• Bulletin of the Korean Chemical Society
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• 제31권4호
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• pp.781-788
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• 2010

Experimental and theoretical studies show that all covalent azides possess a nonlinear azide group. They also rationalize this remarkable structural feature. We have seen that the most important non-covalent contributions in the covalently bound azides system (X-N1-N2-N3) are the $\pi$-delocalization over the entire molecule and a strong negative hyperconjugation which donates electron density from the filled $\sigma$ (X-N1) orbital into the unfilled, antibonding $\pi^*$ (N2-N3) orbital. For transition metal azide complexes, a bent configuration and a small difference between the N-N bond lengths, generally the longer one being adjacent to the transition metal, were observed.

• 한국수학교육학회지시리즈B:순수및응용수학
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• 제4권2호
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• pp.137-144
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• 1997

In this paper we consider covering problems in spherical geometry. Let $cov_q{S_1}^n$ be the smallest radius of q equal metric balls that cover n-dimensional unit sphere ${S_1}^n$. We show that $cov_q{S_1}^n\;=\;\frac{\pi}{2}\;for\;2\leq\;q\leq\;n+1$ and $\pi-arccos(\frac{-1}{n+1})$ for q = n ＋ 2. The configuration of centers of balls realizing $cov_q{S_1}^n$ are established, simultaneously. Moreover, some properties of $cov_{q}$X for the compact metric space X, in general, are proved.

• Bulletin of the Korean Chemical Society
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• 제22권12호
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• pp.1316-1322
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• 2001

Transition metal complexes of novel mono- and di-ferrocene-substituted porphyrins have been synthesized and characterized by structural and electrochemical methods. The X-ray structures of Mn(FPTTP)Cl and Mn(DFTTP)Cl showed the distorted square pyramidal coordination geometry with syn configuration of chloride and ferrocenyl substituents. The electrochemistry of ferrocene-substituted porphyrins and their metal complexes has been determined to elucidate the ${\pi}-conjugation$ effect of the porphyrin ring. The ferrocenyl group of H2FPTTP underwent a reversible one-electron transfer process at 0.30 V, indicating the good electron donating effect of the phorphyrin ring to the ferrocene substituent. The redox potential of the ferrocenyl subunit and porphyrin ring was affected by the central metal ions of the metalloporphyrins, that is, Zn(II) and Ni(II) made the oxidation of ferrocene much easier and Mn(III) made it harder. The ferrocene subunits of H2DFTTP interacted electrochemically with each other with peak splitting of 0.21 V. The strength of the electrochemical interactions between the two ferrocenyl substituents can be controlled by central metal ions of metalloporphyrins.

• 대한화학회지
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• 제68권3호
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• pp.146-150
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• 2024

Precise molecular configuration elucidation of poly(3-hexylthiophene) (P3HT) through advanced spectroscopic techniques is pivotal for enhancing P3HT-based photovoltaic device efficiencies since its high charge-carrier mobility is directly correlated to its well-ordered structure. In this study, we examine Raman depolarization ratios of annealed and non-annealed P3HT films to elucidate their intermolecular π-π configurations. Our findings suggest that the backbone of the annealed film possesses stronger π-π conjugation overlaps than that of the non-annealed film owing to the greater depolarization ratio of the annealed film. In addition, the depolarization ratios are also supported by theoretical calculations, where parallel-stacked thiophene structures display a higher depolarization ratio compared with that of twisted-stacked structures, as calculated by the Møller-Plesset perturbation theory. This study highlights the utility of polarized Raman spectroscopy as a versatile tool for assessing the degree of molecular order in highly conjugated polymer films.

• 한국전자통신학회논문지
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• 제11권4호
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• pp.433-440
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• 2016

최근 IT분야에서 화두가 되고 있는 빅데이터 처리를 위한 시스템 환경의 구축을 위해서는 다수의 컴퓨터를 네트워크 장비를 통해 연결하여 노드를 구성하거나, 하나의 컴퓨터에 다수의 가상 호스트를 통한 클라우딩 환경을 구축하여야 한다. 그러나 이러한 빅데이터 분석 시스템을 구축하는 것은 복잡한 시스템 구성과 비용적인 측면에서 많은 제약이 따른다. 이러한 제약은 중요한 국가 경쟁력의 하나로 부각되고 있는 빅데이터 전문 인력 양성에 큰 걸림돌이 되고 있다. 이에 본 연구에서는 빅데이터 분야의 인력 양성을 위한 교육현장에서 저렴한 가격으로 실용적인 교육이 가능한 라즈베리파이 보드 기반의 교육용 빅데이터 분석 시스템을 제안하였다.

• Journal of Electrical Engineering and Technology
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• 제13권3호
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• pp.1131-1137
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• 2018

In this paper, the authors suggest a new control algorithm for a three-phase four-wire photovoltaic (PV) inverter with imbalance load compensation function using conventional proportional-integral (PI) controllers. The maximum power of PV panel is calculated by the MPPT control loop. The reference varying signals of current controllers are transformed to two different rotating frames where they become constant signals. Then simple PI controllers are applied to achieve zero steady-state error of the controllers. The proposed control algorithm are modeled and simulated with imbalance load configuration to verify its performance. The simulation results show that the maximum PV power is transferred to the grid and the imbalance power is compensated successfully by the proposed control algorithm. The inverter has a fast response (~4 cycles) during the transient period. The proposed control algorithm can be effectively utilized to the three-phase four-wire inverter with imbalance load compensation function.

• 한국세라믹학회지
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• 제23권4호
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• pp.47-54
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• 1986

Since the wall mobility of bubble magnetic materials havin g the large q (q=Kac/2$\pi$$M_s^2$) like a $YFeO_3$ has been found to be proportional to the wall energy theoretically crystallographical direction dependence of wall energy calculated by the basis on the spin configuration of the bubble wall which lies in the ac plane was compared with the crystallographical direction dependence of wall mobility which was measured by the experiment. The sample was a single crystal of $YFeO_3$ which was cut into plate normal to the C axis and polished t a thickness of about 60${\mu}{\textrm}{m}$ The measurement of the wall mobility was carried out by optical system using the magneto-optic Faraday effect. From the good agreement of the crystallographical direction dependence of wall mobility and will energy it was found that the spin configuration of the bubble wall suggested is fair.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 1992년도 한국자동제어학술회의논문집(국내학술편); KOEX, Seoul; 19-21 Oct. 1992
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• pp.658-663
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• 1992

In this paper, the control of a DC servo motor position control is implemented with fuzzy controller using IBM PC AT. In addition to the fuzzy controller with the error and change of error inputs PI controller is applied as well to improve the steady state error response. It shows the above configuration results in a good control characteristics.

• 한국전자통신학회논문지
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• 제9권7호
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• pp.791-797
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• 2014

빅데이터의 병렬분산처리 시스템을 위한 아파치 하둡 환경을 구축하기 위해서는 다수의 컴퓨터를 연결하여 노드를 구성하거나, 하나의 컴퓨터에 다수의 가상 노드 구성을 통해 클라우딩 환경을 구축하여야 한다. 그러나 이러한 시스템을 교육 환경에서 실습용으로 구축하는 것은 복잡한 시스템 구성과 비용적인 측면에서 많은 제약이 따른다. 따라서 빅데이터 처리 분야의 입문자들과 교육기관의 실습용으로 사용할 수 있는 실용적이고 저렴한 학습 시스템의 개발이 시급하다. 본 연구에서는 라즈베리파이 보드를 기반으로 하둡과 NoSQL과 같은 빅데이터 처리 및 분석 실습이 가능한 빅데이터 병렬분산처리 학습시스템을 설계 및 구현하였다. 구현된 빅데이터 병렬분산처리시스템은 교육현장과 빅데이터를 시작하는 입문자들에게 유용한 시스템이 될 것으로 기대된다.

• 한국통신학회논문지
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• 제29권4A호
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• pp.458-465
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• 2004

본 논문에서는 CMOS 공정을 사용하여 선형적으로 제어가 가능한 П모델 감쇄기를 구현하였고, 브릿지 T모델을 사용한 감쇄기를 제안하였다. CMOS 공정으로 코어의 수동소자를 트랜지스터로 구현하여 기존의 수동소자나 능동소자를 사용하는데 따른 문제점을 개선하였으며 GaAs MESFET공정의 문제점인 높은 비용 또한 해결하였다. П모델 감쇄기는 2-poly 4-metal 0.35$\mu\textrm{m}$ CMOS 공정을 사용하여 구현하였으며 기존의 수백 MHz의 동작 주파수범위를 DC-l㎓ 대역으로 향상시켰다. 또한 700$\mu\textrm{m}$${\times}$300$\mu\textrm{m}$ 로 면적을 줄였으며 일정한 주파수에서 감쇄 값과 제어 전압 사이의 선형적인 관계를 개선하였다. 제안된 브릿지 T모델 감쇄기는 П모델에서 동작주파수를 제한하던 매칭 특성을 향상시킴으로써 동작 주파수 템위를 DC-2㎓ 대역으로 넓혔다.