk;Suh, Ho-Cheol;Park, Sun-Hong;Kim, In-Tae;Jang, Sung-Wook
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.6
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    • pp.53-60
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    • 2011
  • The effect of exhaust heat recovery system can be evaluated by two well known method. First method is to measure the time duration from engine start under cold coolant temperature till coolant get warmed. By this methodology coolant warming duration can be index of warm-up effect. Second method is to analyze heat balance of the engine during warm-up phase under steady engine operation so that wasted energy by losses such as cooling and exhaust can be index of warm-up effect. This study focused on evaluation of warming-up effect by both methodology above mentioned using 2L SI engine under from idle to 2000rpm steady condition. Results, idle operation showed low heat recovery efficiency but under higher engine speed condition, remarkable heat recovery efficiency improvement was observed. In 2000rpm steady condition, warm-up duration of engine is decreased by exhaust heat recovery system.

Recovery and Characterization of Lactic Acid from Fermentation Broth Using Chemical Precipitation (화학침전을 이용한 발효액의 젖산 회수 및 유기물 특성분석)

  • Lee, Wontae
    • Journal of the Korea Organic Resources Recycling Association
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    • v.26 no.1
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    • pp.47-53
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    • 2018
  • Recovery of lactic acid from fermentation broth using chemical precipitation was investigated with various chemicals. Effects of chemical types, mixing speeds, settling duration, and solvent addition were evaluated to improve the recovery rates of lactic acid. Overall, recovery efficiencies increased as the dosage of chemicals increased. Recovery rate of lactic acid by CaO was higher than those of $Ca(OH)_2$ and $CaCO_3$. Recovery of lactic acid increased by 48% under the optimized reaction conditions which included a mixing speed at 180 rpm, a settling duration of 24 h, and addition of ethanol at 25%(v/v). Practical application needs to consider types and concentrations of other organic acids as well as lactic acid. Based upon the results of fluorescence excitation emission matrix (FEEM), size exclusion chromatography (SEC), characteristics of recovered lactic acid were same as that in the fermentation broth.

A 40 Gb/s Clock and Data Recovery Module with Improved Phase-Locked Loop Circuits

  • Park, Hyun;Kim, Kang-Wook;Lim, Sang-Kyu;Ko, Je-Soo
    • ETRI Journal
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    • v.30 no.2
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    • pp.275-281
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    • 2008
  • A 40 Gb/s clock and data recovery (CDR) module for a fiber-optic receiver with improved phase-locked loop (PLL) circuits has been successfully implemented. The PLL of the CDR module employs an improved D-type flip-flop frequency acquisition circuit, which helps to stabilize the CDR performance, to obtain faster frequency acquisition, and to reduce the time of recovering the lock state in the event of losing the lock state. The measured RMS jitter of the clock signal recovered from 40 Gb/s pseudo-random binary sequence ($2^{31}-1$) data by the improved PLL clock recovery module is 210 fs. The CDR module also integrates a 40 Gb/s D-FF decision circuit, demonstrating that it can produce clean retimed data using the recovered clock.

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Feasibility of Phosphorus Recovery from Biological Livestock Wastewater Treatment Plant (생물학적 축산분뇨처리시설에서 인 회수의 가능성 평가)

  • Ahn, Johwan;Kim, Jangho;Min, Sungjae
    • Journal of Korean Society on Water Environment
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    • v.32 no.4
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    • pp.343-348
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    • 2016
  • A chemical sequencing batch reactor was operated to test the feasibility of nutrient recovery from a biological livestock wastewater treatment plant. Both phosphate and ammonia could be successfully recovered as magnesium ammonium phosphate (MAP) crystals. The contents of TP and TN in the recovered MAP crystals were 26.2% and 4.0%, respectively. Zn, Cr and Ti were identified in the crystals, but the contents remained below the Korean standard for an organic fertilizer. Chemical analyses confirmed that the MAP crystals could be useful phosphate fertilizers. On the other hand, the results of physical analyses using an X-ray diffractometer and an energy dispersive X-ray spectrometer strongly suggested that crystalline materials like magnesium potassium phosphate (KMP) and hydroxyapatite (HAP) were also formed during the MAP crystallization, depending on the availability of K+ and Ca2+.