• Title/Summary/Keyword: $Al_2O_3

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Lamination of Dielectric Layers by High Pressure Spray Coating for LTCC (고압 스프레이 코팅법에 의한 저온동시소성세라믹(LTCC) 유전체 층의 적층방법)

  • Lee, Jee-Hee;Kim, Young-Jin
    • Journal of the Microelectronics and Packaging Society
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    • v.13 no.3 s.40
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    • pp.33-38
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    • 2006
  • Aerosol slurry composed of dielectric materials, distilled water, and deflocculants was sprayed on the substrates, through a high-pressure spray gun as an aerosol. The coated layers were cofired together with $Al_{2}O_{3}$ substrates and green sheets on which the inner connectors were printed. Although the coating rate of coated layers strongly depended on slurry viscosity, spray shape, and the pressure of the spray gun, the coated density was not changed. Buried conductors were maintained as printed by high pressure spray coating method, because the pressing process was not used. At the optimum condition of air controller step 3-4 and slurry viscosity c.p 2000-4000, dense and uniform layers could be achieved. Comparing with conventional lamination process using green sheets, spray coating method enabled thin dielectric layers of $20{\sim}50{\mu}m$.

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Novel Mutations in IL-10 Promoter Region -377 (C>T), -150 (C>A) and their Association with Psoriasis in the Saudi Population

  • Al-Balbeesi, Amal O.;Halwani, Mona;Alanazi, Mohammad;Elrobh, Mohammad;Shaik, Jilani P.;Khan, Akbar Ali;Parine, Narasimha Reddy
    • Asian Pacific Journal of Cancer Prevention
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    • v.16 no.3
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    • pp.1247-1250
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    • 2015
  • Background: Psoriasis, a common cutaneous disorder characterized by inflammation and abnormal epidermal proliferation with a prevalence of 2-3% in the general population, may be linked to certain types of cancer. Several studies have reported an association between interleukin 10 (IL-10) variant polymorphisms and inflammatory diseases such as psoriasis vulgaris although the results vary according to the population studied. No studies have been performed in the Saudi population. The present study concerned novel variants and other genetic polymorphisms of the promoter and exonic regions of the IL10 gene in patients with moderate to severe psoriasis and potential differences in genotype compared to a group of healthy volunteers. Materials and Methods: Patients with moderate to severe psoriasis and healthy controls with no personal or family history of psoriasis were selected from the central region of Saudi Arabia. Polymorphisms of the IL 10 gene of both groups were genotyped. Results: We observed two novel variants in 5'UTR region of the promoter precursor with higher prevalence of the genotype with both wild-type alleles in patients compared to the healthy control group. The differences at positions -377 and -150 were significantly associated with disease, both the variants conferred strong protection against psoriasis in Saudi patients. Conclusions: This observation provides further support for the importance of the part that IL10 plays in the pathophysiology of this disease. Confirmation of our findings in larger populations of different ethnicities would provide evidence for the role of IL-10 in psoriasis.

How will surface treatments affect the translucency of porcelain laminate veneers?

  • Turgut, Sedanur;Bagis, Bora;Ayaz, Elif Aydogan;Korkmaz, Fatih Mehmet;Ulusoy, Kivanc Utku;Bagis, Yildirim Hakan
    • The Journal of Advanced Prosthodontics
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    • v.6 no.1
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    • pp.8-13
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    • 2014
  • PURPOSE. The purpose of this study was to evaluate whether surface treatments affect the translucency of laminate veneers with different shades and thicknesses. MATERIALS AND METHODS. A total of 224 disc-shaped ceramic veneers were prepared from A1, A3, HT (High Translucent) and HO (High Opaque) shades of IPS e.max Press (Ivoclar Vivadent) with 0.5 mm and 1.0 mm thicknesses. The ceramics were divided into four groups for surface treatments. Group C: no surface treatments; Group HF: etched with hydrofluoric acid; Group SB: sandblasted with 50-${\mu}m$ $Al_2O_3$; and Group L; irradiated with an Er;YAG laser. A translucent shade of resin cement (Rely X Veneer, 3M ESPE) was chosen for cementation. The color values of the veneers were measured with a colorimeter and translucency parameter (TP) values were calculated. A three-way ANOVA with interactions for TP values was performed and Bonferroni tests were used when appropriate (${\alpha}=0.05$). RESULTS. There were significant interactions between the surface treatments, ceramic shades and thicknesses (P=.001). For the 0.5-mm-thick specimens there were significant differences after the SB and L treatments. There was no significant difference between the HF and C treatments for any shades or thicknesses (P>.05). For the 1-mm-thick ceramics, there was only a significant difference between the L and C treatments for the HT shade ceramics (P=.01). There were also significant differences between the SB and C treatments except not for the HO shades (P=.768). CONCLUSION. The SB and L treatments caused laminate veneers to become more opaque; however, HF treatment did not affect the TP values. When the laminate veneers were thinner, both the shade of the ceramic and the SB and laser treatments had a greater effect on the TP values.

The effects of different surface treatments on the shear bond strengths of two dual-cure resin cements to CAD/CAM restorative materials

  • Turker, Nurullah;Buyukkaplan, Ulviye Sebnem;Basar, Ebru Kaya;Ozarslan, Mehmet Mustafa
    • The Journal of Advanced Prosthodontics
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    • v.12 no.4
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    • pp.189-196
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    • 2020
  • PURPOSE. The aim of the present study was to investigate the effects of surface treatments on the bond strengths between polymer-containing restorative materials and two dual-cure resin cements. MATERIALS AND METHODS. In the present study, rectangular samples prepared from Lava Ultimate (LU) and Vita Enamic (VE) blocks were used. The specimen surfaces were treated using CoJet sandblasting, 50 ㎛ Al2O3 sandblasting, % 9 HF (hydrofluoric) acid, ER,Cr:YSGG laser treatment, and Z-Prime. Dual-cure resin cements (TheraCem and 3M RelyX U 200) were applied on each specimen's treated surface. A micro-tensile device was used to evaluate shear bond strength. Statistical analysis was performed using the SAS 9.4v3. RESULTS. While the bond strength using TheraCem with LU or VE was not statistically significant (P=.164), the bond strength using U200 with VE was statistically significant (P=.006). In the TheraCem applied VE groups, Z-Prime and HF acid were statistically different from CoJet, Laser, and Sandblast groups. In comparison of TheraCem used LU group, there was a statistically significant difference between HF acid and other surface treatments. CONCLUSION. The bonding performance between the restorative materials and cements were material type-dependent and surface treatment had a large effect on the bond strength. Within the limitations of the study, the use of both U200 and TheraCem may be suggested if Z-prime was applied to intaglio surfaces of VE. The cementation of LU using TheraCem is suitable after HF acid conditioning of the restoration surfaces.

Experimental investigation of aerosols removal efficiency through self-priming venturi scrubber

  • Ali, Suhail;Waheed, Khalid;Qureshi, Kamran;Irfan, Naseem;Ahmed, Masroor;Siddique, Waseem;Farooq, Amjad
    • Nuclear Engineering and Technology
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    • v.52 no.10
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    • pp.2230-2237
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    • 2020
  • Self-priming venturi scrubber is one of the most effective devices used to collect aerosols and soluble gas pollutants from gaseous stream during severe accident in a nuclear power plant. The present study focuses on investigation of dust particle removal efficiency of the venturi scrubber both experimentally and theoretically. Venturi scrubber captures the dust particles in tiny water droplets flowing into it. Inertial impaction is the main mechanism of particles collection in venturi scrubber. The water injected into venturi throat is in the form of jets through multiple holes present at venturi throat. In this study, aerosols removal efficiency of self-priming venturi scrubber was experimentally measured for different operating conditions. Alumina (Al2O3) particles with 0.4-㎛ diameter and 3950 kg/㎥ density were treated as aerosols. Removal efficiency was calculated for different gas flow rates i.e. 3-6 ㎥/h and liquid flow rates i.e. 0.009-0.025 ㎥/h. Experimental results depict that aerosols removal efficiency increases with the increase in throat velocity and liquid head. While at lower air flow rate of 3 ㎥/h, removal efficiency decreases with the increase in liquid head. A theoretical model of venturi scrubber was also employed and experimental results were compared with mathematical model. Experimental results are found to be in good agreement with theoretical results.

A Comparison of Methods to Remove the Boron Rich Layer Formed at Boron Doping Process for c-Si Solar Cell Applications (결정질 실리콘 태양전지의 적용을 위해 보론 확산 공정에서 생성되는 Boron Rich Layer 제거 연구)

  • Choi, Ju Yeon;Cho, Young Joon;Chang, Hyo Sik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.10
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    • pp.665-669
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    • 2015
  • We investigated and compared two methods of in-situ oxidation and chemical etching treatment (CET) to remove the boron rich layer (BRL). The BRL is generally formed during boron doping process. It has to be controlled in order not to degrade carrier lifetime and reduce electrical properties. A boron emitter is formed using $BBr_3$ liquid source at $930^{\circ}C$. After that, in-situ oxidation was followed by injecting oxygen of 1,000 sccm into the furnace during ramp down step and compared with CET using a mixture of acid solution for a short time. Then, we analyzed passivation effect by depositing $Al_2O_3$. The results gave a carrier lifetime of $110.9{\mu}s$, an open-circuit voltage ($V_{oc}$) of 635 mV at in-situ oxidation and a carrier lifetime of $188.5{\mu}s$, an $V_{oc}$ of 650 mV at CET. As a result, CET shows better properties than in-situ oxidation because of removing BRL uniformly.

A study on improving the surface morphology of recycled wafer forsolar cells using micro_blaster (Micro blaster를 이용한 태양전지용 재생웨이퍼의 표면 개선에 관한 연구)

  • Lee, Youn-Ho;Jo, Jun-Hwan;Kim, Sang-Won;Kong, Dae-Young;Seo, Chang-Taeg;Cho, Chan-Seob;Lee, Jong-Hyun
    • Journal of Sensor Science and Technology
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    • v.19 no.4
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    • pp.291-296
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    • 2010
  • Recently, recycling method of waste wafer has been an area of solar cell to cut costs. Micro_blasting is one of the promising candidates for recycling of waste wafer due to their extremely simple and cost-effective process. In this paper, we attempt to explore the effect of micro_blasting and DRE(damage removal etching) process for solar cell. The optimal process conditions of micro_blasting are as follows: $10{\mu}m$ sized $Al_2O_3$ powder, jetting pressure of 400 kPa, and scan_speed of 30 cm/s. And the particles formed on micro_blasted wafer were removed by DRE precess which was performed by using HNA(HF/$HNO_3$/$CH_3COOH$) and TMAH(tetramethyl ammonium hydroxide). Structural analysis was done using a-step and the XRD patterns.

국내산 납석의 부존현황 및 광물특성

  • 노진환;고상모
    • Mineral and Industry
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    • v.18 no.1
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    • pp.1-17
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    • 2005
  • 국내의 납석 광상은 대부분 백악기의 화산암류들이 열수변질되어 형성된 광상으로서, 주로 전남 및 경남 지역에 밀집되어 분포한다. 납석은 지질 여건상 주로 경상분지 내에 국제적인 규모의 풍부한 부존자원이 있지만, 그 동안의 개발에 의해서 고품위 황석들은 상당히 채진된 상황이다. 현재 개발되고 있는 광체들은 몇 곳의 광산을 제외하고는 대부분 저품위 광상을 이루고 있기 때문에, 새로운 광체의 탐광이 이루어지지 않는다면 앞으로 고품위 광석에 관한 한 국내의 수요를 충당하기 어려운 상황에 이를 것으로 예견된다. 현재 국내에서 납석으로 개발되고 있는 광석의 상당수(대략 $40\%$ 정도)가 엄밀한 의미에서는 사실상 납석이 아닌 고령토나 견운모 광석인 것으로 밝혀졌다. 엽납석을 함유하는 정상적인 형태의 납석들은 그수반 점토광물상에 의거하여 (l) 엽납석질, (2) 딕카이트질. (3) 일라이트질 및 (4) 딕카이트-일라이트질 유형으로 구분될 수 있다. 고령토 광물로는 대부분 딕카이트가 수반되고 외국에서는 흔히 수반되는 것으로 알려져 있는 고령석은 거의 함유되지 않는 것이 특징이다. 석영은 납석에서 점토광물 못지않게 그 용도를 가름하는 주요 성분으로서 대부분의 광석 유형에서 수반되지만 특히 일라이트질 납석에서 흔히 그리고 보다 많이 수반되는 양상을 보인다. X-선회절 정랑분석법은 납석의 품위를 산정하는데 유력한 수단이 될 수 있다. 특히 납석 이외의 점토광물들의 조성, 특히 일라이트의 함유 정도는 납석의 용도별 품위와 품질을 가름하는 주요 사항이다. 화학분석에 의한 납석의 평가 방식은 특히 납석의 백색 도기류와 같은 각종 세라믹스 제조 용도에서의 품질 평가에 결정적인 단서를 제공하는 유력한 평가수단이다. 특히 착색유발 성분인 철분의 존재와 그 함량을 정하고 요업용도에서 중요한 $Al_3O_3$와 알칼리 성분 함량을 검증하는데 필수적인 평가 방법이다. 이외에 주사전자현미경 관찰을 통해서 납석의 주요 품질 기준이 되는 극미립상 엽납석의 결정형, 조직 및 미시적 산출상태를 보다 정밀하게 평가할 수 있는 방안을 제공한다. 현행 광업법상의 납석을 비롯한 관련 광종들의 광물분류 체계가 모호하게 설정되어 있고 관련 인허가 부서에서의 전문성 및 지도력 부족으로 관련 산업계에 심각한 비효율성과 오류가 야기되고 있는 실정이다. 이를 개선하기 위해서는 납석의 광석평가 방식이 그 품위와 품질 개념 하에서 응용광물학적으로 적용되어야 할 것이다.

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Evaluation for Applicability as the Inorganic Binder with Rapid Setting Property for Construction Material of LFS Produced from Various Manufacturing Process (다양한 철강제조공정에서 부산되는 전기로 환원슬래그의 급경성 무기결합재로의 적용성 검토)

  • Kim, Jin-Man;Choi, Sun-Mi;Kim, Ji-Ho
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.2
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    • pp.70-77
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    • 2012
  • The Ladle Furnace Slag, about 20% of the electric arc furnace slag, has high content of free CaO and free MgO, which generates the expansion collapse by hydration reaction. Although many researchers have been endeavoring to recycle the EAF reducing slag in construction fields, there is not found the effective recycling method up to now. However, the LFS(Ladle Furnace Slag) contains mineral composition of the system of calcium aluminate with high-reactivity. Therefore, it is possible to developed the quick setting property and the high strength at the early age by the rapid cooling. This study aimed to check the reactive minerals and predict the reactivity with water on the LFS discharged from different steel product plants. The test results show that many types of LFS has hydration reactivity and can use in construction field as a inorganic binder with the rapid setting property.

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Characteristics of Manufacturing for Special Cement Using High Chlorine by-product (고염소 부산물을 이용한 특수시멘트 제조 특성)

  • Moon, Kiyeon;Cho, Jinsang;Choi, Moonkwan;Cho, Kyehong
    • Resources Recycling
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    • v.30 no.6
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    • pp.68-75
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    • 2021
  • This study aims to investigate the manufacturing process of calcium chloride-based special cement, i.e., CCA (calcium chloro aluminate, C11A7·CaCl2), which uses limestone, by using one type of random industrial by-product, domestic coal ash, cement kiln dust. The manufacturing process of was examined in detail, and the results suggested that the amount of CCA synthesized increased with an increase in the firing temperature. The manufacturing process of CCA was investigated at 1200℃, which was determined as the optimum firing temperature. The results showed that in general, the amount of CCA synthesized tended to increase with an increase in the firing time; however, the clinker melted when the firing time was more than 30 min, thereby suggesting that a firing time of less than 20 min would be suitable for the clinkering process. The optimal firing conditions for manufacturing CCA were obtained as follows: heating rate of 10 ℃/min, firing temperature of 1200 ℃, and holding time of 20 min. The results also suggest that manufacturing CCA will be easier when high chlorine-containing cement kiln dust is used.