• Applied Science and Convergence Technology
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• 제24권2호
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• pp.33-40
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• 2015

$ZrO_2$ and Al-Zr composite oxide film was prepared by vacuum assisted sol-gel dip coating method and anodizing. $ZrO_2$ films annealed above $400^{\circ}C$ have tetragonal structure. $ZrO_2$ layers inside etch pits were successfully coated from the $ZrO_2$ sol. The double layer structures of samples were obtained after being anodized at 100 V to 600 V. From the TEM images, it was found that the outer layer was $Al_2O_3$, the inner layer was multi-layer of $ZrO_2$, Al-Zr composite oxide and Al hydrate. The capacitance of $ZrO_2$ coated foil exhibited about 28.3% higher than that of non-coating foil after being anodized at 100 V. The high capacitance of $ZrO_2$ coated foils anodized at 100 V can be attributed to the relatively high percentage of inner layer in total thickness. The electrical properties, such as withstanding voltage and leakage current of coated and non-coated Al foils showed similar values. From the results, $ZrO_2$ and Al-Zr composite oxide is promising to be used as the partial dielectric of high voltage capacitor to increase the capacitance.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2005년도 제24회 춘계학술대회논문집
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• pp.106-111
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• 2005

Failure mechanisms were investigated for the two layer thermal barrier coatings consisting of NiCrAlY bond coat and $ZrO_2-8wt.\% Y_{2}O_3$ ceramic coating during cyclic oxidation. $Al_{2}O_3$ developed at the ceramic coating/bond coat interface first, followed by the Cr/Ni rich oxides such as $NiCr_{2}O_4 and Ni(Al,Cr)_{2}O_4$ during cyclic oxidation It was observed that the spalling of ceramic coatings took place primarily within the NiCrAlY bond coat oxidation products or at the interface between the bond coat oxidation products and zirconia based ceramic coating or the bond coat. It was also observed that the fracture within these oxidation products occurred with the formation of $Ni(Cr,Al)_{2}O_4$ spinel or Cr/Ni rich oxides. It was therefore concluded that the formation of these oxides was a life-limiting event for the thermal barrier coatings.

• The Korean Journal of Ceramics
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• 제4권4호
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• pp.340-344
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• 1998

Failure mechanisms were investigated for the two layer thermal barrier coatings consisting of NiCrAlY bond coat and $ZrO_2$-8wt.% $Y_2O_3$ ceramic coating during cyclic oxidation. $Al_2O_3$ developed at the ceramic coating/bond coat interface first, followed by the Cr/Ni rich oxides such as $NiCr_2O_4$ and $Ni(Al, Cr)_2O_4$ during cyclic oxidation. It was observed that the spalling of ceramic coatings took place primarily within the NiCrAlY bond coat oxidation products or at the interface between the bond coat oxidation products and zirconia based ceramic coating or the bond coat. It was also observed that the fracture within these oxidation products occurred with the formation of $Ni(Cr, Al)_2O_4$ spinel or Cr/Ni rich oxides. It was therefore concluded that the formation of these oxides was a life-limiting event for the thermal barrier coatings.

• 한국산학기술학회논문지
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• 제10권9호
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• pp.2396-2401
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• 2009

본 연구는 건축자재로 널리 사용되는 PVC 바닥상재의 표면을 스크래치로부터 보호하기 위하여 기존에 사용하는 광경화형 우레탄-아크릴 수지에 내마모성을 향상시킨 광경화형 하드 코팅액 개발에 관한 것이다. PVC 바닥상재용으로 사용되는 내마모성이 없는 우레탄-아크릴 수지에 $Al_2O_3$(Al-160SG-3), $Al(OH)_3$(SH-8W) 및 $SiO_2$(KS-5000) 등 서로 다른 내마모성을 지닌 물질을 분말 형태로 수지의 양 대비 함량(wt%)을 $10{\sim}30%$로 변화하여 첨가한 후 링밀(Ring Mill)을 사용, 배합하여 수지의 내마모성을 향상시킨 하드 코팅액을 제조하였다. 제조한 하드 코팅액은 코팅층의 두께조절이 가능한 코팅(Bar-coating)을 사용하여 PVC 바닥상재에 코팅 한 후 내마모성, 연필경도, 부착력, 코팅두께 등의 코팅층 표면물성을 평가하였다. 연구결과, 수지에 $Al_2O_3$ 분말 30%를 혼합하여 제조한 하드 코팅액이 내마모성 1등급, 연필경도 H, 부착력 100%로 가장 좋은 물성을 보였으며, 전반적으로 입자크기가 작고, 분말 함량이 많을수록 또한 코팅두께가 두꺼워 질수록 경도 및 내마모성이 우수한 것으로 나타났다.

• Journal of Advanced Marine Engineering and Technology
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• 제24권1호
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• pp.49-58
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• 2000

Thermal spraying is one of the most common surface coating techniques to be used for many applications and flame spraying covers a wide range of different materials which can be coated onto various substrates. The purpose of this study is to investigate the effects of mixed ratio in composite coatings on the mechanical and anti-corrosion properties. The five different types of composite coatings were made with $Al_2O_3$ ceramic and Ni-alloy powder on the mild steel substrate by flame spraying method. The mechanical properties such as microhardness, adhesive strength and erosion resistance and corrosion resistance were tested for the sprayed coating specimens. The results obtained are summarized as follows; 1. The composite coating layers greatly improve the microstructure, erosion resistance and adhesive strength by increasing the content of Ni-Al alloy. 2. Microhardness of the compsite coating layer is decreased by increasing the content of Ni-Al alloy. 3. The anti-corrosion properties is considerably improved by increasing the compsite rate of Ni-Al alloy.

• Journal of Electrochemical Science and Technology
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• 제10권4호
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• pp.424-432
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• 2019

Planar BiVO₄ and 3 wt% Mo-doped BiVO₄ (abbreviated as Mo:BiVO₄) film were prepared by the facile spin-coating method on fluorine doped SnO₂(FTO) substrate in the same precursor solution including the Mo precursor in Mo:BiVO₄ film. After annealing at a high temperature of 450℃ for 30 min to improve crystallinity, the films exhibited the monoclinic crystalline phase and nanoporous architecture. Both films showed no remarkably discrepancy in crystalline or morphological properties. To investigate the effect of surface passivation exploring the Al₂O₃ layer, the ultra-thin Al₂O₃ layer with a thickness of approximately 2 nm was deposited on BiVO₄ film using the atomic layer deposition (ALD) method. No distinct morphological modification was observed for all prepared BiVO₄ and Mo:BiVO₄ films. Only slightly reduced nanopores were observed. Although both samples showed some reduction of light absorption in the visible wavelength after coating of Al₂O₃ layer, the Al₂O₃ coated BiVO₄ (Al₂O₃/BiVO₄) film exhibited enhanced photoelectrochemical performance in 0.5 M Na₂SO₄ solution (pH 6.5), having higher photocurrent density (0.91 mA/㎠ at 1.23 V vs. reversible hydrogen electrode (RHE), briefly abbreviated as V_RHE) than BiVO₄ film (0.12 mA/㎠ at 1.23 V_RHE). Moreover, Al₂O₃ coating on the Mo:BiVO₄ film exhibited more enhanced photocurrent density (1.5 mA/㎠ at 1.23 V_RHE) than the Mo:BiVO₄ film (0.86 mA/㎠ at 1.23 V_RHE). To examine the reasons, capacitance measurement and Mott-Schottky analysis were conducted, revealing that the significant degradation of capacitance value was observed in both BiVO₄ film and Al₂O₃/Mo:BiVO₄ film, probably due to degraded capacitance by surface passivation. Furthermore, the flat-band potential (V_FB) was negatively shifted to about 200 mV while the electronic conductivities were enhanced by Al₂O₃ coating in both samples, contributing to the advancement of PEC performance by ultra-thin Al₂O₃ layer.

• 한국표면공학회지
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• 제54권6호
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• pp.315-323
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• 2021

In general, surface treatments of electroless Ni-P coating are extensively applied in the industry due to their excellent properties for considerable wear resistance, hardness, corrosion resistance. This study aims to determine the effect of ultrasonic conditions on the morphology, alumina content, roughness, hardness, and corrosion resistance of electroless Ni-P-Al₂O₃ composite coatings. The characteristics were analyzed by Energy-dispersive X-ray spectroscopy (EDX), x-ray diffractions (XRD), and atomic force microscopy (AFM), etc. In this study, the effect of ultrasonic condition uniformly distributed alumina within Ni-P solution resulting in a smoother surface, lower surface roughness. Furthermore, the corrosion resistance behavior of the coating was analyzed using tafel polarization curves in a 3.5 wt.% NaCl solution at 25 ℃. Under ultrasonic, Al₂O₃ content in Ni-P composite solution increased from 0.5 to 5.0 g/L, Al₂O₃ content at 3.0 g/L was showed a significantly enhanced corrosion resistance. These results suggested that ultrasonic condition was an effective method to improve the properties of the composite coating.

• 한국세라믹학회지
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• 제45권10호
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• pp.584-588
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• 2008

Porous hydroxyapatite(HA) and HA-coated porous $Al_2O_3$ possessing pore characteristics required for bone substitutes were prepared by a slurry foaming method combined with gelcasting. The HA coating was deposited by heating porous $Al_2O_3$ substrates in an aqueous solution containing $Ca^{2+}$ and ${PO_4}^{3-}$ ions at $65{\sim}95^{\circ}C$ under ambient pressure. The pore characteristic, microstructure, and compressive strength were investigated and compared for the two kinds of samples. The porosity of the samples was about 81% and 80% for HA and $Al_2O_3$, respectively with a highly interconnected network of spherical pores with size ranging from 50 to $250{\mu}m$. The porous $Al_2O_3$ sample showed much higher compressive strength(25 MPa) than the porous HA sample(10 MPa). Fairly dense and uniform HA coating(about $2{\mu}m$ thick) was deposited on the porous $Al_2O_3$ sample. Since the compressive strength of cancellous bone is $2{\sim}12$ MPa, both the porous HA and HA-coated porous $Al_2O_3$ samples could be successfully utilized as scaffolds for bone repair. Especially the latter is expected suitable for load bearing bone substitutes due to its excellent strength.

• 공업화학
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• 제10권7호
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• pp.1061-1065
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• 1999

Calorizing 처리에서 코팅분말의 입자크기 및 코팅온도가 금속표면에 형성된 코팅층의 두께에 미치는 영향을 XRD, SEM, 및 EDXS를 사용하여 고찰하였다. 코팅분말은 입자크기별로 3단계로 분리하였으며 코팅온도는 $950^{\circ}C$와 $980^{\circ}C$로 변화하였다. Calorizing 처리는 공기 및 아르곤 분위기에서 5시간 동안 행하였다. XRD 결과 공기분위기의 calorizing 처리과정에서 금속산화물($Al_2O_3$)과 질화물(AlN)이 형성됨을 관찰하였다. 공기 및 아르곤 분위기의 calorizing 처리 결과 코팅분말의 입자크기가 감소하고 코팅온도가 증가할수록 코팅층의 두께와 코팅층에서의 알루미늄의 함량이 증가함을 알 수 있었다.

• 한국재료학회지
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• 제10권8호
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• pp.558-563
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• 2000

$Y_2SiO_5:Ce$ 형광체를 $In_2O_3$, $Al_2O_3$ 및 $SiO_2$로 코팅한 후 전계 방출 디스플레이에 요구되는 음극선 발광 특성을 조사하였다. $Al_2O_3$ 코팅으로 $Y_2$SiO(sub)5:Ce 형광체의 발광 효율과 에이징 특성은 감소되었다. 한편 $Al_2$$O_3$코팅으로 형광체의 발광효율은 증가하였으나 발광스펙트럼과 색좌표는 일부 변화하였다. 그러나 $Y_2SiO_5:Ce$ 청색 형과체의 발광 효율은 $SiO_2$코팅으로 크게 증가하였으며, 또한 $SiO_2$ 코팅한 $Y_2SiO_5:Ce$ 형광체의 에이징 특성은 코팅 전에 비하여 크게 향상되었다.