Browse > Article
http://dx.doi.org/10.5012/bkcs.2010.31.04.781

Inorganic and Transition Metal Azides  

Seok, Won-K. (Department of Chemistry, Dongguk University)
Klapotke, Thomas M. (Department of Chemistry, University of Munich (LMU))
Publication Information
Bulletin of the Korean Chemical Society / v.31, no.4, 2010 , pp. 781-788 More about this Journal
Abstract
Experimental and theoretical studies show that all covalent azides possess a nonlinear azide group. They also rationalize this remarkable structural feature. We have seen that the most important non-covalent contributions in the covalently bound azides system (X-N1-N2-N3) are the $\pi$-delocalization over the entire molecule and a strong negative hyperconjugation which donates electron density from the filled $\sigma$ (X-N1) orbital into the unfilled, antibonding $\pi^*$ (N2-N3) orbital. For transition metal azide complexes, a bent configuration and a small difference between the N-N bond lengths, generally the longer one being adjacent to the transition metal, were observed.
Keywords
Covalent inorganic azides; Transition metal azide complexes; $^{14}N$ NMR spectrum;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
Times Cited By Web Of Science : 5  (Related Records In Web of Science)
Times Cited By SCOPUS : 5
연도 인용수 순위
1 Allen, A. D.; Senoff, C. W. Chem. Commun. 1965, 621.
2 Mackay, B. A.; Fryzuk, M. D. Chem. Rev. 2004, 104, 385.   DOI   ScienceOn
3 Leising, R. A.; Kubow, S. A.; Churchill, M. R.; Buttrey, L. A.; Ziller, J. W.; Takeuchi, K. Inorg. Chem. 1990, 29, 1306.   DOI
4 Greenwood, N. N.; Earnshaw, A. Chemistry of the Elements; Pergamon: Oxford, 1984.
5 Hantzsch, A.; Schümann, M. Ber. Dtsch. Chem. Ges. 1900, 33, 522.   DOI
6 Geissler, P.; Klapotke, T. M.; Kroth, K.-H. Spectrochim. Acta 1995, 51A, 1075.
7 Tornieporth-Oetting, I. C.; Klapotke, T. M. Angew. Chem. Int. Ed. 1995, 34, 511.   DOI   ScienceOn
8 Sima, J. Coord. Chem. Rev. 2006, 250, 2325.   DOI   ScienceOn
9 Mazumder, B.; Chirico, P.; Hector, A. L. Inorg. Chem. 2008, 47, 9684.   DOI   ScienceOn
10 Concepcion, J. J.; Jurss, J. W.; Templeton, J. L.; Meyer, T. J. J. Am. Chem. Soc. 2008, 130, 16462.   DOI   ScienceOn
11 Strähle, J. Z. Anorg. Allg. Chem. 2007, 633, 1757.   DOI   ScienceOn
12 Suzuki, T.; Kotera, M.; Takayama, A.; Kojima, M. Polyhedron 2009, 28, 2287   DOI   ScienceOn
13 Ercan, F.; Ates, B. M.; Aksu, L.; Soezeri, H.; Ercan, I.; Akatol, O. Z. Kristallogr. 2007, 222, 498.   DOI   ScienceOn
14 Massoud, S. S.; Mautner, F. A.; Abu-Youssef, M. A. M.; Shuaib, N. M. Polyhedron 1999, 18, 2061.   DOI   ScienceOn
15 Munz, H.-O.; Bodenseh, H.-K.; Klapötke, T. M. 14th Colloquium on High-Resolution Molecular Spectroscopy, September 11-15, Dijon, 1995.
16 Tornieporth-Oetting, I. C.; Buzek, P.; Schleyer, P. v. R.; Klapotke,T. M. Angew. Chem. Int. Ed. Engl. 1992, 31, 1338.   DOI
17 Tornieporth-Oetting, I. C.; Klapotke, T. M.; Schulz, A.; Buzek,P.; Schleyer, P. v. R. Inorg. Chem. 1993, 32, 5640.   DOI   ScienceOn
18 Schulz, A.; Tornieporth-Oetting, I. C.; Klapotke, T. M. Inorg Chem. 1995, 34, 4343.   DOI   ScienceOn
19 Klapotke, T. M. In Moderne Anorganische Chemie, 3rd ed.; Riedel, E., Ed.; Walter de Gruyter: Berlin, 2007.
20 Janoschek, R. Angew. Chem. Int. Ed. 1993, 32, 230.   DOI
21 Holleman, A. F.; Wiberg, E.; Niberg, N. Lehrbuch der Anorganischen Chemie; Walter de Gruyter: Berlin-New York, 1985.
22 Campana, C. F.; Lo, F. Y.-K.; Dahl, L. F. Inorg. Chem. 1979, 18,3060.   DOI
23 Christe, K. O.; Wilson, W. W.; Dixon, D. A.; Khan, S. I.; Bau, R.;Metzenthin, T.; Lu, R. J. Am. Chem. Soc. 1993, 115, 1836.   DOI   ScienceOn
24 Almenningen, A.; Bak, B.; Jansen, P.; Strand, T. G. Acta Chem. Scand. 1973, 27, 1531.
25 McMahan, M. K.; Lasar, R. Phys. Rev. Lett. 1985, 54, 1929.   DOI   ScienceOn
26 Christe, K. O.; Christen, D.; Oberhammer, H.; Schack, C. J. Inorg. Chem. 1984, 23, 4283.   DOI
27 Ebsworth, E. A. V.; Jenkins, D. R.; Mays, M. J.; Sugden, T. M.Proc. Chem. Soc. 1963, 21.
28 Muidoch, J. D.; Rankin, D. W. H. Chem. Commun. 1972, 748.
29 Haiges, R.; Boatz, J. A.; Bau, R.; Schneider, S.; Schroer, T.; Yousufuddin,M.; Christe, K. O. Angew. Chem. Int. Ed. 2005, 44, 1860.   DOI   ScienceOn
30 Walstrom, A.; Pink, M.; Yang, X.; Tomaszewski, J.; Baik, M.-H.;Caulton, K. G. J. Am. Chem. Soc. 2005, 127, 5330.   DOI   ScienceOn
31 Zhang, L.; Li, L.-C.; Jiang, Z.-H.; Yan, S.-P.; Shen, P.-W. Inorg. Chimica Acta 2001, 320, 141.   DOI   ScienceOn
32 Shin, J. H.; Bridgewater, B. M.; Churchill, D. G.; Baik, M.-H.;Friesner, R. A.; Parkin, G. J. Am. Chem. Soc. 2001, 123, 10111.   DOI   ScienceOn
33 Belton, P. S.; Woollins, J. D. Magn. Reson. Chem. 1986, 24, 1080.   DOI
34 Passmore, J.; Schriver, M. J. Inorg. Chem. 1988, 27, 2749.   DOI
35 Winnewisser, B. P. J. Mol. Spectrosc. 1980, 82, 220.   DOI   ScienceOn
36 Seok, W. K.; Lee, H. N.; Kim, M. Y.; Klapotke, T. M.; Dong, Y. K.; Yun, H. J. Organomet. Chem. 2002, 654, 170.   DOI   ScienceOn
37 Crawford, M.-J.; Ellern, A.; Mayer, P. Angew. Chem. Int. Ed. 2005, 44, 7874   DOI   ScienceOn
38 Candan, P.; Manzano, C.; Losada, M. Nature 1976, 262, 715.   DOI
39 White, R. E.; Coon, M. J. Annu. Rev. Biochem. 1980, 49, 315.   DOI   ScienceOn
40 Averill, B. A. Chem. Rev. 1996, 96, 2951.   DOI   ScienceOn
41 Nugent, W. A.; Mayer, J. M. Metal-Ligand Multiple Bonds; Wiley-Interscience: New York, 1988.
42 Berry, J. F.; Bill, E.; Bothe, E.; George, S. D.; Mienert, B.; Neese, F.; Wieghardt, K. Science 2006, 312, 1937.   DOI   ScienceOn
43 Glukhovtsev, M. N.; Schleyer, P. v. R. Chem. Phys. Lett. 1992,198, 547.   DOI   ScienceOn
44 Ang, H. G.; Kwik, W.-L.; Lee, Y. W.; Oberhammer, H. Inorg. Chem. 1994, 33, 4425.   DOI   ScienceOn
45 Ang, H. G.; Kwik, W.-L.; Lee, Y. W.; Liedle, S.; Oberhammer, H.J. Mol. Struct. 1992, 268, 389.   DOI   ScienceOn
46 Ang, H. G.; Lee, Y. W.; Novak, I.; Potts, A. W. J. Phys. Chem.1994, 98, 12526.   DOI   ScienceOn
47 Harcourt, R. D. J. Mol. Struct. 1993, 300, 245.   DOI   ScienceOn
48 Harcourt, R. D. Chem. Eng. News 1985, 53(3), 77.
49 Harcourt, R. D. New J. Chem. 1992, 16, 667.
50 Harcourt, R. D. J. Mol. Struct. (Theochem) 1992, 259, 155   DOI   ScienceOn
51 Harcourt, R. D.; Sillitoe, J. F. Aust. J. Chem. 1974, 27, 691.   DOI
52 Cook, R. L.; Gerry, M. C. L. J. Chem. Phys. 1970, 53, 2525.   DOI
53 Johnson, J. P.; MacLean, G. K.; Passmore, J.; White, P. S. Can. J. Chem. 1989, 67, 1687.   DOI
54 Tornieporth-Oetting, I. C.; Klapötke, T. M. Combustion Efficiency and Air Quality; Hargittai, I., Vidoczy, T., Eds.; Plenum: New York,1995.
55 Dehnicke, K. Adv. Inorg. Chem. Radiochem. 1983, 26, 169.   DOI
56 Klapotke, T. M. Chem. Ber. 1997, 130, 443.   DOI
57 Seok, W. K.; Yim, S. B.; Klapotke, T. M.; White, P. S. J. Organomet. Chem. 1998, 559, 165.   DOI   ScienceOn
58 Scepaniak, J. J.; Fulton, M. D.; Bontchev, R. P.; Duesler, E. N.; Kirk, M. L.;Smith, J. M. J. Am. Chem. Soc. 2008, 130, 10515.   DOI   ScienceOn
59 Christen, D.; Mack, H. G.; Schatte, G.; Willner, H. J. Am. Chem. Soc. 1988, 110, 707.   DOI
60 Aliaga-Alcalde, N.; George, S. D.; Mienert, B.; Bill, E.; Wieghardt,K.; Neese, F. Angew. Chem. Int. Ed. 2005, 44, 2908.   DOI   ScienceOn
61 Kim, W. S.; Kim, Y.-J.; Lee, S. W. Bull. Korean Chem. Soc.2002, 23, 1177   과학기술학회마을   DOI   ScienceOn
62 Kim, Y.-J.; Lee, S.-H.; Lee, S.-H; Jeon, S. I.;Lim, M. S.; Lee, S. W. Inorg. Chimica Acta 2005, 358, 650.   DOI   ScienceOn
63 Matsumura, S.; Shikano, K.; Oi, T.; Suzuki, N.; Nagao, H. Inorg. Chem. 2008, 47, 9125.   DOI   ScienceOn
64 Demadis, K. D.; Meyer, T. J.; White, P. S. Inorg. Chem. 1998, 37,3610.   DOI   ScienceOn
65 Richardson, W. C.; Setser, D. W. Can. J. Chem. 1969, 47, 2725.   DOI
66 Alexander, M. H.; Werner, H.-J.; Dagdigina, P. J. J. Chem. Phys.1988, 89, 1388.   DOI
67 Kajimoto, O.; Yamamoto, T.; Fueno, T. J. Phys. Chem. 1979, 83,429.   DOI
68 Otto, M.; Lotz, S. D.; Frenking, G. Inorg. Chem. 1992, 31, 3647.   DOI
69 Schulz, A.; Tornieporth-Oetting, I. C.; Klapotke, T. M. Inorg. Chem. 1995, 34, 4343.   DOI   ScienceOn
70 Hargittai, M.; Tornieporth-Oetting, I. C.; Klapötke, T. M.; Kolonitz,M.; Hargittai, I. Angew. Chem. Int. Ed. 1993, 32, 759.   DOI   ScienceOn
71 Buzek, P.; Klapötke, T. M.; Schleyer, P. v. R.; Tornieporth-Oetting,I. C.; White, P. S. Angew. Chem. Int. Ed. 1993, 32, 275.   DOI
72 Kotera, M.; Sekioka, Y.; Suzuki, T. Inorg. Chimica Acta 2008,361, 1479.   DOI   ScienceOn
73 Hargittai, M.; Molnar, J.; Klapötke, T. M.; Tornicporth-Oetting,I. C.; Kolonitz, M.; Hargittai, I. J. Phys. Chem. 1994, 98, 10095.   DOI   ScienceOn
74 Schleyer, P. v. R.; Kos, A. J. Tetrahedron 1983, 39, 1141.   DOI   ScienceOn
75 Schleyer, P. v. R.; Kaufmann, E.; Kos, A, J.; Mayr, H.; Chandrasekhar,J. Chem. Commun. 1986, 1583.
76 Dave, B. C.; Czemuszewicz, R. S. J. Coord. Chem. 1994, 33, 257.   DOI   ScienceOn
77 Reed, A. E.; Curtiss, L. A.; Weinhold, F. Chem. Rev. 1988, 88, 899.   DOI
78 Seok, W. K.; Yim, S. B.; Lee, H. N.; Klapötke, T. M. Z. Naturforsch.2000, 55b, 462.
79 Dorner, H.; Dehnicke, K.; Massa, W.; Schmidt, R. Z. Naturforsch. B 1983, 38, 437.
80 Dubgen, R.; Dehnicke, K. Naturwissenschaften 1978, 65, 535.   DOI
81 Dehnicke, K. Angew. Chem. Int. Ed. 1967, 6, 240.   DOI
82 Ang, H. G.; Cai, Y. M.; Kwik, W. L. 11th Winter Fluorine ACS Conference, Lecture 35, St. Petersburg, USA, 1993.
83 Siivari, J.; Chivers, T.; Laitinen, R. Angew. Chem. Int. Ed. 1992,31, 1518.   DOI
84 Erments, M. I.; Gavriliuk, A. G.; Serebryanaya, N. R.; Trojan, I.A.; Dzivenko, D. A.; Boehler, R.; Mao, H. K.; Hemley, R. J. J. Chem. Phys. 2004, 121, 11296.   DOI   ScienceOn
85 Evans, W. J.; Kozimor, S. A.; Ziller, J. W. Science 2005, 309, 1835.   DOI   ScienceOn
86 Kolb, H. C.; Finn, M. G.; Sharpless, K. B. Angew. Chem. Int. Ed.2001, 40, 2004.   DOI   ScienceOn
87 Evans, R. A. Aust. J. Chem. 2007, 60, 384.   DOI   ScienceOn
88 Erments, M. I.; Gavriliuk, A. G.; Trojan, I. A.; Dzivenko, D. A.;Boehler, R. Nature Materials 2004, 121, 11296.
89 Erments, M. I.; Popov, M. Y.; Trojan, I. A,; Denisov, V. N.;Boehler, R.; Hemley, R. J. J. Chem. Phys. 2004, 120, 10618.   DOI   ScienceOn
90 Hanfland, M.; Lorenzen, M.; Wassilew-Ruel, C.; Zontone, F. Rev. High Pressure Sci. Technol. 1998, 7, 787.   DOI
91 Martin, R. M.; Needs, R. J. Phys. Rev. B 1986, 34, 5082.   DOI   ScienceOn