• Title/Summary/Keyword: $BaTiO_3$ system

Search Result 204, Processing Time 0.026 seconds

Preparation and Evaluation of Hybrid Porous Membrane for the Application of Alkaline Water Electrolysis (알칼리 수전해 적용을 위한 하이브리드 다공성 격리막 제조 및 특성평가)

  • Han, Seong Min;Im, Kwang Seop;Jeong, Ha Neul;Kim, Do Hyeong;Nam, Sang Yong
    • Membrane Journal
    • /
    • v.31 no.6
    • /
    • pp.443-455
    • /
    • 2021
  • In this study, polyphenylene sulfide (PPS) was used as a support and a separator was manufactured using polysulfone and inorganic additives to manufacture a separator with low membrane resistance for application of an alkali water electrolysis system, and then the effect on the thickness and porosity of the support was analyzed. The PPS felt used as a support was compressed with variables of temperature (100℃, 150℃, 200℃) and pressure (1 ton, 2 tons, 3 tons, 5 tons) to adjust the thickness. A porous separator could be manufactured by preparing a slurry with polysulfone using BaTiO3 and ZrO2 which have high hydrophilicity and excellent alkali resistance as inorganic particles and casting the slurry on a compressed PPS felt. Changes in morphology of the separator according to compression conditions were confirmed through an electron scanning microscope (SEM). After that, the porosity was calculated, and the thickness and porosity tended to decrease as the compression conditions increased. Various characteristics were evaluated to confirm whether it could be used as a separator for water electrolysis. As a result of measuring the mechanical strength, it was confirmed that the tensile strength gradually increased as the compression conditions (temperature and pressure) increased. Finally, it was confirmed that the porous separator manufactured through the alkali resistance test has excellent alkali resistance, and through the IV test, it was confirmed that the membranes compressed at 100℃ and 150℃ had a lower voltage and improved performance than the existing uncompressed membrane.

The Electrical Properties of Mutilayer Chip Capacitor with X7R by Addition of Rare-Earth Ions (Y2O3, Er2O3) using Design of Experiments (실험계획법을 적용한 X7R 적층 칩 커패시터의 희토류(Y2O3, Er2O3) 첨가에 따른 전기적 특성)

  • Yoon, Jung-Rag;Moon, Hwan;Lee, Heun-Young
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.23 no.3
    • /
    • pp.216-221
    • /
    • 2010
  • Employing statistical design of experiments, the difference in doping behaviors of rare-earth ions and their effects on the dielectric property and microstructure of $BaTiO_3$-MgO-$MnO_2$-($Ba_{0.4}Ca_{0.6}$) $SiO_3-Re_2O_3$ (Re = $Y_2O_3$, $Er_2O_3$) system were investigated. Through the statistical analysis we have found that the amount of $Re_2O_3$ are significantly affecting on the dielectric properties. The $Re_2O_3$ improved the dielectric constant, dielectric loss and R*C constant, so the appropriate contents of $Y_2O_3$ and $Er_2O_3$ were 0.8 ~ 1.2 mol% and 0.8 ~ 1.3 mol%, respectively. The MLCC(mutilayer chip capacitor) with $2.0{\times}1.2{\times}1.2mm$ size and 475 nF was also suited for X7R with the above composition. It showed that the dielectric constant and RC constant were 2,839 and 3,675 ${\Omega}F$, respectively in the sintering condition at $1250^{\circ}C$ in $Po_2$ $10^{-7}$ Mpa.

Development on Electrical Fire Prevention System of Small Size and High Speed by using PTC Thermistor (PTC 서미스터를 이용한 소형 고속응성의 전기화재 방재시스템 개발)

  • Kwak, Dong-Kurl
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.15 no.1
    • /
    • pp.51-58
    • /
    • 2008
  • This paper is studied on a prevention system for electrical fire and electrical faults by using electrical temperature characteristic of PTC thermistor. The PTC thermistor has characteristic of positive resistivity temperature coefficient according to the temperature variation, which is construction of a regular square and cube demarcation with $BaTiO_3$ ceramics of positive temperature coefficient. Also PTC shows the phenomenon which is rapidly increased in the resistivity if the temperature is increased over Curie temperature point. This paper is proposed on a protective control system used with temperature sensor of PTC thermistor. The proposed prevention system will prevent electrical fires due to electric short circuit faults or overload faults. And the prevention system will solve the problems that circuit breakers to be commonly used at existing are happened frequently electrical fires and electrical disasters due to incapable operation, weak reliability and low speed response. Some experimental results of the proposed apparatus are confirmed to the validity of the analytical results.

  • PDF

Dielectric and Electrical Characteristics of Lead-Free Complex Electronic Material: Ba0.8Ca0.2(Ti0.8Zr0.1Ce0.1)O3

  • Sahu, Manisha;Hajra, Sugato;Choudhary, Ram Naresh Prasad
    • Korean Journal of Materials Research
    • /
    • v.29 no.8
    • /
    • pp.469-476
    • /
    • 2019
  • A lead-free bulk ceramic having a chemical formula $Ba_{0.8}Ca_{0.2}(Ti_{0.8}Zr_{0.1}Ce_{0.1})O_3$ (further termed as BCTZCO) is synthesized using mixed oxide route. The structural, dielectric, impedance, and conductivity properties, as well as the modulus of the synthesized sample are discussed in the present work. Analysis of X-ray diffraction data obtained at room temperature reveals the existence of some impurity phases. The natural surface morphology shows close packing of grains with few voids. Attempts have been made to study the (a) effect of microstructures containing grains, grain boundaries, and electrodes on impedance and capacitive characteristics, (b) relationship between properties and crystal structure, and (c) nature of the relaxation mechanism of the prepared samples. The relationship between the structure and physical properties is established. The frequency and temperature dependence of the dielectric properties reveal that this complex system has a high dielectric constant and low tangent loss. An analysis of impedance and related parameters illuminates the contributions of grains. The activation energy is determined for only the high temperature region in the temperature dependent AC conductivity graph. Deviation from the Debye behavior is seen in the Nyquist plot at different temperatures. The relaxation mechanism and the electrical transport properties in the sample are investigated with the help of various spectroscopic (i.e., dielectric, modulus, and impedance) techniques. This lead free sample will serve as a base for device engineering.

Microwave Properties of Tunable Phase Shifter Using High Temperature Superconducting Thin Film (고온초전도 박막을 이용한 튜너블 이상기의 마이크로파 특성)

  • Kwak Min Hwan;Kim Young Tae;Moon Seong Eon;Ryu Han Cheol;Lee Su Jae;Kang Kwang Yong
    • Progress in Superconductivity and Cryogenics
    • /
    • v.7 no.1
    • /
    • pp.13-16
    • /
    • 2005
  • High temperature superconductor, $\YBa_2Cu_3O_{7-x}$ (YBCO) and ferroelectric, $\Ba_{0.1}Sr_{0.9}TiO_{3}$ (BST) multilayer thin films were deposited using on MgO(100) substrates pulsed laser deposition. The thin films exhibited only (001) peaks of YBCO and 1357 The HTS thin films demonstrated excellent zero resistance temperature of 92.5 K. We designed and fabricated HTS ferroelectric phase shifter using high frequency system simulator and standard photolithography method, respectively The HTS phase shifter shows a low insertion loss (2.97 dB) and large phase change ($\162^{circ}$) with 40 V do bias at 10 GHz. The HTS phase shifter shows 54 of figure of merit. These results can be applicable to phased anay antenna system for satellite communication services.

Optical Arithmetic Technique Using Optical Phase Conjugate Wave (위상 공액파를 이용한 광학적 연산 방식)

  • 엄순영
    • Proceedings of the Optical Society of Korea Conference
    • /
    • 1990.02a
    • /
    • pp.95-101
    • /
    • 1990
  • Parallel optical arithmetic techniques have been developed using the correlation property of optical phase conjugate wave generated by degenerated four wave-mixing. In this paper, conventional rectangular-type coded pattern used for optical logic system is replaced by circular one for effective beam coupling in a photorefractive $BaTiO_3$ material. By adequately adjusting the distance between circular-type pixels of the input pattern and grouping the correlated output, optical binary half addition/subtraction, binary multiplication and, matrix-matrix computation are demonstrated.

  • PDF

Powder EL device with 7-segment type and Driving Circuit (7-segment형 후막 EL소자와 구동회로)

  • 이종찬;박대희
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
    • /
    • 2000.11a
    • /
    • pp.60-63
    • /
    • 2000
  • In this paper, 7-segment was implemented using AC powder EL. ZnS:Cu and BaTiO3 was used as a phosphor and dielectric respectively. The preparation of phosphor and dielectric layer was performed with screen printing. The implemented system of 7-segment was divided as following; EL display, driving circuit, software for driving. The properties of fabricated devices was measured with EL spectrum and brightness.

  • PDF

Flexible Information Display using Powder Electroluminescent Device (후막 전계 발광 소자를 이용한 정보 표시형 Flexible Display)

  • Lee, Jong-Chan;Park, Dae-Hee
    • Proceedings of the KIEE Conference
    • /
    • 2000.11c
    • /
    • pp.428-430
    • /
    • 2000
  • In this paper, the Flexible information display was implemented using AC powder electroluminescent device. ZnS:Cu and $BaTiO_3$ was used as a phosphor and dielectric respectively. The preparation of phosphor and dielectric layer was performed with screen printing. The implemented system of the Flexible information display was divided as following; EL display, driving circuit, software for driving. The properties of fabricated devices was measured with EL spectrum and brightness.

  • PDF

All-Optical Implementation of Volume Holographic Associative Memory (부피격자형 연상메모리의 광학적 구현)

  • 오창석;이권연;박한규
    • Journal of the Korean Institute of Telematics and Electronics
    • /
    • v.25 no.9
    • /
    • pp.1102-1107
    • /
    • 1988
  • We describe a volume holographic associative memory using photorefractive material and conventional planar mirror. Multiple hologram is generated with two angular multiplexed writing beams and Fourier transformed object beam in Ba Ti O3 crystal at 0.6328 um. Complete image can be recalled successfully by partial input of the original stored image without any additional thresholding and optical feedback process. It is proved that our system is useful for optical implementation of real-time associative memory and location addressable memory.

  • PDF

Corona Discharge and Strong Electrolyzed Water Generation Characteristics of the Electrode System Bedded by Dielectric Pellets (유전체구 충진형 전극계의 코로나방전과 강전해수 발생특성)

  • 김진규
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
    • /
    • v.16 no.4
    • /
    • pp.46-54
    • /
    • 2002
  • A dielectric pellets bedded parallel plates with a membrane centered have been proposed as an ion separation and collection system in water. and effects of the relative dielectric constant and the applied square wave pulse voltage on the characteristics of ion separation and collection in tap water and NaCl dissolved tap water have been investigated. As a result, electrolyzed water of pH 3.1 and 10.6 were obtained with only tap water at the pulse current of 1.0[A] and flow rate of 0.5[LPM]. And the higher ionized water of pH 2.8 and pH 11.7 ware obtained in 0.1[%wt] NaCl dissolved water. When the dielectric pellets of BaTiO$_3$ having the highest dielectric constant were bedded in the ion separation and collection cell, the ionized water of pH 2.7 and pH 11.7 were obtained with only tap water. And the ionized water of pH 2.4 and pH 12.0 were obtained in 0.1[wt%] NaCl dissolved tap water with the dielectrics pellets bedded ones.