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검색결과 634건 처리시간 0.028초

A Study on the Thermal Decomposition Characteristics of Intermediate of Saccharin (삭카린 중간체의 열분해 특성에 관한 연구)

  • 김관응;김영수;신창섭
    • Journal of the Korean Society of Safety
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    • 제13권4호
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    • pp.180-185
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    • 1998
  • The evaluation of thermal and pressure hazard of chemicals on the manufacturing, transporting and storaging is important in the chemical industry for safety. In this study, the thermal decomposition characteristics of intermediate of Saccharin were investigated by using Accelerating Rate Calorimeter(ARC) and Differential Scanning Calorimeter(DSC). Experimental results showed that decomposition temperatures in p-TSA were about 280~$318^{\circ}C$ by DSC and $201^{\circ}C$ by ARC. In case of o-TSA were about $336^{\circ}C$~$360.8^{\circ}C$ by DSC and $299^{\circ}C$ by ARC. The decomposition temperature acquired by ARC was about $70^{\circ}C$ lower than that by DSC. The exothermic runaway reaction in case of p-TSA occured in 598 minute and o-TSA in 5 minute. For the safety in the chemical industry, we should consider the ARC data as well as DSC data in the handling and design of process.

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A Study on the Synthesis of Fine Zirconium Nitride Powder from Zirconium Chloride(IV) (염화지르코늄(IV)으로부터 질화지르코늄 미분체의 합성에 관한 연구)

  • 김영우;장윤식;박홍채;오기동
    • Journal of the Korean Ceramic Society
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    • 제25권2호
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    • pp.184-190
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    • 1988
  • ZrN powder was prepared from the powder mixture of ZrCl4 and Al by the halogenide process in nitrogen gas flow (100-150ml/min) at the temperatures from 200$^{\circ}$to 1050$^{\circ}C$. ZrN powder was formed about 600$^{\circ}C$ and in the slow nitriding reaction, however, an intermediate product of Al3Zr was formed. The fine powder (0.1-10$\mu\textrm{m}$) of single phase ZrN was obtained at 1050$^{\circ}C$ after 1 hour. The lattice parameter and crystallite size of ZrN were 4.5787A and 360A, respectively. According to SEM observation, the particles were apt to agglomerates. The apparent activation energy for the formation of ZrN was approximately 13.2kcal/mole(750$^{\circ}$-1000$^{\circ}C$).

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Structural study on storytelling of VR contents (VR 콘텐츠의 스토리텔링에 대한 구조적 연구)

  • CHO, Il-hyun
    • Journal of Digital Convergence
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    • 제17권1호
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    • pp.295-300
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    • 2019
  • Modern society is the era of convergence, and storytelling requires the necessity of storytelling in which two types of data types, emotional stories and information, are fused. Particularly, in the case of VR contents, the user must directly participate in the content and select the information through the process of freely searching $360^{\circ}$ space, so that the user can interact with the content immediately. Therefore, there is a limit to access to the existing storytelling method, and it is considered that the implementation of 'convergent storytelling' that meets two areas of sensitivity and information is considered to be an urgent genre. In this paper, we focus on the spatial characteristics of VR contents, and then, as a way to effectively implement 'convergent storytelling' in VR contents, We propose a custom system by organizing the type into a circle structure. Based on this, it is expected that the technology will be developed into a research of a personalized system that meets two areas of emotion and information by utilizing the context recognition process for VR content and interaction in the fourth industrial revolution era.

Thermal Properties of Diglycidy1 ether of bisphenol A-4,4'- Methylene dianiline Succinonitrile Hydroquinone system (Diglycidy1 ether of bisphenol A-Mthylene dianiline Succinonitrile Hydroquinone계의 열적 성지)

  • Jeong, Sin-Gyeong;Cheon, In-Suk;Sim, Mi-Ja;Kim, Sang-Uk
    • Korean Journal of Materials Research
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    • 제4권8호
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    • pp.915-920
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    • 1994
  • The thermal properties of Iliglycldyl ether of bisphenol A(DGEBA)-4, 4'-methylene dianiline (MDA)system with SN(Succinonitri1e) as a chain extender and HQ(Hydroquinone) as a reactive accelerator were investigated. Glass transition ternperature(Tg), heat deflection ternperature(HDT) and decomposition ternperature(Td) were measured with IiQ content in wh~ch SN : HQ content was fixed 4 : 1. Tg and HIIT were slightly decreased with increasing IIQ content. Td was stable at about $360^{\circ}C$ according to the changing HQ content and cure temperature.

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Color and Brightness Calibration Convergence Technology for 5D Virtual Reality Attractions (5D 가상현실 어트랙션을 위한 색상 및 밝기 보정 융합 기술)

  • Han, Jung-Soo
    • Journal of the Korea Convergence Society
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    • 제7권1호
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    • pp.25-30
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    • 2016
  • Virtual reality items are increased take-all type of markets like Universal, such as the United States as a leader in the virtual reality technology. Multi-user have to get direct experiences with the whole body like visual, tactile, hearing, sense of movement, and it must be developed new forms of content platform to enjoy immerse deeply into the content. Visitors are not to enjoy the content passively but rather to enjoy the content actively. So it like that should develope content to maximize the immersion. It need the development of new forms of mixed 5D virtual reality Attraction content with all of factors like $360^{\circ}$ circle vision, stereoscopic images, interaction, simulator, and the environmental effect. We proposes how to make the color and brightness calibration technology for this purpose.

Synthesis and Photocharacteristics of Polysiloxane substituted Naphthoquinone-1,2-diazide sulfonyl group (Naphthoquinone-1,2-Diazaide-Sulfonyl기 치환 Polysiloxane의 합성과 그 감광특성)

  • Kang, Doo-Whan;Chung, Nag-Jin
    • Applied Chemistry for Engineering
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    • 제2권4호
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    • pp.348-355
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    • 1991
  • Polysiloxane copolymers were prepared by copolymerizing hexamethylcyclotrisiloxane with tetramethylcyclotetrasiloxane, and then reacted with allyamine. Copolymers containing naphthoquinone-1,2-diazide-5-sulfonyl group were synthesized by reacting naphthoquinone-1,2-diazide-5-sulfonyl chloride with siloxane copolymers having amino group. Thermal decomposition temperatures of copolymers were $360{\sim}450^{\circ}C$, and photosensitive characteristics were dependent on the molecular weights of backbone resins and sensitizers. Sensitivity of copolymers was $50{\sim}120mJ/cm^2$ and contrast(${\gamma}$) was 1.4~2.1.

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VR & Changes in Cinematic Storytelling - Focusing on film composition unit, montage, space, mise-en-scène and perspective - (VR과 영화 스토리텔링의 변화 - 영화 구성단위, 몽타주, 공간성, 미장센, 시점을 중심으로 -)

  • Jeon, Byoungwon;Cha, Minchol
    • Journal of Korea Multimedia Society
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    • 제21권8호
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    • pp.991-1001
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    • 2018
  • In the context of the 4th Industrial Revolution, IoT, Big Data, and VR are rapidly emerging as core sectors of future industries. In particular, the VR has been under the limelight as a new media content appealing to new generation. And the VR user is not merely a 'spectator', but the 'actor'. In other words, the newness of VR is not in the 'more likely representation of the virtual reality', but in the 'making it act more virtual (more technically, 'interactive')' in the virtual world. In this paper, we examine the VR cinema in terms of film composition unit, montage, cinematic space, mise-en-$sc{\grave{e}}ne$ and perspective. The VR cinema, which is in the early stage of evolution, is basically based on $360^{\circ}$ image that strengthens the autonomy of the audience's point of view, but other factors like haptic or sonic immersion are becoming increasingly important. In addition, the VR cinema will be combined with AR, MR, SR, and Interactive technologies, and will expand its horizon as it is produced in various forms. Therefore, it is expected that more detailed viewpoint will be applied in the subsequent study on VR cinema.

A Study on Characteristics of an Terrestrial Magnetism Sensor with Bluetooth (Bluetooth를 이용한 지자기센서의 특성에 관한 연구)

  • Park, Sun-Jin;Jeong, Jung-Su
    • Convergence Security Journal
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    • 제6권3호
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    • pp.37-47
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    • 2006
  • In this research, We connect the terrestrial magnetism sensor of the Philips to a bluetooth communication system and measured 360 degree of the azimuth change the angle with an incline of 5 degrees to an order direction. The value of the azimuth to be measured sent to the Bluetooth communication system and analyzed the measuring value in the 100m as moved. Using the bluetooth, we could send the measuring value of the azimuth without the bearing error in the plain without an electric wave obstacle within a distance in straight line 100M. We got the value of the azimuth have 98% reliability to maintain at a level with the terrestrial magnetism sensor. Based on this research. We send the measuring value of the azimuth which the accuracy is improved to a mobile intelligent robot moving a land inclined equipped with this system and can track the azimuth of it.

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A Design of IQ Modulator for Direct Carrier Modulation Systems (직접 반송파 변조 시스템을 위한 IQ 변조기 설계)

  • Mun, Tae-Su;Kim, Phirun;Jeong, Yong-Chae
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • 제22권9호
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    • pp.847-851
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    • 2011
  • In this paper, a novel IQ modulator that precisely controls the magnitude and phase of input signals is proposed. The proposed IQ modulator consists of low phase deviation attenuators, a splitter, and a combiner. In order to overcome the phase deviation characteristics found in conventional attenuators, a novel phase compensation technique has been adopted and mathematically analyzed. Linear vector arrays along the center point with large magnitude output signal variations in a full $360^{\circ}$ phase control are achieved on a polar plane by the proposed IQ modulator.

Characterization of Heat Reformed Naphtha Cracking Bottom Oil Extracts

  • Oh, Jong-Hyun;Lee, Jae-Young;Kang, Seok-Hwan;Rhee, Tai-Hyung;Ryu, Seung-Kon
    • Carbon letters
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    • 제9권4호
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    • pp.289-293
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    • 2008
  • Naphtha Cracking Bottom (NCB) oil was heat reformed at various reforming temperature and time, and the volatile extracts were characterized including yields, molecular weight distributions, and representative compounds. The yield of extract increased as the increase of reforming temperature ($360{\sim}420^{\circ}C)$ and time (1~4 hr). Molecular weight of the as-received NCB oil was under 200, and those of extracts were distributed in the range of 100-250, and far smaller than those of precursor pitches of 380-550. Naphtalene-based compounds were more than 70% in the as-received NCB oil, and most of them were isomers of compounds bonding functional groups, such as methyl ($CH_{3^-}$) and ethyl ($C_2H_{5^-}$). When the as-received NCB oil was reformed at $360^{\circ}C$ for 1 hr, the most prominent compound was 1,2-Butadien, 3-phenyl- (24.57%), while naphthalene became main component again as increasing the reforming temperature.