• Current Applied Physics
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• 제18권11호
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• pp.1352-1358
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• 2018

In recent years, one-dimensional (1D) magnetic nanostructures, such as magnetic nanorods and chains of magnetic nanoparticles have received great attentions due to the breadth of applications. Especially, magnetic nanorods has been opened an area of active research and applications in medicine, sensors, optofluidics, magnetic swimming, and microrheology since they possess the unique magnetic and geometric features. This study focuses on the molecular dynamics (MD) simulations of an infinitely long crystal ${\beta}-Fe_2O_3$ nanorod. To elucidate the structural properties and dynamics behavior of ${\beta}-Fe_2O_3$ nanorods, MD simulation is a powerful technique. The structural properties such as equation of state and radial distribution function of bulk ${\beta}-Fe_2O_3$ are performed by lattice dynamics (LD) simulations. In this work, we consider three main mechanisms affecting on deformation characteristics of a ${\beta}-Fe_2O_3$ nanorod: 1) temperature, 2) the rate of mechanical compression, and 3) the rate of mechanical torsion.

• 한국재료학회지
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• 제22권11호
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• pp.620-625
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• 2012

A general synthetic method to make $Fe_3O_{4-{\delta}}$ (activated magnetite) is the reduction of $Fe_3O_4$ by $H_2$ atmosphere. However, this process has an explosion risk. Therefore, we studied the process of synthesis of $Fe_3O_{4-{\delta}}$ depending on heat-treatment conditions using $FeC_2O_4{\cdot}2H_2O$ in Ar atmosphere. The thermal decomposition characteristics of $FeC_2O_4{\cdot}2H_2O$ and the ${\delta}$-value of $Fe_3O_{4-{\delta}}$ were analyzed with TG/DTA in Ar atmosphere. ${\beta}-FeC_2O_4{\cdot}2H_2O$ was synthesized by precipitation method using $FeSO_4{\cdot}7H_2O$ and $(NH_4)_2C_2O_4{\cdot}H_2O$. The concentration of the solution was 0.1 M and the equivalent ratio was 1.0. ${\beta}-FeC_2O_4{\cdot}2H_2O$ was decomposed to $H_2O$ and $FeC_2O$4 from $150^{\circ}C$ to $200^{\circ}C$. $FeC_2O4$ was decomposed to CO, $CO_2$, and $Fe_3O_4$ from $200^{\circ}C$ to $250^{\circ}C$. Single phase $Fe_3O_4$ was formed by the decomposition of ${\beta}-FeC_2O_4{\cdot}2H_2O$ in Ar atmosphere. However, $Fe_3C$, Fe and $Fe_4N$ were formed as minor phases when ${\beta}-FeC_2O_4{\cdot}2H_2O$ was decomposed in $N_2$ atmosphere. Then, $Fe_3O_4$ was reduced to $Fe_3O_{4-{\delta}}$ by decomposion of CO. The reduction of $Fe_3O_4$ to $Fe_3O_{4-{\delta}}$ progressed from $320^{\circ}C$ to $400^{\circ}C$; the reaction was exothermic. The degree of exothermal reaction was varied with heat treatment temperature, heating rate, Ar flow rate, and holding time. The ${\delta}$-value of $Fe_3O_{4-{\delta}}$ was greatly influenced by the heat treatment temperature and the heating rate. However, Ar flow rate and holding time had a minor effect on ${\delta}$-value.

• 한국분말재료학회지
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• 제20권3호
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• pp.210-214
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• 2013

This manuscript reports on compared color evolution about phase transformation of ${\alpha}-FeOOH@SiO_2$ and ${\beta}-FeOOH@SiO_2$ pigments. Prepared ${\alpha}$-FeOOH and ${\beta}$-FeOOH were coated with silica for enhancing thermal properties and coloration of both samples. To study phase and color of ${\alpha}$-FeOOH and ${\beta}$-FeOOH, we prepared nano sized iron oxide hydroxide pigments which were coated with $SiO_2$ using tetraethylorthosilicate and cetyltrimethyl-ammonium bromide as a surface modifier. The silica-coated both samples were calcined at high temperatures (300, 700 and $1000^{\circ}C$) and characterized by scanning electron microscopy, CIE $L^*a^*b^*$ color parameter measurements, transmission electron microscopy and UV-vis spectroscopy. The yellow ${\alpha}$-FeOOH and ${\beta}$-FeOOH was transformed to ${\alpha}-Fe_2O_3$ with red, brown at 300, $700^{\circ}C$, respectively.

• 한국재료학회지
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• 제1권4호
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• pp.198-205
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• 1991

$Fe_2O_3,\;Al_2O_3,\;TiO_2$ 및 Si분말을 사용하여 고상반응법으로 써어미스터 소결체를 합성하였다. 합성된 소결체의 조식특성을 SEM으로 조사하고, 액체항온조에서 $-50~+50^{\circ}C$ 온도영역에서의 측정 결과 $\beta$상수가 972~4005K의 값을 갖는 써어미스터 소결체를 얻었다. 이 소결체는 고공기온측정을 위한 라디오존데용 온도센서로 사용될 수 있다.

• 한국세라믹학회:학술대회논문집
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• 한국세라믹학회 2002년도 추계총회 및 연구발표회 초록집
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• pp.70.1-70
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• 2002

• Corrosion Science and Technology
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• 제2권3호
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• pp.148-154
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• 2003

The addition of Ni leads to the formation of protective rust layer on steel and subsequently high corrosion resistance of steel in $Cl^-$-containing environment. $\alpha$-FeOOH, $\beta$-FeOOH, $\gamma$-FeOOH and $Fe_3O_4$ are formed mainly on steels exposed to $Cl^-$-containing environment. As the first work of this kind, this study reports the influence of Ni on the oxidation behavior of $Ni_xFe_{1-x}(OH)_2$ in $Cl^-$-containing solution at two different pH regions(condition I under which the solution pH is allowed to decrease and condition I under which solution pH is maintained at 8) where $\gamma$-FeOOH and $Fe_3O_4$ are predominantly formed, respectively, upon oxidation of $Fe(OH)_2$, In the presence of Ni(II) in the starting solution, the formation of $\beta$-FeOOH was facilitated and the formation of $\gamma$-FeOOH was suppressed with increasing Ni(II) content and with increasing oxidation rate of Fe(II). Ni(II) was found to have $Fe_3O_4$-suppressing effect under condition II.

• 한국자기학회지
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• 제2권1호
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• pp.29-36
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• 1992

본 연구에서는 장래의 전자공업 및 정보산업의 기본소재로서 그 응용이 기대되고 있는비정질 산화물자성체를 개발하기 위한 기초연구를 수행하였다. 현재 연구보고 되어 있는 강자성비정질 산화물은 같은 조성의 다결정 ferrite에 비하여 그 자성이 빈약하므로 자성이 좀더 강한비정질 spinel ferrite의 개발이 요구된다. 자체 제작한 쌍 roller 초급내장치로써 $CaO-B_{2}O_{3}$ 계 amorphous ferrite 시료를 제조하고 얻어진 시편의 제특성을 조사하기 위해 XRD, DTA/TG, VSM, $M\"{o}ssbauer$ spectrum으로 측정한 결과 다음과 같은 결론을 얻었다. $CaO-Bi_{2}O_{3}$ 계 amorphous ferrite는 10-50 mole% CaO, 10-50 mole% $Bi_{2}O_{3}$. 40-70 mole% $Fe_{2}O_{3}$의 조성 영역에서 제조가 가능하고 $BiFeO_{3}$와 $CaFe_{4}O_{7}$의 혼합 조성부근에서 강력한 자화를 나타낸다. 특히 ${(CaO)}_{20}-{(Bi_{2}O_{3})}_{15}{(Fe_{2}O_{3}}_{65}$의 조성에 있어서는 자화가 약 21.84 emu/g(10 kOe)이며 강 자성적인 거동을 나타낸다. 이 비정질 ferrite는 반강자성상($\alpha$-상)과 강자성상($\beta$-상)으로 되어 있다. 비정질 ferrite의 결정화는 $550^{\circ}C$와 $775^{\circ}C$에서 2단계로 일어나고, 그때 나타나는 결정상은 $BiFeO_{3}$의 perovskite 상과 ${\alpha}-Fe_{2}O_{3}$ 상이다.

• 대한약리학회지
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• 제31권3호
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• pp.345-353
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• 1995

Harmaline을 포함한 ${\beta}-Carboline$ 알카로이드들은 마이크로조움의 효소성 또는 비효소성 지질 과산화를 억제한다고 제시되고 있으나, 이들의 항산화 작용기전은 분명하지 않다. 본 연구에서는 $Fe^{2+}$와 $H_2O_2$에 의한 hyaluronic acid, 지질과 콜라젠의 산화성 손상에 있어 harmaline과 harmalol의 항산화 능력을 관찰하였다. 또한 반응성 산소대사물에 대한 이들의 제거작용을 조사하였다. Harmaline, harmalol, superoxide dismutase, catalase와 DMSO는 $Fe^{2+}$와 $H_2O_2$에 의한 hyaluronic acid의 변성과 $Fe^{2+}$에 의한 지질 과산화를 억제하였다. 이들 반응에서 DABCO는 hyaluronic acid의 변성을 억제하였으나 지질 과산화에 영향을 나타내지 않았다. ${\beta}-Carboline$은 $Fe^{2+}$, $H_2O_2$와 ascorbic acid에 의한 cartilage collagen의 변성을 억제하였다. Superoxide dismutase에 의하여 억제되는 $Fe^{2+}$의 자가산화에 따른 ferricytochrome c의 환원은 harmaline과 harmalol의 영향을 받지 않았다. 또한 이들은 $H_2O_2$에 대하여 분해작용을 나타내지 않았다. $Fe^{2+}$와 $H_2O_2$의 존재하에서 OH 생성은 harmaline, harmalol과 DMSO에 의하여 억제되었다. Harmaline과 harmalol은 반응성 산소대사물인 OH 과 아마도 철이온-산소 복합체에 대한 제거작용으로써 $Fe^{2+}$와 $H_2O_2$에 의한 hyaluronic acid, 지질과 콜라젠의 산화성 손상을 억제하고, 항산화 능력을 나타낼 것으로 추정된다.

• 한국재료학회지
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• 제17권3호
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• pp.132-136
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• 2007

Oxidation resistance of sintered ${\beta}-FeSi_{2}$ was investigated at intermediate temperature range in air atmosphere. Fully dense and porous bodies of ${\beta}-FeSi_{2}$ samples were fabricated by using the Spark Plasma Sintering (SPS). They were annealed at $900^{\circ}C$ for 5days to obtain ${\beta}-FeSi_{2}$ phase. The bulk samples were oxidized at $800,\;900\;and\;950^{\circ}C$ in air atmosphere. The high temperature oxidation tests reveal that amorphous $SiO_{2}$ layer, similar to Si was formed and grew parabolically on ${\beta}-FeSi_{2}$. Accelerated oxidation is not observed as well as cracks and grain boundary oxidation. Granular ${\varepsilon}-FeSi$ was developed below the oxide layer as a result of oxidation of ${\beta}-FeSi_{2}$. Oxidation resistance of sintered ${\beta}-FeSi_{2}$ was excellent for high-temperature thermoelectric application.

• 한국결정성장학회지
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• 제22권1호
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• pp.57-63
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• 2012

$Al_2TiO_5$에 LAS(${\beta}$-spodumene)와 $Fe_2O_3$를 첨가하여 고상법으로 세라믹 소결체를 제조하였다. $Al_2TiO_5$에 첨가된 LAS는 액상을 형성하고, $Fe_2O_3$는 입자 성장을 억제시켜 소결체를 치밀화하였다. 첨가제의 양을 변화시켜 소결특성, 기계적 특성 및 열충격 특성에 대하여 조사하였다. $Fe_2O_3$가 20 wt% 첨가된 LAS를 $Al_2TiO_5$에 20 wt% 첨가하였을 때, 꺽임 강도는 120 MPa 이상이었고, 열충격에 대한 저항성은 $1200^{\circ}C$ 이상으로 우수함을 확인하였다.