• Journal of the Korean Chemical Society
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• v.28 no.1
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• pp.26-33
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• 1984

The rate constants for the following vibration-to-vibration energy exchange reactions have been calculated theoretically for the temperature range from 300 to 800K and for n = 2 to 5. HF(v=n) + DF(v=0) ${\to}$ HF(v=n-l) + DF(v=l) + ${\Delta}E$(a) DF(v=n) + HF(v=0) ${\to}$ DF(v=n-l) + HF(v=l) + ${\Delta}E$(b) In calculation the loosely-held, non-rigid dimer collision model and semiclassical method have been employed. The results show that the rate constants for the processes (a) are much greater than those for the processes (b). Also, it is found that the rate constants for the processes (a) increase with decreasing temperature and with increasing quantum number, while those for the processes (b) show the opposite tendencies. These findings are explained in terms of the sign and magnitude of the energy mismatch, ${\Delta}E$.

• Journal of the Korean Chemical Society
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• v.31 no.4
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• pp.334-343
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• 1987

The Chemical reactions between $NiL_m{^{2+}}\{$Ni(rac-1[14]7-diene)^{2+},\;Ni(meso-1[14]7-diene)^{2+},\;Ni(1[14]4-diene)^{2+},\;{\alpha}-Ni(rac-[14]-decane)^{2+},\;{\beta}-Ni(rac-[14]-decane)^{2+},\;and\;Ni(meso-[14]-decane)^{2+}$}\and\ CN^-$ ion were studied by the spectrophotometric method. The equilibrium constants (K_1$) for the 1:1 complex ion, $[NiL_m(CN)]^+\;with\;NiL_m{^{2+}}\;and\;CN^-$ ion were determined in the range of 3 to $25^{\circ}C$. The $K_1\;for\;Ni(rac-1[14]7-diene)^{2+},\;Ni(meso-1[14]7-diene)^{2+},\;Ni(1[14]4-diene)^{2+},\;{\alpha}-Ni(rac-[14]-decane)^{2+},\;{beta}-Ni(rac-[14]-decane)^{2+},\;and\;Ni(meso-[14]-decane)^{2+}\;at\;15^{\circ}C$ was 4.7, 5.3, 6.2, 7.5, 9.4, and 9.8, respectively. The values of $K_1$ decreased with increasing temperature. From the temperature effect on equilibrium constant ($K_1$), thermodynamic parameters $({\Delta}H^{\circ},\;{\Delta}S^{\circ},\;{\Delta}G^{\circ})$ for reaction were evaluated and the reaction of $NiL_m{^{2+}}\;and\;CN^-$ ion was exothermic. $NiL_m{^{2+}\;reacts\;with\;CN^-$ ion to give $Ni(CN)_4{^{2-}}$ ion and macrocyclic ligand $(L_m)$. The kinetics of formation of the $Ni(CN)_4{^{2-}}$ ion of varying the $[CN^-],\;[HCN],\;and\;[OH^-]$ have been investigated at 3∼$25^{\circ}C\;and\;0.5M\;NaClO_4$. Maintaining a constant $[CN^-],\;k_{obs}/[CN^-]^2$ increases linearly with increasing [HCN]. In the presence of large quantities of $[OH^-],\;k_{obs}/[CN^-]^2$ also increases linearly with $[OH^-]$. From the temperature effect on kinetic constant (k_{obs})$, parameter of activation $({\Delta}H^{\neq},\;{\Delta}S^{\neq})$ of reaction of $NiL_m{^{2+}}\;with\;CN^-$ ion were determined. For the $Ni(rac-1[14]7-diene)^{2+},\;Ni(meso-1[14]7-diene)^{2+},\;{\alpha}-Ni(rac-[14]-decane)^{2+},\;{\beta}-Ni(rac-[14]-decane)^{2+},\;and\;Ni(meso-[14]-decane)^{2+}\;series\;{\Delta}H^{\neq}$ gradually decrease as the d-d transition energy, $ν(cm^{-1})$ decrease. And the reaction of the five $NiL_m{^{2+}}\;with\;CN^-$ ion take place by way of equal paths.

• Bulletin of the Korean Chemical Society
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• v.23 no.6
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• pp.851-856
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• 2002

The Reaction of S-methyl-S-cysteine(L-Smc) with racemic $s-cis-[Co(demba)Cl_2]-1$ (Hydmedba = $NN'-dimethylethylenediamine-NN'-di-\alpha-butyric$, acid) yields ${\Delta}$-s-cis-[Co(dmedba)(L-Smc)] 2 with N, O-chelation. Oxidation of sulfur of 2 with $H_2O_2$ in a 1 : 1 mole ratio gives ${\Delta}$-s-cis[Co(dmedba)(L-S(O)mc)] 3 having an uncoordinated sulfenate group. Oxidation of sulfur of L-Sm with $H_2O_2in$ a 1: 1 mole ratio produces S-methyl-L-cysteinesulfenate (L-S(O)me) 5. Direct reaction of 1 with 5 in basic medium gives an N.O-chelated ${\Delta}$s-cis[Co(dmedba)(L-S(O)mc)-N.O], which turmed out be same as obtained by oxidation of 2, while an N, S-chelated ${\Delta}$-s-cis-[Co(dmedba)(S-S(O)mc)-N,O] complex 4 is obtained in acidic medium from the reaction of 1 with 5. This is one of the rare $[$Co^{III}$(N_2O_2-type$ ligand)(amino acid)] type complex preparations, where the reaction conditions determine which mode of N, O and N, S caelation modes is favored.

• East Asian mathematical journal
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• v.6 no.2
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• pp.133-144
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• 1990

In 1982, N. Miller [5] showed a weighted $L^p$ boundedness theorem for pseudo differential operators with symbols $S^0_{1.0}$. In this paper, we shall prove the pointwise estimates, in terms of the Fefferman, Stein sharp function and Hardy Littlewood maximal function, for pseudo differential operators with reduced symbols and show a weighted $L^p$-boundedness for pseudo differential operators with symbol in $S^m_{\rho,\delta}$, 0{$\leq}{\delta}{\leq}{\rho}{\leq}1$, ${\delta}{\neq}1$, ${\rho}{\neq}0$ and $m=(n+1)(\rho-1)$.

• Ocean Science Journal
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• v.40 no.3
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• pp.167-176
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• 2005

A time-series sediment trap was deployed at 1,034 m water depth in the eastern Bransfield Strait for a complete year from December 25, 1998 to December 24, 1999. About 99% of total mass flux was trapped during an austral summer, showing distinct seasonal variation. Biogenic particles (biogenic opal, particulate organic carbon, and calcium carbonate) account for about two thirds of annual total mass flux $(49.2\;g\;m^{-2})$, among which biogenic opal flux is the most dominant (42% of the total flux). A positive relationship (except January) between biogenic opal and total organic carbon fluxes suggests that these two variables were coupled, due to the surface-water production (mainly diatoms). The relatively low $\delta^{13}C$ values of settling particles result from effects on C-fixation processes at low temperature and the high $CO_2$ availability to phytoplankton. The correspondingly low $\delta^{l5}N$ values are due to intense and steady input of nitrates into surface waters, reflecting an unlikely nitrate isotope fractionation by degree of surface-water production. The $\delta^{l5}N$ and $\delta^{l3}C$ values of sinking particles increased from the beginning to the end of a presumed phytoplankton bloom, except for anomalous $\delta^{l5}N$ values. Krill and the zooplankton fecal pellets, the most important carriers of sinking particles, may have contributed gradually to the increasing $\delta^{l3}C$ values towards the unproductive period through the biomodification of the $\delta^{l3}C$ values in the food web, respiring preferentially and selectively $^{12}C$ atoms. Correspondingly, the increasing $\delta^{l5}N$ values in the intermediate-water trap are likely associated with a switch in source from diatom aggregates to some remains of zooplankton, because organic matter dominated by diatom may be more liable and prone to remineralization, leading to greater isotopic alteration. In particular, the tendency for abnormally high $\delta^{l5}N$ values in February seems to be enigmatic. A specific species dominancy during the production may be suggested as a possible and speculative reason.

• Science of Emotion and Sensibility
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• v.9 no.1
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• pp.39-48
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• 2006

This study was carried out to investigate sound sensation of Korean traditional silk fabrics with similar sound pressure levels (SPL) and to identify secondary physical factors excluding SPL which determine sound sensation of the fabrics. Sounds of the silk fabrics tended to be perceived differently from one another as for some of sensation such as clearness ant roughness. They were felt more strongly in aspects of loudness, roughness, and highness than of softness, sharpness, clearness, and pleasantness. Subjective clearness, roughness, and highness were significantly correlated with some of sound parameters including roughness(z), ${\Delta}L,\;and\;{\Delta}f$. Especially, both of clearness and roughness which were varied among the fabrics were found as determined by ${\Delta}L$. This result means that ${\Delta}L$ as well as roughness(z) and ${\Delta}f$ could be utilized secondary to SPL in order to satisfy some of human sensibility for sound from traditional silk fabrics without variation of physical loudness.

• Proceedings of the Korean Society of Agricultural Engineers Conference
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• 2000.10a
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• pp.513-518
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• 2000

It has been acknowledged that fertilizer, natural soil nitrogen and animal waste, municipal waste have different mass ratio of nitrogen which is presented as a symbol of $\delta^{15}$N. and that the values of $\delta^{15}$N for fertilizer and natural soil nitrogen and animal waste are placed less than +5$\textperthousand$ and higher than +10$\textperthousand$, respectively. thus, Nitrogen pollution sources and contribution can be interpreted in watershed through $\delta^{15}$N analysis and then, analysis is performed with Kjeldhl-Dumas method. In this study, The values of $\delta^{15}$N are between +1.46$\textperthousand$ and +8.97$\textperthousand$, and the nitrate concentration is placed less than 3.31mg/L and higher than 0.19mg/L, respectively. Thus, this watershed is noncontamination area at the present time. But as a result of $\delta^{15}$N, contribution of natural soil nitrogen be discovered in this watershed, presently.

• Journal of the Chungcheong Mathematical Society
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• v.13 no.1
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• pp.109-118
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• 2000

In this paper, we introduce strict extensions on a ${\delta}$-frame, and show that if L is a regular strong ${\delta}$-frame, then $\mathcal{T}_XL$ is regular ${\delta}$-frame.

• Bulletin of the Korean Mathematical Society
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• v.33 no.1
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• pp.107-110
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• 1996

Usng the Pochhammer symbol $(\lambda)_n$ given by $$ (1.1) (\lambda)_n = {1, if n = 0 {\lambda(\lambda + 1) \cdots (\lambda + n - 1), if n \in N = {1, 2, 3, \ldots}, $$ we define a general double hypergeometric series by [3, pp.27] $$ (1.2) F_{q:s;\upsilon}^{p:r;u} [\alpha_1, \ldots, \alpha_p : \gamma_1, \ldots, \gamma_r; \lambda_1, \ldots, \lambda_u;_{x,y}][\beta_1, \ldots, \beta_q : \delta_1, \ldots, \delta_s; \mu_1, \ldots, \mu_v; ] = \sum_{l,m = 0}^{\infty} \frac {\prod_{j=1}^{q} (\beta_j)_{l+m} \prod_{j=1}^{s} (\delta_j)_l \prod_{j=1}^{v} (\mu_j)_m)}{\prod_{j=1}^{p} (\alpha_j)_{l+m} \prod_{j=1}^{r} (\gamma_j)_l \prod_{j=1}^{u} (\lambda_j)_m} \frac{l!}{x^l} \frac{m!}{y^m} $$ provided that the double series converges.

• Journal of the Korean Society for Nondestructive Testing
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• v.16 no.4
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• pp.215-224
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• 1997

A study has been made to investigate the acoustic emission(AE) behavior during the tensile and fracture tests of an Al-Li 8090 alloy, and to correlate it with the deformation mechanisms as a function of microstructure and plate orientation. Mechanical tests and AE measurements were conducted on the specimens with different microstructures (the ${\delta}'$ phase dominant microstructure and the $S'+{\delta}'$ microstructure) and with different orientations (L and ST). In the ${\delta}'$ structure, continuous emissions were produced in both the L and ST oriented specimens, while only the burst emissions were observed to occur in the $S'+{\delta}'$ structure. It was inferred from the above results that continuous type emissions were mainly attributed to the shearing of coherent ${\delta}'$ precipitates in the ${\delta}'$ structure, while the burst type emissions were produced due to the shearing or microcracking of incoherent S' phase in the $S'+{\delta}'$ structure. As to the effect of plate orientation, the ST oriented specimens showed more burst emissions than the LT oriented ones. A large number of burst emissions produced in the ST specimen were presumably due to the rapid crack propagation along the intergranular boundary located parallel to the crack propagation direction.