• Title/Summary/Keyword: $B-KNO_3$

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A Study on Acceleration Aging Characteristics of B-KNO3 Igniter (B-KNO3 점화제의 가속 노화 특성 연구)

  • Paik, Jong Gyu;Ryu, Byung Tae;Kwon, Mira
    • Korean Chemical Engineering Research
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    • v.52 no.2
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    • pp.166-174
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    • 2014
  • This research investigated the aging properties of the $B-KNO_3$ system as the igniter. The $B-KNO_3$ system showed the degradation in ignition properties depending on the method and period of storage. It should be found out the cause of the degradation to predict the reliability of the igniters. The changes of the properties by the degradation after aging tests were analyzed by microstructure analysis, XRD analysis and thermal analysis using DSC. It was found out that the lattice parameters of the $KNO_3$ as the oxidizer in the ignition system was changed into the JCPDS values as the aging time increased. Conclusively, the changes of the crystal structure of oxidizer affected the activation energy increasing as aging time increased.

Ignition of Solid Propellants at Subatmospheric Pressures (대기압 이하에서 고체 추진제의 점화 특성 향상 연구)

  • Kim In-Chul;Ryoo Baek-Neung;Jung Jung-Yong
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.05a
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    • pp.383-386
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    • 2006
  • Several HTPB/AP and HTPB/AP/HMX propellants were investigated experimentally for ignition characteristics in subatmospheric pressure. The threshold ignition pressure was 4psia for HTPB/AP composite propellant. The partial replacement of AP in HTPB/AP composite propellant by $5\sim15%$ of HMX, HNIW showed improvements in the threshold pressure was below 0.4psia. This appears to be due to the exothermic dissociation characteristics of HMX and HNIW at lower temperature $(\sim220^{\circ}C)$ than that of AP. The ignition substance B/KNO3 was coated thinly on the propellant surface for better ignition effect. As a result, ignition delay time of 15% was improved. NC is applied to $B/KNO_3$ ignition substance as a secondary binder and $NC-B/KNO-3$ suspension solution is coated to the propellant surface.

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Ignition of Solid Propellants at Subatmospheric Pressures (대기압 이하에서 고체 추진제의 점화 특성 향상 연구)

  • Kim, In-Cul;Ryoo, Baek-Neung;Jung, Jung-Yong
    • Journal of the Korean Society of Propulsion Engineers
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    • v.10 no.3
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    • pp.67-72
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    • 2006
  • Several propellants were investigated experimentally for ignition characteristics in subatmospheric pressure. The threshold ignition pressure was 4 psia for HTPB/AP composite propellant. The partial replacement of AP in HTPB/AP propellant by $5{\sim}l5%$ of HMX, HNIW showed that the improvements in ignition delay was over 50% and the threshold pressure was below 0.4 psia. This appears to be due to the characteristics of HMX and HNIW exothermic dissociated at the temperature(${\sim}220^{\circ}C$) love. than that of AP. The ignition substance $B/KNO_3$ was coated thinly on the propellant surface for better ignition performance. As a result, ignition delay time of 15% was improved. NC is applied to $B/KNO_3$ ignition substance as a secondary binder and $NC-B/KNO_3$ suspension solution is coated to the propellant surface.

B-KNO$_3$ 점화제의 노화 현상 분석

  • 장승교;류병태
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 1997.11a
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    • pp.14-14
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    • 1997
  • 추진제의 노화 못지 않게 점화제의 노화도 추진 기관 성능에 큰 영향을 미칠 것으로 예측된다. 따라서 10년 이상 경과된 활성 모터에서 점화기를 분해하여 노화에 의한 점화제의 성능 변화를 알아보았다. 분석에 사용한 점화제는 II-D Bi-Convex형상의 B-KNO$_3$ 펠렛으로 열량, 자동 점화온도, 기계적 물성의 변화를 관찰하였고, 밀폐 용기(Closed bomb)에서 연소시험을 통하여 노화에 따른 점화알약의 압력변화를 측정하고 이론 값과 비교하였다. 또한 비활성 모타를 이용한 연소시험으로 점화기의 점화지연시간, 최대 압력, 최대 압력 도달시간 등을 측정하고 이론식과 비교하여 노화에 의한 변화를 관찰하였다.

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Optimization of Major Culture Elements on Growth and Shikonin Production in the Lithospermum erythrorhizon Hairy Root Culture

  • Hwang, Ok-Jin;Kim, Yu-Jeong;Sung, Nak-Sul;Ahn, Jun-Cheul;Kim, Sik-Eung;Hwang, Baik
    • Korean Journal of Medicinal Crop Science
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    • v.10 no.4
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    • pp.243-248
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    • 2002
  • The effects of basal media, carbon, nitrogen, phosphate and some major macro elements on growth and shikonin production in Lithospermum erythrorhizon hairy root culture were studied. Among examined media, growth of hairy root cultured in B5 liquid medium was rapid, whereas shikonin production was high in MS liquid medium. Under B5 basal medium, sucrose concentration for optimal growth and shikonin production was 9% and 4% respectively. The growth and shikonin production on pH changes in B5 medium resulted little effect in pH 5.8 to pH 8.8 ranges, whereas growth was decreased dramatically in both above 8.8 and under 5.8. Nitrogen source and concentration effected on the growth and shikonin production. The highest growth rate was in B5 medium (50 mM $KNO_3$ and 1 mM $NaH_2PO_4)$, whereas the highest shikonin production was in the condition supplemented with 5 mM $KNO_3$ and 10 mM $NaH_2PO_4$.

Histological studies on in vitro Propagation of Pulsatilla koreana Nakai (할미꽃 기내증식(器內增殖)에 관(關)한 조직학적(組織學的) 연구(硏究))

  • Lee, Man-Sang;Oh, Ki-Hong
    • Korean Journal of Medicinal Crop Science
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    • v.1 no.2
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    • pp.137-157
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    • 1993
  • This study was carried out to investigate the optimal condition for multiple propagation through leaf tissue culture and to apply anther culture techniques to Pulsatilla koreana Nakai breeding. Leaf and anther of Pulsatilla koreana Nakai were cultured on MS, MT, LS and $B_5$ media supplemented with several growth regulators and nitrogen sources under various conditions. For callus induction and differentiation from the Pulsatilla koreana leaf segments were more effective in the combination of zeatin and auxin than auxin alone. The color of the callus was green when treated with IBA alone. Shoot differentiation was more effective when treated with zeatin than auxin alone, especially the best hormoal combination for shoot differentiation was zeatin 1.0mg/l +NAA 0.1mg/l, while 2,4-D inhibited shoot differentiation. The appeared rate of S pollen was 35% in vivo, while that of S pollen by low temperature$(4^{\circ}C)$ pretreatment for 4 days was increased by 53% and the optimum culture time for callus induction from anther was uni-nucleate stage. $B_5$ basal medium supplemented with NAA 0.5mg/l and zeatin 1 mg/l was the most effective on callus formation and the best results of plant regeneration were obtained from combination of NAA 0.5mg/l and zeatin 0.5mg/l in anther culture. $NH_{4}NO_3$ as more effectives as the nitrogen source than $KNO_3$ and the combination with zeatin 2.0mg /L was the best effective. The best combination for plant regeneration in callus induced from anther was $NH_{4}NO_3$ 1650mg/l + $KNO_3$ 3800mg/l + zeatin 2.0mg/l. Ploidy level of anther-derived plants appeared 28% haploid, 47% diploid and the others were triploid, tetraploid and mixploid. In compare with E.S.T, M.D.H and P.X banding patterns were distinguished among callus, haploid and diploid plants in electrophoresis.

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Optimization of Medium Components for the Production of Crude Biosurfactant by Bacillus subtilis JK-1 (Bacillus subtilis JK-1의 생물계면활성도를 위한 최적 배지 조성)

  • Joo, Myeong-Hoon;Kim, Ji-Yeon
    • Journal of Applied Biological Chemistry
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    • v.54 no.1
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    • pp.7-14
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    • 2011
  • Bacillus subtilis JK-1 showed degradation activity against crude oil, gasoline, kerosene, and light oil, and this strain was used as a crude biosurfactant producing microorganism in this study. To optimize the culture medium for production of crude biosurfactant, the influences of various carbon, nitrogen and mineral sources were assessed. The highest biosurfactant production by B. subtilis JK-1 was observed after 96 h cultivation, containing 1.0% (w/v) soluble starch as a carbon source and 0.5% (w/v) skim milk as a nitrogen source, and carbon to nitrogen concentraion (C/N) ratio was 2.0. For the biosurfactant production 0.1% (w/v) of $KNO_3$ was the most effective mineral source. Comparison of biosurfactant production indicates that B. subtilis JK-1 produces more biosurfactant in the optimum medium established in this study than LB and TSB. Under the optimum medium, the surface tension of culture broth of B. subtilis JK-1 was decreased from 47.3 dyne/cm to 24.0 dyne/cm after cultivation of 48 h.

Kinetic Analysis of Energetic Materials Using Differential Scanning Calorimetry (DSC를 이용한 고에너지 물질의 반응속도식 추출과 활용)

  • Kim, Yoocheon;Park, Jungsoo;Yang, Seungho;Park, Honglae;Yoh, Jai-Ick
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.1
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    • pp.33-41
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    • 2015
  • The kinetic analysis of energetic materials using Differential Scanning Calorimetry (DSC) is proposed. Friedman Isoconversional method is applied to DSC experiment data and AKTS software is used for analysis. The proposed kinetic scheme has considerable advantage over the standard method based on One-Dimenaionl Time to Explosion (ODTX). Reaction rate and product mass fraction simulation are conducted to validate extracted kinetic scheme. Also a slow cook-off simulation is implemented on $B/KNO_3$ for validating the applicability of the extracted kinetics scheme to a practical thermal experiment.

Evaluation of the Aging Effects on the Performance of the Pyrotechnic Igniter (파이로 테크닉 점화기의 노화 성능 평가)

  • 장승교;류병태
    • Journal of the Korean Society of Propulsion Engineers
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    • v.1 no.2
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    • pp.91-102
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    • 1997
  • In order to evaluate the effects of aging on the ignition performance, pyrotechnic igniters were separated from twelve-year-old, fifteen-year-old, and sixteen-year-old live rocket motors. The characteristic values of the ignition material were measured, and the firing tests of the igniters were performed. The moisture content, the outer dimension, the crush strength, the thermal decomposition characteristics, and the heat of formation the B/$KNO_3$ ignition pellet were measured. The crush strength was increased and the heat of formation was reduced as aged, but no change was detected for other characteristic values. The burning test results of the igniter pellet in the closed bomb and the inert motor showed that the burning rate of the ignition pellet was increased by 10%, and the integration of pressure $P_t$ of the p-t curve was reduced by 15% for aged samples. It was inferred that the burning rate was increased as the crack was appeared in the pellet and $P_t$ could be proportionally decreased with the heat of explosion.

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Effects of Temperature, Light Condition, and Priming Treatment on Seed Germination of Bidens bipinnata L. (온도, 광 및 Priming 처리가 도깨비바늘 종자의 발아에 미치는 영향)

  • Lee, Sang Yong;Baek, Jun Pill
    • Journal of Bio-Environment Control
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    • v.22 no.2
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    • pp.188-191
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    • 2013
  • This study was carried out to investigate the effects of light, temperature, and priming treatment on the germination of Bidens bipinnata seeds for the purpose of cultivation of new vegetable crop. The results showed that the treatment of $25^{\circ}C$ yielded the highest germination percentages and the highest germination speed in both light and dark conditions. Light condition had no effect on the germination of B. bipinnata. Priming treatments demon-strated the following improved germination percentages: $Ca(NO_3)_2$ 0.1 M (68.3%), $K_3PO_4$ 0.1 M (63.3%), and $KNO_3$ 0.1 M (53.3%), with $Ca(NO_3)_2$ 0.1 M treatment giving the greatest improvement. Consequentially, the results suggested that $25^{\circ}C$ light condition, and $K_3PO_4$ 0.1 M or $Ca(NO_3)_2$ 0.1 M priming treatments would be effective method to improve the germination of Bidens bipinnata seeds.